WO1995032637A1 - Chewing gum having improved texture and containing medium chain triglycerides - Google Patents
Chewing gum having improved texture and containing medium chain triglycerides Download PDFInfo
- Publication number
- WO1995032637A1 WO1995032637A1 PCT/US1995/006583 US9506583W WO9532637A1 WO 1995032637 A1 WO1995032637 A1 WO 1995032637A1 US 9506583 W US9506583 W US 9506583W WO 9532637 A1 WO9532637 A1 WO 9532637A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- base
- gum
- medium chain
- chain triglycerides
- gum base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/066—Chewing gum characterised by the composition containing organic or inorganic compounds characterised by the fat used
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/08—Chewing gum characterised by the composition containing organic or inorganic compounds of the chewing gum base
Definitions
- the present invention relates generally to chewing gum. More specifically, the present invention relates to improved formulations for bases and methods of making same.
- Chewing gum generally consists of a water insoluble gum base and a water soluble portion along with flavors.
- the insoluble gum base generally comprises elastomers, resins, fats and oils, softeners, and inorganic fillers.
- Elastomers can include synthetic elastomers including polyisobutylene, isobutylene- isoprene copoly ers, ⁇ tyrene-butadiene copolymers, polyvinyl acetate, polyisoprene, polyethylene, vinyl acetate - vinyl laurate copolymers, and combinations thereof.
- Natural elastomers that can be used include natural rubber.
- the gum base can include elastomer plasticizers. Such elastomer plasticizers can include natural rosin esters, as well as other elastomer plasticizers. Additionally, the gum base can include fillers/texturizers and softeners/emulsifiers. Softeners are added to chewing gum in order to optimize the chewability and mouth feel of the gum. Softeners/emulsifiers that are typically used include tallow, hydrogenated tallow, hydrogenated and partially hydrogenated vegetable oils, cocoa butter, glycerol monostearate, glycerol triacetate, lecithin, and combinations thereof.
- a typical chewing gum composition includes a water soluble portion and one or more flavoring agents. The water soluble portion can include bulk sweeteners, high intensity sweeteners, flavoring agents, softeners, emulsifiers, colors, acidulants, fillers, antioxidants, and other components that provide desirable attributes.
- the present invention provides improved chewing gum formulations and bases, as well as methods of producing chewing gum and bases.
- a base is provided that includes medium chain triglycerides.
- the medium chain triglycerides are used in the base as a softener and/or emulsifier or to replace some or a large portion of hydrogenated fats.
- the base can be used to create a chewing gum having improved texture and softness.
- the base formulations of the present invention may be conventional bases that include wax or are wax-free, tacky or non-tacky and/or bubble gum-type bases.
- the gum formulations can be low or high moisture formulations containing low or high amounts of moisture-containing syrup.
- Medium chain triglycerides can also be used in low sugar and non-sugar containing gum formulations made with sorbitol, mannitol, other polyols, and non-sugar carbohydrates.
- Non-sugar formulations can include low or high moisture sugar-free chewing gums.
- the medium chain triglycerides are used in the base as a softener and/or are combined with other base softeners for use in chewing gum base.
- Such other softeners include, but are not limited to, fats and oils, such as tallow, hydrogenated and partially hydrogenated vegetable oils, cocoa butter, mono- and di- glycerides, acetylated monoglycerides, softeners such as glycerol triacetate, waxes such as paraffin and icrocrystalline waxes, and emulsifiers such as lecithin.
- the medium chain triglycerides are used to replace at least a substantial portion of hydrogenated fats in the base.
- the medium chain triglyceride softener when used according to the present invention, affords the chewing gum an improved texture, improved shelf life, and improved flavor quality. Even though medium chain triglycerides are similar to other fats and oils in some respects, medium chain triglycerides are easily digested and provide other health attributes that create a resultant chewing gum product that has a high consumer- acceptability.
- the present invention provides a gum base comprising an elastomer and a sufficient amount of medium chain triglycerides to create a gum base that is softer than a gum base that does not include medium chain triglycerides.
- the base comprises at least 0.02% by weight medium chain triglycerides.
- the base is wax-free.
- the base is non-tacky. In an embodiment, the base is a bubble gum-type base.
- the base includes at least one resin.
