WO1997045571A3 - Alkoxylated dimercaptans as copper additives - Google Patents

Alkoxylated dimercaptans as copper additives Download PDF

Info

Publication number
WO1997045571A3
WO1997045571A3 PCT/US1997/008632 US9708632W WO9745571A3 WO 1997045571 A3 WO1997045571 A3 WO 1997045571A3 US 9708632 W US9708632 W US 9708632W WO 9745571 A3 WO9745571 A3 WO 9745571A3
Authority
WO
WIPO (PCT)
Prior art keywords
alkoxylated
dimercaptans
copper additives
additives
copper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1997/008632
Other languages
French (fr)
Other versions
WO1997045571A2 (en
Inventor
Sylvia Martin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MacDermid Enthone Inc
Original Assignee
Enthone OMI Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enthone OMI Inc filed Critical Enthone OMI Inc
Priority to DE69714446T priority Critical patent/DE69714446T2/en
Priority to EP97926652A priority patent/EP0912777B1/en
Priority to BR9709899-0A priority patent/BR9709899A/en
Priority to AU31365/97A priority patent/AU706220B2/en
Priority to AT97926652T priority patent/ATE221583T1/en
Priority to JP54269597A priority patent/JP3306438B2/en
Publication of WO1997045571A2 publication Critical patent/WO1997045571A2/en
Publication of WO1997045571A3 publication Critical patent/WO1997045571A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/38—Electroplating: Baths therefor from solutions of copper
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Engineering & Computer Science (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Push-Button Switches (AREA)
  • Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
  • Organic Insulating Materials (AREA)
  • Fodder In General (AREA)

Abstract

A copper electroplating process using alkoxylated dimercaptan ethers as an additive. The additives prevent dendritic formations which short out electrodes.
PCT/US1997/008632 1996-05-30 1997-05-15 Alkoxylated dimercaptans as copper additives Ceased WO1997045571A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
DE69714446T DE69714446T2 (en) 1996-05-30 1997-05-15 ALCOXYLATED MERCAPTAINS AS A COPPER ADDITIVE
EP97926652A EP0912777B1 (en) 1996-05-30 1997-05-15 Alkoxylated dimercaptans as copper additives
BR9709899-0A BR9709899A (en) 1996-05-30 1997-05-15 Alkoxylated dimercaptans as copper additives.
AU31365/97A AU706220B2 (en) 1996-05-30 1997-05-15 Alkoxylated dimercaptans as copper additives
AT97926652T ATE221583T1 (en) 1996-05-30 1997-05-15 ALKOXYLATED MERCAPTANS AS COPPER ADDITIVES
JP54269597A JP3306438B2 (en) 1996-05-30 1997-05-15 Alkoxylated dimercaptans as copper additives

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/656,410 US5730854A (en) 1996-05-30 1996-05-30 Alkoxylated dimercaptans as copper additives and de-polarizing additives
US08/656,410 1996-05-30

Publications (2)

Publication Number Publication Date
WO1997045571A2 WO1997045571A2 (en) 1997-12-04
WO1997045571A3 true WO1997045571A3 (en) 1998-02-19

Family

ID=24632921

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1997/008632 Ceased WO1997045571A2 (en) 1996-05-30 1997-05-15 Alkoxylated dimercaptans as copper additives

Country Status (14)

