WO1999043391A1

WO1999043391A1 - Fire retardant concentrates and methods for preparation thereof and use

Info

Publication number: WO1999043391A1
Application number: PCT/US1999/003946
Authority: WO
Inventors: Howard L. Vandersall; Gary H. Kegeler
Original assignee: Solutia Inc
Current assignee: Solutia Inc
Priority date: 1998-02-27
Filing date: 1999-02-24
Publication date: 1999-09-02
Anticipated expiration: 2000-08-27
Also published as: EP1056519A1; CA2321904A1; AR018294A1; ES2237910T3; DE69924980D1; AU762501B2; BR9908279A; ATE294011T1; US6322726B1; AU2784099A; ZA991547B; CA2321904C; EP1056519B1; TR200002512T2

Abstract

This invention comprises a concentrate further comprising a salt(s), a rheological modifier(s), an effective amount of a stabilizing compound selected from the group consisting of aliphatic carboxylic acids optionally substituted with one or more hydroxyl groups, aliphatic polycarboxylic acids optionally substituted with one or more hydroxyl groups, aliphatic and alicyclic organic compounds having at least three hydroxyl groups, glycols, mixtures thereof and the like and water which is present in an amount at least sufficient to solubilize the stabilizing compound(s) up to an amount at which said thickening compound is activated. This composition, upon dilution, after aging has the viscosity development characteristic(s) of a freshly diluted concentrate. If desired, this concentrate further comprises performance additives and other components and is preferably formulated for use in preparing a fire retardant concentrate.

Description

FIRE RETARD ANT CONCENTRATES AND METHODS FOR PREPARATION THEREOF AND USE

This invention relates to chemical fire retardants and more particularly to concentrates adapted for dilution with water to produce long-term fire retardant solutions comprising such concentrates.

BACKGROUND OF THE INVENTION

Agencies responsible for managing wildland eco systems in which accidental or natural fire is a significant concern often use long-term fire retardants in order to assist in extinguishing and controlling such fires so as to sustain only a minimum of damage. Such retardants can be applied from ground engines or aerially from helicopters and fixed wing aircraft. Fire retardants formulated for this purpose usually contain an ammonium phosphate, ammonium sulfate or mixtures thereof as the active fire retardant component. Such retardant formulations often contain, also, polygalactomannan gums to improve aerial application characteristics and cling of the fire retardant solution to the fuels on which they are applied. In addition, such formulations may contain coloring agents, corrosion inhibitors, bactericides and/or other such functional components as desired under use conditions.

One form of retardant is provided as a dry powder concentrate which, after delivery to the using location or using depot, is mixed with water and stored in a tank or tanks ready for transfer to the delivery vehicle when an emergency need arises.

When these dry powder retardant concentrates are mixed with water, the polygalactomannan gum(s) which they contain are readily activated as reflected by a change in the rheological properties of the resultant solution within two to ten minutes or so after initial contact during mixing or addition is made.

Another form of retardant is provided as an aqueous fluid concentrate wherein the polygalactomannan gum and other insoluble components are suspended in a concentrated solution of the fire retardant salt(s) and auxiliary components. When suspended in high ionic strength concentrated fluids of this type, the - 2 -

polygalactomannan gum(s) remains inactive with no significant change in rheological properties. The concentrated fluid retardant formulations are delivered to using locations and stored as the concentrate until a fire emergency occurs. The length of storage varies dependent on the situation, e.g., from within minutes of delivery during an active emergency to the next fire occurrence which may be a year or even more in the future. Activation of the polygalactomannan gum, which is suspended in the fluid concentrate formulation, is brought about when additional water is introduced to dilute the concentrate to prepare the use-level solution. The concentrated fluids are generally not diluted until such time as the emergency occurs and they are transferred directly, following dilution, to the delivery or application vehicle. Dilution water is frequently mixed with the concentrate in the plumbing system between the storage and loading areas. As with the dry-powder concentrates, the polygalactomannan gum suspended in the concentrate is activated by the dilution water resulting in the desired change in rheological properties within, at most, thirty minutes of bringing the two together.

Fire retardant solution prepared from either type of concentrate may be delivered to and applied for the intended purpose within a few minutes of being loaded or, on the other hand, the fire emergency may have changed prior to use of the diluted solution and consequently, the delivery vehicle may remain loaded or the solution may be transferred to an independent holding tank until the next need. This may be, perhaps, as long as thirty days or more after concentrate dilution and loading.

Some illustrative prior fire retardant compositions are described in United States Patent numbers 4,839,065; 4,971,728; and 4,983,326 all of which are incorporated herein in their entirety by reference.

In view of above described storage and use conditions, it is desired that (1) the fire retardant concentrate rapidly achieve the desired rheological characteristics so that it will perform as expected almost immediately after mixing or dilution with water and (2) the resultant fire retardant solution maintain these desirable rheological properties until use even if that does not occur for some time. - 3 -

United States Patent 3,077,879 which issued to Wesley A. Jordan on November 7, 1961, addresses the loss of viscosity during storage of high viscosity aqueous guar gum solutions and discloses methods said to be useful for preventing same. The instant invention, on the other hand, addresses the rate of initial viscosity development when guar gum containing concentrates and dilution water are brought together.

