WO2000009770A1 - Process and apparatus for recovering metal material from waste material - Google Patents

Process and apparatus for recovering metal material from waste material Download PDF

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Publication number
WO2000009770A1
WO2000009770A1 PCT/FI1999/000667 FI9900667W WO0009770A1 WO 2000009770 A1 WO2000009770 A1 WO 2000009770A1 FI 9900667 W FI9900667 W FI 9900667W WO 0009770 A1 WO0009770 A1 WO 0009770A1
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WO
WIPO (PCT)
Prior art keywords
metal
gasifier
waste material
process according
separating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FI1999/000667
Other languages
French (fr)
Inventor
Jorma Nieminen
Juha Palonen
Markku ITÄPELTO
Pekka Harkki
Lauri MÄKIPAJA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Amec Foster Wheeler Energia Oy
Original Assignee
Foster Wheeler Energia Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foster Wheeler Energia Oy filed Critical Foster Wheeler Energia Oy
Priority to EP99938415A priority Critical patent/EP1119645B1/en
Priority to AU52923/99A priority patent/AU5292399A/en
Priority to AT99938415T priority patent/ATE244314T1/en
Priority to DE69909309T priority patent/DE69909309T2/en
Priority to JP2000565203A priority patent/JP2002522644A/en
Priority to US09/762,718 priority patent/US6409798B1/en
Publication of WO2000009770A1 publication Critical patent/WO2000009770A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
    • D21B1/00—Fibrous raw materials or their mechanical treatment
    • D21B1/04—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
    • D21B1/12—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by wet methods, by the use of steam
    • D21B1/30—Defibrating by other means
    • D21B1/32—Defibrating by other means of waste paper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00—Preliminary treatment of ores or scrap
    • C22B1/005—Preliminary treatment of scrap
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/02—Obtaining noble metals by dry processes
    • C22B11/021—Recovery of noble metals from waste materials
    • C22B11/025—Recovery of noble metals from waste materials from manufactured products, e.g. from printed circuit boards, from photographic films, paper, or baths
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B21/00—Obtaining aluminium
    • C22B21/0038—Obtaining aluminium by other processes
    • C22B21/0069—Obtaining aluminium by other processes from scrap, skimmings or any secondary source aluminium, e.g. recovery of alloy constituents
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/001—Dry processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/005—Separation by a physical processing technique only, e.g. by mechanical breaking
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/30—Wastewater or sewage treatment systems using renewable energies
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/40—Valorisation of by-products of wastewater, sewage or sludge processing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/64—Paper recycling

