WO2000004129A3 - Detergent tablet - Google Patents

Detergent tablet Download PDF

Info

Publication number
WO2000004129A3
WO2000004129A3 PCT/US1999/015492 US9915492W WO0004129A3 WO 2000004129 A3 WO2000004129 A3 WO 2000004129A3 US 9915492 W US9915492 W US 9915492W WO 0004129 A3 WO0004129 A3 WO 0004129A3
Authority
WO
WIPO (PCT)
Prior art keywords
phase
tablet
detergent tablet
mould
strength
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1999/015492
Other languages
French (fr)
Other versions
WO2000004129A2 (en
Inventor
Patrizio Ricci
Brenda Frances Bennie
Christopher James Binder
Valerio Delduca
Andrea Esposito
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB9815525.2A external-priority patent/GB9815525D0/en
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to JP2000560228A priority Critical patent/JP2002520482A/en
Priority to EP99935462A priority patent/EP1144584B1/en
Priority to AU50936/99A priority patent/AU5093699A/en
Priority to US09/743,877 priority patent/US6551981B1/en
Priority to DE69931812T priority patent/DE69931812T2/en
Priority to CA002337402A priority patent/CA2337402C/en
Publication of WO2000004129A2 publication Critical patent/WO2000004129A2/en
Anticipated expiration legal-status Critical
Publication of WO2000004129A3 publication Critical patent/WO2000004129A3/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0086—Laundry tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0065—Solid detergents containing builders
    • C11D17/0073—Tablets
    • C11D17/0078—Multilayered tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3792—Amine oxide containing polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38609—Protease or amylase in solid compositions only
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Control Of Motors That Do Not Use Commutators (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Sealing With Elastic Sealing Lips (AREA)

Abstract

A multi-phase detergent tablet for use in a washing machine, the tablet comprising: a) a first phase in the form of a shaped body having at least one mould therein; and b) a second phase in the form of a particulate solid compressed within said mould. The multi-phase tablets provide improved dissolution and cleaning characteristics together with excellent tablet integrity and strength.
PCT/US1999/015492 1998-07-17 1999-07-09 Detergent tablet Ceased WO2000004129A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2000560228A JP2002520482A (en) 1998-07-17 1999-07-09 Cleaning tablets
EP99935462A EP1144584B1 (en) 1998-07-17 1999-07-09 Detergent tablet
AU50936/99A AU5093699A (en) 1998-07-17 1999-07-09 Detergent tablet
US09/743,877 US6551981B1 (en) 1998-07-17 1999-07-09 Detergent tablet
DE69931812T DE69931812T2 (en) 1998-07-17 1999-07-09 DETERGENT TABLET
CA002337402A CA2337402C (en) 1998-07-17 1999-07-09 Detergent tablet

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GBGB9815525.2A GB9815525D0 (en) 1998-07-17 1998-07-17 Detergent tablet
GB9815525.2 1998-07-17
GB9911218.7 1999-05-17
GB9911218A GB2339791B (en) 1998-07-17 1999-05-17 Detergent tablet

Publications (2)

Publication Number Publication Date
WO2000004129A2 WO2000004129A2 (en) 2000-01-27
WO2000004129A3 true WO2000004129A3 (en) 2001-08-23

Family

ID=26314050

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/US1999/014862 Ceased WO2000004128A2 (en) 1998-07-17 1999-07-09 Detergent tablet
PCT/US1999/015492 Ceased WO2000004129A2 (en) 1998-07-17 1999-07-09 Detergent tablet

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/US1999/014862 Ceased WO2000004128A2 (en) 1998-07-17 1999-07-09 Detergent tablet

Country Status (22)

