WO1997002733A2 - Microwave/millimeter wave circuit structure with discrete flip-chip mounted elements, and method of fabricating the same - Google Patents

Microwave/millimeter wave circuit structure with discrete flip-chip mounted elements, and method of fabricating the same Download PDF

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Publication number
WO1997002733A2
WO1997002733A2 PCT/US1996/011144 US9611144W WO9702733A2 WO 1997002733 A2 WO1997002733 A2 WO 1997002733A2 US 9611144 W US9611144 W US 9611144W WO 9702733 A2 WO9702733 A2 WO 9702733A2
Authority
WO
WIPO (PCT)
Prior art keywords
substrate
circuit
bumps
pads
flip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1996/011144
Other languages
French (fr)
Other versions
WO1997002733A3 (en
Inventor
Mehran Matloubian
Perry A. Macdonald
David B. Rensch
Lawrence A. Larson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Raytheon Co
Original Assignee
Hughes Aircraft Co
HE Holdings Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hughes Aircraft Co, HE Holdings Inc filed Critical Hughes Aircraft Co
Priority to DE69637906T priority Critical patent/DE69637906D1/en
Priority to CA002198088A priority patent/CA2198088C/en
Priority to EP96923570A priority patent/EP0782766B1/en
Priority to JP9505862A priority patent/JPH10505466A/en
Publication of WO1997002733A2 publication Critical patent/WO1997002733A2/en
Priority to MXPA/A/1997/001735A priority patent/MXPA97001735A/en
Publication of WO1997002733A3 publication Critical patent/WO1997002733A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W90/00Package configurations
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q23/00Antennas with active circuits or circuit elements integrated within them or attached to them
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/30Assembling printed circuits with electric components, e.g. with resistors
    • H05K3/32Assembling printed circuits with electric components, e.g. with resistors electrically connecting electric components or wires to printed circuits
    • H05K3/34Assembling printed circuits with electric components, e.g. with resistors electrically connecting electric components or wires to printed circuits by soldering
    • H05K3/3452Solder masks
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W44/00Electrical arrangements for controlling or matching impedance
    • H10W44/20Electrical arrangements for controlling or matching impedance at high-frequency [HF] or radio frequency [RF]
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/0213Electrical arrangements not otherwise provided for
    • H05K1/0237High frequency adaptations
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/01Dielectrics
    • H05K2201/0137Materials
    • H05K2201/0175Inorganic, non-metallic layer, e.g. resist or dielectric for printed capacitor
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/03Metal processing
    • H05K2203/0315Oxidising metal
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W44/00Electrical arrangements for controlling or matching impedance
    • H10W44/20Electrical arrangements for controlling or matching impedance at high-frequency [HF] or radio frequency [RF]
    • H10W44/241Electrical arrangements for controlling or matching impedance at high-frequency [HF] or radio frequency [RF] for passive devices or passive elements
    • H10W44/248Electrical arrangements for controlling or matching impedance at high-frequency [HF] or radio frequency [RF] for passive devices or passive elements for antennas
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W72/00Interconnections or connectors in packages
    • H10W72/071Connecting or disconnecting
    • H10W72/072Connecting or disconnecting of bump connectors
    • H10W72/07231Techniques
    • H10W72/07236Soldering or alloying
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W72/00Interconnections or connectors in packages
    • H10W72/071Connecting or disconnecting
    • H10W72/072Connecting or disconnecting of bump connectors
    • H10W72/07251Connecting or disconnecting of bump connectors characterised by changes in properties of the bump connectors during connecting
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W72/00Interconnections or connectors in packages
    • H10W72/20Bump connectors, e.g. solder bumps or copper pillars; Dummy bumps; Thermal bumps
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W72/00Interconnections or connectors in packages
    • H10W72/20Bump connectors, e.g. solder bumps or copper pillars; Dummy bumps; Thermal bumps
    • H10W72/251Materials
    • H10W72/252Materials comprising solid metals or solid metalloids, e.g. PbSn, Ag or Cu

Definitions

  • This invention relates to microwave/millimeter wave circuits, and more particularly to circuit structures in this wavelength range that employ discrete circuit ele ⁇ ments.
  • the microwave/mi11imeter wave spectrum is generally defined as extending from about 1 m at 300 MHz to about 1 mm at 300 GHz, with the millimeter wave portion of the spectrum covering about 30-300 GHz.
  • Microwave/millimeter wave circuits have been developed for numerous applications, such as telephone transmission, microwave ovens, radar, and automotive uses that include collision warning radar, millimeter wave imaging systems, blind-spot radar, toll exchanges and radar for monitoring road surfaces. They have generally been implemented as either hybrid circuits, with discrete elements wire bonded to a circuit board substrate, or as monolithic microwave integrated circuits (MMICs) in which active circuit compo ⁇ nents are integrated on the same wafer as passive com ⁇ ponents. While the development of microwave devices such as collision warning radars has been based upon the use of MMICs, several factors make the fabrication of MMICs con- siderably more expensive than fabricating discrete devices.
  • MMICs monolithic microwave integrated circuits
  • MMICs are much larger than discrete devices and ac ⁇ cordingly take up a larger area of the semiconductor wafer; the cost of a chip depends heavily upon its size. Also, due to the complexity of fabricating MMICs, their typical yield is on the order of 15%-30%, as opposed to yields of more than 80% that can easily be achieved with discrete devices. For example, from a 7.6 cm (3 inch) wafer it is possible to obtain approximately 14,000 working discrete devices, as compared to approximately 400 MMICs.
  • Sakai et al. also proposed a bump technology that is based upon the use of an insulate resin with no heating. This results in a relatively low accuracy of device place- ment, which is a critical factor at the high frequencies involved in microwave/millimeter wave circuits.