Achieving and maintaining the aforementioned desirable rheological properties in a dry powder concentrate type fire retardant is possible using current technology, i. e., the polygalactomannan gum(s) remain essentially unchanged during even long term storage in the dry powder. However, the rate of viscosity development of solutions prepared from concentrated fluid type retardants often varies dependent on the length and temperature of concentrate storage prior to dilution. The rate and extent of viscosity development is one measure of the desirable rheological characteristics of fire retardant solutions. In general, viscosity development becomes progressively slower with the length of storage and increasing storage temperature. This change can be of sufficient magnitude so as to render the solution less effective in its ability to free fall from the delivery vehicles to the fuel treatment area, for example, and to cling to and protect the threatened vegetation.

In view of the emergency nature of wildland fires which occur without notice, time is critical in delivering the fire retardant solution to the fire. In order to avoid delays, the fire retardant solution must develop the desired rheological properties rapidly when needed. Any delay in ability to be readily used for any reason could make such solutions less effective than desired. Thus the invention disclosed and claimed herein is a needed improvement in this area.

OBJECTS OF THE INVENTION

It is an object of this invention to provide a fluid type fire retardant concentrate whose critical rheological properties are not significantly affected by storage temperature and storage time.

It is another object of this invention to provide a fire retardant concentrate adapted to be diluted and useful for controlling, suppressing, and extinguishing fires which has rapid viscosity development characteristics even after storing at high temperatures for long periods.

It is yet another object to provide a fire retardant solution which exhibits sufficiently stable rheological properties to allow its use even when stored for significant periods after dilution.

These and other objects are met by the concentrates of this invention which are described in more detail hereinafter.

BRIEF SUMMARY OF THE INVENTION

This invention comprises a concentrate further comprising a salt(s), a rheological modifier(s), an effective amount of a stabilizing component selected from the group consisting of aliphatic carboxylic acids optionally substituted with one or more hydroxyl groups, aliphatic polycarboxylic acids optionally substituted with one or more hydroxyl groups, aliphatic and alicyclic organic compounds having at least three hydroxyl groups, glycols and mixtures thereof and the like and water present in at least an amount sufficient to solubilize any water soluble component(s) up to the amount at which said rheological modifier is activated or substantially activated. Preferably this composition, upon dilution after aging, has the initial viscosity development characteristics and other desirable rheological properties of a solution prepared by diluting a fresh, non-aged, fire retardant concentrate. If desired, this composition further comprises performance additives and other optional components.

The concentrates of this invention are useful in preventing, controlling and extinguishing fires in wildland fuels.

DETAILED DESCRIPTION OF THE INVENTION

The desired concentrate preferably exhibits a viscosity of less than about 2000 centipoise and contains between about 0.75% and about 6% by weight of a rheological modifier and at least about 24% by weight of fire retardant, salts, e.g., particularly diammonium phosphate, diammonium sulfate, a blend of diammonium phosphate and diammonium sulfate, a blend of monoammonium phosphate and diammonium phosphate having a nitrogen to phosphorus ratio of at least about 1.25, or a blend of monoammonium phosphate, diammonium sulfate and diammonium phosphate having a nitrogen to phosphorus ratio of at least about 1.25.

A rheological modifier is a substance which provides benefits such as increased viscosity, elasticity and the like. One or more rheological modifiers may be employed if desired according to use conditions.

In relation to use(s) as disclosed in United States Patent 4,839,065

('065), the salt employed herein is a water soluble fire retardant salt such as those disclosed above in the '065 patent. Preferably one or more such water soluble salts may be employed.

Useful salts include, but are not limited to mixed salt containing formulations. A mixed salt formulation is typically one which contains a mixture consisting of monoammonium phosphate and/ or diammonium phosphate and diammonium sulfate as the active fire retardant component and the like.

Illustrative nonlimiting rheological modifiers which may be employed herein include one or more thickening agent(s) disclosed in the'065 patent and in addition any rheological modifiers which, when used in a fire retardant composition of this invention, produces the beneficial viscosity development characteristics disclosed herein.

In practice, preferably, the respective stabilizing component(s) is added to the water of composition of the concentrated fluid retardant following dissolution of the fire retardant salt(s) therein but may be added at any time prior to the addition of the rheological modifier.

The stabilizing compound useful herein is selected from the group consisting of aliphatic carboxylic acids optionally substituted with hydroxyl groups, aliphatic polycarboxylic acids optionally substituted with hydroxyl groups, aliphatic and alicyclic organic compounds having at least three hydroxyl groups, glycols, mixtures thereof and the like. The stabilizing component(s) is one which, when employed in a composition of this invention, has sufficient water solubility that the benefits of the use of this invention are realized. Combinations of stabilizing components may be employed if desired although this is not required.

In providing the benefits of this invention, the utilized stabilizing component or its salt(s), reaction product(s) or mixture of such components modify the behavior of the rheological modifier incorporated in the concentrated fluid retardant so that the concentrated fluid retardant essentially retains its initial viscosity development characteristics.

Illustrative nonlimiting aliphatic carboxylic acids useful herein include those acids optionally substituted with one or more hydroxyl groups such as acetic acid, gluconic acid, formic acid, propionic acid, butyric acid, mixtures thereof and the like. A preferred aliphatic carboxylic acid is gluconic acid.

Illustrative nonlimiting aliphatic polycarboxylic acids optionally substituted with one or more hydroxyl groups useful herein include citric acid, tartaric acid, fumaric acid, maleic acid, malic acid, succinic acid, glutaric acid, adipic acid, saccharic acid, mixtures thereof and the like.