Country Link
US (1) US5730854A (en)
EP (1) EP0912777B1 (en)
JP (1) JP3306438B2 (en)
CN (1) CN1220709A (en)
AT (1) ATE221583T1 (en)
AU (1) AU706220B2 (en)
BR (1) BR9709899A (en)
CO (1) CO4780049A1 (en)
DE (1) DE69714446T2 (en)
ES (1) ES2181000T3 (en)
ID (1) ID17398A (en)
PE (1) PE38598A1 (en)
TW (1) TW432127B (en)
WO (1) WO1997045571A2 (en)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7244677B2 (en) 1998-02-04 2007-07-17 Semitool. Inc. Method for filling recessed micro-structures with metallization in the production of a microelectronic device
US6197181B1 (en) 1998-03-20 2001-03-06 Semitool, Inc. Apparatus and method for electrolytically depositing a metal on a microelectronic workpiece
TWI223678B (en) * 1998-03-20 2004-11-11 Semitool Inc Process for applying a metal structure to a workpiece, the treated workpiece and a solution for electroplating copper
US6565729B2 (en) * 1998-03-20 2003-05-20 Semitool, Inc. Method for electrochemically depositing metal on a semiconductor workpiece
JP2001073182A (en) * 1999-07-15 2001-03-21 Boc Group Inc:The Improved acidic copper electroplating solution
US6605204B1 (en) 1999-10-14 2003-08-12 Atofina Chemicals, Inc. Electroplating of copper from alkanesulfonate electrolytes
KR100366631B1 (en) 2000-09-27 2003-01-09 삼성전자 주식회사 Electrolyte for copper plating comprising polyvinylpyrrolidone and electroplating method for copper wiring of semiconductor devices using the same
US6776893B1 (en) 2000-11-20 2004-08-17 Enthone Inc. Electroplating chemistry for the CU filling of submicron features of VLSI/ULSI interconnect
US20040046121A1 (en) * 2001-07-15 2004-03-11 Golden Josh H. Method and system for analyte determination in metal plating baths
US20030049858A1 (en) * 2001-07-15 2003-03-13 Golden Josh H. Method and system for analyte determination in metal plating baths
US20030030800A1 (en) * 2001-07-15 2003-02-13 Golden Josh H. Method and system for the determination of arsenic in aqueous media
WO2003023395A1 (en) * 2001-09-12 2003-03-20 Microbar Systems, Inc. Enhanced detection of metal plating additives
US7025866B2 (en) * 2002-08-21 2006-04-11 Micron Technology, Inc. Microelectronic workpiece for electrochemical deposition processing and methods of manufacturing and using such microelectronic workpieces
US20050092611A1 (en) * 2003-11-03 2005-05-05 Semitool, Inc. Bath and method for high rate copper deposition
US7182849B2 (en) * 2004-02-27 2007-02-27 Taiwan Semiconducotr Manufacturing Co., Ltd. ECP polymer additives and method for reducing overburden and defects
CN101302635B (en) * 2008-01-18 2010-12-08 梁国柱 Steel member acidic electroplating additive for copper pre-plating and pre-plating process
DE102011008836B4 (en) * 2010-08-17 2013-01-10 Umicore Galvanotechnik Gmbh Electrolyte and method for depositing copper-tin alloy layers
JP5363523B2 (en) * 2011-03-28 2013-12-11 上村工業株式会社 Additive for electrolytic copper plating and electrolytic copper plating bath
JP6318719B2 (en) * 2014-03-10 2018-05-09 住友金属鉱山株式会社 Sulfuric acid copper electrolyte and method for producing dendritic copper powder using this electrolyte
JP6318718B2 (en) * 2014-03-10 2018-05-09 住友金属鉱山株式会社 Sulfuric acid copper electrolyte and method for producing granular copper powder using the electrolyte
CN114214677A (en) * 2021-12-30 2022-03-22 佛山亚特表面技术材料有限公司 Acidic copper plating deep hole agent, preparation method thereof and electroplating method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4376685A (en) * 1981-06-24 1983-03-15 M&T Chemicals Inc. Acid copper electroplating baths containing brightening and leveling additives
US5417841A (en) * 1990-08-03 1995-05-23 Mcgean-Rohco, Inc. Copper plating of gravure rolls

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3328273A (en) * 1966-08-15 1967-06-27 Udylite Corp Electro-deposition of copper from acidic baths
SE322956B (en) * 1966-08-20 1970-04-20 Schering Ag
GB1235101A (en) * 1967-05-01 1971-06-09 Albright & Wilson Mfg Ltd Improvements relating to electrodeposition of copper
FR2085243A1 (en) * 1970-04-01 1971-12-24 Peugeot & Renault
DE2039831C3 (en) * 1970-06-06 1979-09-06 Schering Ag, 1000 Berlin Und 4619 Bergkamen Acid bath for the galvanic deposition of shiny copper coatings
US3987246A (en) * 1970-07-21 1976-10-19 Electromitor, Inc. Apparatus for automatically sending data over a telephone system from a remote station to a central station
US3770598A (en) * 1972-01-21 1973-11-06 Oxy Metal Finishing Corp Electrodeposition of copper from acid baths
US3985784A (en) * 1972-07-10 1976-10-12 Oxy Metal Industries Corporation Thioether sulfonates for use in electroplating baths
GB1526076A (en) * 1975-03-11 1978-09-27 Oxy Metal Industries Corp Electrodeposition of copper
US4292155A (en) * 1979-10-31 1981-09-29 Ppg Industries, Inc. Cationic electrodeposition employing novel mercapto chain extended products
US4272335A (en) * 1980-02-19 1981-06-09 Oxy Metal Industries Corporation Composition and method for electrodeposition of copper
US4336114A (en) * 1981-03-26 1982-06-22 Hooker Chemicals & Plastics Corp. Electrodeposition of bright copper
US4347108A (en) * 1981-05-29 1982-08-31 Rohco, Inc. Electrodeposition of copper, acidic copper electroplating baths and additives therefor
US4683036A (en) * 1983-06-10 1987-07-28 Kollmorgen Technologies Corporation Method for electroplating non-metallic surfaces
GB8801736D0 (en) * 1988-01-27 1988-02-24 Ciba Geigy Ag Method of making patterns
US5219523A (en) * 1989-05-08 1993-06-15 Calgon Corporation Copper and copper alloy corrosion inhibitors
US5236626A (en) * 1990-09-24 1993-08-17 Calgon Corporation Alkoxybenzotriazole compositions and the use thereof as copper and copper alloy corrosion inhibitors
GB9114098D0 (en) * 1991-06-29 1991-08-14 Ciba Geigy Ag Method of making patterns
US5200057A (en) * 1991-11-05 1993-04-06 Mcgean-Rohco, Inc. Additive composition, acid zinc and zinc-alloy plating baths and methods for electrodedepositing zinc and zinc alloys
US5151170A (en) * 1991-12-19 1992-09-29 Mcgean-Rohco, Inc. Acid copper electroplating bath containing brightening additive
US5256275A (en) * 1992-04-15 1993-10-26 Learonal, Inc. Electroplated gold-copper-silver alloys
US5328589A (en) * 1992-12-23 1994-07-12 Enthone-Omi, Inc. Functional fluid additives for acid copper electroplating baths
AU682356B2 (en) * 1993-04-19 1997-10-02 Ga-Tek Inc. Process for making copper metal powder, copper oxides and copper foil
US5425873A (en) * 1994-04-11 1995-06-20 Shipley Company Llc Electroplating process