- the base includes at least one softener chosen from the group consisting of: tallow; hydrogenated tallow; hydrogenated and partially hydrogenated vegetable oils; cocoa butter; glycerol monostearate; glycerol triacetate; and lecithin.
- the medium chain triglycerides comprise not more than 20% by weight of the base.
- the present invention provides a method for creating chewing gum comprising the step of substituting for a typical softener or emulsifier in a gum base that is used to create a chewing gum medium chain triglycerides.
- the medium chain triglycerides comprise approximately 0.01% to about 5% by weight of the chewing gum formulation.
- the present invention provides a method for creating gum base comprising the step of substituting for a hydrogenated fat in a gum base formulation medium chain triglycerides.
- a further advantage of the present invention is to provide an improved base that can be used to create chewing gum.
- Another advantage of the present invention is that it provides an improved chewing gum softener.
- an advantage of the present invention is that it provides a method of replacing at least some of the hydrogenated fats in base formulations.
- an advantage of the present invention is that it provides an improved emulsifying agent for chewing gum.
- an advantage of the present invention is that it provides an improved method for creating chewing gum.
- an advantage of the present invention is that it provides a softer base.
- an advantage of the present invention is that it provides a chewing gum having improved flavor quality.
- FIGURE illustrates, graphically, the effects of triglyceride chain length on base hardness.
- the present invention provides improved chewing gum formulations and base formulations.
- Pursuant to the present invention medium chain triglycerides are used.
- the medium chain triglycerides can be used in base formulations to provide improved properties.
- the medium chain triglycerides can be used as softeners and/or emulsifying agents or to replace some or all of the hydrogenated fats that are typically used in a gum base.
- Medium chain triglycerides are fat/oil substances that can be obtained from the fractionation of coconut oil.
- Medium chain triglycerides are made up of a mixture of medium chain fatty acids (MCFA) ranging from caproic to lauric (C 6 -C 12 ) in its triglyceride form.
- MCFA medium chain fatty acids
- Fractionated coconut oil is generally about 95% caprylic (C 8 :0) and capric (C 10 :0).
- the triglycerides of coconut oil are heat hydrolyzed to form free fatty acid and glycerol, and to methyl esters of fatty acids.
- the esters are fractionally distilled to separate the medium chain fatty acids and reesterified with glycerol to form medium chain triglycerides.
- Medium chain triglycerides are a clear, tasteless, odorless product that has a low viscosity and good spreadability. Medium chain triglycerides are somewhat more soluble in water than long chain triglycerides. Due to the medium chain triglycerides' tasteless and odorless properties, medium chain triglycerides provide a good flavor carrier and solvent and can be used in candy as a release agent.
- medium chain triglycerides are saturated, they have a low potential for oxidation.
- Medium chain triglycerides also have a lower molecular weight than most fats/oils and therefore, are a thin oil that affords a soft gum base when added to other gum base ingredients.
- the inventors have discovered that medium chain triglycerides will afford a gum base that is softer than a gum base that includes long chain triglycerides or even short chain triglycerides.
- Medium chain triglycerides also have a very clear flavor and do not contribute any off flavors to the gum base.
- medium chain triglycerides can be used in base formulations.
- the medium chain triglycerides can be used as softeners and/or emulsifying agents.
- the medium chain triglycerides can be used in a variety of different chewing gum and base formulations.
- chewing gum generally consists of a water insoluble gum base, a water soluble portion, and flavors.
- the insoluble gum base generally comprises elastomers, resins, fats and oils, softeners, and inorganic fillers.
- the gum base may or may not include wax.
- the insoluble gum base can constitute approximately 5 to about 95 percent, by weight, of the chewing gum, more commonly, the gum base comprises 10 to about 50 percent of the gum, and in some preferred embodiments, 20 to about 35 percent, by weight, of the chewing gum.
- the chewing gum base of the present invention contains about 20 to about 60 weight percent synthetic elastomer, 0 to about 30 weight percent natural elastomer, about 5 to about 55 weight percent elastomer plasticizer, about 4 to about 35 weight percent filler, about 5 to about 35 weight percent softener, and optional minor amounts (about one percent or less) of miscellaneous ingredients such as colorants, antioxidants, etc.