  • a primary reason for the movement towards MMICs as opposed to hybrid circuits is the high cost of hybrid circuits that results from the need to hand tune each circuit; this pro ⁇ cess is both time consuming and expensive.
  • Duroid sub ⁇ strates or other similar plastic type substrates have been developed which have both a lower cost and a lower loss level.
  • Duroid is a trademark of Rogers Corporation for a doped Teflon ® composition (the chemical formula for Teflon is PTFE) .
  • Low-loss plastic type substrates are available inexpensively with metalization on both sides, and do not require the deposition of Si0 2 and the two metal layers of Sakai et al. to fabricate low-loss transmission lines.
  • Duroid substrates are relatively soft and it is therefore difficult to wire bond discrete devices onto them.
  • the present invention seeks to provide a microwave/ millimeter wave circuit structure and related fabrication method that is less expensive and achieves a higher yield than presently available MMIC techniques, and yet avoids the excessive losses, lack of accuracy in device placement with respect to line width, and relatively high substrate cost of the Sakai et al. approach.
  • a microwave/millimeter wave circuit structure that employs a non-ceramic and non- semiconductor dielectric substrate, preferably a low-loss plastic, in which discrete circuit elements are flip-chip mounted to the substrate and electrically interconnected by an interconnection network on the substrate.
  • the spacings between the interconnected circuit elements are compatible with electrical signals in the microwave/millimeter wave range, and a highly accurate device placement that avoids the need for hand tuning is achieved through the use of solder bumps on the chips that self-align with contact pads on the substrate.
  • the surface of the intercon ⁇ nection network is oxidized, while the substrate contact pads are formed from a non-oxidyable material, preferably nickel/gold.
  • the oxidized surface inhibits a flow of the solder bumps onto it, thereby enhancing an accurate self- alignment of the bumps and their associated circuit ele ⁇ ments on the substrate pads.
  • the spacings between adjacent bumps are less than about 125 micrometers, and the pad widths are no greater than about 50 micrometers.
  • the substrate may be coated with a passiva- tion layer in which openings are formed at the bump loca ⁇ tions, with the bumps extending through respective openings to contact the underlying interconnection network.
  • a low cost stiffening substrate is preferably ad ⁇ hered to the principal substrate.
  • a compact transceiver device can be implemented by laminating two Duroid sub ⁇ strates back-to-back, with one of the substrates bearing a transceiver circuit and the other an antenna that communi- cates with the transceiver circuit through the substrates and preferably has a lower dielectric constant than the circuit substrate.
  • a metal layer between the two sub ⁇ strates serves the dual function of a ground plane and a stiffening layer; a separate stiffening substrate may also be provided' over the flip-chip circuitry.
  • FIGs. 1, 2 and 3 are fragmentary sectional views il ⁇ lustrating sequential steps in the fabrication of bump con ⁇ tacts on a flip-chip circuit;
  • FIG. 4 is a fragmentary sectional view illustrating the flip-chip mounted on an interconnection substrate;
  • FIGs. 5 and 6 are respectively fragmentary sectional and plan views of an interconnection substrate with an oxi ⁇ dized lead which bears a non-oxidized bump contact pad;
  • FIG. 7 is a perspective view of a circuit substrate in accordance with the invention that includes a passivation layer with bump contact openings and a stiffening backing;
  • FIG. 8 is a sectional view of a circuit substrate as in FIG. 7, with a pair of circuit chips flip-chip mounted to the substrate;
  • FIG. 9 is a perspective view of a dual substrate con ⁇ figuration with a flip-chip transceiver circuit on one side and an antenna on the opposite side;
  • FIG. 10 is an illustrative sectional view showing a flip-chip and a beam lead chip mounted to the structure of FIG. 9;
  • FIG. 11 is a sectional view of two substrates used in the formation of the dual substrate structure of FIG. 9;
  • FIG. 12 is a perspective view showing the antenna side of a dual antenna/circuit substrate.
  • FIG. 13 is a perspective view showing the circuit side of the FIG. 12 structure.
  • the invention improves upon the reliability and cost of microwave/millimeter wave circuits by flip-chip mounting discrete active circuit elements to a novel substrate for this purpose.
  • the invention overcomes the critical align ⁇ ment problems that would otherwise be expected to be an inhibiting factor in this high frequency range.
  • FIGs. 1-3 illustrate the formation of bonding pads on a flip-chip device.
  • a flip-chip 2 that is formed from a semiconductor such as InP or GaAs is shown with its circuit side facing up, although the circuit itself is not illustrated in the figure.
  • the circuit side of the chip is coated with a photoresist 4 that is patterned with openings within which contact pads 6 are formed in contact with the circuit.
  • the pads are typically formed from Ti/Pt/Au or Ni/Au.
  • Solder contact "bumps" (made from alloys such as tin- /lead) 8 are then plated up in the upper portion of the photoresist opening.
  • the invention provides a more accurate device placement that permits alignment accuracy on the order of approximately 2 micrometers (with a transmission line-width of 125 micrometers) without any need for lengthy alignment by an automated system.
  • the photoresist is removed as shown in FIG. 2.
  • the bumps are typically 25 micrometers high and 50 micrometers wide, and in any event no more than about 100 micrometers wide, and the spacing between adjacent bumps on a given device are kept to typically about 150 micrometers. This con ⁇ trasts with typical prior flip-chip bump dimensions of 75 micrometers high and wide, and 250-375 micrometer between adjacent bumps.
  • the bumps 8 are pre- flowed to give them a somewhat flattened contour, as illus ⁇ trated in FIG. 3.
  • a preflow temperature of 220° C is suit ⁇ able for tin lead solder.
  • the chip is then flipped over and mounted to a special substrate 12 that has unique char ⁇ acteristics as described below.
