WO1995019639A1

WO1995019639A1 - Metal halide lamp

Info

Publication number: WO1995019639A1
Application number: PCT/EP1994/004233
Authority: WO
Inventors: Andreas Hohlfeld; Dirk Hoffmann; Akihiro Kanda; Katsuya Otani
Original assignee: Patent Treuhand Gesellschaft fuer Elektrische Gluehlampen mbH; Osram Melco Ltd
Current assignee: Osram GmbH; Osram Melco Ltd
Priority date: 1994-01-18
Filing date: 1994-12-20
Publication date: 1995-07-20
Anticipated expiration: 1996-07-18
Also published as: JPH09507606A; KR100375613B1; EP0740848A1; TW323379B; DE69419622T2; US5854535A; DE69419622D1; KR970700932A; EP0740848B1

Abstract

The invention relates to a metal halide lamp having an outer envelope (3, 23) of quartz glass which surrounds a discharge vessel (2, 22) of quartz glass. The discharge vessel (2, 22) gas-tightly retains an ionizable fill comprising sodium. In order to avoid loss of sodium from the fill in the discharge vessel (2, 22), the quartz glass of the outer envelope (3, 23) is doped with materials absorbing UV radiation. These doping materials are preferably cerium aluminate and titanium oxide.

Description

Metal Halide Lamp

The invention relates to a metal halide lamp in accordance with the preamble of claim 1.

Metal halide lamps have long life and light of high quality and are therefore suitable for indoor illumination, for example, of entrance halls and salesrooms and for residential lighting. They have a warm white to neutral white color, that is, a color temperature of about 2500 to 5000 Kelvin which is obtained by a sodium additive in the ionizable fill. A technical problem observed with all sodium containing high- pressure discharge lamps is the occurrence of loss of sodium from the ionizable fill in the discharge vessel, caused by diffusion of the sodium ions through the wall of the discharge vessel. This problem is particularly acute with metal halide lamps of low power rating whose ionizable fill has a low sodium content, and with metal halide lamps operated at unsaturated sodium vapor pressure. The loss of sodium from the fill in the discharge vessel causes a change in the color temperature, increases the ignition voltage and, finally, leads to premature failure of the lamps.

The European Patent Application EP 0 464 083 discloses a lamp as described in the preamble of claim 1. To avoid loss of sodium, the lamp has an outer envelope of low thermal loading which consists of highly pure quartz glass of low electrical conductivity. A disadvantage of this solution is that a comparatively expensive raw material is required for the outer envelope in order to avoid loss of sodium. Also, the desired low thermal loading of the outer envelope requires relatively large spacing of the outer envelope from the discharge vessel. This increases the outer dimensions of the lamp and may lead to problems when fitting the lamps into the fixtures intended therefor.

The US Patent 5,111,104 describes a metal halide lamp having a color temperature of about 3600 Kelvin and a luminous efficacy of about 90 lm/YV. Its discharge vessel is surrounded by an evacuated outer envelope to avoid loss of sodium from the fill in the discharge vessel. The outer envelope, in turn, is surrounded by a gas-tighdy closed second outer envelope filled with inert gas. The second outer envelope, however, increases the manufacture costs of the lamp. It is the object of the invention to provide a metal halide lamp in accordance with the preamble of claim 1 which has a longer life and sufficiendy constant operating parameters over the life of the lamp.

This object is attained, in accordance with the invention, by the characterizing features of claim 1. Advantageous embodiments of the invention are described in the subclaims.

The life of the sodium containing metal halide lamps in accordance with the preamble of claim 1 is limited essentially by the sodium loss from the ionizable fill in the discharge vessel. In order to reduce this sodium loss, the metal halide lamps of the invention are provided with an outer envelope of quartz glass comprising a UV radiation absorbing doping material. The positive influence of the UV radiation absorbing doping material in the material of the outer envelope can be seen from the curves of Figs. 3 and 4.

