WO1995018299A1 - System and method for controlling noxious components in automotive emissions - Google Patents

System and method for controlling noxious components in automotive emissions Download PDF

Info

Publication number
WO1995018299A1
WO1995018299A1 PCT/GB1994/002715 GB9402715W WO9518299A1 WO 1995018299 A1 WO1995018299 A1 WO 1995018299A1 GB 9402715 W GB9402715 W GB 9402715W WO 9518299 A1 WO9518299 A1 WO 9518299A1
Authority
WO
WIPO (PCT)
Prior art keywords
exhaust gas
conditioned
sensor
stream
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB1994/002715
Other languages
French (fr)
Inventor
Raymond Lawrence Willey
Robert Walter Mccabe
Jeffrey Scott Hepburn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ford Motor Company of Canada Ltd
Ford Werke GmbH
Ford France SA
Ford Motor Company Ltd
Ford Motor Co
Original Assignee
Ford Motor Company of Canada Ltd
Ford Werke GmbH
Ford France SA
Ford Motor Company Ltd
Ford Motor Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ford Motor Company of Canada Ltd, Ford Werke GmbH, Ford France SA, Ford Motor Company Ltd, Ford Motor Co filed Critical Ford Motor Company of Canada Ltd
Priority to EP95903412A priority Critical patent/EP0737270B1/en
Priority to DE69417065T priority patent/DE69417065T2/en
Publication of WO1995018299A1 publication Critical patent/WO1995018299A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02D—CONTROLLING COMBUSTION ENGINES
    • F02D41/00—Electrical control of supply of combustible mixture or its constituents
    • F02D41/0025—Controlling engines characterised by use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures
    • F02D41/0027—Controlling engines characterised by use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures the fuel being gaseous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9495—Controlling the catalytic process
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N13/00—Exhaust or silencing apparatus characterised by constructional features
    • F01N13/009—Exhaust or silencing apparatus characterised by constructional features having two or more separate purifying devices arranged in series
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N13/00—Exhaust or silencing apparatus characterised by constructional features
    • F01N13/011—Exhaust or silencing apparatus characterised by constructional features having two or more purifying devices arranged in parallel
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02D—CONTROLLING COMBUSTION ENGINES
    • F02D19/00—Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures
    • F02D19/02—Controlling engines characterised by their use of non-liquid fuels, pluralities of fuels, or non-fuel substances added to the combustible mixtures peculiar to engines working with gaseous fuels
    • F02D19/021—Control of components of the fuel supply system
    • F02D19/023—Control of components of the fuel supply system to adjust the fuel mass or volume flow
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M21/00—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form
    • F02M21/02—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels
    • F02M21/0203—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels characterised by the type of gaseous fuel
    • F02M21/0215—Mixtures of gaseous fuels; Natural gas; Biogas; Mine gas; Landfill gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Toxicology (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Output Control And Ontrol Of Special Type Engine (AREA)

Abstract

The invention relates to an improved emission control system. The system has particular applicability for use in an internal combustion engine (10) utilising alternative fuels such as natural gas. More particularly, the invention provides an apparatus and method wherein hydrogen is removed by a conditioning catalyst (16) from the exhaust gas stream (21) to produce a conditioned exhaust gas (22). An exhaust gas oxygen (EGO) sensor (18) is in communication with the conditioned exhaust gas (22) and generates a signal in response to the sensed oxygen concentration of the conditioned exhaust gas (22). The A/F mixture entering engine (10) is adjusted by closed loop control means (14) in response to the signal generated by EGO sensor (18). The removal of hydrogen from the exhaust gas stream (21) eliminates lean shifts and allows oxygen sensor (18) and closed loop control means (14) to more accurately control the A/F ratio. As a result of improved control over the A/F mixture entering engine (10), main three-way catalyst (20) optimally converts noxious components present in the conditioned exhaust gas (22) to produce a purified exhaust stream (23).
PCT/GB1994/002715 1993-12-27 1994-12-12 System and method for controlling noxious components in automotive emissions Ceased WO1995018299A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP95903412A EP0737270B1 (en) 1993-12-27 1994-12-12 System for controlling noxious components in automotive emissions
DE69417065T DE69417065T2 (en) 1993-12-27 1994-12-12 DEVICE FOR REGULATING POLLUTANT EMISSIONS IN THE EXHAUST GAS OF THE COMBUSTION ENGINE OF A MOTOR VEHICLE

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US172,997 1993-12-27
US08/172,997 US5433071A (en) 1993-12-27 1993-12-27 Apparatus and method for controlling noxious components in automotive emissions using a conditioning catalyst for removing hydrogen

Publications (1)

Publication Number Publication Date
WO1995018299A1 true WO1995018299A1 (en) 1995-07-06