- Synthetic elastomers may include, but are not limited to, polyisobutylene with a GPC weight average molecular weight of about 10,000 to about 95,000, isobutylene-isoprene copolymer (butyl elastomer) , styrene-butadiene copolymers having styrene-butadiene ratios of about 1:3 to about 3:1, polyvinyl acetate having a GPC weight average molecular weight of about 2,000 to about 90,000, polyisoprene, polyethylene, vinyl acetate-vinyl laurate copolymer having vinyl laurate content of about 5 to about 50 percent by weight of the copolymer, and combinations thereof.
- Preferred ranges are, for polyisobutylene, 50,000 to 80,000 GPC weight average molecular weight, for styrene-butadiene, 1:1 to 1:3 bound styrene-butadiene, for polyvinyl acetate, 10,000 to 65,000 GPC weight average molecular weight with the higher molecular weight polyvinyl acetates typically used in bubble gum base, and for vinyl acetate-vinyl laurate, vinyl laurate content of 10-45 percent.
- Natural elastomers may include natural rubber such as smoked or liquid latex and guayule as well as natural gums such as jelutong, lechi caspi, perillo, sorva. massaranduba balata, massaranduba chocolate, nispero, rosindinha, chicle, gutta hang kang, and combinations thereof.
- the preferred synthetic elastomer and natural elastomer concentrations vary depending on whether the chewing gum in which the base is used is adhesive or conventional, bubble gum or regular gum, as discussed below.
- Preferred natural elastomers include jelutong, chicle, sorva and massaranduba balata.
- Elastomer plasticizers may include, but are not limited to, natural rosin esters, often called estergums, such as glycerol esters of partially hydrogenated rosin, glycerol esters polymerized rosin, glycerol esters of partially dimerized rosin, glycerol esters of rosin, pentaerythritol esters of partially hydrogenated rosin, methyl and partially hydrogenated methyl esters of rosin, pentaerythritol esters of rosin; synthetics such as terpene resins derived from alpha-pinene, beta-pinene, and/or d-limonene; and any suitable combinations of the foregoing.
- the preferred elastomer plasticizers will also vary depending on the specific application, and on the type of elastomer which is used.
- Fillers/texturizers may include magnesium and calcium carbonate, ground limestone, silicate types such as magnesium and aluminum silicate, clay, alumina, talc, titanium oxide, mono-, di- and tri-calcium phosphate, cellulose polymers, such as wood, and combinations thereof.
- softeners/emulsifiers may include tallow, hydrogenated tallow, hydrogenated and partially hydrogenated vegetable oils, cocoa butter, glycerol monostearate, glycerol triacetate, lecithin, mono-, di- and triglycerides, acetylated monoglycerides, fatty acids (e.g. stearic, palmitic, oleic and linoleic acids) , and combinations thereof.
- fatty acids e.g. stearic, palmitic, oleic and linoleic acids
- Colorants and whitener ⁇ may include FD&C-type dyes and lakes, fruit and vegetable extracts, titanium dioxide, and combinations thereof.
- the base may or may not include wax.
- An example of a wax-free gum base is disclosed in U.S. Patent No.
- a typical chewing gum composition includes a water soluble bulk portion and one or more flavoring agents.
- the water soluble portion can include bulk ⁇ weeteners, high intensity sweeteners, flavoring agents, softeners, emulsifier ⁇ , colors, acidulants, filler ⁇ , antioxidant ⁇ , and other components that provide desired attribute ⁇ .
- the ⁇ oftener ⁇ which are al ⁇ o known as plasticizers and plasticizing agents, generally constitute between approximately 0.5 to about 15% by weight of the chewing gum.
- the ⁇ oftener ⁇ may, in addition to including medium chain triglycerides, include glycerin, lecithin, and combinations thereof.
- Aqueous ⁇ weetener solutions such a ⁇ those containing sorbitol, hydrogenated starch hydrolysates, corn syrup and combinations thereof, may also be used a ⁇ softener ⁇ and binding agent ⁇ in chewing gum.
- Bulk sweeteners include both sugar and sugarless components.
- Bulk ⁇ weetener ⁇ typically con ⁇ titute 5 to about 95% by weight of the chewing gum, more typically,
- Sugar sweeteners generally include "saccharide- containing components commonly known in the chewing gum art, including, but not limited to, sucrose, dextrose, maltose, dextrin, dried invert sugar, fructose, levulose, galactose, corn syrup ⁇ olid ⁇ , and the like, alone or in combination.