  • the substrate carries a metallized interconnection network on its upper surface, typically a patterned copper network of which a pair of leads 10 are shown in FIG. 4.
  • Pads 14 are provided on the substrate metallization at the desired contact sites; the substrate pads 14 will generally be similar to the chip pads 6.
  • the solder pads 8 are heated and reflowed so that they adhere to, and form electrical contacts with, the substrate pads 14.
  • the necessary heat can be provided by conventional techniques such as placing the assembly in a convection oven, flowing hot gas onto the chip or the use of a heat lamp. During the heating process the solder's surface tension tends to make the bumps self-align with the substrate pads 14. This is helpful in obtaining the necessary high placement accu ⁇ racy.
  • the placement accuracy is further improved by combin ⁇ ing an oxidizable substrate metallization with a non-oxi- dizable contact pad on that metallization.
  • This structure is illustrated in FIGs. 5 and 6.
  • the substrate metalliza ⁇ tion 10 is formed from a conventional material such as cop ⁇ per, while the contact pad 14' is formed from a material that does not oxidize (or that oxidizes at a substantially higher temperature than the metallization) .
  • a nickel layer 16 covered by a gold layer 18 is preferred for this pur ⁇ pose; successive titanium, platinum and gold layers could also be used.
  • the substrate is heated to form an oxide layer 20 over the metallization 10, but not over the con ⁇ tact pad 14' .
  • the surrounding metalliza ⁇ tion oxide 20 prevents the solder from flowing onto the metallization, since the oxide presents a non-wettable sur ⁇ face to the solder.
  • the pad thus presents a preferential wettable surface for the solder which enhances the self- alignment of the solder bump to the pad, and thus the pre ⁇ cision of the flip-chip placement on the substrate.
  • a suitable tin lead solder reflow temperature range is 180°- 250° C.
  • the substrate in this embodiment is a relatively thin layer 22 of a non- ceramic and non-semiconductor dielectric material that pro ⁇ vides special advantages and is discussed in greater detail below, backed by a stiffening substrate 24.
  • the overall substrate is coated with a thin passivation layer 26, pref ⁇ erably a polyimide, that adheres to the substrate 22.
  • Ar ⁇ rays of small openings 28 are formed through the passiva ⁇ tion layer, corresponding to the desired locations for the contact bumps 8 of the various flip-chips 2.
  • the openings 28 are only slightly larger than the contact bumps, thus assisting in a precise alignment between the bumps and the metallization (not shown) on substrate 22 that underlies the passivation layer 26.
  • This type of passivation layer has been used previously with flip-chips, but not to pro- vide the high precision device placements required for mi ⁇ crowave/millimeter wave operation.
  • the primary substrate 22 upon which the interconnec ⁇ tion network is formed for the various flip-chips consists of a non-ceramic and non-semiconductor dielectric material, preferably Duroid.
  • Duroid is inexpen ⁇ sive but has generally been considered too flexible for flip-chip applications.
  • the invention attains the low cost benefits of a low-cost plastic substrate, but modifies the substrate structure so that it is compatible with flip-chip technology. " Such modification is necessary for substrate thicknesses less than about 600 micrometers, at which Du ⁇ roid normally does not have sufficient rigidity for flip- chip mounting.
  • a stiffening substrate 24 is provided from a ma ⁇ terial that is separated from the electrical circuitry by the Duroid substrate 22, and therefore does not have to have the electrical properties normally associated with a flip-chip mounting substrate.
  • Preferred stiffening sub ⁇ strates for this purpose are FR4, an industry standard plastic commonly used for the fabrication of surface boards, and polyimides.
  • FIG. 9 shows another application of the invention, in which two Duroid substrates are laminated together to form a double-sided high frequency device, with circuit elements on opposite faces.
  • Passive circuit elements such as transmission lines, bias circuits, antennas and power com- biners, can be fabricated directly on one or both sub ⁇ strates at low cost. The fabrication of such passive cir ⁇ cuit elements does not require very fine geometries and lithography steps, and as a result can be mass produced at low cost.
  • Discrete active elements such as transistors, varactors, PIN-switches and diode mixers, as well as other passive components such as capacitors and resistors, can be added to one or both low cost substrates using flip-chip technology.
  • one of the substrates 32 bears an antenna 34, while the other sub- strate 36 bears transceiver circuitry associated with the antenna.
  • This circuitry includes passive elements such as inductors 38, transmission lines 40 and contact pads 42 formed directly on the substrate, active elements such as a power HEMT (high electron mobility transistor) 44, var- actor 46, low noise HEMT 48, HBT (heterojunction bipolar transistor) 50 and PIN diode 52 secured by flip-chip mount ⁇ ing, and additional passive elements such as capacitor 54 and resistor 57 that are also secured by flip-chip mount ⁇ ing.
  • a ground plane 56 preferably copper, separates the two substrates.
  • the ground plane is preferably formed from copper and is patterned with an array of openings 58 (see FIG. 10) at the locations where communication between the transceiver circuitry and the underlying antenna is de- sired; the high frequency signals are transmitted between the antenna and its associated circuitry via the continuous dielectric paths that include these openings in the ground plane.
  • FIG. 10 shows only one illustrative flip-chip package 60 mounted to corresponding pads on the upper substrate 36. Also shown is a beam lead package 62, which is a conven ⁇ tional circuit package that is similar to a flip-chip but employs a conductive ring 64 around its edge rather than contact bumps on its under circuit surface. Beam lead de- vices are mounted in a manner similar to flip-chips, and for purposes of the invention can be considered to be equivalent to flip-chips.
  • FIG. 11 shows the two Duroid substrates 32 and 36 be ⁇ fore they are laminated together.