Fig. 3 shows the lamp operating voltage (in volts) plotted above the time of operation of the lamp (in hours). Curve 1 shows the characteristic of the lamp operating voltage with increasing time of operation for a prior art 150 W metal halide lamp with an outer envelope without UV radiation absorbing doping material. Curve 2 shows the change of the lamp operating voltage as a function of the time of operation for a metal halide lamp of the invention in accordance with the second embodiment in which the glass of the outer envelope comprises a UV radiation absorbing doping material. Curve 1 shows a steeper rise of the lamp operating voltage as the time of operation increases than curve 2. The operating voltage of a prior art metal halide lamp in accordance with curve 1 has risen fro an initial 80 V to 120 V after 4000 hours of operation, whereas the operating voltage of the metal halide lamp of the invention in the same period has risen to only 110 V. The rise in lamp operating voltage with increasing time of operation or increasing age of the lamp is taken to be the result of sodium loss from the fill in the discharge vessel caused by migration of sodium ions. This assumption is supported by the curves shown in Fig. 4 which illustrate the change in color temperature with increasing time of operation of the lamps. After about 4000 hours of operation of the prior art metal halide lamps (curve 1), the color temperature shifted from an initial 4500 Kelvin to about 5500 Kelvin, that is, the long- wave red and yellow proportions of the lamp emmission spectrum are weakened, compared to the blue proportion of the emission spectrum, due to the sodium loss from the fill in the discharge vessel. With the metal halide lamp of the invention (curve 2), however, the color temperature remains nearly constant over the same period.

These measurements were carried out with several test lamps in which the glass of the outer envelope was undoped or contained a UV radiation absorbing doping material.

Fig. 5 shows a comparison of the mortality behavior of the metal halide lamps of the invention and of prior art test lamps. From this figure (curve 1) it can be seen that, with prior art metal halide lamps after about 4000 hours of operation 50% of the tested lamps were no longer operable, that is, the life time of these metal halide lamps was about 4000 hours of operation. In contrast, the metal halide lamps of the invention did not exhibit a single failure of a lamp even after 4500 hours of operation. Based on the lamp operating voltage characteristic shown in Fig. 3, lamp failures of metal halide lamps of the invention are expected only after about 6000 hours of operation, signifying an increase in lamp life by at least 50%.

The long lamp life of the metal halide lamps of the invention may presumably be explained by a reduced photoelectron emission from the current supply wires extending within the outer envelope. The UV radiation emitted from the discharge vessel is partially reflected from the wall of the outer envelope and releases photoelectrons when impinging on the current supply wires extending within the outer envelope. A further portion of the UV radiation penetrates into the wall of the outer envelope, is partially reflected back from the outer surface of the outer envelope into the interior of the lamp, and also contributes to the photo-ionisation at the current supply wires. This last mentioned portion of the UV radiation is substantially reduced in the metal halide lamps of the invention by the UV radiation absorbing material used with the glass of the outer envelope so that the photo- ionization at the current supply wires which promotes the migration of sodium is reduced.

The doping materials used preferably are compounds of cerium and/or titanium, particularly cerium aluminate and/or titanium oxide which influence only slightly the transmission of the outer envelope in the spectral region of the visible light. Only quartz glass is suitable as a material for the outer envelope for thermally highly loaded lamps where the outer envelope surrounds the discharge vessel relatively closely. The doping materials have a weight proportion in the quartz glass of the outer envelope of at most 2%, in order to avoid a significant reduction of the softening point of the doped quartz glass. The outer envelope is preferably evacuated to ensure satisfactory thermal isolation of the discharge vessel.

The invention may be used primarily with metal halide lamps having a double-ended pinch-sealed discharge vessel which is surrounded by a double-ended outer envelope and with metal halide lamps having a single-ended pinch-sealed discharge vessel located within a single-ended outer envelope. These two lamp types do not comprise any metallic current supply elements passing alongside the discharge space at which a considerable amount of photo-ionization can occur, caused by the UV radiation generated by the discharge. With metal halide lamps having a metallic current supply element, that is, with metal halide lamps having a double-ended pinch-sealed discharge vessel inside a single-ended outer envelope, the invention also brings about an extension of lamp life, if the portion of the metallic current supply element passing alongside the discharge space is provided with an isolation means which prevents the photoelectrons from being generated which would promote the migration of sodium ions caused by the UV radiation impinging directiy on the metallic current supply element.