Definitions

  • the present invention refers to a process and an apparatus for recovering metal material from waste material including organic material, such as plastic, and metal material in the form of thin foil material, as specified in the preamble of appending independent claims.
  • wastes contain valuable materials like metals, glass, paper fibers, wood and plastics. Part of the valuable materials can be rather easily separated from the waste material.
  • paper fibers can be separated from other waste material by mixing the waste material with water. Fibers mixed with water form an aqueous suspension, which can rather easily be separated from the rest of the waste material.
  • iron may be separated from waste material by crushing the waste material and separating iron magnetically. Some metal materials may be separated from waste material by combusting the organic material in the waste and recovering metal from the combustion residue.
  • the combustion of waste material can, however, be difficult, if the content of metals in the waste is high and if the metals have a low melting temperature, e.g. below typical combustion temperatures, e.g. below 1100°C.
  • Such metals are e.g. Al, Ag, Au, Mg, Pb, Zn and Sn.
  • Molten metals tend to form deposits on surfaces and cause serious fouling in the waste combusting boilers.
  • Alkali salts present in the waste material tend to increase the problem caused by deposits and fouling in combustors.
  • Many waste materials contain aluminum in a form which may melt already at temperatures of about 670 - 700 °C. Such waste material, if combusted or gasified with air, should therefore be treated at temperatures well below the melting point of aluminum present therein, preferably well below 650 °C, in order to avoid problems derived from molten aluminum.
  • Aluminum dust may be a very hazardous component in any combustion process.
  • Aluminum if oxidized may form locally very high temperatures, temperatures above 2000°C, or even almost 3000°C. Such high local temperatures in combustors can cause severe damage to the combustor.
  • Further aluminum in dust form is an explosive material when mixed with air.
  • metallic aluminum may react with alkali hydroxide, e.g. present in fly ash, and form aluminum hydroxide and hydrogen gas. It is well known that hydrogen gas under certain conditions may easily form explosive gas mixtures. Also storage of fly ash with aluminum may cause problems as formation of hydrogen gas in the fly ash may continue for a long time in its dumping place.
  • the present invention sets out to provide an improved process for recovering metal material from waste material and an improved apparatus therefore, which overcomes drawbacks discussed above. It is also an object of the present invention to provide a process and apparatus for recovering metal material from waste material in which the heating value of plastic material present in the waste material is recovered in an optimum way.
  • a typical process for recovering metal from waste material including organic material, such as plastic, and metal material in the form of thin foil material includes following steps:
  • step (a) introducing the waste material from which metal is to be recovered into a fluidized bed gasifier, for gasification of the organic material, and (b) separating metal material from gas produced in step (a) .
  • a typical apparatus for recovering metal from waste material includes - a fluidized bed gasifier with a fluidized bed of solids therein, for gasification of the organic material in the waste material from which metal is to be recovered, and - a separator for separating metal material from gas produced in the gasifier.
  • metal such as Ag, Al, Au, Mg, Pb, Zn and/or Sn
  • the foil material may have a thickness of about 5 - 50 ⁇ m.
  • the actual gas velocity in the fluidized bed is to be set such that the metal flakes are entrained with the gas up to the gas outlet, but the not yet gasified waste material and bed particles stay in the bed.
  • a slowly fluidized, bubbling fluidized bed having a gas velocity ⁇ 2 m/s, typically 0,5 - 1 m/s, may be used.
  • the bed typically consists of inert solid particles having a mean diameter of about 0,5 to 2 mm, typically about 1 mm.
  • the metal foils are generally more or less permanently combined to some organic material, such as plastic or paper. If the waste includes polyethylene or other plastic material, which does not contain chlorine, the waste material can rather easily be gasified with air.
  • Polyethylene has a high heating value and consists of almost 100 % volatiles, which can almost totally be converted to gases and vapors in an air blown gasifier at temperatures well below the melting temperature of aluminum present.
  • the plastic material is thereby a very valuable fuel.
