WO1997048512A1 - Submerged nozzle for the continuous casting of thin slabs - Google Patents
Submerged nozzle for the continuous casting of thin slabs Download PDFInfo
- Publication number
- WO1997048512A1 WO1997048512A1 PCT/IT1997/000135 IT9700135W WO9748512A1 WO 1997048512 A1 WO1997048512 A1 WO 1997048512A1 IT 9700135 W IT9700135 W IT 9700135W WO 9748512 A1 WO9748512 A1 WO 9748512A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- diffuser
- baffle
- dip pipe
- cross
- section
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/50—Pouring-nozzles
Definitions
- the present invention relates to a feed dip pipe for the continuous casting of thin slabs and more in particular a submerged nozzle for guiding in the best way as possible a molten metal or alloy from a ladle having a nearly constant head for feeding the same, without turbulence or swirling, to a level underneath the head or meniscus of a slab being formed within a cooling mould in which the slab itself takes a shape by solidification.
- Thin slabs are known which are formed of four walls extending in vertical direction with horizontal cross-section having two sides of prevailing length with respect to the other two.
- connection conduit for introducing molten metal, especially steel, fed from a vessel above, into the inside of the mould, a connection conduit is used, being called “submerged", as its lower mouth is dipped in the molten bath within the mould and is adapted as much as possible to the thin size of the same mould in order to keep a sufficient distance from the cooling walls. Therefore dip pipes for thin slabs are usually employed in the technique as having in the lower portion horizontal cross-section of rectangular, polygonal or elliptical shape, with outlet boards directed the narrow sides and/or downwards.
- the lubricating slag will generally gather in the lower portions of the wave-shaped meniscus, while leaving the picks uncovered, with consequent lack of lubrication or poor distribution thereof, which gives rise to mould wear as well as a poor surface quality of the slab and incorrect thermal exchange of the forming slab with the mould, that is a cause of possible cracks.
- the zones where the fluid swirls come back again into the liquid bath show a marked bent of the meniscus, in which the particles of powder and lubricating slag are easily entrapped in the forming slab, thus providing an additional cause of cracks and other surface defects.
- the turbulence at the level of meniscus in the mould is also an important cause of wear for the nozzle the life of which is then reduced.
- the flow is accelerated until a point of cross-section reduction and then it is evenly slowed down while maintaining the lower portion of the diffuser filled with liquid.
- FIGURE 1 shows a longitudinal, sectional view of the nozzle according to the invention being immersed in a thin mould, taken in a median plane, parallel to the large faces of the mould itself;
- FIGURE 2 shows a longitudinal sectional view of the nozzle immersed in the mould, taken along a plane ll-ll parallel to the narrow faces of the mould;
- FIGURE 3 shows a sectional view along the line Ill-Ill of Figure 2.
- a dip pipe 1 feeds by gravity with a molten metal or alloy 2, contained in an upper ladle 3 having a nearly constant head, a slab 4 being formed at the inside of a thin mould 5, with cooling walls and formed of four walls extending in a vertical direction with a horizontal cross-section wherein two sides are of prevailing length with respect to the other two.
- the mould can have slightly convex or polygonal walls or even with a longitudinal trend slightly different from the perfectly vertical one represented in Figure 2, without departing from the features of the dip pipe according to the invention.
- the dip pipe comprises a length of vertical pipe of a circular cross- section, being connected to the upper ladle 3 in a known way.
- the dip pipe can be provided, at its upper portion, with a flow control surface 7, while downwards extends itself, through a fitting zone 18, with a flattened distributing portion, in the following called diffuser 8, having lower discharge 9, 9'.
- the diffuser 8 provides for feeding the molten material under the head 17, from which the term "dip" or "submerged”, at the inside of the slab 4 being formed in the thin mould 5 while keeping a given distance from the walls of the mould itself.
- the slab 4 being formed as being represented with solid walls of increasing thickness from the top to the bottom, while the inner core must be still considered liquid or however not yet completely solidified.