Country Link
EP (3) EP0976819B1 (en)
JP (2) JP2002520481A (en)
CN (1) CN1309694A (en)
AT (3) ATE212660T1 (en)
AU (2) AU5093699A (en)
BR (1) BR9912833A (en)
CA (2) CA2333894C (en)
DE (3) DE69900833T2 (en)
DK (2) DK0976819T3 (en)
ES (3) ES2208477T3 (en)
FI (1) FI4407U1 (en)
FR (1) FR2782092B1 (en)
IE (1) IES990570A2 (en)
IT (2) ITMI991510A1 (en)
MA (1) MA24934A1 (en)
NL (1) NL1012584C1 (en)
PL (1) PL189559B1 (en)
PT (2) PT976819E (en)
RU (1) RU2203933C2 (en)
SK (1) SK612001A3 (en)
TR (1) TR200100093T2 (en)
WO (2) WO2000004128A2 (en)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE241004T1 (en) * 1998-07-17 2003-06-15 Procter & Gamble DETERGENT TABLETS AND THEIR PRODUCTION
DE29911484U1 (en) * 1998-07-17 2000-02-24 The Procter & Gamble Co., Cincinnati, Ohio Detergent tablet
DE69908605T2 (en) * 1998-07-17 2004-04-29 The Procter & Gamble Company, Cincinnati detergent tablet
DK0976819T3 (en) * 1998-07-17 2002-05-13 Procter & Gamble detergent
CA2362413A1 (en) † 1999-03-09 2000-09-14 The Procter & Gamble Company Process for producing coated detergent particles
GB9911949D0 (en) * 1999-05-21 1999-07-21 Unilever Plc Detergent compositions
DE19937428A1 (en) * 1999-08-07 2001-02-08 Henkel Kgaa Detergent tablets
EP1090981A1 (en) * 1999-10-07 2001-04-11 The Procter & Gamble Company Fabric rejuvenating treatment
EP1090980A1 (en) * 1999-10-07 2001-04-11 The Procter & Gamble Company Fabric rejuvenating treatment
GB0015350D0 (en) * 2000-06-23 2000-08-16 Reckitt Benckiser Nv Improvements in or relating to compositions
DE10053416A1 (en) † 2000-10-27 2002-05-08 Bsh Bosch Siemens Hausgeraete Process for the mechanical cleaning of textiles or solid objects
EP1201741A1 (en) 2000-10-31 2002-05-02 The Procter & Gamble Company Detergent compositions
EP1405900B1 (en) * 2002-10-01 2006-03-08 Unilever Plc Detergent compositions
KR100798785B1 (en) * 2003-12-09 2008-01-29 삼성전자주식회사 washer
US7820198B2 (en) 2004-10-19 2010-10-26 Arch Chemicals, Inc. Pool chemical tablet
DE602005014328D1 (en) 2005-01-04 2009-06-18 Unilever Nv Detergent tablets
ATE404660T1 (en) 2005-03-23 2008-08-15 Unilever Nv BODY-SHAPED DETERGENT OR CLEANING COMPOSITIONS
EP1705240A1 (en) 2005-03-23 2006-09-27 Unilever N.V. Detergent tablets
EP1709978A1 (en) * 2005-04-06 2006-10-11 Chemische Fabrik Dr. Weigert GmbH & Co. KG. Cleaning and disinfection of surgical and medical instruments and devices
EP1746151A1 (en) 2005-07-20 2007-01-24 Unilever N.V. Detergent tablet compositions
EP1746152A1 (en) 2005-07-20 2007-01-24 Unilever N.V. Detergent compositions
EP1903099A1 (en) * 2006-09-22 2008-03-26 Dalli-Werke GmbH & Co. KG Coated detergent compositions and manufacture process
US7781387B2 (en) * 2008-01-22 2010-08-24 Access Business Group International, Llc. Automatic phosphate-free dishwashing detergent providing improved spotting and filming performance
GB0913808D0 (en) 2009-08-07 2009-09-16 Mcbride Robert Ltd Dosage form detergent products
EP3034597A1 (en) 2014-12-17 2016-06-22 The Procter and Gamble Company Detergent composition
EP3034588B1 (en) 2014-12-17 2019-04-24 The Procter and Gamble Company Detergent composition
EP3034596B2 (en) * 2014-12-17 2021-11-10 The Procter & Gamble Company Detergent composition
EP3448975B1 (en) * 2016-04-27 2020-04-01 Basf Se Formulations, their preparation and use, and suitable compounds
JP6943961B2 (en) * 2016-09-07 2021-10-06 エコラボ ユーエスエー インコーポレイティド Detergent composition containing an enzyme stabilized by phosphonate
CN110373287B (en) * 2019-08-15 2021-11-09 广州立白企业集团有限公司 Automatic dish-washing machine cleaning sheet with multiphase structure
GB202115335D0 (en) * 2021-10-25 2021-12-08 Econic Tech Ltd Surface-active agent