  • a combustible gas having a high heat value of about 7 - 15 MJ/m 3 , typically 9 - 10 MJ/m 3 may be produced in the gasifier. The gas can be used in power production or other processes utilizing combustion heat.
  • the temperature in the gasifier is typically maintained close to but just below the melting temperature of the metal material to be recovered from the gas produced in the gasifier.
  • the temperature thereby typically is kept below 1100°C.
  • Gasification of plastic material usually takes place at a temperature ⁇ 650°C.
  • Gasification of polyethylene can take place at a temperature of about 400 - 550°C.
  • step (a) The gas produced in step (a) is typically cooled and heat energy recovered therefrom before the metal material is separated from the gas.
  • the gasification may have to be done at a higher temperature than the melting temperature of the metal.
  • the gas produced will include molten metal particles.
  • the gas may be cooled in a fluidized bed gas cooler, in which the gas produced and molten particles entrained therein are mixed with cooled particles. The molten metal particles contact cooled particles and are rapidly cooled to a temperature below their melting temperature, whereafter they can be separated from the gas.
  • the organic material gasified in the gasifier includes Cl, i.e. if PVC plastic material is gasified, then the produced gas can be washed after cooling to separate HCl from the gas.
  • the waste material from which metal is to be recovered may be pretreated by crushing and/or washing.
  • Coarse heavy solid impurities may be separated from the uncrushed or crushed waste material prior to introduction of the waste material into the gasifier.
  • iron material may be separated mechanically or magnetically from plastic material and light weight aluminum material.
  • Heavy solid impurities typically originate from iron scrap, refractory material or metal straps used to bind the waste material into bales.
  • Crushed or possibly uncrushed waste material may be washed or soaked in water or solvent for dissolving soluble components, such as alkali salts or other harmful components. Soluble components may thus be separated from the waste material prior to introduction of the waste material into the gasifier.
  • alkali salts may at least partly be removed from the waste material prior to introduction thereof into the gasifier.
  • recoverable fiber material present in the waste material may be removed by washing or slushing of the waste material, prior to the introduction into the gasifier.
  • a conventional separator such as a centrifugal cyclone, may be arranged downstream of the gasifier for separating the metal material being discharged from the gasifier with the gas produced in the gasifier.
  • the present invention provides a recycling process in which the light metal fraction of the waste material may be separated from organic material without thereby simultaneously separating and mixing into the light metal fraction other metal material or other heavy impurities possibly present in the waste material.
  • Waste material 10 is introduced into an optional pretreatment apparatus 12, such as a washer and/or crusher. During the pretreatment the waste material may be mixed with water 14 or other liquid for e.g. separating alkali salts or fibers from the waste material. Liquid introduced into the pretreament apparatus is discharged through outlet 16. Heavy impurities, such as iron scrap, may be discharged through another outlet 18.
  • the pretreated waste material is conveyed through channel 20 into a gasifier 22.
  • Gasification air 24 is introduced into the gasifier through bottom grid 26 for fluidizing a bed 28 of solid particles therein.
  • Bottom ash and heavy impurities are discharged from the bed 28 through an outlet 30 connected to an opening in the grid 26.
  • Gas produced in the gasifier is discharged through an outlet 32 in the top of the gasifier. Thin metal flakes released from the waste material during gasification are entrained by the gas flowing upward in the gasifier and discharged through outlet 32 as well.
  • the gas flow is conveyed through a gas cooler 34. Heat may be utilized in e.g. power production (not shown) .
  • the cooled gas is introduced into a centrifugal cyclone 36. The thin flakes or particles of metal material are separated from the gas in the cyclone. Metal is discharged through outlet 38 and cleaned gas through outlet 40.
  • the clean gas may be used in power production or any other process utilizing combustion heat.
  • the process also allows e.g. plastic to be gasified at a relatively high temperature, at which the degree of carbon conversion (in plastic) to gas is high.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Processing Of Solid Wastes (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Paper (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Wrappers (AREA)
  • Machines For Manufacturing Corrugated Board In Mechanical Paper-Making Processes (AREA)

