WO1995030737A3 - Personal cleansing soap-synthetic bar compositions with low levels of nonionic, polyethylene/polypropylene glycol polymers for improved mildness - Google Patents

Personal cleansing soap-synthetic bar compositions with low levels of nonionic, polyethylene/polypropylene glycol polymers for improved mildness Download PDF

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Publication number
WO1995030737A3
WO1995030737A3 PCT/US1995/005486 US9505486W WO9530737A3 WO 1995030737 A3 WO1995030737 A3 WO 1995030737A3 US 9505486 W US9505486 W US 9505486W WO 9530737 A3 WO9530737 A3 WO 9530737A3
Authority
WO
WIPO (PCT)
Prior art keywords
nonionic
personal cleansing
bar compositions
c22alkyl
polyethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1995/005486
Other languages
French (fr)
Other versions
WO1995030737A2 (en
Inventor
Sherri Vesalga Cox
James Charles Dunbar
Marilyn Ann Richard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to DE69531303T priority Critical patent/DE69531303T2/en
Priority to CA002189565A priority patent/CA2189565C/en
Priority to BR9507685A priority patent/BR9507685A/en
Priority to JP7529061A priority patent/JP2974782B2/en
Priority to MX9605449A priority patent/MX9605449A/en
Priority to EP95918929A priority patent/EP0766731B1/en
Priority to AT95918929T priority patent/ATE245186T1/en
Publication of WO1995030737A2 publication Critical patent/WO1995030737A2/en
Publication of WO1995030737A3 publication Critical patent/WO1995030737A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5422—Polymers characterized by specific structures/properties characterized by the charge nonionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/126—Acylisethionates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/16—Sulfonic acids or sulfuric acid esters; Salts thereof derived from divalent or polyvalent alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/345—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/92—Sulfobetaines ; Sulfitobetaines

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Animal Behavior & Ethology (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

The present invention relates to personal cleansing bar compositions comprising: A. from about 1 part to about 70 parts bY bar weight of a mild synthetic surfactant selected from the group consisting of sodium cocoyl isethionate, sodium topped cocoyl isethionate, essentially saturated C15-C22alkyl sulfate, essentially saturated C15-C22alkyl sarcosinate, essentially saturated C15-C22alkyl glyceryl ether sulfonate, and mixtures thereof; B. from about 0.01 part to about 1 part by bar weight of a nonionic polymer; wherein the nonionic polymer is selected from the group consisting of (I) H(0[CH2]x)nOH, (II) (see formula above) and (III) mixtures thereof; wherein x is 2; and n has an average value of from about 2,000 to about 115,000 and wherein the pH is from about 4 to about 9. These bar compositions provide enhanced clinical mildness to the skin while maintaining good lathering, increased lather lubricity and lather creaminess.
PCT/US1995/005486 1994-05-10 1995-05-03 Personal cleansing soap-synthetic bar compositions with low levels of nonionic, polyethylene/polypropylene glycol polymers for improved mildness Ceased WO1995030737A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE69531303T DE69531303T2 (en) 1994-05-10 1995-05-03 SYNDET SOAP BAR FOR BODY CARE WITH A LOW CONTENT OF NON-IONIC POLYETHYLENE / POLYPROPYLENE GLYCOL POLYMERS FOR IMPROVED TENDERNESS
CA002189565A CA2189565C (en) 1994-05-10 1995-05-03 Personal cleansing soap-synthetic bar compositions with low levels of nonionic, polyethylene/polypropylene glycol polymers for improved mildness
BR9507685A BR9507685A (en) 1994-05-10 1995-05-03 Synthetic soap bar compositions for personal cleaning with low levels of non-ionic polyethylene / Poly (propylene glycol) polymers for improved smoothness
JP7529061A JP2974782B2 (en) 1994-05-10 1995-05-03 Bar cleaning-soap composition for personal use with low levels of nonionic polyethylene / polypropylene glycol polymer to improve irritation
MX9605449A MX9605449A (en) 1994-05-10 1995-05-03 Personal cleansing soap-synthetic bar compositions with low levels of nonionic, polyethylene/polypropylene glycol polymers for improved mildness.
EP95918929A EP0766731B1 (en) 1994-05-10 1995-05-03 Personal cleansing soap-synthetic bar compositions with low levels of nonionic, polyethylene/polypropylene glycol polymers for improved mildness
AT95918929T ATE245186T1 (en) 1994-05-10 1995-05-03 SYNDET SOAP BAR FOR PERSONAL CARE WITH LOW NON-IONIC POLYETHYLENE/POLYPROPYLENE GLYCOL POLYMERS FOR IMPROVED SOFTNESS