- a central baffle 14 is also provided, integral to both the larger walls of the diffuser, suitable to divide the flow in two distinct conduits 16, 16' ending with the two holes 9, 9' for discharging downwards.
- the flow passage cross-section 10, at the highest level of the diffuser height, at the end of the fitting portion 18 with the pipe 6, has been preferably represented coincident with the upper end of the baffle 14 although this is not an essential feature of the invention.
- the area of such a cross-section 10 is less than that corresponding to the cross-section area of the upper pipe 6, which has been indicated with reference numeral 11.
- This condition is better shown in Figure 2. It will be noted that, in spite of the fact that the side walls of fitting 18 appear to diverge downwards in Figure 1 , i.e. at the cross-section parallel to the large faces of the mould, in all the other sectional planes their are convergent, thus giving rise to a reduction of cross-section in the downward direction.
- the inner side walls 12, 12' of the diffuser 8 towards the narrow sides of the thin mould 5 are diverging downwards and form each with a vertical axis 13 from which they depart an angle ⁇ that is less than or equal to 7.5°.
- the flow partition baffle 14 is narrowing in its lower portion 15, 15' along the sides facing the narrow sides of the thin mould 5, by forming with the vertical axis 13 to angles ⁇ ⁇ 7.5°: It should be appreciated that angles ⁇ can be equal or different from angles ⁇ , provided that the above-mentioned conditions are met.
- the two passage conduits 16, 16' which- consequently are formed from opposite sides of the partition baffle 14, have a cross-section at right angles with the flow that is increasing in a downwards direction, but without making easier a flow detachment from the walls. Owing to the restriction imposed to angles ⁇ and ⁇ , a flow separation is avoided and the flow rate along the two conduits 16, 16' results to be the maximum technically obtainable in relation to the desired speed of outflow from the 7/48512 PCMT97/00135
- the dip pipe or nozzle according to the invention is substantially like it would present to the flow of molten material a compression chamber in correspondence with the cross-section 11 , more precisely between the latter and the reduced cross-section 10. Subsequently the flow has its maximum acceleration, then slowing down downstream, starting from cross-section 10, gradually along the two conduits 16, 16', but still preserving the continuity of contact with the walls. However it is convenient that the flow rate is still accelerated along the upper portion, with diverging faces of the baffle 14 in order to keep clear both conduits 16, 16' of any deposit of oxides, such a deposit already occurring in this zone at the presence of an excessive or too early slowing down of the flow.
- both conduits 16, 16' is still decreasing between the highest cross- section 10 of the diffuser and that of the maximum width of the baffle, it would be possible to obtain such a condition e.g. by imposing for the above-mentioned upper zone of the baffle 14, assuming that said edges 19, 19' are provided as shown in Figure 1 , that these are inclined by an angle > ⁇ . In this way the two upper zones of conduit 16, 16', where start to form by departing about the upper edges 19, 19' of baffle 14 will be slightly convergent before starting of the divergent zone in the actual diffuser 8.
- dip pipe 1 instead of being provided with a flow control surface 7, as indicated in Figures 1 and 2, could be directly flanged in a way per se known to the bottom of ladle 3, while the flow control surface could be provided on a different member, placed within the ladle itself.