Citations (7)

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Publication number Priority date Publication date Assignee Title
US3185649A (en) * 1960-07-28 1965-05-25 Lever Brothers Ltd Bleaching compositions
GB1307387A (en) * 1969-02-18 1973-02-21 Lion Fat Oil Co Ltd Cleansing agent having a shell structure
US4099912A (en) * 1974-05-15 1978-07-11 Colgate-Palmolive Company Detergent compositions and washing methods including and utilizing separate tablets of components
EP0055100A1 (en) * 1980-12-18 1982-06-30 Jeyes Group Limited Lavatory cleansing blocks
EP0481547A1 (en) * 1990-10-17 1992-04-22 Unilever N.V. Machine dishwashing detergent tablets
EP0481793A1 (en) * 1990-10-19 1992-04-22 Unilever Plc Detergent composition in tablet form
GB2327949A (en) * 1997-08-02 1999-02-10 Procter & Gamble Detergent tablet

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US3962107A (en) * 1974-06-24 1976-06-08 Johnson & Johnson Enzyme-containing denture cleanser tablet
JPS5476836A (en) * 1977-12-02 1979-06-19 Kukidento Kuruto Kurisupu Kg Tablet for cleaning false tooth and production thereof
DE3479394D1 (en) * 1984-02-08 1989-09-21 Richardson Gmbh Anti-plaque denture cleansing tablet
DE3541146A1 (en) * 1985-11-21 1987-05-27 Henkel Kgaa MULTILAYERED DETERGENT TABLETS FOR MACHINE DISHWASHER
DE3541147A1 (en) * 1985-11-21 1987-05-27 Henkel Kgaa CLEANER COMPACT
GB9015503D0 (en) * 1990-07-13 1990-08-29 Unilever Plc Detergent composition
JP2898375B2 (en) * 1990-08-20 1999-05-31 ポーラ化成工業株式会社 Composite solid and method for producing the same
EP0585363B1 (en) * 1991-05-14 1995-04-12 Ecolab Incorporated Two part chemical concentrate
JPH07109499A (en) * 1993-10-08 1995-04-25 Osaka Seiyaku:Kk Foaming detergent
WO1997003177A1 (en) * 1995-07-13 1997-01-30 Joh. A. Benckiser Gmbh Dish washer product in tablet form
US5900395A (en) * 1996-12-23 1999-05-04 Lever Brothers Company Machine dishwashing tablets containing an oxygen bleach system
US5837663A (en) * 1996-12-23 1998-11-17 Lever Brothers Company, Division Of Conopco, Inc. Machine dishwashing tablets containing a peracid
ES2198769T3 (en) * 1997-11-10 2004-02-01 THE PROCTER & GAMBLE COMPANY MULTIPLE LAYER DETERGENT PAD THAT HAS BOTH PORTIONS COMPRESSED AND NOT COMPRESSED.
BR9813201A (en) * 1997-11-10 2000-08-29 Procter & Gamble Process for preparing a detergent tablet
CA2309251C (en) * 1997-11-10 2003-12-30 The Procter & Gamble Company Detergent tablet
ATE276350T1 (en) * 1997-11-26 2004-10-15 Procter & Gamble METHOD FOR PRODUCING A DETERGENT TABLET
WO1999027069A1 (en) * 1997-11-26 1999-06-03 The Procter & Gamble Company Detergent tablet
ATE218612T1 (en) * 1997-11-26 2002-06-15 Procter & Gamble DISHWASHING METHOD
ATE296346T1 (en) * 1997-11-26 2005-06-15 Procter & Gamble DETERGENT TABLET
DE69908605T2 (en) * 1998-07-17 2004-04-29 The Procter & Gamble Company, Cincinnati detergent tablet
DK0976819T3 (en) * 1998-07-17 2002-05-13 Procter & Gamble detergent
AU5093599A (en) * 1998-07-17 2000-02-07 Procter & Gamble Company, The Detergent tablet
DE29911484U1 (en) * 1998-07-17 2000-02-24 The Procter & Gamble Co., Cincinnati, Ohio Detergent tablet
ATE277166T1 (en) * 1998-07-17 2004-10-15 Procter & Gamble DETERGENT TABLET
ATE241004T1 (en) * 1998-07-17 2003-06-15 Procter & Gamble DETERGENT TABLETS AND THEIR PRODUCTION