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US24019094A 1994-05-10 1994-05-10
US08/240,190 1994-05-10

Publications (2)

Publication Number Publication Date
WO1995030737A2 WO1995030737A2 (en) 1995-11-16
WO1995030737A3 true WO1995030737A3 (en) 1995-12-21

Family

ID=22905508

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1995/005486 Ceased WO1995030737A2 (en) 1994-05-10 1995-05-03 Personal cleansing soap-synthetic bar compositions with low levels of nonionic, polyethylene/polypropylene glycol polymers for improved mildness

Country Status (11)

Country Link
US (1) US5945389A (en)
EP (1) EP0766731B1 (en)
JP (1) JP2974782B2 (en)
CN (1) CN1120884C (en)
AT (1) ATE245186T1 (en)
BR (1) BR9507685A (en)
CA (1) CA2189565C (en)
DE (1) DE69531303T2 (en)
ES (1) ES2201107T3 (en)
MX (1) MX9605449A (en)
WO (1) WO1995030737A2 (en)

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DE19949002A1 (en) * 1999-10-11 2001-04-19 Anton Huebner Gmbh & Co Kg Syndet compositions and sticks with improved ecological accepability and avoidance of skin problems have at least part of their paraffin wax builder replaced by candellila wax
US6849585B1 (en) 2004-01-13 2005-02-01 Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. Bar with good user properties comprising acid-soap complex as structurant and low levels of synthetic
CN101142308B (en) * 2005-03-18 2012-10-10 3M创新有限公司 Solid cleaners for heated food preparation surfaces
CN101608150B (en) * 2009-07-14 2011-05-11 江南大学 Formula of foaming agent in neutral soap
ES2599504T3 (en) 2012-05-30 2017-02-02 Clariant International Ltd Use of N-methyl-N-acyl-glucamines as solubilizing agents
IN2014DN09937A (en) 2012-05-30 2015-08-14 Clariant Int Ltd
DE102012021647A1 (en) 2012-11-03 2014-05-08 Clariant International Ltd. Aqueous adjuvant compositions
MX395188B (en) 2013-11-25 2025-03-25 Unilever Ip Holdings B V SKIN-ENHANCING SOAP BAR FORMULATIONS THAT COMPRISE A NON-IONIC POLYMER STRUCTURING SYSTEM.
DE102014005771A1 (en) 2014-04-23 2015-10-29 Clariant International Ltd. Use of aqueous drift-reducing compositions
DE102015219651A1 (en) 2015-10-09 2017-04-13 Clariant International Ltd. Compositions containing sugar amine and fatty acid
DE102015219608B4 (en) 2015-10-09 2018-05-03 Clariant International Ltd Universal pigment dispersions based on N-alkylglucamines
JP2017137273A (en) * 2016-02-05 2017-08-10 株式会社ファンケル Powdery or granular skin cleansing agent
US9717674B1 (en) 2016-04-06 2017-08-01 The Procter & Gamble Company Skin cleansing compositions comprising biodegradable abrasive particles
DE102016207877A1 (en) 2016-05-09 2017-11-09 Clariant International Ltd Stabilizers for silicate paints
GB202113089D0 (en) * 2021-09-14 2021-10-27 Innospec Ltd Cleansing composition and method
WO2025210670A1 (en) * 2024-03-30 2025-10-09 Reliance Consumer Products Limited Personal cleansing composition comprising mild surfactant and soap

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EP0441652A1 (en) * 1990-02-09 1991-08-14 Unilever Plc Detergent composition
WO1991013958A1 (en) * 1990-03-05 1991-09-19 The Procter & Gamble Company Improved personal cleansing stamped synbar
WO1992016609A1 (en) * 1991-03-13 1992-10-01 The Procter & Gamble Company LOW pH MILD PERSONAL CLEANSING BAR

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CA2189565A1 (en) 1995-11-16
MX9605449A (en) 1997-12-31
JP2974782B2 (en) 1999-11-10
ES2201107T3 (en) 2004-03-16
DE69531303T2 (en) 2004-04-22
CN1150456A (en) 1997-05-21
EP0766731A2 (en) 1997-04-09
ATE245186T1 (en) 2003-08-15
CN1120884C (en) 2003-09-10
DE69531303D1 (en) 2003-08-21
US5945389A (en) 1999-08-31
EP0766731B1 (en) 2003-07-16
BR9507685A (en) 1997-11-18
WO1995030737A2 (en) 1995-11-16
CA2189565C (en) 2000-04-18
JPH10500155A (en) 1998-01-06

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