The invention will now be more closely described by way of several preferred embodiments. The figures show:

Fig. 1 a schematic illustration of a metal halide lamp of the invention in accordance with embodiments one , two and four;

Fig. 2 a schematic illustration of a metal halide lamp of the invention in accordance with a third embodiment;

Fig. 3 the characteristic of the operation voltage of the lamp as a function of the time of operation of a metal halide lamp without UV radiation absorbing doping material in the glass of the outer envelope (curve 1) compared to a metal halide lamp of the invention (curve 2);

Fig. 4 the change of color temperature as a function of the time of operation of a metal halide lamp without UV radiation absorbing doping material in the glass of the outer envelope (curve 1) compared to a metal halide lamp of the invention (curve 2); Fig. 5 the mortality curve for metal halide lamps without UV radiation absorbing doping material in the glass of the outer envelope (curve 1) compared to a metal halide lamp of the invention (curve 2);

Fig. 1 shows a metal halide lamp of the invention in accordance with the first two embodiments. The lamp 1 has a double-ended pinch-sealed gas-tightly closed discharge vessel 2 of quartz glass which is surrounded by a double-ended evacuated outer envelope 3 of quartz glass. The quartz glass of the outer envelope is doped with cerium and titanium added to the quartz melt in the form of 0.51% by weight of cerium aluminate and 0.04% by weight of titanium oxide. The wall thickness of the outer envelope is approximately 1 mm. Two tungsten electrodes 4, 5 between which a gas discharge forms in operation of the lamp, are located in the interior of the discharge vessel 2. The electrodes 4, 5 are gas-tightly melt-sealed in the pinch-sealed ends of the discharge vessel 2 and are electrically connected via molybdenum foils 6, 7 to current supply wires 8, 9. The current supply wires 8, 9 are electrically connected via the molybdenum foil seals 10, 11 of the outer envelope 3 to the electrical terminals 12, 13 of the lamp 1. A getter 14 secured to one pinch-sealed end of the discharge vessel 2 is located in the interior of the outer envelope 3. The ends of the discharge vessel 2 each have a heat reflecting coating 15, 16.

The lamp of the first embodiment (fig. 1) is a 150 W metal halide lamp. Its discharge vessel has a volume of approximately 2.5 cm The spacing between the electrodes is about 18 mm. The spacing of the outer envelope from the discharge vessel is at most 5 mm. The ionizable fill retained in the discharge vessel consists essentially of mercury, noble gas and metal halides. The total amount of metal halides is about 5.4 g comprising Nal (32.2% by weight), Til (9.0% by weight) and Dyl3, Tml3 and H0I3 (each 19.6% by weight) leading to a sodium iodide amount of approximately 1.73 mg. The pure sodium content of the ionizable fill is approximately 0.10 mg cm^ discharge volume. This lamp has a neutral white light color, that is, a color temperature of about 4400 Kelvin.

The lamp of the second embodiment (fig. 1) is a 70 W metal halide lamp. Its discharge vessel has a volume of approximately 0.7 CΠ The spacing between the electrodes is about 7 mm. The ionizable fill retained in the discharge vessel consists essentially of mercury, noble gas and metal halides. The total amount of metal halides is about 2 mg co prising Nal (75.0% by weight), Til (5.0% by weight) and SCI3 (20.0% by weight). The fill comprises approximately 1.50 mg sodium iodide. The pure sodium content of the ionizable fill is approximately 0.33 mg/cm^ discharge volume. This lamp has a warm white light color, that is, a color temperature of about 3000 Kelvin.