- the pipe 1 could also be flanged, again in a way per se know, under a "drawer" of flow control placed on the bottom of ladle 3, acting in a known way by choking at the passage port between two holed and facing plates feeding one above the other.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
- Continuous Casting (AREA)
- Glass Compositions (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Laminated Bodies (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Glanulating (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
Description
Claims
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE69702984T DE69702984T2 (en) | 1996-06-19 | 1997-06-16 | SUBMERSIBLE PIPE FOR CONTINUOUSLY THIN SLAM |
| CA002257486A CA2257486C (en) | 1996-06-19 | 1997-06-16 | Submerged nozzle for the continuous casting of thin slabs |
| US09/194,687 US6152336A (en) | 1996-06-19 | 1997-06-16 | Submerged nozzle for the continuous casting of thin slabs |
| AT97928424T ATE195896T1 (en) | 1996-06-19 | 1997-06-16 | IMMERSION CASTING TUBE FOR CONTINUOUS CASTING OF THIN SLABES |
| JP50263898A JP3919228B2 (en) | 1996-06-19 | 1997-06-16 | Feeding immersion pipe for continuous casting of thin slabs |
| BR9709860A BR9709860A (en) | 1996-06-19 | 1997-06-16 | Immersed tube for gravity feeding |
| AU32726/97A AU717406B2 (en) | 1996-06-19 | 1997-06-16 | Submerged nozzle for the continuous casting of thin slabs |
| EP97928424A EP0925132B1 (en) | 1996-06-19 | 1997-06-16 | Submerged nozzle for the continuous casting of thin slabs |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI96A001243 | 1996-06-19 | ||
| IT96MI001243A IT1284035B1 (en) | 1996-06-19 | 1996-06-19 | DIVER FOR CONTINUOUS CASTING OF THIN SLABS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1997048512A1 true WO1997048512A1 (en) | 1997-12-24 |
Family
ID=11374446
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/IT1997/000135 Ceased WO1997048512A1 (en) | 1996-06-19 | 1997-06-16 | Submerged nozzle for the continuous casting of thin slabs |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6152336A (en) |
| EP (1) | EP0925132B1 (en) |
| JP (1) | JP3919228B2 (en) |
| CN (1) | CN1072538C (en) |
| AT (1) | ATE195896T1 (en) |
| AU (1) | AU717406B2 (en) |
| BR (1) | BR9709860A (en) |
| CA (1) | CA2257486C (en) |
| DE (1) | DE69702984T2 (en) |
| ES (1) | ES2150781T3 (en) |
| IT (1) | IT1284035B1 (en) |
| WO (1) | WO1997048512A1 (en) |
| ZA (1) | ZA974619B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1002600A3 (en) * | 1998-11-20 | 2001-04-04 | SMS Demag AG | Submerged nozzle for feeding molten metal into a mould for the continuous casting of thin material |
| WO2005021187A1 (en) * | 2003-08-27 | 2005-03-10 | Chosun Refractories Co., Ltd. | Submerged entry nozzle for continuous casting |
| CN100377815C (en) * | 2003-08-27 | 2008-04-02 | 朝鲜耐火株式会社 | Submerged nozzles for continuous casting |
| US7832460B2 (en) | 2005-04-07 | 2010-11-16 | Giovanni Arvedi | Process and system for manufacturing metal strips and sheets without discontinuity between continuous casting and rolling |
| WO2015189742A1 (en) * | 2014-06-11 | 2015-12-17 | Arvedi Steel Engineering S.P.A. | Thin slab nozzle for distributing high mass flow rates |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19724232C2 (en) * | 1997-06-03 | 1999-04-15 | Mannesmann Ag | Method and device for producing slabs |
| BE1013745A3 (en) * | 2000-10-10 | 2002-07-02 | Ct De Rech S Metallurg Ass San | Method and device for casting continuous steel chemical composition a mixed. |