  • Such substrates are con- ventionally"provided with metallization layers on both fac ⁇ es; the upper and lower metallization layers on substrates 32 and 36 are identified respectively as 32a, 32b and 36a.
  • metal lay ⁇ er 36b Prior to laminating the two substrates together, metal lay ⁇ er 36b is etched away.
  • the antenna 34 is patterned from metallization layer 32b, the interconnection network for the transceiver circuitry is patterned from metallization layer 36a, and the inner metallization layer 32a is fused to the non-metallized surface of the substrate 36 to form the ground plane 56.
  • ground plane openings 58 are formed in the metallization layer 32a.
  • the bonding film typically PTFE Bonding film
  • the fused metallizations 32a and 36b stiffen the overall sub- strate and allow it to be thinner than would otherwise be the case in the absence of a stiffening substrate as shown in FIGs. 7 and 8.
  • a stiffening substrate can be added over the cir ⁇ cuit substrate 36, with cavities left in the stiffening substrate for the various electrical components.
  • the two substrates 32 and 36 can also be fabricated with different dielectric constants, if desired.
  • a lower dielectric con ⁇ stant for the antenna substrate 32 will help to prevent the field radiated from the antenna from being confined in the substrate, while a higher dielectric constant for the cir ⁇ cuit substrate 36 will reduce the reguired length of its transmission lines.
  • Duroid-type materials with different dielectric constants are readily available.
  • FIGs. 12 and 13 show a particular implementation of the self-contained antenna device illustrated in FIG. 9, with the antenna array 66 shown in FIG. 12 and the circuit ⁇ ry on the opposite face in FIG. 13.
  • the substrates in this particular case are about 7.5 x 10 cm, with the antenna and circuit substrates 32 and 36 respectively 125 and 250 mi ⁇ crometers thick; all of these dimensions can vary depending upon the particular application.
  • Each antenna communicates with the transceiver circuitry on the opposite side through openings (not shown) in the ground plane 56 that are aligned with the antenna input end 68a.
  • the transceiver circuit on the opposite side includes five terminals 70 that communicate with different respective antennas on the opposite side of the substrates, and PIN diode switches 72 that provide switched connections between the terminals 70 and a 5:1 power com- biner 74.
  • the power combiner is connected in turn to am ⁇ plifiers 76 and 78, with amplifier 76 providing a signal between mixers 80 and 82.
  • a voltage controller oscillator (VCO) 84 supplies a reference frequency signal to a fre- quency doubler 86, the output of which is connected along with amplifier 78 to the mixers 80 and 82.
  • the opposite mixer terminals from amplifier 76 are the in-phase (I) channel 88 and the quadrature (Q) channel 90. This type of antenna is particularly useful in automotive applications such as collison warning radar.
  • the invention provides low cost, high reliability cir ⁇ cuit structures for microwave and millimeter wave applica ⁇ tions, without the undesirable parasitic effects of prior high frequency structures. While particular embodiments of the invention have been shown and described, numerous vari ⁇ ations and alternate embodiments will occur to those skilled in the art. Such variations and alternate embodi ⁇ ments are contemplated, and can be made without departing from the spirit and scope of the invention as defined in the appended claims.

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Wire Bonding (AREA)
  • Combinations Of Printed Boards (AREA)
  • Waveguides (AREA)

Abstract

A microwave/millimeter wave circuit structure supports discrete circuit elements (2) by flip-chip mounting to an interconnection network (10) on a low cost non-ceramic and non-semiconductor dielectric substrate (2), preferably Duroid. The necessary precise alignment of the circuit elements with contact pads (14) on the substrate network required for the high operating frequencies is facilitated by oxidizing (20) the interconnection network, but providing the contact pads from a non-oxidizable material (14') to establish a preferential solder bump (8) wetting for the pads. Alternately, the contact bumps on the flip-chips can be precisely positioned through corresponding openings (28) in a passivation layer (26) over the interconnection network. For thin circuit substrates that are too soft for successful flip-chip mounting, stiffening substrates (24) are laminated to the circuit substrates. In a self-contained antenna application in which two of the circuit substrates (32, 36) are laminated together, with an antenna (34) on one side and circuitry on the other side, a metallic ground plane (56) between the substrates also serves a stiffening function.

Description

MICROWAVE/MILLIMETER WAVE CIRCUIT STRUCTURE WITH
DISCRETE FLIP-CHIP MOUNTED ELEMENTS, AND METHOD
OF FABRICATING THE SAME
BACKGROUND OF THE INVENTION Field of the Invention
This invention relates to microwave/millimeter wave circuits, and more particularly to circuit structures in this wavelength range that employ discrete circuit ele¬ ments.
Description of the Related Art
The microwave/mi11imeter wave spectrum is generally defined as extending from about 1 m at 300 MHz to about 1 mm at 300 GHz, with the millimeter wave portion of the spectrum covering about 30-300 GHz.
Microwave/millimeter wave circuits have been developed for numerous applications, such as telephone transmission, microwave ovens, radar, and automotive uses that include collision warning radar, millimeter wave imaging systems, blind-spot radar, toll exchanges and radar for monitoring road surfaces. They have generally been implemented as either hybrid circuits, with discrete elements wire bonded to a circuit board substrate, or as monolithic microwave integrated circuits (MMICs) in which active circuit compo¬ nents are integrated on the same wafer as passive com¬ ponents. While the development of microwave devices such as collision warning radars has been based upon the use of MMICs, several factors make the fabrication of MMICs con- siderably more expensive than fabricating discrete devices. MMICs are much larger than discrete devices and ac¬ cordingly take up a larger area of the semiconductor wafer; the cost of a chip depends heavily upon its size. Also, due to the complexity of fabricating MMICs, their typical yield is on the order of 15%-30%, as opposed to yields of more than 80% that can easily be achieved with discrete devices. For example, from a 7.6 cm (3 inch) wafer it is possible to obtain approximately 14,000 working discrete devices, as compared to approximately 400 MMICs.