Abstract

Process and apparatus for recovering metal material from waste material including organic material, such as plastic, and metal material in the form of thin foil material. The process includes following steps: (a) introducing the waste material from which metal is to be recovered into a fluidized bed gasifier, for gasification of the organic material, and (b) separating metal material from gas produced in step (a). The apparatus includes: a fluidized bed gasifier with a fluidized bed of solids therein, for gasification of the organic material in the waste material from which metal is to be recovered, and a separator for separating metal material from gas produced in the gasifier.

Description

PROCESS AND APPARATUS FOR RECOVERING METAL MATERIAL FROM WASTE MATERIAL
The present invention refers to a process and an apparatus for recovering metal material from waste material including organic material, such as plastic, and metal material in the form of thin foil material, as specified in the preamble of appending independent claims.
Many wastes contain valuable materials like metals, glass, paper fibers, wood and plastics. Part of the valuable materials can be rather easily separated from the waste material. E.g. paper fibers can be separated from other waste material by mixing the waste material with water. Fibers mixed with water form an aqueous suspension, which can rather easily be separated from the rest of the waste material.
It is also well known that iron may be separated from waste material by crushing the waste material and separating iron magnetically. Some metal materials may be separated from waste material by combusting the organic material in the waste and recovering metal from the combustion residue.
It is also known to combust waste, as such, in order to recover energy therefrom as thermal energy. It has further been suggested to gasify community waste or other similar waste material for providing useful product gas, which may be used for energy generation.
The combustion of waste material can, however, be difficult, if the content of metals in the waste is high and if the metals have a low melting temperature, e.g. below typical combustion temperatures, e.g. below 1100°C.
Such metals are e.g. Al, Ag, Au, Mg, Pb, Zn and Sn. Molten metals tend to form deposits on surfaces and cause serious fouling in the waste combusting boilers. Alkali salts present in the waste material tend to increase the problem caused by deposits and fouling in combustors. Many waste materials contain aluminum in a form which may melt already at temperatures of about 670 - 700 °C. Such waste material, if combusted or gasified with air, should therefore be treated at temperatures well below the melting point of aluminum present therein, preferably well below 650 °C, in order to avoid problems derived from molten aluminum.
Aluminum dust may be a very hazardous component in any combustion process. Aluminum if oxidized may form locally very high temperatures, temperatures above 2000°C, or even almost 3000°C. Such high local temperatures in combustors can cause severe damage to the combustor. Further aluminum in dust form is an explosive material when mixed with air. Also metallic aluminum may react with alkali hydroxide, e.g. present in fly ash, and form aluminum hydroxide and hydrogen gas. It is well known that hydrogen gas under certain conditions may easily form explosive gas mixtures. Also storage of fly ash with aluminum may cause problems as formation of hydrogen gas in the fly ash may continue for a long time in its dumping place.
However, many waste materials originating from packing and insulation industry, electronic devices or components, car demolition wastes contain such amounts of low melting metals that recovery of these is of high interest. Circuit boards for instance include thin foils of particularly valuable metals. E.g. etiquettes, on the other hand, contain considerable amounts of metal foils. Often the metal is in the form of thin metal foils, the thickness usually being between 5 - 50 μm, which renders a mechanical separation of the metal almost impossible.
The present invention sets out to provide an improved process for recovering metal material from waste material and an improved apparatus therefore, which overcomes drawbacks discussed above. It is also an object of the present invention to provide a process and apparatus for recovering metal material from waste material in which the heating value of plastic material present in the waste material is recovered in an optimum way.
It is a further object of the present invention to provide a process and apparatus for recovering metal material from waste material in which metal, such as aluminum, present in the waste material, may be recovered in a optimum form.
It is a still further object of the present invention to provide a process and apparatus for recovering metal material from waste material at a relatively low temperature, at which many problems arising from high temperatures can be avoided.
The present improved process and apparatus for recovering metal material from waste material thereby are characterized by what is more closely stated in the characterizing portions of appending independent claims.
Thereby a typical process for recovering metal from waste material including organic material, such as plastic, and metal material in the form of thin foil material, includes following steps:
(a) introducing the waste material from which metal is to be recovered into a fluidized bed gasifier, for gasification of the organic material, and (b) separating metal material from gas produced in step (a) .
Correspondingly a typical apparatus for recovering metal from waste material includes - a fluidized bed gasifier with a fluidized bed of solids therein, for gasification of the organic material in the waste material from which metal is to be recovered, and - a separator for separating metal material from gas produced in the gasifier.
Typically metal, such as Ag, Al, Au, Mg, Pb, Zn and/or Sn, present as thin metal foils in waste material may be recovered according to the present invention. The foil material may have a thickness of about 5 - 50 μm. In the fluidized bed in the gasifier the thin foil material is torn into small flakes. The actual gas velocity in the fluidized bed is to be set such that the metal flakes are entrained with the gas up to the gas outlet, but the not yet gasified waste material and bed particles stay in the bed. A slowly fluidized, bubbling fluidized bed, having a gas velocity < 2 m/s, typically 0,5 - 1 m/s, may be used. The bed typically consists of inert solid particles having a mean diameter of about 0,5 to 2 mm, typically about 1 mm.
In waste material the metal foils are generally more or less permanently combined to some organic material, such as plastic or paper. If the waste includes polyethylene or other plastic material, which does not contain chlorine, the waste material can rather easily be gasified with air. Polyethylene has a high heating value and consists of almost 100 % volatiles, which can almost totally be converted to gases and vapors in an air blown gasifier at temperatures well below the melting temperature of aluminum present. The plastic material is thereby a very valuable fuel. A combustible gas having a high heat value of about 7 - 15 MJ/m3, typically 9 - 10 MJ/m3, may be produced in the gasifier. The gas can be used in power production or other processes utilizing combustion heat.