Family

ID=22630070

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1994/002715 Ceased WO1995018299A1 (en) 1993-12-27 1994-12-12 System and method for controlling noxious components in automotive emissions

Country Status (5)

Country Link
US (1) US5433071A (en)
EP (1) EP0737270B1 (en)
DE (1) DE69417065T2 (en)
ES (1) ES2129191T3 (en)
WO (1) WO1995018299A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1052010A1 (en) * 1999-05-11 2000-11-15 Ford Global Technologies, Inc. Emission control system for internal combustion engine
CN100360782C (en) * 2002-08-01 2008-01-09 福特全球科技公司 Method and system for detecting hydrogen-fuel IC. engine air/fuel ratio

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5783160A (en) * 1995-01-27 1998-07-21 Toyota Jidosha Kabushiki Kaisha Method for purifying combustion exhaust gas
DE19645279A1 (en) * 1995-11-11 1997-05-15 Volkswagen Ag Exhaust gas cleaning for IC engine
US5998210A (en) * 1997-10-01 1999-12-07 Ford Global Technologies, Inc. Method and apparatus for aging a catalyst
GB9722950D0 (en) * 1997-10-30 1998-01-07 Lotus Car A method of monitoring efficiency of a catalytic converter and a control systemsuitable for use in the method
US6052989A (en) * 1998-01-23 2000-04-25 Ford Global Technologies, Inc. Emission control system for internal combustion engines
JP3799824B2 (en) * 1998-06-26 2006-07-19 日産自動車株式会社 Exhaust gas purification device for internal combustion engine
US6365108B1 (en) * 1999-10-12 2002-04-02 Caterpillar Inc. Siloxane filter for O2 sensor for bio-gas engine
DE10239258A1 (en) * 2002-08-22 2004-03-04 Volkswagen Ag Internal combustion engine and method for operating an internal combustion engine with a fuel control device
US6948475B1 (en) 2002-11-12 2005-09-27 Clean Air Power, Inc. Optimized combustion control of an internal combustion engine equipped with exhaust gas recirculation
US6774080B2 (en) 2002-11-25 2004-08-10 Delphi Technologies, Inc. Gas treatment device comprising SMSI material and methods for making and using the same
EP1518597A3 (en) * 2003-09-26 2005-11-09 DAS - Dünnschicht Anlagen Systeme GmbH Modular system for the treatment of process gases containing impurities
DE10360355A1 (en) * 2003-09-26 2005-04-28 Das Duennschicht Anlagen Sys Modular system to detoxify gases arising from thin-film manufacturing process has electronic control unit
US20080098725A1 (en) * 2006-10-31 2008-05-01 Caterpillar Inc. Exhaust system having mid-reducer NOx sensor
US20130160432A1 (en) * 2011-09-28 2013-06-27 International Engine Intellectual Property Company Llc Limiting nox emissions
EP2788215B1 (en) 2011-12-07 2020-01-15 Agility Fuel Systems LLC Systems and methods for monitoring and controlling fuel systems
US11035315B2 (en) 2019-09-27 2021-06-15 Ford Global Technologies, Llc Modeling to compensate for HEGO sensor drift
US11085386B1 (en) * 2020-03-17 2021-08-10 Denso International America, Inc. UHEGO control to mitigate threshold catalyst losses
CN114412624A (en) * 2022-01-04 2022-04-29 浙江吉利控股集团有限公司 Exhaust system, range extender and automobile
FR3145014A1 (en) * 2023-01-17 2024-07-19 Renault S.A.S Blow-by gas heater for a powertrain incorporating a hydrogen-powered internal combustion engine and associated powertrain
FR3145015B1 (en) * 2023-01-17 2024-11-29 Renault Sas Oil decanter for powertrain incorporating a hydrogen-powered internal combustion engine and associated powertrain

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3872213A (en) * 1971-08-30 1975-03-18 Kobe Steel Ltd Method for removing harmful components from exhaust gases
US4134262A (en) * 1974-10-30 1979-01-16 Nissan Motor Company, Limited Exhaust gas catalytic converter system
US5083427A (en) * 1990-02-12 1992-01-28 Ford Motor Company Apparatus and method to reduce automotive emissions using filter catalyst interactive with uego
US5146743A (en) * 1988-04-25 1992-09-15 Emitec Gesellschaft Fur Emissionstechnologie Mbh Process for accelerating the response of an exhaust gas catalyst, and apparatus and electrically heatable carrier bodies for performing the method