The use of flip-chip bonding techniques, in which con¬ ductive contact "bumps" are provided on the circuit face of a chip which is "flipped" and both electrically and me¬ chanically affixed to a circuit board via the bumps, is disclosed in H. Sakai et al., "A Novel Millimeter-Wave IC on Si Substrate Using Flip-Chip Bonding Technology", IEEE MTT-S Digest. 1994, pages 1763-1766. In this publication, millimeter wave heterojunction transistors are flip-chip bonded to microstrip lines formed on a silicon substrate. However, silicon has very high losses at millimeter wave frequencies. To overcome these losses, Sakai et al. depos¬ ited 9 micrometer thick Si02 on the silicon substrate to use in the fabrication of microstrip transmission lines. How¬ ever, the loss for 50 ohm transmission lines at 60 GHz was still 0.55 dB/mm, which is too high for low-loss matching elements, power combiners and couplers. In fact, the cir¬ cuit that was reported to have been constructed for testing operated at 20 GHz rather than 60 GHz, presumably because of excessive transmission line losses at the higher fre- quency. Furthermore, silicon as well as the ceramic mate¬ rials that are conventionally used for circuit boards at lower frequencies are relatively expensive.
Sakai et al. also proposed a bump technology that is based upon the use of an insulate resin with no heating. This results in a relatively low accuracy of device place- ment, which is a critical factor at the high frequencies involved in microwave/millimeter wave circuits. In fact, a primary reason for the movement towards MMICs as opposed to hybrid circuits is the high cost of hybrid circuits that results from the need to hand tune each circuit; this pro¬ cess is both time consuming and expensive. The higher the frequency, the smaller is the length of matching elements (transmission lines) , and the more sensitive is the circuit performance to variations in the line lengths and device placement. Flip-chip mounting has been primarily used at lower frequencies, at which slight variations in the device mounting location is not important to the circuit perfor¬ mance. In the microwave/millimeter wave range, however, the accuracy of device placement and attachment is highly important to the achievement of low cost circuits and sys¬ tems. Sakai et al. achieved a chip alignment accuracy of 5.5 micrometers for transmission line widths of only 16 micrometers; such a low placement accuracy with respect to the line width is believed to be unacceptable at millimeter wave frequencies for achieving reproducible circuit perfor¬ mance.
In contrast to the relatively high loss and expensive silicon substrate employed by Sakai et al., Duroid sub¬ strates or other similar plastic type substrates have been developed which have both a lower cost and a lower loss level. Duroid is a trademark of Rogers Corporation for a doped Teflon® composition (the chemical formula for Teflon is PTFE) . Low-loss plastic type substrates are available inexpensively with metalization on both sides, and do not require the deposition of Si02 and the two metal layers of Sakai et al. to fabricate low-loss transmission lines. However, Duroid substrates are relatively soft and it is therefore difficult to wire bond discrete devices onto them. At lower frequencies these substrates are used for microwave circuits that employ previously packaged compo- nents, such as discrete transistors that are wire bonded inside a package which in turn is mounted on the Duroid substrate. However, the package parasitics of the compo¬ nents are too high for this approach to work at millimeter wave frequencies. Also, up to a thickness of about 600 micrometers Duroid substrates are too flexible for reliable automated flip-chip mounting; MMICs are therefore conven¬ tionally flip-chip mounted on very hard substrates, such as alumina. Thus, despite their desirable low cost, Duroid substrates have not been suitable for flip-chip mounting of high frequency MMICs.
SUMMARY OF THE INVENTION
The present invention seeks to provide a microwave/ millimeter wave circuit structure and related fabrication method that is less expensive and achieves a higher yield than presently available MMIC techniques, and yet avoids the excessive losses, lack of accuracy in device placement with respect to line width, and relatively high substrate cost of the Sakai et al. approach.
These goals are achieved with a microwave/millimeter wave circuit structure that employs a non-ceramic and non- semiconductor dielectric substrate, preferably a low-loss plastic, in which discrete circuit elements are flip-chip mounted to the substrate and electrically interconnected by an interconnection network on the substrate. The spacings between the interconnected circuit elements are compatible with electrical signals in the microwave/millimeter wave range, and a highly accurate device placement that avoids the need for hand tuning is achieved through the use of solder bumps on the chips that self-align with contact pads on the substrate.
In a preferred embodiment the surface of the intercon¬ nection network is oxidized, while the substrate contact pads are formed from a non-oxidyable material, preferably nickel/gold. The oxidized surface inhibits a flow of the solder bumps onto it, thereby enhancing an accurate self- alignment of the bumps and their associated circuit ele¬ ments on the substrate pads. To optimize performance at millimeter wave frequencies, the spacings between adjacent bumps are less than about 125 micrometers, and the pad widths are no greater than about 50 micrometers. As an alternate way to enhance the accuracy of the circuit ele¬ ment placement, the substrate may be coated with a passiva- tion layer in which openings are formed at the bump loca¬ tions, with the bumps extending through respective openings to contact the underlying interconnection network.
To provide the requisite rigidity for plastic sub¬ strates that are thinner than approximately 600 micro- meters, a low cost stiffening substrate is preferably ad¬ hered to the principal substrate. A compact transceiver device can be implemented by laminating two Duroid sub¬ strates back-to-back, with one of the substrates bearing a transceiver circuit and the other an antenna that communi- cates with the transceiver circuit through the substrates and preferably has a lower dielectric constant than the circuit substrate. A metal layer between the two sub¬ strates serves the dual function of a ground plane and a stiffening layer; a separate stiffening substrate may also be provided' over the flip-chip circuitry.