The temperature in the gasifier is typically maintained close to but just below the melting temperature of the metal material to be recovered from the gas produced in the gasifier. The temperature thereby typically is kept below 1100°C. Gasification of plastic material usually takes place at a temperature < 650°C. Gasification of polyethylene can take place at a temperature of about 400 - 550°C.
The gas produced in step (a) is typically cooled and heat energy recovered therefrom before the metal material is separated from the gas.
If metal materials having very low melting temperatures, e.g. 200 - 400 °C, are to be gasified in the gasifier, then the gasification may have to be done at a higher temperature than the melting temperature of the metal. In such cases the gas produced will include molten metal particles. The gas may be cooled in a fluidized bed gas cooler, in which the gas produced and molten particles entrained therein are mixed with cooled particles. The molten metal particles contact cooled particles and are rapidly cooled to a temperature below their melting temperature, whereafter they can be separated from the gas.
If the organic material gasified in the gasifier includes Cl, i.e. if PVC plastic material is gasified, then the produced gas can be washed after cooling to separate HCl from the gas.
The waste material from which metal is to be recovered may be pretreated by crushing and/or washing. Coarse heavy solid impurities may be separated from the uncrushed or crushed waste material prior to introduction of the waste material into the gasifier. Thus, e.g. iron material may be separated mechanically or magnetically from plastic material and light weight aluminum material. Heavy solid impurities typically originate from iron scrap, refractory material or metal straps used to bind the waste material into bales.
Most heavy impurities are, as discussed above, separated from the waste material before it is introduced into the gasifier. Some heavy metal material may, however, still remain in the material introduced into the gasifier. Such remaining heavy metal impurities will discharge from the gasifier together with bottom ash, being discharged from the bottom of gasifier. Impurities originating from heavy metal scrap or the like is too heavy to be entrained by the upward gas flow in the gasifier and is therefore not mixed into the product gas and the light metal material fraction being discharged from the top of the gasifier.
Crushed or possibly uncrushed waste material may be washed or soaked in water or solvent for dissolving soluble components, such as alkali salts or other harmful components. Soluble components may thus be separated from the waste material prior to introduction of the waste material into the gasifier. Thus e.g. alkali salts may at least partly be removed from the waste material prior to introduction thereof into the gasifier.Also, recoverable fiber material present in the waste material may be removed by washing or slushing of the waste material, prior to the introduction into the gasifier.
A conventional separator, such as a centrifugal cyclone, may be arranged downstream of the gasifier for separating the metal material being discharged from the gasifier with the gas produced in the gasifier.
The present invention provides a recycling process in which the light metal fraction of the waste material may be separated from organic material without thereby simultaneously separating and mixing into the light metal fraction other metal material or other heavy impurities possibly present in the waste material.
The present invention will now be described in more detail in accordance with enclosed figure showing schematically a process according to the invention.
Waste material 10 is introduced into an optional pretreatment apparatus 12, such as a washer and/or crusher. During the pretreatment the waste material may be mixed with water 14 or other liquid for e.g. separating alkali salts or fibers from the waste material. Liquid introduced into the pretreament apparatus is discharged through outlet 16. Heavy impurities, such as iron scrap, may be discharged through another outlet 18.
The pretreated waste material is conveyed through channel 20 into a gasifier 22. Gasification air 24 is introduced into the gasifier through bottom grid 26 for fluidizing a bed 28 of solid particles therein. Bottom ash and heavy impurities are discharged from the bed 28 through an outlet 30 connected to an opening in the grid 26.
Gas produced in the gasifier is discharged through an outlet 32 in the top of the gasifier. Thin metal flakes released from the waste material during gasification are entrained by the gas flowing upward in the gasifier and discharged through outlet 32 as well.
The gas flow is conveyed through a gas cooler 34. Heat may be utilized in e.g. power production (not shown) . The cooled gas is introduced into a centrifugal cyclone 36. The thin flakes or particles of metal material are separated from the gas in the cyclone. Metal is discharged through outlet 38 and cleaned gas through outlet 40. The clean gas may be used in power production or any other process utilizing combustion heat.
Following advantages may be achieved with the process shown in the drawing:
- Washing of the waste material before introduction into the gasifier removes solvable alkali salts, which usually are causing problems in thermal processes, such as gasification. Problems, such as corrosion, deposits on surfaces, fouling and emissions from the thermal process may be minimized. - Washing also allows for the separation of larger metal pieces from the waste material, thus providing a rather clean fuel for the gasification.
- The process also allows e.g. plastic to be gasified at a relatively high temperature, at which the degree of carbon conversion (in plastic) to gas is high.
- When operating at a temperature below the melting point of metal to be recovered, many problems in the gasification and gas cleaning can be avoided. The temperature in the gasification process can be controlled in a very accurate way and it is therefore possible to operate the gasifier very close to the melting point of the metal and avoid problems emanating from the metal melting. It is also possible to produce a gas, which contains low amounts of ungasified carbon. - As the soot content in the gas flow is low, the metal flakes separated from the gas are almost free of carbon and can easily be recovered for metal production.
The present invention should not be limited to only cover the specific application described above. The present invention is, on the contrary, intended to provide a protection for the present invention as broadly as defined by the appended claims.