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54163225A (en) * 1978-06-16 1979-12-25 Nissan Motor Device for controlling number of cylinders to be supplied with fuel
JPS58573B2 (en) * 1978-06-16 1983-01-07 日産自動車株式会社 Fuel supply cylinder number control device
JPS5535181A (en) * 1978-09-05 1980-03-12 Nippon Denso Co Ltd Air fuel ratio control device
US5052177A (en) * 1989-03-03 1991-10-01 Toyota Jidosha Kabushiki Kaisha Air-fuel ratio feedback control system having single air-fuel ratio sensor downstream of or within three-way catalyst converter
JPH0417747A (en) * 1990-05-07 1992-01-22 Japan Electron Control Syst Co Ltd Air-fuel ratio control device for internal combustion engines
JP2861377B2 (en) * 1990-11-20 1999-02-24 三菱自動車工業株式会社 Air-fuel ratio feedback control method for multi-fuel internal combustion engine
US5230322A (en) * 1992-11-06 1993-07-27 Ford Motor Company Method and apparatus for compensating for errors associated with a fuel type sensor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3872213A (en) * 1971-08-30 1975-03-18 Kobe Steel Ltd Method for removing harmful components from exhaust gases
US4134262A (en) * 1974-10-30 1979-01-16 Nissan Motor Company, Limited Exhaust gas catalytic converter system
US5146743A (en) * 1988-04-25 1992-09-15 Emitec Gesellschaft Fur Emissionstechnologie Mbh Process for accelerating the response of an exhaust gas catalyst, and apparatus and electrically heatable carrier bodies for performing the method
US5083427A (en) * 1990-02-12 1992-01-28 Ford Motor Company Apparatus and method to reduce automotive emissions using filter catalyst interactive with uego

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1052010A1 (en) * 1999-05-11 2000-11-15 Ford Global Technologies, Inc. Emission control system for internal combustion engine
CN100360782C (en) * 2002-08-01 2008-01-09 福特全球科技公司 Method and system for detecting hydrogen-fuel IC. engine air/fuel ratio

Also Published As

Publication number Publication date
EP0737270A1 (en) 1996-10-16
DE69417065D1 (en) 1999-04-15
EP0737270B1 (en) 1999-03-10
US5433071A (en) 1995-07-18
ES2129191T3 (en) 1999-06-01
DE69417065T2 (en) 1999-07-08

Similar Documents

Publication Publication Date Title
EP0737270A1 (en) System and method for controlling noxious components in automotive emissions
CA2033400A1 (en) Apparatus and method to reduce automotive emissions using filter catalyst interactive with uego
EP0814248A3 (en) Method of controlling an engine exhaust gas system and method of detecting deterioration of catalyst/adsorbing means
WO1999018333A8 (en) Method and apparatus for using free radicals to reduce pollutants in the exhaust gases from the combustion of a fuel
EP0799988A3 (en) Air-fuel ratio control system for internal combustion engines
EP0799985A3 (en) Air-fuel ratio control system for internal combustion engines
EP0898067A3 (en) Exhaust gas purifying system of internal combustion engine
ATE387571T1 (en) SYSTEM AND METHOD FOR IMPROVED EMISSION CONTROL OF INTERNAL COMBUSTION ENGINES
EP1039104A3 (en) Exhaust gas purification apparatus of internal combustion engine and catalyst for purifying exhaust gas of internal combustion engine
EP1387069A3 (en) Exhaust purification apparatus and method for internal combustion engine
EP0814249A3 (en) Method for controlling engine exhaust gas system
EP0402953A3 (en) Apparatus for detecting abnormality of oxygen sensor and controlling air/fuel ratio
DE69911242D1 (en) SELECTIVE CATALYTIC REDUCTION SYSTEM AND METHOD
EP0802315A3 (en) An exhaust gas purification device for an internal combustion engine
EP0915244A3 (en) Exhaust gas purifying apparatus of internal combustion engine
AU2003234560A1 (en) Reducing oxides of nitrogen using hydrogen generated from engine fuel and exhaust
JP2951831B2 (en) Exhaust gas purification device for internal combustion engine
EP1064985A3 (en) Exhaust gas purifying system
CA2120389A1 (en) Engine Catalyst Aging System and Method for Aging Catalyst
EP1188908A3 (en) Exhaust gas purifying system
SE9800473D0 (en) Procedure for exhaust gas purification and gas burner
EP0924399A3 (en) Internal combustion engine having lean NOx catalyst
MX9802171A (en) Method for catalytically processing gases with a high oxygen content to reduce nitrogen oxide emissions.
ATE237073T1 (en) AIR INJECTION STRATEGIES FOR EFFECTIVE COMBUSTION OF HYDROCARBONS ELIMINATED THROUGH A HYDROCARBON FILTER
EP0896143A3 (en) Apparatus and method for estimating concentration of vaporized fuel purged into intake air passage of internal combustion engine

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): BR CA

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 1995903412

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1995903412

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: CA

WWG Wipo information: grant in national office

Ref document number: 1995903412

Country of ref document: EP