WO2000004124A3 - Detergent tablet - Google Patents

Detergent tablet Download PDF

Info

Publication number
WO2000004124A3
WO2000004124A3 PCT/US1999/014863 US9914863W WO0004124A3 WO 2000004124 A3 WO2000004124 A3 WO 2000004124A3 US 9914863 W US9914863 W US 9914863W WO 0004124 A3 WO0004124 A3 WO 0004124A3
Authority
WO
WIPO (PCT)
Prior art keywords
phase
tablet
mould
detergent
detergent tablet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1999/014863
Other languages
French (fr)
Other versions
WO2000004124A2 (en
Inventor
Patrizio Ricci
Brenda Frances Bennie
Christopher James Binder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26314051&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2000004124(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from GBGB9815525.2A external-priority patent/GB9815525D0/en
Priority to BR9912157-3A priority Critical patent/BR9912157A/en
Priority to EP99933627A priority patent/EP1097192B1/en
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to AU49644/99A priority patent/AU4964499A/en
Priority to JP2000560223A priority patent/JP2002520479A/en
Priority to DE69909095T priority patent/DE69909095T2/en
Priority to CA002333468A priority patent/CA2333468C/en
Priority to US09/743,878 priority patent/US6544943B1/en
Priority to SK60-2001A priority patent/SK602001A3/en
Priority to AT99933627T priority patent/ATE243737T1/en
Publication of WO2000004124A2 publication Critical patent/WO2000004124A2/en
Publication of WO2000004124A3 publication Critical patent/WO2000004124A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • C11D17/0078Multilayered tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • C11D17/0086Laundry tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • C11D17/0091Dishwashing tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • C11D3/1253Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • C11D3/1253Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1273Crystalline layered silicates of type NaMeSixO2x+1YH2O
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776Heterocyclic compounds, e.g. lactam
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3792Amine oxide containing polymers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38609Protease or amylase in solid compositions only
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38645Preparations containing enzymes, e.g. protease or amylase containing cellulase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40Dyes ; Pigments
    • C11D3/42Brightening agents ; Blueing agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Sealing With Elastic Sealing Lips (AREA)

Abstract

A multi-phase detergent tablet comprising: a) a first phase in the form of a shaped body having at least one mould therein; and b) a second phase in the form of a compressed body adhesively contained within said mould, wherein the tablet composition comprises one or more detergent actives which is predominantly concentrated in the second phase, and wherein the second phase additionally comprises a disrupting agent. The multi-phases tablets provide improved dissolution and cleaning characteristics together with excellent tablet integrity and strength.
PCT/US1999/014863 1998-07-17 1999-07-09 Detergent tablet Ceased WO2000004124A2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
SK60-2001A SK602001A3 (en) 1998-07-17 1999-07-09 Detergent tablet
AT99933627T ATE243737T1 (en) 1998-07-17 1999-07-09 DETERGENT TABLET
US09/743,878 US6544943B1 (en) 1998-07-17 1999-07-09 Detergent tablet
BR9912157-3A BR9912157A (en) 1998-07-17 1999-07-09 Detergent tablet
AU49644/99A AU4964499A (en) 1998-07-17 1999-07-09 Detergent tablet
JP2000560223A JP2002520479A (en) 1998-07-17 1999-07-09 Cleaning tablets
DE69909095T DE69909095T2 (en) 1998-07-17 1999-07-09 DETERGENT TABLET
CA002333468A CA2333468C (en) 1998-07-17 1999-07-09 A multi-phase detergent tablet
EP99933627A EP1097192B1 (en) 1998-07-17 1999-07-09 Detergent tablet

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GBGB9815525.2A GB9815525D0 (en) 1998-07-17 1998-07-17 Detergent tablet
GB9815525.2 1998-07-17
GB9911264.1 1999-05-17
GB9911264A GB2339792B (en) 1998-07-17 1999-05-17 Detergent tablet

Publications (2)

Publication Number Publication Date
WO2000004124A2 WO2000004124A2 (en) 2000-01-27
WO2000004124A3 true WO2000004124A3 (en) 2000-04-20

Family

ID=26314051

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1999/014863 Ceased WO2000004124A2 (en) 1998-07-17 1999-07-09 Detergent tablet

Country Status (21)