Claims

Claims :
1. Process for recovering metal material from waste material including - organic material, such as plastic, and
- metal material in the form of thin foil material, characterized by the process including following steps:
(a) introducing the waste material from which metal is to be recovered into a fluidized bed gasifier, for gasification of the organic material, and
(b) separating metal material from gas produced in step (a) .
2. Process according to claim 1, characterized by cooling gas produced in step (a) and recovering heat energy therefrom before separating metal material therefrom.
3. Process according to claim 2 , characterized by maintaining the temperature in the gasifier below the melting temperature of the metal material to be recovered from the gas produced in the gasifier.
4. Process according to claim 1 , characterized by the gasification of organic material in step (a) taking place at a temperature below 1100°C.
5. Process according to claim 1, characterized by the gasification of plastic material in step (a) taking place at a temperature of 550 - 650°C.
6. Process according to claim 1, characterized by the gasification of polyethylene in step (a) at a temperature of 400 - 550°C.
7. Process according to claim 1, characterized by
- maintaining the temperature in the gasifier above the melting temperature of a metal material to be recovered from the gas produced in the gasifier, and - introducing gas produced in the gasifier and including molten metal material into a fluidized bed gas cooler for solidifying and recovering the molten metal material.
8. Process according to claim l, characterized by in a pretreatment step prior to step (a) crushing waste material from which metal is to be recovered.
9. Process according to claim 1, characterized bv washing crushed waste material in water or solvent for dissolving soluble components, such as alkali salts, and separating the soluble components from the waste material prior to introduction of the waste material into the gasifier.
10. Process according to claim 1, characterized by washing crushed waste material in water or solvent for slushing and separating slushable components, such as fibers, from the waste material prior to introduction of the waste material into the gasifier.
11. Process according to claim 8, characterized by separating coarse heavy metal components from the crushed waste material prior to introduction of the waste material into the gasifier.
12. Process according to claim 1, characterized by recovering Al, Ag, Au, Mg, Pb, Zn and/or Sn foil material from waste material.
13. Process according to claim 1, characterized by recovering foil material having a thickness of about 5 - 50 μm.
14. Process according to claim 1, characterized by forming in the gasifier a bubbling fluidized bed of solid particles, the particles having a size of about 0,5 - 2 mm, and fluidizing the bed with a fluidization velocity of < 2 m/s, typically 0,5 - 1 m/s.
15. Process according to claim 1, characterized by discharging heavy impurities, such as iron material, from the gasifier with the gasifier bottom ash.
16. Process according to claim 1, characterized by producing in step (a) a combustible gas having a high heat value of about 7 - 15 MJ/m3, typically 9 - 10 MJ/m3, for use in power production or other processes utilizing combustion heat.
17. Process according to claim 1, characterized by recovering metal from electronic devices and components, such as circuit boards, car demolition components, insulation material, packing material and/or etiquettes.
18. Apparatus for recovering metal material from waste material including
- organic material, such as plastic, and
- metal material in the form of thin foil material, characterized by the apparatus including: - a fluidized bed gasifier with a fluidized bed of solids therein, for gasification of the organic material in the waste material from which metal is to be recovered, and
- a separator for separating metal material from gas produced in the gasifier.
19. An apparatus according to claim 18, characterized by the apparatus including a gas cooling means, for cooling the gas produced in the fluidized bed gasifier and recovering heat energy therefrom,
20. An apparatus according to claim 19, characterized by the separator for separating metal from gas being arranged downstream of the gas cooling means.
21. An apparatus according to claim 18, characterized by the separator for separating metal from gas being a centrifugal cyclone.
22. An apparatus according to claim 18, characterized by the apparatus including crushing means, for crushing the waste material from which metal is to be recovered.
23. An apparatus according to claim 21, characterized by the apparatus including a washing means for washing the crushed waste material and separating soluble components therefrom.
AMENDED CLAIMS
[received by the International Bureau on 13 January 2000 (13.01.00); original claims 1 - 23 replaced by new claims 1 - 19 (3 pages)]
Claims :
1. Process for recovering metal material from waste material including - organic material, such as plastic, and
- metal material in the form of thin foil material, characterized bv the process including following steps: (a) introducing the waste material from which metal is to be recovered into a fluidized bed gasifier, for gasification of the organic material, while maintaining the temperature in the gasifier below the melting temperature of the metal material to be recovered from the gas produced in the gasifier, and (b) separating metal material from gas produced in step (a) .