Fig. 2 shows a 70 W metal halide lamp of the invention in accordance with a third embodiment. The lamp 21 comprises a single-ended pinch-sealed discharge vessel 22 which is surrounded by a single-ended pinch-sealed outer envelope 23. The outer envelope is doped with cerium and titanium added to the quartz melt in the form of 0.51% by weight of cerium aluminate and 0.04% by weight of titanium oxide. The wall thickness of the outer envelope is approximately 1 mm. Two tungsten electrodes 24, 25 between which a gas discharge is formed in operation of the lamp are located in the interior of the discharge vessel 22. The electrodes 24, 25 are gas-tightly melt- sealed in the pinch-sealed end of the discharge vessel 22 and are electrically connected via molybdenum foils 26, 27 to the current supply wires 28, 29. The current supply wires 28, 29, in turn, are electrically connected via molybdenum foils 30, 31 in the pinched-sealed end of the outer envelope 23 to the electrical terminals 32, 33 of the lamp 21. A getter 34 secured to the pinch-sealed end of the discharge vessel 22 is located in the interior of the outer envelope 23. The discharge vessel has volume of approximately 0.3 cm^. The spacing between the electrodes is about 4.5 mm. The ionizable fill retained in the discharge vessel consists essentially of mercury, noble gas and the metal halides Nal, SnFj and Til. The total metal halide amount is approximately 0.95 mg comprising Nal (30% by weight), Snl2 (63% by weight) and Til (7% by weight). The fill comprises approximately 0.285 mg sodium iodide leading to a pure sodium content of about 0.15 mg cm^ discharge volume. This lamp has a warm white light color.

The lamp of the fourth embodiment (fig. 1) is a 70 W metal halide lamp. Its discharge vessel has a volume of approximately 0.7 cmA The spacing between the electrodes is about 7 mm. The ionizable fill retained in the discharge vessel consists essentially of mercury, noble gas and metal halides. The total amount of the metal halides in the ionizable fill is about 4 mg. The metal halides comprise Nal (75% by weight), SCI3 (20.0% by weight) and Til (5.0% by weight) leading to a sodium iodide amount in the fill of approximately 3.0 mg. The pure sodium content of the ionizable fill is approximately 0.66 mg/cm^ discharge volume. This lamp has a warm white light color.

Claims

1. A metal halide lamp having a discharge vessel (2, 22) made of quartz glass; an ionizable fill gas-tightly retained in the discharge vessel (2, 22), said ionizable fill including sodium or a sodium compound; and a light transmissive outer envelope (3, 23) surrounding the discharge vessel (2, 22), characterized in that the outer envelope (3, 23) consists of UV radiation absorbing doped quartz glass to reduce loss of sodium from the ionizable fill.

2. The metal halide lamp of claim 1, characterized in that the lamp has a double- ended pinch-sealed discharge vessel (2) and a double-ended outer envelope (3).

3. The metal halide lamp of claim 1, characterized in that the lamp has a single- ended pinch-sealed discharge vessel (22) and a single-ended outer envelope (23).

4. The metal halide lamp of claim 1, characterized in that the outer envelope (3,

23) consists essentially of quartz glass doped with cerium or a cerium compound.

5. The metal halide lamp of claim 1, characterized in that the outer envelope (3, 23) consists essentially of quartz glass doped with titanium or a titanium compound.

6. The metal halide lamp of claim 5, characterized in that the quartz glass is doped with cerium aluminate and/or titanium oxide.

7. The metal halide lamp of claim 6, characterized in that the weight proportion of the doping material with respect to the quartz glass of the outer envelope is equal to or smaller than 2%.

8. The metal halide lamp of claim 1, characterized in that the outer envelope (3,

23) is evacuated.

9. The metal halide lamp of claim 1, characterized in mat the sodium content in the ionizable fill is at most 0.7 mg/cm^ discharge volume.

10. The metal halide lamp of claim 1, characterized in that the outer envelope (3, 23) surrounds the discharge vessel closely, without touching it.

11. The metal halide lamp of claim 10, characterized in that the spacing of the outer envelope (3, 23) from the discharge vessel (2, 22) is at most 5 mm.