WO1999052829A1 - A method and a device for the treatment of water - Google Patents

A method and a device for the treatment of water Download PDF

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Publication number
WO1999052829A1
WO1999052829A1 PCT/DK1999/000186 DK9900186W WO9952829A1 WO 1999052829 A1 WO1999052829 A1 WO 1999052829A1 DK 9900186 W DK9900186 W DK 9900186W WO 9952829 A1 WO9952829 A1 WO 9952829A1
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WO
WIPO (PCT)
Prior art keywords
drops
water
wire
shaped elements
pipe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/DK1999/000186
Other languages
French (fr)
Inventor
Finn Lebech
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unicon Beton Holding AS
Original Assignee
Unicon Beton Holding AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unicon Beton Holding AS filed Critical Unicon Beton Holding AS
Priority to DK99911639T priority Critical patent/DK1070022T3/en
Priority to AT99911639T priority patent/ATE227696T1/en
Priority to AU30254/99A priority patent/AU3025499A/en
Priority to EP99911639A priority patent/EP1070022B1/en
Priority to DE69903931T priority patent/DE69903931T2/en
Publication of WO1999052829A1 publication Critical patent/WO1999052829A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/02—Aerobic processes
    • C02F3/04—Aerobic processes using trickle filters
    • C02F3/043—Devices for distributing water over trickle filters
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/74—Treatment of water, waste water, or sewage by oxidation with air
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/02—Aerobic processes
    • C02F3/04—Aerobic processes using trickle filters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/10—Biological treatment of water, waste water, or sewage