2. Process according to claim 1, characterized by cooling gas produced in step (a) and recovering heat energy therefrom before separating metal material therefrom.
3. Process according to claim 1, characterized by the gasification of organic material in step (a) taking place at a temperature below 1100°C.
4. Process according to claim 1, characterized by the gasification of plastic material in step (a) taking place at a temperature of 550 - 650°C.
5. Process according to claim 1, characterized by the gasification of polyethylene in step (a) at a temperature of 400 - 550°C.
6. Process according to claim 1, characterized by in a pretreatment step prior to step (a) crushing waste material from which metal is to be recovered.
7. Process according to claim 1, characterized by washing crushed waste material in water or solvent for dissolving soluble components, such as alkali salts, and separating the soluble components from the waste material prior to introduction of the waste material into the gasifier.
8. Process according to claim 1, characterized bv washing crushed waste material in water or solvent for slushing and separating slushable components, such as fibers, from the waste material prior to introduction of the waste material into the gasifier.
9. Process according to claim 6, characterized by separating coarse heavy metal components from the crushed waste material prior to introduction of the waste material into the gasifier.
10. Process according to claim 1, characterized by recovering Al, Ag, Au, Mg, Pb, Zn and/or Sn foil material from waste material.
11. Process according to claim 1, characterized by recovering foil material having a thickness of about 5 - 50 μm.
12. Process according to claim 1, characterized by forming in the gasifier a bubbling fluidized bed of solid particles, the particles having a size of about 0,5 - 2 mm, and fluidizing the bed with a fluidization velocity of < 2 m/s, typically 0,5 - 1 m/s.
13. Process according to claim 1 , characterized by discharging heavy impurities, such as iron material, from the gasifier with the gasifier bottom ash.
14. Process according to claim 1, characterized bv producing in step (a) a combustible gas having a high heat value of about 7 - 15 MJ/m3, typically 9 - 10 MJ/m3, for use in power production or other processes utilizing combustion heat.
15. Process according to claim 1, characterized by recovering metal from electronic devices and components, such as circuit boards, car demolition components, insulation material, packing material and/or etiquettes.
16. Apparatus for recovering metal material from waste material including
- organic material, such as plastic, and
- metal material in the form of thin foil material, characterized bv the apparatus including: - a pretreatment apparatus, for crushing the waste material from which metal is to be recovered, washing the crushed waste material and separating soluble components therefrom,
- a fluidized bed gasifier with a fluidized bed of solids therein, for gasification of the organic material in the pretreated waste material from which metal is to be recovered, and
- a separator for separating metal material from gas produced in the gasifier.
17. An apparatus according to claim 16, characterized by the apparatus including a gas cooling means, for cooling the gas produced in the fluidized bed gasifier and recovering heat energy therefrom,
18. An apparatus according to claim 17, characterized by the separator for separating metal from gas being arranged downstream of the gas cooling means.
19. An apparatus according to claim 16, characterized by the separator for separating metal from gas being a centrifugal cyclone.
PCT/FI1999/000667 1998-08-12 1999-08-12 Process and apparatus for recovering metal material from waste material Ceased WO2000009770A1 (en)

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EP99938415A EP1119645B1 (en) 1998-08-12 1999-08-12 Process and apparatus for recovering metal material from waste material
AU52923/99A AU5292399A (en) 1998-08-12 1999-08-12 Process and apparatus for recovering metal material from waste material
AT99938415T ATE244314T1 (en) 1998-08-12 1999-08-12 METHOD AND DEVICE FOR RECOVERING METALS FROM WASTE MATERIAL
DE69909309T DE69909309T2 (en) 1998-08-12 1999-08-12 METHOD AND DEVICE FOR RECOVERY OF METALS FROM WASTE MATERIAL
JP2000565203A JP2002522644A (en) 1998-08-12 1999-08-12 How to recover metallic materials from waste
US09/762,718 US6409798B1 (en) 1998-08-12 1999-08-12 Process for recovering metal material from waste material

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FI981742A FI981742A0 (en) 1998-08-12 1998-08-12 Liquid packaging board waste material recycling process and device for recycling liquid packaging board waste material
FI981742 1998-08-12

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US6409798B1 (en) 2002-06-25
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RU2222617C2 (en) 2004-01-27
ES2201755T3 (en) 2004-03-16
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DE69909309T2 (en) 2004-05-27
WO2000009771A1 (en) 2000-02-24

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