Preferably an aliphatic polycarboxylic acid useful herein is selected from the group consisting of tartaric acid, malic acid, fumaric acid, mixtures thereof and the like.

Illustrative nonlimiting aliphatic and alicyclic organic compounds useful herein are those having at least three hydroxyl groups such as sorbitol, d-arabitol, d-mannitol, pentaerythritol, sucrose, glycerol, galactose, lactose, maltose, fructose, glucose, mixtures thereof and the like. Of these, sorbitol, d-mannitol and glycol are preferred aliphatic and alicyclic organic compounds having at least three hydroxyl groups are especially useful herein.

An illustrative nonlimiting preferred alicyclic water soluble compound useful herein is sucrose. Typically the concentration of the stabilizing component or combination of stabilizing components in a concentrate of this invention ranges from about 0.01% to about 10% and preferably from about 0.1% to about 5%, although those of skill in the art will recognize that greater and lesser concentrations and amounts of stabilizing component may be employed in achieving the benefits of this invention. Those of skill in the art will also recognize that the benefits of the use of this invention may be greater when the concentration of the stabilizing component is greater as for example with citric acid and ethylene glycol. This will be apparent from a reading of this specification and the accompanying Tables 1-7.

A preferred concentrate of this invention is one wherein said fire retardant salt is a mixture of monoammonium phosphate, diammonium phosphate and diammonium sulfate, the rheological modifier is a polyhydroxylated guar gum and the stabilizing component is sorbitol.

Another preferred concentrate of this invention is one wherein said fire retardant salt is a mixture of monoammonium phosphate and diammonium phosphate, the rheological modifier is a polyhydroxylated guar gum and the stabilizing component is sorbitol or a mixture of sorbitol and citric acid.

Yet another preferred fire retardant concentrate of this invention is one wherein said fire retardant salt is a mixture of monoammonium phosphate and diammonium phosphate, the rheological modifier is a derivatized guar gum and the stabilizing component is tartaric acid.

Optional additives useful in a composition of this invention include but are not limited to those disclosed in United States Patents 4,839,065; 4,971,728 and 4,983,326.

Preferably, water is present in a concentrate of this invention in an amount at least sufficient to solubilize the stabilizing compound(s) up to an amount at which said thickening compound is activated. The fire retardant solution of this invention is prepared by admixing the fire retardant concentrate with an appropriate amount of water. The appropriate amount of water used in this mixture varies and is dependent on the fire retardant salt type and amount and the ratio of those other functional components contained in the concentrate formulation. The composition of the fire retardant solution is generally expressed in terms of the volume of water which is admixed with one volume of the concentrate. These compositions generally range from about three to about four volumes of water per volume of concentrate, i.e., 3:1 to 4:1, although those skilled in the art will recognize that greater and lesser ratios may be employed depending on the composition of the concentrate component and other factors which will become apparent from reading this specification. Preferably, the stabilizing component(s) are added to the concentrate prior to or simultaneous with the addition of a rheological modifier.

An effective amount of the composition of this invention comprises an effective amount of the salt, rheological modifier and stabilizing component to achieve the benefits of the use of this invention.

The resulting concentrate of this invention develops substantially the same desirable rheological properties, as illustrated by the rate and extent of viscosity development, both immediately after being prepared and after being stored at varying temperatures and for varying lengths of time. The term "substantially the same" as employed herein means that for purposes of the intended use herein that any differences between the viscosity development characteristic of an aged concentrate of this invention and a freshly diluted concentrate are minimal and not of significance to one of skill in the art in practicing this invention.

The following Examples are provided merely to better define and more specifically describe the teachings and embodiments of the present invention. These Examples are for illustrative purposes only, and it is recognized that minor changes and/or alterations might be made that are not immediately disclosed therein. It is to be understood that to the extent that any such changes do not materially alter the final product or its functionality, they are considered as falling within the spirit and scope of the invention as defined by the claims that follow. - 9 -

EXAMPLES

To further illustrate this invention, a series of fire retardant concentrates, each containing a fire retardant salt(s) component was prepared. Stabilizing component(s) identified in the first column in Tables 1-7, were employed as illustrative of a stabilizing compound individually in each concentrate. These concentrates were effective in providing the benefits of the use of this invention.

The stabilizing compound was added to water following dissolution of the fire retardant component therein but prior to or about the same time or at the same time as the addition of a rheological modifier. This produced a desired concentrate of this invention.

EXPERIMENTAL PROCEDURES

The water component of the concentrated fluid was placed in a high shear mixer and the other components added in the order listed below. In some instances the individual components were premixed and added as a single component. In that case the stabilizing compound was added to the composition just prior to the addition of the guar gum rheological modifier.

Water To 100.0

Carboxymethyl guar gum suspending agent 0.6

Color pigment 0.5 Diammonium sulfate 32.2

1 : 1 weight ratio of mono and diammonium phosphate 11.4

Tolyltriazole 0.1

Sodium molybdate 0.1

Tricalcium phosphate 0.7 Stabilizing compound Varied as per Tables 1 -7

Hydroxypropyl guar gum 2.6

Dimercaptothiadiazole 0.4

Polyglycol antifoaming additive 0.1 - 10 -

The stabilizing compound was added at a level of about 0.5% and/or about 1% by weight or more based on the total weight of the fire retardant concentrate.