These and other features and advantages of the inven¬ tion will be apparent to those skilled in the art from the following detailed description, taken together with the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
FIGs. 1, 2 and 3 are fragmentary sectional views il¬ lustrating sequential steps in the fabrication of bump con¬ tacts on a flip-chip circuit; FIG. 4 is a fragmentary sectional view illustrating the flip-chip mounted on an interconnection substrate;
FIGs. 5 and 6 are respectively fragmentary sectional and plan views of an interconnection substrate with an oxi¬ dized lead which bears a non-oxidized bump contact pad; FIG. 7 is a perspective view of a circuit substrate in accordance with the invention that includes a passivation layer with bump contact openings and a stiffening backing;
FIG. 8 is a sectional view of a circuit substrate as in FIG. 7, with a pair of circuit chips flip-chip mounted to the substrate;
FIG. 9 is a perspective view of a dual substrate con¬ figuration with a flip-chip transceiver circuit on one side and an antenna on the opposite side;
FIG. 10 is an illustrative sectional view showing a flip-chip and a beam lead chip mounted to the structure of FIG. 9;
FIG. 11 is a sectional view of two substrates used in the formation of the dual substrate structure of FIG. 9;
FIG. 12 is a perspective view showing the antenna side of a dual antenna/circuit substrate; and
FIG. 13 is a perspective view showing the circuit side of the FIG. 12 structure.
DETAILED DESCRIPTION OF THE INVENTION The invention improves upon the reliability and cost of microwave/millimeter wave circuits by flip-chip mounting discrete active circuit elements to a novel substrate for this purpose. The invention overcomes the critical align¬ ment problems that would otherwise be expected to be an inhibiting factor in this high frequency range.
FIGs. 1-3 illustrate the formation of bonding pads on a flip-chip device. In FIG. 1 a flip-chip 2 that is formed from a semiconductor such as InP or GaAs is shown with its circuit side facing up, although the circuit itself is not illustrated in the figure. The circuit side of the chip is coated with a photoresist 4 that is patterned with openings within which contact pads 6 are formed in contact with the circuit. With Au used for the circuit interconnections, the pads are typically formed from Ti/Pt/Au or Ni/Au. Solder contact "bumps" (made from alloys such as tin- /lead) 8 are then plated up in the upper portion of the photoresist opening. While contact bumps per se are not new and are disclosed, for example, in Sakai et al., supra, the accuracy with which solder bump devices can be mounted to a substrate is inadequate for microwave/millimeter wave circuitry. The invention provides a more accurate device placement that permits alignment accuracy on the order of approximately 2 micrometers (with a transmission line-width of 125 micrometers) without any need for lengthy alignment by an automated system.
Once the solder bumps 8 have been plated up, the photoresist is removed as shown in FIG. 2. For compatibil¬ ity with microwave/millimeter wave frequencies, the bumps are typically 25 micrometers high and 50 micrometers wide, and in any event no more than about 100 micrometers wide, and the spacing between adjacent bumps on a given device are kept to typically about 150 micrometers. This con¬ trasts with typical prior flip-chip bump dimensions of 75 micrometers high and wide, and 250-375 micrometer between adjacent bumps.
After removal of the photoresist the bumps 8 are pre- flowed to give them a somewhat flattened contour, as illus¬ trated in FIG. 3. A preflow temperature of 220° C is suit¬ able for tin lead solder. The chip is then flipped over and mounted to a special substrate 12 that has unique char¬ acteristics as described below. The substrate carries a metallized interconnection network on its upper surface, typically a patterned copper network of which a pair of leads 10 are shown in FIG. 4. Pads 14 are provided on the substrate metallization at the desired contact sites; the substrate pads 14 will generally be similar to the chip pads 6. When the chip has been put in place, the solder pads 8 are heated and reflowed so that they adhere to, and form electrical contacts with, the substrate pads 14. The necessary heat can be provided by conventional techniques such as placing the assembly in a convection oven, flowing hot gas onto the chip or the use of a heat lamp. During the heating process the solder's surface tension tends to make the bumps self-align with the substrate pads 14. This is helpful in obtaining the necessary high placement accu¬ racy.
The placement accuracy is further improved by combin¬ ing an oxidizable substrate metallization with a non-oxi- dizable contact pad on that metallization. This structure is illustrated in FIGs. 5 and 6. The substrate metalliza¬ tion 10 is formed from a conventional material such as cop¬ per, while the contact pad 14' is formed from a material that does not oxidize (or that oxidizes at a substantially higher temperature than the metallization) . A nickel layer 16 covered by a gold layer 18 is preferred for this pur¬ pose; successive titanium, platinum and gold layers could also be used. The substrate is heated to form an oxide layer 20 over the metallization 10, but not over the con¬ tact pad 14' . When the solder bump is then reflowed onto the substrate contact pad 14' , the surrounding metalliza¬ tion oxide 20 prevents the solder from flowing onto the metallization, since the oxide presents a non-wettable sur¬ face to the solder. The pad thus presents a preferential wettable surface for the solder which enhances the self- alignment of the solder bump to the pad, and thus the pre¬ cision of the flip-chip placement on the substrate. A suitable tin lead solder reflow temperature range is 180°- 250° C.
An alternate approach to assuring precise device placement is illustrated in FIGs. 7 and 8. The substrate in this embodiment is a relatively thin layer 22 of a non- ceramic and non-semiconductor dielectric material that pro¬ vides special advantages and is discussed in greater detail below, backed by a stiffening substrate 24. The overall substrate is coated with a thin passivation layer 26, pref¬ erably a polyimide, that adheres to the substrate 22. Ar¬ rays of small openings 28 are formed through the passiva¬ tion layer, corresponding to the desired locations for the contact bumps 8 of the various flip-chips 2. The openings 28 are only slightly larger than the contact bumps, thus assisting in a precise alignment between the bumps and the metallization (not shown) on substrate 22 that underlies the passivation layer 26. This type of passivation layer has been used previously with flip-chips, but not to pro- vide the high precision device placements required for mi¬ crowave/millimeter wave operation.