Country Link
EP (2) EP0979866B1 (en)
JP (1) JP2002520479A (en)
CN (1) CN1309692A (en)
AT (4) ATE213767T1 (en)
AU (1) AU4964499A (en)
BR (1) BR9912157A (en)
CA (1) CA2333468C (en)
DE (5) DE29911484U1 (en)
DK (1) DK0979866T3 (en)
ES (4) ES2173707T3 (en)
FI (1) FI4408U1 (en)
FR (1) FR2782090B1 (en)
IE (1) IES990572A2 (en)
IT (2) ITMI991511A1 (en)
NL (1) NL1012585C1 (en)
PL (1) PL346179A1 (en)
PT (1) PT979866E (en)
RU (1) RU2208628C2 (en)
SK (1) SK602001A3 (en)
TR (1) TR200100096T2 (en)
WO (1) WO2000004124A2 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE29911484U1 (en) * 1998-07-17 2000-02-24 The Procter & Gamble Co., Cincinnati, Ohio Detergent tablet
ATE215985T1 (en) * 1998-07-17 2002-04-15 Procter & Gamble DETERGENT TABLET
IES990569A2 (en) * 1998-07-17 2000-07-12 Procter & Gamble Detergent tablet
GB9815525D0 (en) * 1998-07-17 1998-09-16 Procter & Gamble Detergent tablet
ATE212660T1 (en) * 1998-07-17 2002-02-15 Procter & Gamble DETERGENT TABLET
DE19922578C2 (en) * 1999-05-17 2003-12-24 Benckiser Nv Process for the production of a multilayer tablet, in particular detergent tablet, and product which can be produced thereafter
EP1162257B1 (en) * 2000-06-09 2006-02-22 The Procter & Gamble Company A process of treating fabrics with a detergent tablet comprising an ion exchange resin
DE10053416A1 (en) 2000-10-27 2002-05-08 Bsh Bosch Siemens Hausgeraete Process for the mechanical cleaning of textiles or solid objects
EP1478886B2 (en) * 2002-02-26 2015-06-10 Rational AG Method for cleaning a cooking device by way of a cleaning agent in tablet form
DE102011107684A1 (en) * 2011-07-13 2013-01-17 Budich International Gmbh Chlorinated detergent tablet for toilets
CN102965223B (en) * 2012-11-26 2014-01-08 吴金龙 Nano-multifunctional washing sheet
JP2022548319A (en) 2019-09-23 2022-11-17 エコラボ ユーエスエー インコーポレイティド Color-changing detergent composition and method of use
EP3825392A1 (en) 2019-11-21 2021-05-26 Dalli-Werke GmbH & Co. KG Detergent tablet comprising an effervescent system
EP4166638A1 (en) 2021-10-13 2023-04-19 CLARO Products GmbH Cleaning tablet for cleaning spectacles

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0466484A2 (en) * 1990-07-13 1992-01-15 Unilever Plc Detergent compositions
EP0481547A1 (en) * 1990-10-17 1992-04-22 Unilever N.V. Machine dishwashing detergent tablets
WO1997003177A1 (en) * 1995-07-13 1997-01-30 Joh. A. Benckiser Gmbh Dish washer product in tablet form
WO1998055590A1 (en) * 1997-06-06 1998-12-10 Unilever Plc Detergent compositions