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4376685A (en) * 1981-06-24 1983-03-15 M&T Chemicals Inc. Acid copper electroplating baths containing brightening and leveling additives
US5417841A (en) * 1990-08-03 1995-05-23 Mcgean-Rohco, Inc. Copper plating of gravure rolls

Also Published As

Publication number Publication date
CN1220709A (en) 1999-06-23
TW432127B (en) 2001-05-01
EP0912777A2 (en) 1999-05-06
BR9709899A (en) 2000-01-25
JP2000511235A (en) 2000-08-29
ATE221583T1 (en) 2002-08-15
PE38598A1 (en) 1998-07-20
DE69714446T2 (en) 2002-11-14
AU706220B2 (en) 1999-06-10
AU3136597A (en) 1998-01-05
ES2181000T3 (en) 2003-02-16
ID17398A (en) 1997-12-24
US5730854A (en) 1998-03-24
EP0912777B1 (en) 2002-07-31
CO4780049A1 (en) 1999-05-26
DE69714446D1 (en) 2002-09-05
JP3306438B2 (en) 2002-07-24
WO1997045571A2 (en) 1997-12-04

Similar Documents

Publication Publication Date Title
ID17398A (en) CALCULATED THALOXOXATION AS COPPER ADDITIVE MATERIALS
EP1138805A3 (en) Tin electolyte
ZA9710875B (en) Flowability additive.
MY111132A (en) Copper etchant solution additives.
EP0607293A4 (en) Quick attach/detach connector.
EP0624924A3 (en) Conductive connector for switchgear.
EG21939A (en) Drilling quick connectors
EP0632623A3 (en) Adaptive maximum likelihood sequence estimator.
EP0817312A3 (en) Antenna apparatus
EP0644618A3 (en) Electrical connector with improved terminal latching means.
EP0638959A3 (en) Female electrical terminal.
TW392958U (en) Electronic card connector assembly
FR2668658B1 (en) LOW CURRENT SOCKETS FOR BUILDING PRE-CABLE.
AU2001294204A1 (en) Copper electroplating using insoluble anode
EP0637854A3 (en) Soldering terminal.
ZA994730B (en) Method for optimising flotation recovery.
EP0678867A3 (en) Charge pump circuit.
EP0681388A3 (en) Telephone line interface circuit.
FR2667449B1 (en) CONNECTOR FOR AN ARMORED COAXIAL CABLE.
MXPA01010570A (en) Process for electroplating a work piece coated with an electrically conducting polymer.
ZA974703B (en) Substituted sulfonylamino(thio)carbonyl compounds.
GB0012704D0 (en) Method for smelting copper sulfide concentrate
AU3044499A (en) Electroplating solution
EP0750549A4 (en)
GB2333904B (en) Component placement apparatus

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 97195088.1

Country of ref document: CN

AK Designated states

Kind code of ref document: A2

Designated state(s): AU BR CA CN JP KR RU SG TR

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE

AK Designated states

Kind code of ref document: A3

Designated state(s): AU BR CA CN JP KR RU SG TR

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 1997926652

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1997926652

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: CA

WWG Wipo information: grant in national office

Ref document number: 1997926652

Country of ref document: EP