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3185649A (en) * 1960-07-28 1965-05-25 Lever Brothers Ltd Bleaching compositions
GB1307387A (en) * 1969-02-18 1973-02-21 Lion Fat Oil Co Ltd Cleansing agent having a shell structure
US4099912A (en) * 1974-05-15 1978-07-11 Colgate-Palmolive Company Detergent compositions and washing methods including and utilizing separate tablets of components
EP0055100A1 (en) * 1980-12-18 1982-06-30 Jeyes Group Limited Lavatory cleansing blocks
EP0481547A1 (en) * 1990-10-17 1992-04-22 Unilever N.V. Machine dishwashing detergent tablets
EP0481793A1 (en) * 1990-10-19 1992-04-22 Unilever Plc Detergent composition in tablet form
GB2327949A (en) * 1997-08-02 1999-02-10 Procter & Gamble Detergent tablet

Also Published As

Publication number Publication date
DE69931812T2 (en) 2007-05-31
DE69911623T2 (en) 2004-07-01
ES2208477T3 (en) 2004-06-16
FIU990321U0 (en) 1999-07-16
JP2002520482A (en) 2002-07-09
CA2333894C (en) 2004-02-03
ATE250661T1 (en) 2003-10-15
EP1144584B1 (en) 2006-06-07
JP2002520481A (en) 2002-07-09
CA2337402A1 (en) 2000-01-27
PL345973A1 (en) 2002-01-14
PL189559B1 (en) 2005-08-31
DK0976819T3 (en) 2002-05-13
ITMI991570A0 (en) 1999-07-15
EP1098955A2 (en) 2001-05-16
WO2000004129A2 (en) 2000-01-27
IES990570A2 (en) 2000-03-08
FR2782092A1 (en) 2000-02-11
WO2000004128A3 (en) 2000-03-30
DK1144584T3 (en) 2006-10-09
DE69900833T2 (en) 2002-10-31
CA2333894A1 (en) 2000-01-27
ES2267278T3 (en) 2007-03-01
MA24934A1 (en) 2000-04-01
DE69931812D1 (en) 2006-07-20
RU2203933C2 (en) 2003-05-10
AU761595B2 (en) 2003-06-05
NL1012584A1 (en) 2000-01-19
SK612001A3 (en) 2001-07-10
WO2000004128A2 (en) 2000-01-27
CN1309694A (en) 2001-08-22
ES2172290T3 (en) 2002-09-16
ATE212660T1 (en) 2002-02-15
AU5093699A (en) 2000-02-07
EP0976819B1 (en) 2002-01-30
DE69900833D1 (en) 2002-03-14
BR9912833A (en) 2001-10-09
FI4407U1 (en) 2000-05-18
EP1144584A3 (en) 2002-09-11
EP0976819A1 (en) 2000-02-02
FR2782092B1 (en) 2004-11-05
ITMI991510A1 (en) 1999-12-18
ITMI991570A1 (en) 2001-01-15
DE69911623D1 (en) 2003-10-30
CA2337402C (en) 2004-05-04
TR200100093T2 (en) 2002-09-23
EP1144584A2 (en) 2001-10-17
NL1012584C1 (en) 2000-01-25
ATE329001T1 (en) 2006-06-15
PT976819E (en) 2002-06-28
PT1144584E (en) 2006-10-31
AU4964399A (en) 2000-02-07
ITMI991510A0 (en) 1999-07-09

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