In more detail, the proper amount of water is added to the mixing vessel and agitation is begun. A preweighed suspension agent, such as carboxymethyl guar, and a color pigment, when color is desired, is added to the water and agitation increased as viscosity of the solution develops. Agitation should be rapid enough to completely disperse the added reagents but not so rapid that a significant amount of air is entrapped in the solution. The actual agitation rate will vary with the type and geometry of the mixing chamber. Viscosity development (as measured with a Brookfield model RVT viscometer fitted with a No. 4 spindle and rotating at 60 rpm) is allowed to continue until a maximum is reached which will vary dependent on the amount of suspending agent included in the formulation. The maximum viscosity will generally be in the range of 500 to 3000 cps. The fire retardant salt(s) are then added to the relatively viscous water solution. The agitation rate is adjusted as necessary to obtain dispersion and dissolution without a significant amount of air entrapment or splashing from the vessel.

Other functional additives (corrosion inhibitors, flow conditioners, bactericides, antifoaming agents, etc.) can then be added individually or as a mixture which was prepared beforehand. The type and amount of these functional additives may be varied dependent on other compositional variables and the desired properties of the final product. While continuing agitation the gum thickener (rheological modifier) is added. The gum thickener may be a simple guar gum or a derivatized guar gum exemplified by hydroxypropyl guar gum. It is important that the gum thickener be added after essentially all other components have been added and dispersed or dissolved within the solution.

The mixture of fire retardant salts varied in composition as illustrated in Tables 1-7. TABLE 1. THE RATE OF VISCOSITY DEVELOPMENT OF FRESHLY PREPARED AND DILUTED FLUID CONCENTRATE RETARDANT - (Dilution ratio of 3.6 volumes of water per volume of concentrate.)

Stabilizing % in Viscosity (cps) after 70°F storage for indicated time after dilution. Compound Concentrate lO min. 30 min. 60 min. 1 da 3-5 da 7 days IS days 30 days

None 0.0 1381 1390 1375 1386 1378 1314

Sorbitol 0.5 1330 1337 1340 1350 1367 1353 1390 1323 1.0 1280 1293 1300 1303 1303 1310 1307 1280 Glycerol 0.5 1427 1440 1463 1503 1507 1490 1543 1500 1.0 1343 1340 1330 1393 1377 1397 1423 1347 Pentaeryt ritol 0.5 1380 1377 1383 1467 1420 1430 1447 1397 1.0 1360 1367 1580 1443 1413 1403 1420 1417 Sucrose 1.0 1463 1490 1513 1550 1563 1580 1540 1507 1.5 1503 1517 1530 1553 1567 1570 1530 1470 Ethylene glycol 0.5 1467 1493 1530 1540 1543 1537 1543 1513 1.0 1413 1440 1457 1503 1513 1483 1473 1447 2.0 1470 1470 1473 1457 1403 5.0 1473 1470 1483 1400 1483 d-arabitol 0.5 1487 1500 1500 1533 1557 1550 1533 1497 1.0 1497 1517 1533 1570 1597 1600 1573 1543 d-mannitol 0.5 1503 1550 1563 1630 1643 1603 1580 1543 1.0 1460 1463 1470 1527 1537 1510 1497 1477

Succinic acid 1.0 1503 1507 1513 1593 1587 1570 1547 1500 Malic acid 1.0 1527 1520 1547 1603 1610 1580 1537 1490 L-glutamic acid 1.0 1527 1503 1497 1553 1547 1540 1510 1493 O

H Fumaric acid 1.0 1373 1390 1413 1390 1403 1400 1383 1360 Benzoic acid 1.0 1497 1517 1540 1557 1550 1563 1550 1507 Gluconic acid 1.0 1547 1550 1537 1517 1543 1547 1513 1463

- indicates that data is not available.

TABLE 2. TTHHEE RRAATTEE ⁽ OF VISCOSITY DEVELOPMENT OF FLUID CONCENTRATE RETARDANT AGED AT 90°F

FFOORR 3300--3344 DDAYS PRIOR TO DILUTION. - (Dilution ratio of 3.6 volumes of water per volume of concentrate.) vo

VO

Stabilizing % in Viscosity (cps) after 70°F storage for indicated time after dilution. _

Compound Concentrate 10 min. 30 min. 60 min. 1 da 3-5 da 7 days 15 days 30 days VO

None 0.0 1083 1177 1223 1445 1523 1472

Sorbitol 0.5 1627 1723 1747 1760 1747 1697 1680 1600

1.0 1590 1643 1660 1710 1770 1663 1630 1557

Glyccrol 0.5 1443 1470 1503 1610 1607 1633 1610 1587

1.0 1473 1580 1627 1680 1667 1673 1603 1567

Pentaerythritol 0.5 1303 1383 1477 1543 1590 1587 1550 1513

1.0 1277 1407 1483 1593 1600 1600 1547 1493

Sucrose 1.0 1447 1593 1677 1670 1663 1800 1737 1707

1.5 1390 1453 1547 1673 1673 1683 1640 1623 to

Ethylene glycol 0.5 1293 1453 1533 1630 1617 1623 1590 1573

1.0 1333 1547 1530 1653 1660 1663 1657 1643

2.0 1520 1697 1720 1710 1687

5.0 1523 1633 1627 1753 1833 d-arabitol 0.5 1510 1667 1700 1710 1717 1700 1680 1667