- Sorbitol can be u ⁇ ed as a sugarless sweetener.
- sugarless sweeteners can include, but are not limited to, other sugar alcohols such as mannitol, xylitol, hydrogenated starch hydrolysate ⁇ , maltitol, and the like, alone or in combination.
- High inten ⁇ ity artificial ⁇ weetener ⁇ can also be used in combination with the above.
- Preferred sweeteners include, but are not limited to sucralo ⁇ e, a ⁇ partame, ⁇ alt ⁇ of ace ⁇ ulfame, alitame, saccharin and it ⁇ ⁇ alt ⁇ , cyclamic acid and it ⁇ salts, glycyrrhizin, dihydrochalcones, thaumatin, monellin, and the like, alone or in combination.
- Such techniques as wet granulation, wax granulation, spray drying, spray chilling, fluid bed coating, coacervation, and fiber extrusion may be u ⁇ ed to achieve the desired release characteristics.
- usage level of the artificial sweetener will vary greatly and will depend on such factors as potency of the sweetener, rate of release, desired sweetness of the product, level and type of flavor used and cost considerations. Thus, the active level of artificial sweetener may vary from 0.02 to about 8%. When carriers used for encapsulation are included, the usage level of the encapsulated sweetener will be proportionately higher.
- Combinations of sugar and/or sugarle ⁇ s sweetener ⁇ may be u ⁇ ed in chewing gum. Additionally, the ⁇ oftener may al ⁇ o provide additional sweetne ⁇ such a ⁇ with aqueous sugar or alditol solution ⁇ .
- a low caloric bulking agent can be used.
- low caloric bulking agents include: polydextrose; Raftilo ⁇ e, Raftilin; Fructooligo ⁇ accharides (NutraFlora) ; Palatino ⁇ e oligosaccharide; Guar Gum Hydrolysate (Sun Fiber) ; or indigestible dextrin (Fibersol) .
- other low calorie bulking agents can be used.
- flavoring agents can be used.
- the flavor can be used in amounts of approximately 0.1 to about 15 weight percent of the gum, and preferably, about 0.2 to about 5%.
- Flavoring agents may include essential oils, synthetic flavors or mixtures thereof including, but not limited to, oils derived from plants and fruits such a ⁇ citru ⁇ oil ⁇ , fruit essences, peppermint oil, spearmint oil, other mint oil ⁇ , clove oil, oil of wintergreen, anise and the like.
- Artificial flavoring agents and components may also be used. Natural and artificial flavoring agents may be combined in any sen ⁇ orially acceptable fa ⁇ hion.
- the pre ⁇ ent invention can be u ⁇ ed with a variety of proce ⁇ es for manufacturing chewing gum.
- Chewing gum is generally manufactured by sequentially adding the various chewing gum ingredients to commercially available mixers known in the art. After the ingredients have been thoroughly mixed, the chewing gum mas ⁇ is discharged from the mixer and shaped into the desired form, such as by rolling into sheets and cutting into sticks, extruding into chunk ⁇ , or ca ⁇ ting into pellet ⁇ .
- the ingredient ⁇ are mixed by first melting the gum base and adding it to the running mixer.
- the gum base may alternatively be melted in the mixer.
- Color and emulsifiers can be added at this time.
- Medium chain triglycerides in its typical liquid form may be added to chewing gum during manufacture of the ba ⁇ e.
- Medium chain triglycerides may be added at any time during proces ⁇ ing of the base, but preferably, near the end of the batch to act as a softener.
- Medium chain triglycerides may be added to conventional bases that contain wax or are wax-free bases, that may or may not contain polyvinyl acetate or terpene resin ⁇ , or bases that contain natural gums or synthetic bases, bases that are non-tacky, or are bubble gum bases.
- medium chain triglycerides may replace some or most of the partially hydrogenated or hydrogenated vegetable oils, mono- and di-glycerides, acetylated monoglycerides, or other softeners used in the gum base.
- Medium chain triglycerides may also be blended with the other ⁇ ofteners in the gum base and added during the base manufacturing proces ⁇ .
- a chewing gum ba ⁇ e made with medium chain triglyceride ⁇ will have greater oxidative stability due to the presence of medium chain triglyceride ⁇ , and will give chewing gum a cleaner ta ⁇ te due to a reduction of off-tasting fats and oils.