Definitions

  • the crude water is aerated according to the prior art to add to the water a greater content of oxygen which contributes to the conversion of iron and manganese bicarbonate into sparingly soluble compounds, ferrous hydroxide and py- rolusite and causes separation of C0 2 , hydrogen sulphide and methane.
  • the aeration takes place e.g. in that the water is introduced over a perforated tray and drops freely from there as drops toward a basin, or in that the water flows down over oxidation steps.
  • the object of the present invention is to provide a method by means of which crude water may be treated to achieve a satisfactory water quality with respect to content of components which can be removed or at least reduced by aeration.
  • such a method comprises an initiating formation of drops from an introduced water amount and division of the formed drops by mechanical action to form microdrops .
  • Such a formation of microdrops results in a considerably larger surface of the drops relative to the volume of the drops, and improved oxidation can thus take place.
  • the mechanical action ensures that the intended division takes place. It has been found that a division of 50-60 times or optionally more causes formation of drops of a size which is sufficiently small for a satisfactory oxi- dation to take place, and thereby for a satisfactory water quality to be obtained.
  • a microorganism culture may additionally be added to the water prior to the initiating drop formation.
  • components of the crude water which are not converted by the oxidation alone may moreover be removed or reduced by the metabolism of the microorganisms.
  • the concrete microorganism culture may be selected depending on the crude water content of components whose amount is to be reduced.
  • the formed microdrops are introduced into a sedimentation container after completed oxidation. After settling in such a container the water may be conveyed to the user.
  • the invention also relates to an apparatus for performing the method described in the foregoing.
  • Such an apparatus comprises means for forming drops at the initiation of the process, and, in the direction of the gravitational force below these means, additional means for causing division of the drops by contact with these.
  • the means for the initiating drop formation comprise a plate with holes, the drops being formed by the flow of the water through these holes.
  • the means for causing division of the drops preferably comprise wire-shaped elements mutually spaced in the direction of the gravitational force.
  • the wire-shaped elements are hereby advantageously arranged in a mutually intersecting pattern.
  • Such a structure involves a good certainty of drop division, and it has moreover been found by tests that good environmental conditions are hereby formed for an optionally added microorganism culture.
  • At least 50-60 layers of the mutually spaced wire- shaped elements are preferably arranged in the direction of the gravitational force to obtain an expedient fine division of the drops, as described above.
  • more of these layers are arranged so that also the drops which statistically drop through a layer in a gap between two wire-shaped elements, will obtain a division of 50-60 times.
  • 70-80 layers of wire-shaped elements are expediently arranged.
  • the mutual spacing between parallel or substantially parallel wire-shaped elements in the same layer is expedi- ently between 5 and 15 mm, preferably about 10 mm. The spacing between the wires in the same layer will affect the statistical fall of drops, which are thus not divided as there is no contact. A too small spacing between the wires may cause gathering of already divided drops.
  • the mutual spacing between the layers of wire-shaped elements is preferably 30-60 mm, and more preferably 40-50 mm. This ensures that sufficient kinetic energy is added to the drops for rotation to take place, while ensuring that a complete system still has a limited height.
  • means are arranged in the apparatus for collecting the microdrops below the means for dividing the drops.
  • the drops or the caught drops, which form an amount of water, are expediently introduced into a settling container, which forms part of the apparatus in this connection.
  • fig. 1 shows an apparatus, seen from the side
  • fig. 2 shows an apparatus, seen from above, and
  • fig. 3 shows a pipe element associated with the apparatus shown in figs. 1 and 2, and
  • fig. 4 shows four interconnected pipe elements, as shown in fig. 3 and seen from the end.
  • Fig. 1 illustrates a system which uses apparatuses according to the invention for performing the method according to the invention.
  • a system comprises a pipe connection 1 from a bore well and a pump 2 for pumping the water from the bore well.
  • the crude water is conveyed via the pipe 1 to a distribution system consisting of a plate 3 with holes 4.
  • This plate 3 with holes 4 serves to initiate formation of drops. Relatively large drops are involved in this connection.
  • the drops leaving the plate 3 through the holes 4 in it then fall down under the ac- tion of gravity and hereby contact rows of wire-shaped elements, which, in the example shown, are formed by tubular elements 5, 6 arranged side by side with horizontal pipe axes to form pipe layers, a plurality of such pipe layers being arranged on top of each other.
  • the pipe lay- ers are arranged such that every second pipe layer 6 is rotated 90°. In the structure shown, 15 pipe layers are provided. In this constellation, in the event that a large content of components is to be reduced, it will be necessary to recirculate the water to achieve sufficient oxidation. As also mentioned in the preamble to the description, 30-40 pipe layers will expediently be provided.
  • the pipe layers are arranged in a housing 7 which is open at the top and at the bottom. When the water drops leave the lowermost pipe layer at the lower end of the housing 7, the water is collected in a collection basin or a settling container 8, in which solids, if any, can precipitate, and from which the cleaned water may be discharged and transported to the place of use.
  • Fig. 2 shows the plate 3 more clearly seen from above.
  • the holes 4 have a diameter of about 1-2 mm. This diameter may be selected depending on the surface tension of the water, the water pressure, etc.
  • Fig. 3 shows a pipe element which is used for the construction of the pipe layers in the housing.
  • the pipe layers are composed of wire-shaped elements 9 which are arranged in intersecting manner in the pipe wall. By their mutually intersecting pattern, the wire-shaped ele- ments 9 form rhomboid holes in the pipe wall.
  • Fig. 4 shows four such pipe elements in an interconnected state. It appears that circular pipe elements 5 are involved.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Physical Water Treatments (AREA)
  • Biological Treatment Of Waste Water (AREA)
  • Water Treatment By Sorption (AREA)
  • Removal Of Specific Substances (AREA)
  • Excavating Of Shafts Or Tunnels (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)

Abstract

The invention relates to treatment of water, comprising initiating formation of drops from an introduced amount of water and division of the formed drops to form microdrops preferably by division at least 50-60 times. The invention also relates to an apparatus for performing the invention.