The primary substrate 22 upon which the interconnec¬ tion network is formed for the various flip-chips consists of a non-ceramic and non-semiconductor dielectric material, preferably Duroid. As mentioned above, Duroid is inexpen¬ sive but has generally been considered too flexible for flip-chip applications. The invention attains the low cost benefits of a low-cost plastic substrate, but modifies the substrate structure so that it is compatible with flip-chip technology. " Such modification is necessary for substrate thicknesses less than about 600 micrometers, at which Du¬ roid normally does not have sufficient rigidity for flip- chip mounting. Other low cost materials that are similarly not ordinarily considered for flip-chip applications, such as composite resin based materials, could be used instead of Duroid, although Duroid is the most preferred.
For Duroid substrates that are too thin for flip-chip mounting, a stiffening substrate 24 is provided from a ma¬ terial that is separated from the electrical circuitry by the Duroid substrate 22, and therefore does not have to have the electrical properties normally associated with a flip-chip mounting substrate. This opens up a wide range of potential materials that can be used for the stiffener substrate, with the particular material selected for any given application generally depending on its cost, its stiffness properties and whether it will provide some elec¬ trical function for the device. Preferred stiffening sub¬ strates for this purpose are FR4, an industry standard plastic commonly used for the fabrication of surface boards, and polyimides. The Duroid and stiffener sub¬ strates are preferably laminated together through a heat/pressure process with a glue bond 30 between them. The lamination temperature will generally be about 250°- 300° C. FIG. 9 shows another application of the invention, in which two Duroid substrates are laminated together to form a double-sided high frequency device, with circuit elements on opposite faces. Passive circuit elements, such as transmission lines, bias circuits, antennas and power com- biners, can be fabricated directly on one or both sub¬ strates at low cost. The fabrication of such passive cir¬ cuit elements does not require very fine geometries and lithography steps, and as a result can be mass produced at low cost. Discrete active elements such as transistors, varactors, PIN-switches and diode mixers, as well as other passive components such as capacitors and resistors, can be added to one or both low cost substrates using flip-chip technology. In the example shown in FIG. 9, one of the substrates 32 bears an antenna 34, while the other sub- strate 36 bears transceiver circuitry associated with the antenna. This circuitry includes passive elements such as inductors 38, transmission lines 40 and contact pads 42 formed directly on the substrate, active elements such as a power HEMT (high electron mobility transistor) 44, var- actor 46, low noise HEMT 48, HBT (heterojunction bipolar transistor) 50 and PIN diode 52 secured by flip-chip mount¬ ing, and additional passive elements such as capacitor 54 and resistor 57 that are also secured by flip-chip mount¬ ing. A ground plane 56, preferably copper, separates the two substrates. The ground plane is preferably formed from copper and is patterned with an array of openings 58 (see FIG. 10) at the locations where communication between the transceiver circuitry and the underlying antenna is de- sired; the high frequency signals are transmitted between the antenna and its associated circuitry via the continuous dielectric paths that include these openings in the ground plane.
FIG. 10 shows only one illustrative flip-chip package 60 mounted to corresponding pads on the upper substrate 36. Also shown is a beam lead package 62, which is a conven¬ tional circuit package that is similar to a flip-chip but employs a conductive ring 64 around its edge rather than contact bumps on its under circuit surface. Beam lead de- vices are mounted in a manner similar to flip-chips, and for purposes of the invention can be considered to be equivalent to flip-chips.
FIG. 11 shows the two Duroid substrates 32 and 36 be¬ fore they are laminated together. Such substrates are con- ventionally"provided with metallization layers on both fac¬ es; the upper and lower metallization layers on substrates 32 and 36 are identified respectively as 32a, 32b and 36a. Prior to laminating the two substrates together, metal lay¬ er 36b is etched away. The antenna 34 is patterned from metallization layer 32b, the interconnection network for the transceiver circuitry is patterned from metallization layer 36a, and the inner metallization layer 32a is fused to the non-metallized surface of the substrate 36 to form the ground plane 56. Prior to joining the two substrates, ground plane openings 58 are formed in the metallization layer 32a. The bonding film (typically PTFE Bonding film) fills these openings during the fusion process.
In addition to functioning as a ground plane, the fused metallizations 32a and 36b stiffen the overall sub- strate and allow it to be thinner than would otherwise be the case in the absence of a stiffening substrate as shown in FIGs. 7 and 8. However, if additional stiffness is re¬ quired, a stiffening substrate can be added over the cir¬ cuit substrate 36, with cavities left in the stiffening substrate for the various electrical components.
The two substrates 32 and 36 can also be fabricated with different dielectric constants, if desired. For a self-contained antenna application, a lower dielectric con¬ stant for the antenna substrate 32 will help to prevent the field radiated from the antenna from being confined in the substrate, while a higher dielectric constant for the cir¬ cuit substrate 36 will reduce the reguired length of its transmission lines. Duroid-type materials with different dielectric constants are readily available. FIGs. 12 and 13 show a particular implementation of the self-contained antenna device illustrated in FIG. 9, with the antenna array 66 shown in FIG. 12 and the circuit¬ ry on the opposite face in FIG. 13. The substrates in this particular case are about 7.5 x 10 cm, with the antenna and circuit substrates 32 and 36 respectively 125 and 250 mi¬ crometers thick; all of these dimensions can vary depending upon the particular application. Each antenna communicates with the transceiver circuitry on the opposite side through openings (not shown) in the ground plane 56 that are aligned with the antenna input end 68a.