- Medium chain triglycerides may also be added to a chewing gum formulation in its liquid form or may be mixed with other gum or base softeners and added to a gum formulation during proces ⁇ ing.
- Medium chain triglyceride ⁇ may be added during the gum manufacturing at any time during processing, but preferably, early in the batch to allow thorough mixing with the gum base.
- Medium chain triglycerides can be added to the chewing gum formulation so that they comprise approximately 0.01% to about 5% by weight of the chewing gum formulation.
- the medium chain triglycerides comprise approximately 0.02% to about 2% and most preferably, about 0.05% to about 0.5% by weight of the chewing gum formulation.
- Medium chain triglycerides may be blended with other softeners such a ⁇ lecithin, glycerol triacetate, acetylated monoglycerides, mono- and di-glycerides, or other vegetable oils and fats that may be added to a gum formulation.
- a solid softener such as lecithin
- medium chain triglycerides may act as a carrier or solvent for the particulate lecithin. It has been found that lecithin when mixed with medium chain triglycerides will allow for an ea ⁇ ier di ⁇ persion of lecithin in a gum formulation. This should be contrasted with soy bean oil that is typically used as a carrier for lecithin. Unfortunately, soy bean oil has some off-taste and becomes rancid with time; but particulate lecithin in medium chain triglycerides gives a clean taste with good oxidation stability.
- Medium chain triglycerides may al ⁇ o be blended with a wide range of natural and artificial flavor oils and act as a carrier for flavor oils.
- the clean, tasteless, and odorles ⁇ properties of medium chain triglycerides make ⁇ it an excellent carrier for flavor ⁇ such a ⁇ spearmint, peppermint, cinnamon, wintergreen, and fruit flavor ⁇ .
- the level of medium chain triglycerides mixed with flavors can vary over a wide range from approximately 1% to about 99% by weight since most gum flavors are oil soluble.
- Medium chain triglycerides can al ⁇ o act as a carrier for artificial and natural colors such as in FD&C lake dispersions and natural esters like betacarotene and medium chain triglycerides eliminates the off-taste associated with fat/oil carriers and allows higher usage of color.
- Medium chain triglycerides may also be used as a release agent for encapsulated flavors.
- Medium chain triglycerides can be added to an encap ⁇ ulating media to allow for fa ⁇ ter and ea ⁇ ier di ⁇ solution of the encapsulating media.
- Medium chain triglyceride ⁇ may al ⁇ o have ⁇ ome effect a ⁇ an emul ⁇ ifier since medium chain triglycerides have a ⁇ light water solubility unlike concentrated fats and oils.
- medium chain triglycerides can be mixed with the flavor and carrier to provide an easier encapsulation of flavors.
- Example A Example 1-6
- Example 1 used Triacetin
- Example 2 used Tributyrin
- Example 3 used Tricaprylin
- Example 4 used Tricaprin
- Example 5 used Trilaurin
- Example 6 used Trimyri ⁇ tin
- the base concentrate was made at a temperature of 115°C and allowed to cool and solidify.
- the concentrate was portioned and remelted at 115°C to add softeners.
- the base was then allowed to cool to solidify.
- Example A and Example 1-6 At room temperature, Instron Hardne ⁇ s was mea ⁇ ured on the bases made in Example A and Example 1-6. Results are shown in the Figure. It can be seen from this data that Examples 3 and 4 with C 8 and C 1fJ fatty acids have lower Instron Hardness than any of the other fatty acid triglycerides, even those with C 2 and C 4 and thus make softer base ⁇ . It should be noted that medium chain triglyceride ⁇ comprise approximately 90% C 8 and C 10 triglyceride ⁇ .
- the gum ba ⁇ e ⁇ made in Example A and 1-6 were al ⁇ o evaluated by Rheometric ⁇ Dynamic Analyzer (RDA 700 Rheometer) and tested at 25°C, 35°C, and 45°C. Data gave evaluations in terms of:
- the formulas listed in Table I comprise various contemplative sugar formulas in which medium chain triglycerides can be added at various levels to gum.
- Neobee -5 0.05 0.10 0.25 0.50 1.0 2.0
- Example ⁇ 13-18 are the same as Examples 7-12 except that Neobee M-5 i ⁇ pre-blended with the peppermint flavor and added to the gum formulation.