Description

A method and a device for the treatment of water
In connection with the treatment of water, the crude water is aerated according to the prior art to add to the water a greater content of oxygen which contributes to the conversion of iron and manganese bicarbonate into sparingly soluble compounds, ferrous hydroxide and py- rolusite and causes separation of C02, hydrogen sulphide and methane. According to the prior art, the aeration takes place e.g. in that the water is introduced over a perforated tray and drops freely from there as drops toward a basin, or in that the water flows down over oxidation steps.
These known methods have some effect on the water in respect of achieving the intended result, as described above. However, in many cases this treatment is not sufficient. In many cases the insufficiency is caused by an ever poorer crude water quality with a larger content of harmful substances, which must be removed, e.g. by aeration.
Accordingly, the object of the present invention is to provide a method by means of which crude water may be treated to achieve a satisfactory water quality with respect to content of components which can be removed or at least reduced by aeration.
According to the invention, such a method comprises an initiating formation of drops from an introduced water amount and division of the formed drops by mechanical action to form microdrops .
Such a formation of microdrops results in a considerably larger surface of the drops relative to the volume of the drops, and improved oxidation can thus take place. The mechanical action ensures that the intended division takes place. It has been found that a division of 50-60 times or optionally more causes formation of drops of a size which is sufficiently small for a satisfactory oxi- dation to take place, and thereby for a satisfactory water quality to be obtained.
According to an expedient embodiment, a microorganism culture may additionally be added to the water prior to the initiating drop formation. Hereby, components of the crude water which are not converted by the oxidation alone, may moreover be removed or reduced by the metabolism of the microorganisms. In this connection, the concrete microorganism culture may be selected depending on the crude water content of components whose amount is to be reduced.
Particularly expediently, the formed microdrops are introduced into a sedimentation container after completed oxidation. After settling in such a container the water may be conveyed to the user.
The invention also relates to an apparatus for performing the method described in the foregoing.
Such an apparatus comprises means for forming drops at the initiation of the process, and, in the direction of the gravitational force below these means, additional means for causing division of the drops by contact with these.
In an advantageous embodiment, the means for the initiating drop formation comprise a plate with holes, the drops being formed by the flow of the water through these holes. The means for causing division of the drops preferably comprise wire-shaped elements mutually spaced in the direction of the gravitational force. The wire-shaped elements are hereby advantageously arranged in a mutually intersecting pattern. Such a structure involves a good certainty of drop division, and it has moreover been found by tests that good environmental conditions are hereby formed for an optionally added microorganism culture. At least 50-60 layers of the mutually spaced wire- shaped elements are preferably arranged in the direction of the gravitational force to obtain an expedient fine division of the drops, as described above. Preferably, however, more of these layers are arranged so that also the drops which statistically drop through a layer in a gap between two wire-shaped elements, will obtain a division of 50-60 times. Thus, 70-80 layers of wire-shaped elements are expediently arranged. In this connection, the mutual spacing between parallel or substantially parallel wire-shaped elements in the same layer is expedi- ently between 5 and 15 mm, preferably about 10 mm. The spacing between the wires in the same layer will affect the statistical fall of drops, which are thus not divided as there is no contact. A too small spacing between the wires may cause gathering of already divided drops.
The mutual spacing between the layers of wire-shaped elements is preferably 30-60 mm, and more preferably 40-50 mm. This ensures that sufficient kinetic energy is added to the drops for rotation to take place, while ensuring that a complete system still has a limited height.
It has been found expedient to build such a system of tubular elements with an interlaced structure. In this connection, a row of such pipes are placed side by side to form a pipe layer. A plurality of such pipe layers are stacked to form a pipe column. Each pipe layer thus forms two layers of wire-shaped elements mutually spaced, except in the pipe areas adjoining each other in the same layer. In this connection, the pipe layers are expediently arranged with the pipe axes rotated 90 degrees relative to overlying and underlying pipe layers. This has been found to give a particularly good result, and at the same time an increased mechanical stability is achieved.
Preferably, means are arranged in the apparatus for collecting the microdrops below the means for dividing the drops. The drops or the caught drops, which form an amount of water, are expediently introduced into a settling container, which forms part of the apparatus in this connection.
The invention will be explained more fully below with reference to the drawing, in which a preferred embodiment of the invention is shown schematically, and in which
fig. 1 shows an apparatus, seen from the side,
fig. 2 shows an apparatus, seen from above, and
fig. 3 shows a pipe element associated with the apparatus shown in figs. 1 and 2, and
fig. 4 shows four interconnected pipe elements, as shown in fig. 3 and seen from the end.
Fig. 1 illustrates a system which uses apparatuses according to the invention for performing the method according to the invention. Such a system comprises a pipe connection 1 from a bore well and a pump 2 for pumping the water from the bore well. The crude water is conveyed via the pipe 1 to a distribution system consisting of a plate 3 with holes 4. This plate 3 with holes 4 serves to initiate formation of drops. Relatively large drops are involved in this connection. The drops leaving the plate 3 through the holes 4 in it then fall down under the ac- tion of gravity and hereby contact rows of wire-shaped elements, which, in the example shown, are formed by tubular elements 5, 6 arranged side by side with horizontal pipe axes to form pipe layers, a plurality of such pipe layers being arranged on top of each other. The pipe lay- ers are arranged such that every second pipe layer 6 is rotated 90°. In the structure shown, 15 pipe layers are provided. In this constellation, in the event that a large content of components is to be reduced, it will be necessary to recirculate the water to achieve sufficient oxidation. As also mentioned in the preamble to the description, 30-40 pipe layers will expediently be provided. The pipe layers are arranged in a housing 7 which is open at the top and at the bottom. When the water drops leave the lowermost pipe layer at the lower end of the housing 7, the water is collected in a collection basin or a settling container 8, in which solids, if any, can precipitate, and from which the cleaned water may be discharged and transported to the place of use.
Fig. 2 shows the plate 3 more clearly seen from above. In this connection, the holes 4 have a diameter of about 1-2 mm. This diameter may be selected depending on the surface tension of the water, the water pressure, etc.
Fig. 3 shows a pipe element which is used for the construction of the pipe layers in the housing. The pipe layers are composed of wire-shaped elements 9 which are arranged in intersecting manner in the pipe wall. By their mutually intersecting pattern, the wire-shaped ele- ments 9 form rhomboid holes in the pipe wall. Fig. 4 shows four such pipe elements in an interconnected state. It appears that circular pipe elements 5 are involved.