1.0 1620 1703 1770 1753 1757 1690 1673 1640 d-mannitol 0.5 1500 1633 1677 1713 1683 1640 1633 1617

1.0 1637 1690 1720 1767 1730 1673 1660 1650

Succinic acid 1.0 1327 1460 1493 1753 1813 1813 1800 1667

Malic acid 1.0 1663 1717 1653 1727 1760 1803 1790 1560

L-glutamic acid 1.0 1297 1343 1483 1660 1707 1700 1693 1593

O

Fumaric acid 1.0 1303 1340 1403 1613 1593 1587 1587 1547 H

Benzoic acid 1.0 1220 1353 1447 1610 1680 1643 1613 1590 CΛ vo vo

Gluconic acid 1.0 1593 1747 1783 1780

1793 1670 1593 1550 © vo indicates that data is not available. σv

TABLE 3. THE RATE OF - viscosir Y DEVELOI 'MENT OF FLUID CONCENTRATE RETARDANT AGED AT 90°F

FOR 90-92 DAYS PRIOR TO DILUTION.(Dilution ratio of 3.6 volumes of water per volume of concentrate.)

Stabilizing % in Viscosity (cps) after 70°F storage for indicated time after dilution. ≥

Compound Concentrate 10 min. 30 min. 60 min. I day 3-5 day 7 days 15 days 30 days vo

None 0.0 533 619 708 1 127 ~ 1384 — 1458

Sorbitol 0.5 1353 1453 1480 1530 1580 1500 1530 1530

1.0 1617 1729 1687 1663 1770 1607 1640 1593

Glycerol 0.5 913 950 1027 1350 1437 1400 1383 1433

1.0 867 1023 1357 1490 1450 1433 1423 1467

Pentaerythritol 0.5 660 770 907 1300 1453 1420 1403 1457

1.0 533 670 767 1240 1367 1440 1437 1513

Sucrose 1.0 696 773 850 1200 1310 1420 1453 1390

1.5 500 637 723 1 143 1307 1407 1393 1363

Ethylene glycol 0.5 707 897 1000 1370 1400 1533 1580 1527

1.0 790 937 1003 1390 1417 1550 1537 1493

2.0 1290 1390 1527 1640 — — — 1777

5.0 1317 1373 1470 1603 — — — 1783 d-arabitol 0.5 1187 1357 1583 1510 1553 1590 1577 1533

1.0 1250 1337 1437 1557 1600 1557 1547 1530 d-mannitol 0.5 1143 1203 1267 1567 1580 1563 1573 1530

1.0 1273 1390 1473 1523 1587 1620 1573 —

Succinic acid 1.0 647 747 833 1297 1403 1623 1577 1470

Malic acid 1.0 1100 1 183 1247 1513 1550 1647 1637 1470

L-glutamic acid 1.0 543 600 800 1247 1457 1503 1497 1450 *3 o

Fumaric acid 1.0 950 1113 1 127 1410 1520 1603 1640 1437

Benzoic acid 1.0 570 680 777 1227 1423 1467 1483 1387 CΛ vo vo

Gluconic acid 1.0 1520 1603 1633 1673 1620 1647 1587 1467 indicates that data is not available. *-

TABLE 4. RATE OF VIS( :OSITY DE^ røLOPMENl ." OF FLUID » CONCEN1 rRATE RETARDANT A GED AT 90°F FOR

180-182 DAYS PRIOR TO DILUTION. (Dilution ratio of 3.6 volumes of water ^• per volume of concentrate.)

Stabilizing % in Viscosity ( cps) after 70°F storage forindicated time after dilution.

VO

Compound Concentrate 10 min. 30 min. 60 min. 1 day 3-5 day 7 days 15 days 30 days

None 0.0 256 315 396 701 891 1003 1071 1 182

Sorbitol 0.5 1003 1 120 1200 1410 1437 1413 1370 1373

1.0 1457 1500 1570 1600 1607 1590 1497 1490

Glyccrol 0.5 400 520 600 1020 1 170 1207 1247 1250

1.0 440 550 650 1037 1 170 1213 1260 1 150

Pentaerythritol 0.5 333 433 523 913 1073 1 150 1223 1 157

1.0 270 370 440 800 983 1023 1 180 1080

Sucrose 1.0 340 450 520 930 1 107 1 143 1150 1 117

1.5 320 410 510 930 1073 1 143 1 153 1 103

Ethylene glycol 0.5 350 440 527 930 1107 1 183 1 183 1203

1.0 390 500 580 983 1 147 1273 1227 1157

2.0 1090 1193 1307 1400 — — — 1577

5.0 1093 1180 1223 1313 — — - 1780 d-arabitol 0.5 630 770 870 1207 1293 1360 1360 1430

1.0 910 1060 1 120 1370 1460 1503 1387 1290 d-mannitol 0.5 820 980 1030 1330 1380 1467 1453 1340

1.0 1 1 10 1250 1320 1463 1490 1513 1470 1293

Succinic acid 1.0 260 340 420 857 1013 1237 1203 1057

Malic acid 1.0 700 820 900 1230 1317 1453 1347 1183

L-glutamic acid 1.0 280 400 480 887 1017 1220 1133 910 π H

Fumaric acid 1.0 870 980 1030 1 167 1370 1470 1463 1280 03 vo

Benzoic acid 1.0 270 350 420 700 1027 1053 11 17 1393

©

Gluconic acid 1.0 1370 1490 1520 1553 1543 1460 1470 1250

— indicates that data is not available. σ.