- Glycerin b 5.0 5.0 5.0 5.0 5.0 5.0 5.0
- ⁇ Corn syrup is evaporated to 85% solids, 15% moisture.
- b Glycerin and syrup can be blended and co-evaporated.
- c Lecithin and Neobee M-5 can be pre-blended.
- d Flavor and Neobee M-5 can be pre-blended.
- Example ⁇ 24-28 in Table 5 demon ⁇ trate the u ⁇ e of MCT in medium-moi ⁇ ture sugar formulations having about 2% to about 5% moisture. TABLE 5
- Neobee M-5 C 0.05 d 0.2 d 0.5 d 1.0" 2.0 d
- Neobee M-5 and Lecithin can be pre-blended. "Flavor and Neobee M-5 can be pre-blended.
- Examples 29-33 in Table 6 demonstrate the use of MCT ⁇ in high moi ⁇ ture sugar formulations having more than about 5% moisture.
- Lecithin* 0.1 0.1 0.1 —
- Neobee M-5 0.05 0.2 0.5 1.0 2.0
- Examples 34-38 in Table 7 and Examples 39-48 in Tables 8 and 9 demonstrate the u ⁇ e of MCTs in low- and high-moisture gums that are sugar-free. Low-moisture gums have less than about 2% moisture, and high-moisture gums have greater than 2% moisture.
- Neobee M-5 0.05 0.2 0.5 1.0 2.0
- Neobee M-5 0.05 0.2 0.5 1.0 2.0
- Glycerin and HSH syrup may be blended or co-evaporated.
- Table 10 shows sugar chewing gum formulations that can be made with MCTs and various types of sugars.
- Neobee M-5 0.1 1.0 0.1 1.0 0.1 1.0 Ex. 55 Ex. 56 Ex. 57 Ex. 58 Ex. 59 Ex. 60
- Neobee M-5 0.1 1.0 0.1 1.0 0.1 1.0
- Neobee M-5 0.1 1.0
- Table 11 shows chewing gum formulations that are free of sugar. These formulations can use a wide variety of other non-sugar alditols.
- Neobee M-5 0.1 1.0 0.1 1.0 0.1 1.0
- Neobee M-5 0.1 1.0 0.1 1.0 0.1 1.0
- Palm Oil — 2.3 —
- Microcrystalline Wax (MP 180°F) 6.0 3.1 8.5
- Neobee M-5 3.0 1.8 3.3
- Microcrystalline Wax (MP 180°F) 15.2 6.8 6.1
- Acetylated Monoglyceride 2.5 — Hydrogenated Cotton Seed Oil — 4.6 8.0
- Lecithin 0.8 —
- Microcrystalline Wax (MP 180°F) — 7.0 4.4 Paraffin Wax (MP 135 ⁇ F) 1.8 1.5 0.5
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Confectionery (AREA)
- Medicinal Preparation (AREA)
Abstract
Description
Claims
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002190095A CA2190095C (en) | 1994-05-27 | 1995-05-24 | Chewing gum having improved texture and containing medium chain triglycerides |
| EP95920645A EP0760606B1 (en) | 1994-05-27 | 1995-05-24 | Chewing gum having improved texture and containing medium chain triglycerides |
| DK95920645T DK0760606T3 (en) | 1994-05-27 | 1995-05-24 | Chewing gum that has improved texture and contains medium chain triglycerides |
| DE69521892T DE69521892T2 (en) | 1994-05-27 | 1995-05-24 | Chewing gum with improved texture that contains medium-chain triglycerides |
| AU26031/95A AU703363B2 (en) | 1994-05-27 | 1995-05-24 | Chewing gum having improved texture and containing medium chain triglycerides |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US1994/005771 WO1995032634A1 (en) | 1994-05-27 | 1994-05-27 | Improved chewing gum containing medium chain triglycerides |
| USPCT/US94/05771 | 1994-05-27 | ||
| US34650994A | 1994-11-29 | 1994-11-29 | |
| US08/346,509 | 1994-11-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1995032637A1 true WO1995032637A1 (en) | 1995-12-07 |
Family
ID=26788279
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1995/006583 Ceased WO1995032637A1 (en) | 1994-05-27 | 1995-05-24 | Chewing gum having improved texture and containing medium chain triglycerides |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0760606B1 (en) |