Claims

P a t e n t C l a i m s :
1. A method for the treatment of water, comprising:
initiating formation of drops from an introduced amount of water;
division of the formed drops by mechanical action to form microdrops.
2. A method according to claim 1, c h a r a c t e r i z e d in that the drops formed by the initiating drop formation are divided at least 50-60 times.
3. A method according to claim 1 or 2, c h a r a c t e r i z e d in that a microorganism culture is added to the water prior to the initiating drop formation.
4. A method according to claim 1, 2 or 3, c h a r a c t e r i z e d in that the formed microdrops are introduced into a sedimentation container.
5. An apparatus for performing the method according to any one of claims 1-4, c h a r a c t e r i z e d by comprising:
means for forming drops at the initiation of the process, and
in the direction of the gravitational force below these means, means for causing division of the drops by contact with these.
6. An apparatus according to claim 5, c h a r a c - t e r i z e d in that the means for the initiating drop formation comprise a plate with holes, the drops being formed by the flow of the water through these holes.
7. An apparatus according to claim 5 or 6, c h a r a c t e r i z e d in that the means for causing division of the drops comprise wire-shaped elements mutually spaced in the direction of the gravitational force.
8. An apparatus according to claim 7, c h a r a c t e r i z e d by comprising wire-shaped elements arranged in a mutually intersecting pattern.
9. An apparatus according to claims 5-8, c h a r a c - t e r i z e d in that at least 50-60 layers of mutually spaced wire-shaped elements are arranged in the direction of gravitational force.
10. An apparatus according to claim 9, c h a r a c - t e r i z e d in that the mutual spacing between the layers of wire-shaped elements is 30-60 mm, preferably 40-50 mm.
11. An apparatus according to claims 5-10, c h a r a c - t e r i z e d in that means are provided for collecting the microdrops below the means for dividing the drops .
12. An apparatus according to claims 5-11, c h a r a c t e r i z e d by comprising a settling container.
PCT/DK1999/000186 1998-04-01 1999-03-30 A method and a device for the treatment of water Ceased WO1999052829A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DK99911639T DK1070022T3 (en) 1998-04-01 1999-03-30 Water treatment apparatus
AT99911639T ATE227696T1 (en) 1998-04-01 1999-03-30 DEVICE FOR TREATING WATER
AU30254/99A AU3025499A (en) 1998-04-01 1999-03-30 A method and a device for the treatment of water
EP99911639A EP1070022B1 (en) 1998-04-01 1999-03-30 A device for the treatment of water
DE69903931T DE69903931T2 (en) 1998-04-01 1999-03-30 DEVICE FOR TREATING WATER