TABLE 5. RELATIVE EFFECTIVENESS OF STABILIZING COMPOUNDS IN FLUID

CONCENTRATE TYPE RETARDANTS. (Dilution ratio: 3.6 volumes water per volume concentrate.)

VO

Concentrate Storage @ 90°C % Retention of 10 min. Viscosity VO

*-

Stabilizing % in Fresh 30 days 90 days 180 days 30 days 90 days 180 days VO Compound Concentrate 10 minute Viscosity (cps)

None 0.0 1381 1083 533 256 78 39 19

Sorbitol 0.5 1330 1627 1353 1003 122 102 75

1.0 1280 1590 1617 1457 124 126 114

Glycerol 0.5 1427 1443 913 400 101 64 28

1.0 1343 1473 867 440 110 65 33

Pentaerythritol 0.5 1380 1303 660 333 94 48 24

1.0 1360 1277 533 270 94 39 20

Sucrose 0.5 1463 1447 696 340 99 48 23

1.5 1503 1390 500 320 92 33 21

Ethylene Glycol 0.5 1467 1293 707 350 88 48 24

1.0 1413 1333 790 390 94 56 28

2.0 1470 1520 1290 1090 103 88 74

5.0 1473 1523 1317 1093 103 89 74 d-arabitol 0.5 1487 1510 1187 630 102 80 42

1.0 1497 1620 1250 910 108 84 61 d-mannitol 0.5 1503 1500 1143 820 100 76 55

1.0 1460 1637 1273 1110 112 87 76

Succinic Acid 1.0 1503 1327 647 260 43 17

Malic Acid 1.0 1527 1663 1100 700 109 72 46 n

L-Glutamic Acid 1.0 1527 1297 543 280 85 36 18 H

Fumaric Acid 1.0 1373 1303 950 870 95 69 63 CΛ

Benzoic Acid 1.0 1497 1220 570 270 81 38 18 ©<_*>

Gluconic Acid 1.0 1547 1593 1520 1370 103 98 89 VO 4->

OS

- 16

TABLE 6. THE IMPACT OF STABILIZING COMPOUNDS ON THE RATE OF VISCOSITY DEVELOPMENT OF DILUTED FLUID CONCENTRATE TYPE RETARDANTS.

90°F Cone. Storage Before % of Original 30 min. Dilution (days) Viscosity Retained for

Initial Vise. Indicated Time (days)

Stabilizing (cps) 30 - 32 60 - 61 90 182

10 30 Viscosity 30 min. After Dilution

Compound min. min. (cps)**(See Attachment) 30 - 32 60 - 61 90 182

A. 45% Salt Containing Concentrates* (See Attachment) (Dilution ratio 4.0 volumes of water per volume of concentrate.) none 1770 1785 1370 1120 960 477 77 63 54 27

1.0% citric acid 1710 1740 1710 1560 1520 1297 98 90 87 75

B. 43.6% Salt Containing Concentrates

(Dilution ratio 3.6 volumes of water per volume of concentrate.) none 1463 1487 1247 840 663 84 56 45

0.5% citric acid 1410 1437 1310 830 610 91 58 42

0.5% NH4 citrate 1360 1340 1250 800 617 93 60 46

0.25% tartaric acid 1340 1333 1290 840 680 97 63 51

0.5% tartaric acid 1340 1367 1397 983 730 102 72 53

0.75% tartaric acid 1353 1370 1473 1147 873 108 84 64

1.0% tartaric acid 1313 1327 1580 1370 1223 119 103 92

1.0% Na tartrate 1340 1347 1467 1110 867 109 82 64

0.25% sorbitol 1407 1397 1420 1280 1107 102 92 79

0.5% sorbitol 1320 1330 1487 1513 1467 112 114 110

0.75% sorbitol 1297 1303 1477 1493 1477

113 115 113

0.5% each sorbitol and citric acid 1423 1440 1523 1677 1700 106 116 118

C. 40% Salt Containing Concentrates fDilution ratio 3.1 volumes of water per volume of concentrate.) none 1610 1620 1440 1330 1190 643 89 82 73 40

0.4% citric acid 1620 1625 1660 1540 1040 102 95 64

0.9% citric acid 1690 1690 1680 1660 1997 99 98 118

0.9% citric acid 1690 1710 1670 1760 1550 1513 98 103 91 88

1.0% citric acid 1640 1645 1637 1540 1610 1598 100 94 98 97

1.8% citric acid 1680 1685 1690 1740 1750 100 103 104

2.7% citric acid 1710 1700 1640 1710 1977 96 101 116

0.5% NH4 citrate 1690 1685 1530 1470 1213 91 87 72

1.0% NH4 citrate 1640 1650 1610 1600 1200 98 97 73

2.1% NH4 citrate 1640 1640 1680 1680 1520 102 102 93

0.9% acetic acid 1660 1660 1530 1460 1310 863 92 88 79 52

0.9% oxalic acid 1630 1690 1470 1380 1 140 590 87 82 67 35

1.0% tartaric acid 1590 1610 1680 1790 1680 1520 104 1 1 1 104 94 1.2% teφhthalic aci 1690 1690 1520 1410 1200 723 90 83 71 43 0.2% sorbitol 1630 1650 1590 1530 1570 1047 96 93 95 63

0.1% glycerol 1600 1630 1480 1400 1230 690 91

86 75 42 - 17 - TABLE 6. ATTACHMENT

% salt values refer to the percent of fire retardant salt in the concentrated fluid where 74% is diammonium sulfate and 26% is ammonium phosphate.