| AU (1) | AU703363B2 (en) |
| CA (1) | CA2190095C (en) |
| DE (1) | DE69521892T2 (en) |
| DK (1) | DK0760606T3 (en) |
| ES (1) | ES2162636T3 (en) |
| PL (1) | PL317370A1 (en) |
| WO (1) | WO1995032637A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0839516B1 (en) * | 1996-10-30 | 2003-03-19 | Sara Lee/DE N.V. | Triglyceride containing Toothpaste |
| US6599542B1 (en) | 1998-08-11 | 2003-07-29 | Warner-Lambert Company | Non-stick chewing gum base |
| WO2010053908A1 (en) * | 2008-11-06 | 2010-05-14 | Allison Flynn | Biodegradable chewing gum bases and uses thereof |
| ITMI20130686A1 (en) * | 2013-04-24 | 2014-10-25 | Perfetti Van Melle Spa | CHEWING GUM |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4378374A (en) * | 1981-12-21 | 1983-03-29 | Nabisco Brands, Inc. | Chewing gum having improved softness |
| JPS58146241A (en) * | 1982-02-26 | 1983-08-31 | Nippon Oil & Fats Co Ltd | Chewing gum |
| US4446157A (en) * | 1982-09-30 | 1984-05-01 | International Flavors & Fragrances Inc. | Prenyl methyl carbonate and organoleptic uses thereof |
| US4452820A (en) * | 1981-06-05 | 1984-06-05 | Nabisco Brands, Inc. | Gum base and chewing gum containing same |
| US5156866A (en) * | 1990-06-01 | 1992-10-20 | Lotte Company Limited | Flavor and taste composition for a chewing gum |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2040633B1 (en) * | 1991-12-31 | 1994-05-16 | Fitzig Nie Simon | A PROCEDURE FOR THE PREPARATION OF AN ANTIHALITOSIC ORAL COMPOSITION. |
-
1995
- 1995-05-24 AU AU26031/95A patent/AU703363B2/en not_active Ceased
- 1995-05-24 EP EP95920645A patent/EP0760606B1/en not_active Expired - Lifetime
- 1995-05-24 DE DE69521892T patent/DE69521892T2/en not_active Expired - Lifetime
- 1995-05-24 WO PCT/US1995/006583 patent/WO1995032637A1/en not_active Ceased
- 1995-05-24 CA CA002190095A patent/CA2190095C/en not_active Expired - Lifetime
- 1995-05-24 ES ES95920645T patent/ES2162636T3/en not_active Expired - Lifetime
- 1995-05-24 PL PL95317370A patent/PL317370A1/en unknown
- 1995-05-24 DK DK95920645T patent/DK0760606T3/en active
Patent Citations (5)
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Non-Patent Citations (1)
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0839516B1 (en) * | 1996-10-30 | 2003-03-19 | Sara Lee/DE N.V. | Triglyceride containing Toothpaste |
| US6599542B1 (en) | 1998-08-11 | 2003-07-29 | Warner-Lambert Company | Non-stick chewing gum base |
| WO2010053908A1 (en) * | 2008-11-06 | 2010-05-14 | Allison Flynn | Biodegradable chewing gum bases and uses thereof |
| ITMI20130686A1 (en) * | 2013-04-24 | 2014-10-25 | Perfetti Van Melle Spa | CHEWING GUM |
| WO2014173924A1 (en) * | 2013-04-24 | 2014-10-30 | Perfetti Van Melle S.P.A. | Coated chewing gum and its process of manufacture |
| JP2016516430A (en) * | 2013-04-24 | 2016-06-09 | ペルフェッティ ヴァン メッレ ソシエタ ペル アチオニPERFETTI VAN MELLE S.p.A. | Coated chewing gum and method for producing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2162636T3 (en) | 2002-01-01 |
| EP0760606B1 (en) | 2001-07-25 |
| EP0760606A4 (en) | 1998-06-03 |
| PL317370A1 (en) | 1997-04-01 |
| AU2603195A (en) | 1995-12-21 |
| DE69521892T2 (en) | 2001-11-22 |
| CA2190095C (en) | 2000-01-18 |
| DE69521892D1 (en) | 2001-08-30 |
| DK0760606T3 (en) | 2001-09-24 |
| EP0760606A1 (en) | 1997-03-12 |
| AU703363B2 (en) | 1999-03-25 |
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