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DK0459/98 1998-04-01
DK45998 1998-04-01

Publications (1)

Publication Number Publication Date
WO1999052829A1 true WO1999052829A1 (en) 1999-10-21

Family

ID=8093797

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DK1999/000186 Ceased WO1999052829A1 (en) 1998-04-01 1999-03-30 A method and a device for the treatment of water

Country Status (8)

Country Link
EP (1) EP1070022B1 (en)
AT (1) ATE227696T1 (en)
AU (1) AU3025499A (en)
DE (1) DE69903931T2 (en)
DK (1) DK1070022T3 (en)
ES (1) ES2188144T3 (en)
PT (1) PT1070022E (en)
WO (1) WO1999052829A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008540092A (en) * 2005-05-12 2008-11-20 マイクロドロップ・アクア・エイピーエス Method and apparatus for removing trace species, especially arsenic, from water
WO2012095110A1 (en) * 2011-01-11 2012-07-19 Microdrop Aqua Aps A method for preparing potable water from contaminated crude water
WO2013041110A1 (en) * 2011-09-23 2013-03-28 Microdrop Aqua Aps A method and device for blowing off gaseous contaminants from crude water in the production of drinking water

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK3342284T3 (en) * 2016-12-29 2022-04-11 Np Innovation Ab VENTER AND CARBON DIOXIDE SEPARATOR

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4562015A (en) * 1984-05-22 1985-12-31 The Munters Corporation Open mesh fill assembly
DE3818650A1 (en) * 1987-06-02 1988-12-22 Leonhard Foidl Device for humidifying air
GB2241697A (en) * 1989-12-06 1991-09-11 D L Herbertson Limited Aeration of sewage
DK168684B1 (en) * 1993-08-06 1994-05-24 Nielsen Hede As Reactor for oxygen enrichment of fluid - has upright reactor at top of which fluid is inserted through inlet with one or more openings, and gas contg. oxygen inserted through reactor base from which oxygen-enriched fluid is withdrawn

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4562015A (en) * 1984-05-22 1985-12-31 The Munters Corporation Open mesh fill assembly
DE3818650A1 (en) * 1987-06-02 1988-12-22 Leonhard Foidl Device for humidifying air
GB2241697A (en) * 1989-12-06 1991-09-11 D L Herbertson Limited Aeration of sewage
DK168684B1 (en) * 1993-08-06 1994-05-24 Nielsen Hede As Reactor for oxygen enrichment of fluid - has upright reactor at top of which fluid is inserted through inlet with one or more openings, and gas contg. oxygen inserted through reactor base from which oxygen-enriched fluid is withdrawn

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008540092A (en) * 2005-05-12 2008-11-20 マイクロドロップ・アクア・エイピーエス Method and apparatus for removing trace species, especially arsenic, from water
US7947183B2 (en) 2005-05-12 2011-05-24 Microdrop Aqua Aps Method for removing contaminant trace species, especially arsenic, from water
WO2012095110A1 (en) * 2011-01-11 2012-07-19 Microdrop Aqua Aps A method for preparing potable water from contaminated crude water
CN103391899A (en) * 2011-01-11 2013-11-13 微滴爱克有限责任公司 A method for preparing potable water from contaminated crude water
US20140014590A1 (en) * 2011-01-11 2014-01-16 Microdrop Aqua Aps Method for preparing potable water from contaminated crude water
WO2013041110A1 (en) * 2011-09-23 2013-03-28 Microdrop Aqua Aps A method and device for blowing off gaseous contaminants from crude water in the production of drinking water
US10138141B2 (en) 2011-09-23 2018-11-27 Microdrop Aqua Aps Method and device for blowing off gaseous contaminants from crude water in the production of drinking water

Also Published As

Publication number Publication date
DK1070022T3 (en) 2003-03-10
DE69903931D1 (en) 2002-12-19
AU3025499A (en) 1999-11-01
ES2188144T3 (en) 2003-06-16
DE69903931T2 (en) 2003-07-31
EP1070022B1 (en) 2002-11-13
EP1070022A1 (en) 2001-01-24
PT1070022E (en) 2003-03-31
ATE227696T1 (en) 2002-11-15

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