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4460490A (en) * 1980-12-18 1984-07-17 Jeyes Group Limited Lavatory cleansing blocks
DE3541146A1 (en) * 1985-11-21 1987-05-27 Henkel Kgaa MULTILAYERED DETERGENT TABLETS FOR MACHINE DISHWASHER
SU1313868A1 (en) * 1985-12-03 1987-05-30 Украинский Научно-Исследовательский И Конструкторско-Технологический Институт Бытового Обслуживания Detergent
GB9022724D0 (en) * 1990-10-19 1990-12-05 Unilever Plc Detergent compositions
US5900395A (en) * 1996-12-23 1999-05-04 Lever Brothers Company Machine dishwashing tablets containing an oxygen bleach system
US5837663A (en) * 1996-12-23 1998-11-17 Lever Brothers Company, Division Of Conopco, Inc. Machine dishwashing tablets containing a peracid
GB2327949A (en) * 1997-08-02 1999-02-10 Procter & Gamble Detergent tablet
DE19739384A1 (en) * 1997-09-09 1999-03-11 Henkel Kgaa Detergent tablets with improved solubility
DE69816112T2 (en) * 1997-11-10 2004-04-22 The Procter & Gamble Company, Cincinnati METHOD FOR PRODUCING A DETERGENT TABLET
EP1032644B1 (en) * 1997-11-10 2003-03-19 The Procter & Gamble Company Process for preparing a detergent tablet
JP4050463B2 (en) * 1997-11-10 2008-02-20 ザ プロクター アンド ギャンブル カンパニー Multi-layered cleaning tablet with both compressed and uncompressed parts
DE69833335T2 (en) * 1997-11-26 2006-09-28 The Procter & Gamble Company, Cincinnati detergent tablet
EP1034247B1 (en) * 1997-11-26 2005-05-25 The Procter & Gamble Company Detergent tablet
WO1999027068A1 (en) * 1997-11-26 1999-06-03 The Procter & Gamble Company Detergent tablet
DE69828816T2 (en) * 1997-11-26 2005-12-22 The Procter & Gamble Company, Cincinnati DETERGENT TABLET
DE19758176A1 (en) * 1997-12-30 1999-07-01 Henkel Kgaa Dishwasher detergent tablets with surfactants
DE19758175A1 (en) * 1997-12-30 1999-07-01 Henkel Kgaa Dishwasher detergent tablets with specific solubility
DE19758177A1 (en) * 1997-12-30 1999-07-01 Henkel Kgaa Process for producing a dishwasher detergent tablet
DE29811135U1 (en) * 1998-06-24 1998-08-13 Brandenburger, Hardie, 42329 Wuppertal cleaning supplies
CA2337408C (en) * 1998-07-17 2005-11-15 The Procter & Gamble Company A multi-phase detergent tablet
ATE212660T1 (en) * 1998-07-17 2002-02-15 Procter & Gamble DETERGENT TABLET
DE29911484U1 (en) * 1998-07-17 2000-02-24 The Procter & Gamble Co., Cincinnati, Ohio Detergent tablet
IES990569A2 (en) * 1998-07-17 2000-07-12 Procter & Gamble Detergent tablet
ATE215985T1 (en) * 1998-07-17 2002-04-15 Procter & Gamble DETERGENT TABLET
BR9912150A (en) * 1998-07-17 2001-04-10 Procter & Gamble Detergent tablet

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0466484A2 (en) * 1990-07-13 1992-01-15 Unilever Plc Detergent compositions
EP0481547A1 (en) * 1990-10-17 1992-04-22 Unilever N.V. Machine dishwashing detergent tablets
WO1997003177A1 (en) * 1995-07-13 1997-01-30 Joh. A. Benckiser Gmbh Dish washer product in tablet form
WO1998055590A1 (en) * 1997-06-06 1998-12-10 Unilever Plc Detergent compositions

Also Published As

Publication number Publication date
EP0979866A1 (en) 2000-02-16
CN1309692A (en) 2001-08-22
ES2272825T3 (en) 2007-05-01
AU4964499A (en) 2000-02-07
DE69909095T2 (en) 2004-05-06
TR200100096T2 (en) 2001-06-21
DE69900931T2 (en) 2002-11-07
ES2173707T3 (en) 2002-10-16
ES2201741T3 (en) 2004-03-16
ATE242311T1 (en) 2003-06-15
PT979866E (en) 2002-07-31
NL1012585A1 (en) 2000-01-19
FI4408U1 (en) 2000-05-18
NL1012585C1 (en) 2000-01-25
ITMI991567A1 (en) 2001-01-15
DE69933143T2 (en) 2007-08-02
ATE213767T1 (en) 2002-03-15
EP0979866B1 (en) 2002-02-27
IES990572A2 (en) 2000-03-08
ATE338808T1 (en) 2006-09-15
ITMI991511A1 (en) 2000-01-18
SK602001A3 (en) 2001-06-11
CA2333468C (en) 2004-01-20
BR9912157A (en) 2001-04-10
FR2782090B1 (en) 2004-07-09
EP1097192A2 (en) 2001-05-09
DE69900931D1 (en) 2002-04-04
DE69909095D1 (en) 2003-07-31
FR2782090A1 (en) 2000-02-11
CA2333468A1 (en) 2000-01-27
DE69908604T2 (en) 2004-04-29
ITMI991567A0 (en) 1999-07-15
DE29911484U1 (en) 2000-02-24
WO2000004124A2 (en) 2000-01-27
DK0979866T3 (en) 2002-06-17
DE69933143D1 (en) 2006-10-19
JP2002520479A (en) 2002-07-09
ES2199905T3 (en) 2004-03-01
ATE243737T1 (en) 2003-07-15
RU2208628C2 (en) 2003-07-20
DE69908604D1 (en) 2003-07-10
ITMI991511A0 (en) 1999-07-09
EP1097192B1 (en) 2003-06-25
PL346179A1 (en) 2002-01-28
FIU990322U0 (en) 1999-07-16

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