| DE10203594C1 (en) * | 2002-01-23 | 2003-05-15 | Sms Demag Ag | Submerged nozzle for a metallurgical vessel located upstream of a casting device has a cross-section expanding from a circular inlet cross-section to an opening cross-section in the direction of its opening |
| KR20050113230A (en) * | 2003-03-17 | 2005-12-01 | 비수비우스 크루서블 컴패니 | Submerged entry nozzle with dynamic stabilization |
| SI1506827T1 (en) | 2003-08-01 | 2006-02-28 | Hof Te Fiennes N V | Casting system and method of casting non-ferrous metals |
| JP5026418B2 (en) | 2005-07-19 | 2012-09-12 | アルベディ,ジョバンニ | Production method and plant for steel products without interruption |
| ATE485897T1 (en) | 2005-07-19 | 2010-11-15 | Giovanni Arvedi | METHOD AND SYSTEM FOR PRODUCING STEEL PLATES WITHOUT INTERRUPTION |
| ATE450332T1 (en) * | 2006-05-11 | 2009-12-15 | Giovanni Arvedi | IMMERSION CASTING TUBE FOR CONTINUOUS CASTING OF STEEL |
| DE102009012985A1 (en) * | 2009-03-12 | 2010-09-23 | Salzgitter Flachstahl Gmbh | Casting nozzle for a horizontal strip casting plant |
| US8905335B1 (en) * | 2009-06-10 | 2014-12-09 | The United States Of America, As Represented By The Secretary Of The Navy | Casting nozzle with dimensional repeatability for viscous liquid dispensing |
| KR101170673B1 (en) * | 2010-01-18 | 2012-08-03 | 조선내화 주식회사 | Immersion nozzle for casting and continuous casting apparatus including the same |
| ITMI20112292A1 (en) | 2011-12-16 | 2013-06-17 | Arvedi Steel Engineering S P A | SUPPORT AND OSCILLATION DEVICE FOR LINGOTTER IN CONTINUOUS CASTING SYSTEMS |
| CN104057077A (en) * | 2014-07-08 | 2014-09-24 | 华耐国际(宜兴)高级陶瓷有限公司 | High-pulling-speed sheet billet immersion-type water opening |
| CN104907540B (en) * | 2015-06-15 | 2017-03-08 | 江苏大学 | A kind of method of the liquid pouring of electroslag continuous casting billet of strip steel water diverter |
| CN208976824U (en) * | 2017-05-15 | 2019-06-14 | 维苏威美国公司 | For casting the slab mouth of a river of slab made of metal and for the metallurgical component of cast metal slab |
| NZ764461A (en) * | 2017-12-04 | 2021-12-24 | Norsk Hydro As | Casting apparatus and casting method |
| TW202000340A (en) | 2018-06-07 | 2020-01-01 | 日商日本製鐵股份有限公司 | Device and method for controlling steel flow in mold for thin slab casting |
| CN214161385U (en) * | 2019-05-23 | 2021-09-10 | 维苏威集团有限公司 | casting nozzle |
| JP7367370B2 (en) * | 2019-07-31 | 2023-10-24 | セイコーエプソン株式会社 | Liquid injection device and method of controlling the liquid injection device |
| CN110918962A (en) * | 2019-11-18 | 2020-03-27 | 张家港宏昌钢板有限公司 | Retaining wall type continuous casting tundish |
| CN110695349B (en) * | 2019-11-21 | 2024-03-12 | 辽宁科技大学 | CSP sheet billet continuous casting high-pulling-speed submerged nozzle and manufacturing method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1989012519A1 (en) * | 1988-06-16 | 1989-12-28 | Davy (Distington) Limited | Refractory feed tube |
| DE4142447A1 (en) * | 1991-06-21 | 1992-12-24 | Mannesmann Ag | DIVE PIPE - DUENBREAD |
| WO1995029025A1 (en) * | 1994-04-25 | 1995-11-02 | Vesuvius Usa | Submergent entry nozzle |
| DE4436990C1 (en) * | 1994-10-07 | 1995-12-07 | Mannesmann Ag | Immersed pouring pipe where the outer wall acts as a spacer |
| EP0694359A1 (en) * | 1994-07-25 | 1996-01-31 | VOEST-ALPINE INDUSTRIEANLAGENBAU GESELLSCHAFT m.b.H. | An immersed casting tube |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1267284B1 (en) * | 1994-08-08 | 1997-01-28 | Danieli Off Mecc | CONTINUOUS CASTING UNLOADER |
| IT1267299B1 (en) * | 1994-09-30 | 1997-01-28 | Danieli Off Mecc | UNLOADER FOR CRYSTALLIZER FOR CONTINUOUS CASTING OF THIN Slabs |