** During aging, the concentrate is stored in a closed container to prevent evaporation and contamination. In the studies described herein, an aging temperature of 90°F was chosen since this temperature is considered the highest which would generally be encountered by the concentrated fluid during that period of storage prior to dilution and use. The impact of concentrate aging on the viscosity development of its diluted solution is determined by periodic dilution of the concentrate through an aging period as illustrated in Tables 5-7.

TABLE 7. EFFECTIVENESS OF SORBITOL AS A STABILIZING COMPOUND IN PHOSPHATE-BASED FLUID CONCENTRATE RETARDANTS w vo

Stabilizing Length of Concentrate Storage Before Dilution (days)* Compound 0 33 95 128 180

10 minute Viscosity (cps)

A. 72°F CONCENTRATE STORAGE none 1383 1280 1230 1190

1.0% sorbitol 1553 1490 1583 1413

B. 90°F CONCENTRATE STORAGE none 1383 1217 1023 993

1.0% sorbitol 1553 1500 1620 1547

* Dilution involves admixing 4.0 volumes of water with 1.0 volume of the concentrated fluid retardant.

o

H

CΛ vo v --o o_^ w

*-

- 19 -

The amount of water employed in these concentrates was at least that amount sufficient to solubilize the water soluble components in the formulation up to that amount at which the thickening compound was activated as indicated by a perceptible increase in solution viscosity

The concentrated fluid is diluted, aged and tested as follows. Aliquots are taken from the homogenized concentrate and mixed with water at a predetermined ratio dependent on the salt content of the solution and the desired level of fire retardant effectiveness of the resultant solution. The ratio of dilution water to concentrate generally ranges from about 3 : 1 to about 4:1 or so. The water and concentrate are mixed together with sufficient agitation to ensure the preparation of a homogeneous solution.

Immediately after preparation, the concentrate is mixed with water in the manner described above to prepare the diluted solution and viscosity development measured as a function of time thereafter. Viscosity of the diluted solution is measured using a Brookfield Model RVT viscometer fitted with either a No.2 or No. 4 spindle (dependent on the viscosity level of the solution) rotating at 60 φm. Viscosity development is determined via periodic measurements from 10 minutes to 30 days following dilution as illustrated in Tables 1-4. During this 30 day storage period, the diluted solution is stored at 70°F.

The solution viscosity data was determined from about 10 minutes to about 24 hours after dilution of the un-aged concentrate and is considered herein in connection with this invention as the viscosity development characteristic(s) of a freshly diluted concentrate.

After removal of the dilution aliquot, the remainder of the concentrate was placed in a tightly sealed glass jar and maintained at about 90°F during subsequent aging for 30, 90 and 180 days.

At each respective aging period, e.g., 30 days, 90 days, 180 days, an additional aliquot of the aged concentrate was diluted with water to prepare a diluted solution in the manner described above. The viscosity development of this solution - 20 -

was then measured as a function of time during storage at about 70 °F as indicated in the Tables 1-7.

The viscosity development characteristics of diluted solution prepared from aged concentrate was compared to the viscosity development characteristics of diluted solution prepared from fresh concentrate. Effective stabilizing compounds, i.e., those which achieve the object of this invention, reduce the difference in viscosity development obtained when fresh and aged concentrate are diluted. A preferred stabilizing compound(s) is one which, upon use, results in the least difference in viscosity development characteristics over the longest aging period.

Although the invention has been described in terms of specific embodiments which are set forth in considerable detail, it should be understood that this description is by way of illustration only and that the invention is not necessarily limited thereto since alternative embodiments and operating techniques will become apparent to those skilled in the art in view of the disclosure. Accordingly, modifications are contemplated which can be made without departing from the spirit of the described invention.

Claims

- 21 -CLAIM OR CLAIMSWHAT IS CLAIMED IS:

1. A concentrate comprising: a. a fire retardant salt(s) component, b. a rheological modifier(s), c. an effective amount of a stabilizing compound selected from the group consisting of aliphatic carboxylic acids optionally substituted with one or more hydroxyl groups, aliphatic polycarboxylic acids optionally substituted with one or more hydroxyl groups, aliphatic and alicyclic organic compounds having at least three hydroxyl groups, glycols and mixtures thereof and d. water present in an amount at least sufficient to dissolve the water soluble component(s) up to an amount at which said thickening compound is activated, and e. wherein said composition upon dilution after aging has the viscosity development characteristic(s) of a freshly diluted concentrate.

2. The concentrate of claim 1, wherein said concentrate further comprises performance additives and other components.

3. The concentrate of claims 1 or 2, wherein said concentrate is formulated for use in preparing a fire retardant concentrate and is adapted to be diluted.

4. The concentrate of claim 3 wherein said concentrate is a fire retardant and said salt is a fire retardant salt.

5. The concentrate of claim 2 wherein said stabilizing compound is an aliphatic carboxylic acid optionally substituted with one or more hydroxyl groups.