The transceiver circuit on the opposite side, shown in FIG. 13, includes five terminals 70 that communicate with different respective antennas on the opposite side of the substrates, and PIN diode switches 72 that provide switched connections between the terminals 70 and a 5:1 power com- biner 74. The power combiner is connected in turn to am¬ plifiers 76 and 78, with amplifier 76 providing a signal between mixers 80 and 82. A voltage controller oscillator (VCO) 84 supplies a reference frequency signal to a fre- quency doubler 86, the output of which is connected along with amplifier 78 to the mixers 80 and 82. The opposite mixer terminals from amplifier 76 are the in-phase (I) channel 88 and the quadrature (Q) channel 90. This type of antenna is particularly useful in automotive applications such as collison warning radar.
The invention provides low cost, high reliability cir¬ cuit structures for microwave and millimeter wave applica¬ tions, without the undesirable parasitic effects of prior high frequency structures. While particular embodiments of the invention have been shown and described, numerous vari¬ ations and alternate embodiments will occur to those skilled in the art. Such variations and alternate embodi¬ ments are contemplated, and can be made without departing from the spirit and scope of the invention as defined in the appended claims.

Claims

CLAIMS:
1. A microwave/millimeter wave circuit structure, comprising: a non-ceramic and non-semiconductor dielectric substrate (12) , an electrical interconnection network (10) on said substrate, and a plurality of discrete circuit elements (2) flip-chip mounted to said substrate and electrically inter¬ connected by said interconnection network, with spacings between the interconnected circuit elements compatible with electrical signals with wavelengths in at least part of the microwave/millimeter wave range.
2. The circuit structure of claim 1, wherein at least some of said discrete circuit elements include multi¬ ple bumps (8) that electrically contact and mechanically adhere to said interconnection network, with spacings on the order 150 micrometers between adjacent bumps.
3. The circuit structure of claims 1 or 2, said in¬ terconnection network comprising an oxidizing metal with an oxidized surface (20) , and further comprising an array of non-oxidizing conductive pads (14') on said oxidizing metal at the bump locations, with said bumps adhered to respec¬ tive pads.
4. The circuit structure of claims 1, 2 or 3, where¬ in said dielectric substrate is less than approximately 600 micrometers thick, further comprising a stiffening sub¬ strate (24) adhered to said dielectric substrate.
5. The circuit structure of claims 1, 2, 3 or 4, said structure comprising a transceiver circuit on a trans¬ ceiver substrate (36) , and further comprising an antenna substrate (32) with an antenna (34) formed on one side and adhered back-to-back with the transceiver substrate, said antenna communicating with said transceiver circuit through said substrates.
6. A method of fabricating a microwave/millimeter wave circuit structure, comprising: providing a non-ceramic and non-semiconductor dielectric substrate (12) with an electrical interconnec- tion network (10) and an array of conductive contact pads (14) at respective locations on said network, with pad di¬ mensions and spacings between said pads that are compatible with signal wavelengths in at least part of the micro¬ wave/millimeter wave range, providing a plurality of discrete circuit ele¬ ments (2) with contact locations on said elements that cor¬ respond to respective contact pad locations on said subs¬ trate, and flip chip mounting said circuit elements to said substrate with contact bumps (8) that mechanically and electrically connect said circuit element contact locations with respective contact pads on said substrate, with said contact pads self-aligning to their respective bumps during the mounting of said circuit elements.
7. The method of claim 6, wherein said bumps com¬ prise solder bumps that are preflowed on said circuit ele¬ ment prior to mounting said circuit elements on said sub¬ strate, and are reflowed during said mounting.
8. The method of claims 6 or 7, wherein said inter¬ connection network is formed from an oxidizable material and said pads are formed from a non-oxidizable material, further comprising the step of oxidizing the surface (20) of said interconnection network prior to mounting said cir¬ cuit elements to said substrate.
9. The method of claim 8, wherein said contact bumps are provided as solder bumps on said circuit elements and said circuit elements are mounted on said substrate by flowing said bumps onto said pads, the oxidized surface of said interconnection network inhibiting a flow of said sol¬ der bumps onto said surface and thereby self-aligning said bumps and their associated circuit elements on said pads.
PCT/US1996/011144 1995-07-07 1996-07-01 Microwave/millimeter wave circuit structure with discrete flip-chip mounted elements, and method of fabricating the same Ceased WO1997002733A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DE69637906T DE69637906D1 (en) 1995-07-07 1996-07-01 MICROWAVE / MILLIMETER SHAFT CIRCUIT STRUCTURE WITH SINGLE MOUNTED ELEMENTS OF THE FLIP CHIP TYPE AND MANUFACTURING METHOD THEREFOR
CA002198088A CA2198088C (en) 1995-07-07 1996-07-01 Microwave/millimeter wave circuit structure with discrete flip-chip mounted elements, and method of fabricating the same
EP96923570A EP0782766B1 (en) 1995-07-07 1996-07-01 Microwave/millimeter wave circuit structure with discrete flip-chip mounted elements, and method of fabricating the same
JP9505862A JPH10505466A (en) 1995-07-07 1996-07-01 Microwave / millimeter wave circuit structure having discrete elements mounted on flip chip and method of manufacturing the same
MXPA/A/1997/001735A MXPA97001735A (en) 1995-07-07 1997-03-07 Structure of circuit microwave-milimetric waves with discrete elements mounted in the form of micropastilla steering and method for the manufacture of the mi

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US5757074A (en) 1998-05-26
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US5629241A (en) 1997-05-13
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WO1997002733A3 (en) 1997-08-21
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JPH10505466A (en) 1998-05-26
CA2198088C (en) 2001-05-15

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