-
1996
- 1996-06-19 IT IT96MI001243A patent/IT1284035B1/en active IP Right Grant
-
1997
- 1997-05-27 ZA ZA9704619A patent/ZA974619B/en unknown
- 1997-06-16 CA CA002257486A patent/CA2257486C/en not_active Expired - Lifetime
- 1997-06-16 JP JP50263898A patent/JP3919228B2/en not_active Expired - Lifetime
- 1997-06-16 ES ES97928424T patent/ES2150781T3/en not_active Expired - Lifetime
- 1997-06-16 DE DE69702984T patent/DE69702984T2/en not_active Expired - Lifetime
- 1997-06-16 BR BR9709860A patent/BR9709860A/en not_active IP Right Cessation
- 1997-06-16 US US09/194,687 patent/US6152336A/en not_active Expired - Lifetime
- 1997-06-16 CN CN97195649A patent/CN1072538C/en not_active Expired - Lifetime
- 1997-06-16 WO PCT/IT1997/000135 patent/WO1997048512A1/en not_active Ceased
- 1997-06-16 EP EP97928424A patent/EP0925132B1/en not_active Expired - Lifetime
- 1997-06-16 AU AU32726/97A patent/AU717406B2/en not_active Expired
- 1997-06-16 AT AT97928424T patent/ATE195896T1/en active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1989012519A1 (en) * | 1988-06-16 | 1989-12-28 | Davy (Distington) Limited | Refractory feed tube |
| DE4142447A1 (en) * | 1991-06-21 | 1992-12-24 | Mannesmann Ag | DIVE PIPE - DUENBREAD |
| WO1995029025A1 (en) * | 1994-04-25 | 1995-11-02 | Vesuvius Usa | Submergent entry nozzle |
| EP0694359A1 (en) * | 1994-07-25 | 1996-01-31 | VOEST-ALPINE INDUSTRIEANLAGENBAU GESELLSCHAFT m.b.H. | An immersed casting tube |
| DE4436990C1 (en) * | 1994-10-07 | 1995-12-07 | Mannesmann Ag | Immersed pouring pipe where the outer wall acts as a spacer |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1002600A3 (en) * | 1998-11-20 | 2001-04-04 | SMS Demag AG | Submerged nozzle for feeding molten metal into a mould for the continuous casting of thin material |
| WO2005021187A1 (en) * | 2003-08-27 | 2005-03-10 | Chosun Refractories Co., Ltd. | Submerged entry nozzle for continuous casting |
| CN100377815C (en) * | 2003-08-27 | 2008-04-02 | 朝鲜耐火株式会社 | Submerged nozzles for continuous casting |
| US7832460B2 (en) | 2005-04-07 | 2010-11-16 | Giovanni Arvedi | Process and system for manufacturing metal strips and sheets without discontinuity between continuous casting and rolling |
| WO2015189742A1 (en) * | 2014-06-11 | 2015-12-17 | Arvedi Steel Engineering S.P.A. | Thin slab nozzle for distributing high mass flow rates |
| RU2679664C2 (en) * | 2014-06-11 | 2019-02-12 | Арведи Стил Энджиниринг С.П.А. | Nozzle for molding thin slabs for distributing molten metal at high mass-flow rate |
| US10569326B2 (en) | 2014-06-11 | 2020-02-25 | Arvedi Steel Engineering S.P.A. | Thin slab nozzle for distributing high mass flow rates |
| TWI691371B (en) * | 2014-06-11 | 2020-04-21 | 美商維蘇威美國公司 | Thin plate nozzle for distributing high-quality flow |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69702984T2 (en) | 2000-12-28 |
| ITMI961243A0 (en) | 1996-06-19 |
| ITMI961243A1 (en) | 1997-12-19 |
| ES2150781T3 (en) | 2000-12-01 |
| JP2000512909A (en) | 2000-10-03 |
| DE69702984D1 (en) | 2000-10-05 |
| CA2257486C (en) | 2005-03-08 |
| CN1222104A (en) | 1999-07-07 |
| BR9709860A (en) | 1999-08-10 |
| CN1072538C (en) | 2001-10-10 |
| CA2257486A1 (en) | 1997-12-24 |
| US6152336A (en) | 2000-11-28 |
| AU3272697A (en) | 1998-01-07 |
| ATE195896T1 (en) | 2000-09-15 |
| ZA974619B (en) | 1998-01-23 |
| JP3919228B2 (en) | 2007-05-23 |
| AU717406B2 (en) | 2000-03-23 |
| EP0925132A1 (en) | 1999-06-30 |
| IT1284035B1 (en) | 1998-05-08 |
| EP0925132B1 (en) | 2000-08-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2257486C (en) | Submerged nozzle for the continuous casting of thin slabs | |