The concentrate of claim 5 wherein said aliphatic carboxylic acid optionally substituted with one or more hydroxyl groups is selected from the group consisting of acetic acid, gluconic acid , formic acid, propionic acid, butyric acid, and mixtures thereof. - 22 -

7. The concentrate of claim 6 wherein said aliphatic carboxylic acid is gluconic acid.

8. The concentrate of claim 2 wherein said stabilizing compound is an aliphatic polycarboxylic acid optionally substituted with one or more hydroxyl groups.

9. The concentrate of claim 8 wherein said stabilizing compound is selected from the group consisting of citric acid, tartaric acid, fumaric acid, maleic acid, malic acid, succinic acid, glutaric acid, adipic acid, saccharic acid, and mixtures thereof.

10. The concentrate of claim 9 wherein said water soluble compound is selected from the group consisting of tartaric acid, malic acid, and fumaric acid and mixtures thereof.

11. The concentrate of claim 2 wherein said water soluble compound is selected from aliphatic and alicyclic organic compounds having at least three hydroxyl groups.

12. The concentrate of claim 11 wherein said water soluble compound is selected from aliphatic organic compounds having at least three hydroxyl groups.

13. The concentrate of claim 11 wherein said water soluble compound is selected from alicyclic organic compounds having at least three hydroxyl group.

14. The concentrate of claim 11 wherein said water soluble compound is selected from the group consisting of sorbitol, d-arabitol, d-mannitol, pentaerythritol, sucrose, glycerol, galactose, lactose, maltose, fructose, glucose, and mixtures thereof.

15. The concentrate of claim 14 wherein said water soluble compound selected from sorbitol, d-mannitol, glycerol and mixtures thereof. - 23 -

16. The concentrate of claim 1 wherein said fire retardant salt is selected from the group consisting of diammonium phosphate, diammonium sulfate, a blend of diammonium phosphate and diammonium sulfate, a blend of monoammonium phosphate and diammonium phosphate having a nitrogen to phosphorus ratio of at least about 1.25, or a blend of monoammonium phosphate, diammonium sulfate and diammonium phosphate having a nitrogen to phosphorus ratio of at least about 1.25.

17. The concentrate of claim 16 wherein said fire retardant salt is selected from the group consisting of diammonium phosphate, diammonium sulfate, a blend of diammonium phosphate and diammonium sulfate, a blend of monoammonium phosphate and diammonium phosphate having a nitrogen to phosphorus ratio of at least about 1.25

18. The concentrate of claim 17 wherein said fire retardant salt is a mixture of monoammonium phosphate, diammonium phosphate and ammonium sulfate, the rheological modifier is hydroxypropyl guar gum and the stabilizing compound is sorbitol.

19. The concentrate of claim 17 wherein said fire retardant salt is a mixture of monoammonium phosphate, diammonium phosphate and ammonium sulfate, the rheological modifier is a non-derivatized guar gum and the stabilizing compound is sorbitol.

20. The concentrate of claim 17 wherein said fire retardant salt is a mixture of monoammonium phosphate and diammonium phosphate, the rheological modifier is hydroxypropyl guar gum and the stabilizing compound is sorbitol.

21. The concentrate of claim 17 wherein said fire retardant salt is a mixture of monoammonium phosphate and diammonium phosphate, the rheological modifier is a non-derivatized guar gum and the stabilizing compound is sorbitol. - 24 -

22. The concentrate of claim 18 wherein said fire retardant salt is a mixture of monoammonium phosphate, diammonium phosphate and ammonium sulfate, the rheological modifier is hydroxypropyl guar gum and the stabilizing compound d-arabitol.

23. The concentrate of claim 19 wherein said fire retardant salt is a mixture of monoammonium phosphate, diammonium phosphate and ammonium sulfate, the rheological modifier is a non-derivatized guar gum and the stabilizing compound is d-arabitol.

24. The concentrate of claim 20 wherein said fire retardant salt is a mixture of monoammonium phosphate and diammonium phosphate, the rheological modifier is hydroxypropyl guar gum and the stabilizing compound is d-arabitol.

25. The concentrate of claim 21 wherein said fire retardant salt is a mixture of monoammonium phosphate and diammonium phosphate, the rheological modifier is hydroxyl guar gum and the stabilizing compound is d-arabitol.

26. The concentrate of claim 18 wherein said fire retardant salt is a mixture of monoammonium phosphate, diammonium phosphate and ammonium sulfate, the rheological modifier is hydroxypropyl guar gum and the stabilizing compound d-mannitol.

27. The concentrate of claim 19 wherein said fire retardant salt is a mixture of monoammonium phosphate, diammonium phosphate and ammonium sulfate, the rheological modifier is a non-derivatized guar gum and the stabilizing compound is d-mannitol.

28. The concentrate of claim 20 wherein said fire retardant salt is a mixture of monoammonium phosphate and diammonium phosphate, the rheological modifier is hydroxypropyl guar gum and the stabilizing compound is d-mannitol. - 25 -

29. The concentrate of claim 21 wherein said fire retardant salt is a mixture of monoammonium phosphate and diammonium phosphate, the rheological modifier is a non-derivatized hydroxyl guar gum and the stabilizing compound is d-mannitol.