| US4819840A (en) | Refractory submerged pouring nozzle | |
| EP2226141B1 (en) | Casting Nozzle | |
| JP3662973B2 (en) | Discharge nozzle for continuous casting | |
| US3867978A (en) | Method and apparatus for introduction of steel into a continuous casting mold | |
| US5716538A (en) | Discharge nozzle for continuous casting | |
| RU2679664C2 (en) | Nozzle for molding thin slabs for distributing molten metal at high mass-flow rate | |
| KR100364687B1 (en) | Pouring spout | |
| EP1854571B1 (en) | Refractory nozzle for the continous casting of steel | |
| EP1657009A1 (en) | Improved submerged nozzle for steel continuous casting | |
| JPH1147897A (en) | Immersion nozzle for continuous casting of thin-wall wide slabs | |
| KR100485404B1 (en) | Partial Immersion Nozzle for Continuous Casting of Thin Slabs | |
| JP4289182B2 (en) | Tundish injection tube | |
| SK166399A3 (en) | Method and device for producing slabs | |
| RU2173608C2 (en) | Immersion pouring cup for continuous casting of thin slabs | |
| JPH04220148A (en) | Molten steel supplying nozzle | |
| EP4139069A2 (en) | Submerged nozzle with rotatable insert | |
| CA2473316A1 (en) | Casting system and method for pouring nonferrous metal molten masses | |
| KR101003940B1 (en) | Tundish, and method of manufacturing high purity metal strips | |
| US5662862A (en) | Device for guiding molten steel in a tundish | |
| JPH04238658A (en) | Immersion nozzle for continuous casting | |
| US20180154430A1 (en) | Continuous casting nozzle deflector | |
| RU2066592C1 (en) | Apparatus for line vacuum treatment of metal under continuous casting | |
| SU1015541A1 (en) | Method and apparatus for continuous casting of metals | |
| JPH03226340A (en) | Submerged nozzle for continuous casting |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WWE | Wipo information: entry into national phase |
Ref document number: 97195649.9 Country of ref document: CN |
|
| AK | Designated states |
Kind code of ref document: A1 Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GE HU IL IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK TJ TM TR TT UA UG US UZ VN YU ZW AM AZ BY KG KZ MD RU TJ TM |
|
| AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH KE LS MW SD SZ UG ZW AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE |
|
| DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
| WWE | Wipo information: entry into national phase |
Ref document number: 09194687 Country of ref document: US |
|
| ENP | Entry into the national phase |
Ref document number: 2257486 Country of ref document: CA Ref document number: 2257486 Country of ref document: CA Kind code of ref document: A |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 1019980710342 Country of ref document: KR |
|
| WWE | Wipo information: entry into national phase |
Ref document number: PA/A/1999/000106 Country of ref document: MX |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 1997928424 Country of ref document: EP |
|
| REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
| WWP | Wipo information: published in national office |
Ref document number: 1997928424 Country of ref document: EP |
|
| WWP | Wipo information: published in national office |
Ref document number: 1019980710342 Country of ref document: KR |
|
| WWG | Wipo information: grant in national office |
Ref document number: 1997928424 Country of ref document: EP |
|
| WWG | Wipo information: grant in national office |
Ref document number: 1019980710342 Country of ref document: KR |