WO2000046163A1 - Baustoff, verfahren zur herstellung eines baustoffes und bauelement - Google Patents
Baustoff, verfahren zur herstellung eines baustoffes und bauelement Download PDFInfo
- Publication number
- WO2000046163A1 WO2000046163A1 PCT/EP2000/000635 EP0000635W WO0046163A1 WO 2000046163 A1 WO2000046163 A1 WO 2000046163A1 EP 0000635 W EP0000635 W EP 0000635W WO 0046163 A1 WO0046163 A1 WO 0046163A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- silicate
- containing material
- building material
- weight
- building
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
Definitions
- the invention relates to a building material with a main component made of a silicate-containing material.
- the invention further relates to a method for producing a building material.
- the building material according to the invention can be used for a wide variety of purposes.
- building elements can be produced from the building material, which, for example, can be plate-shaped, rectangular or cube-shaped and with which buildings, walls, floors or ceilings can be produced.
- the building material according to the invention can also be processed into mortars, plasters, spatulas, screeds, adhesives and the like.
- the object of the invention is in particular a component made from the building material of the invention.
- DE 41 32 009 AI describes, for example, a building material consisting of clay, sawdust and wood shavings, chopped straw, cement and plaster as well as water. This building material is pumpable and sprayable and can be applied to a suitable plaster base. This is intended to produce a homogeneous clay coating.
- DE 41 40 093 AI the production of light clay bricks from straw and clay is also known. Such a light clay brick is produced with little water and extensive crushing and pelleting of the raw materials.
- the building materials known to date from the prior art or the components produced therefrom are generally distinguished by considerable disadvantages. A majority of the known building materials or components do not have sufficient moisture resistance. Many building materials are environmentally problematic and cannot be disposed of easily.
- the invention is based on the technical problem of specifying a building material of the type mentioned at the outset with which the disadvantages described above are avoided, which can be produced in a simple and inexpensive manner in particular and which also meets all requirements in the long term.
- the invention is further based on the technical problem of specifying a method for producing such a building material.
- the invention first teaches a building material with a main component made of a silicate-containing material,
- the silicate-containing material being subjected to mechanical activation before being used as the main component
- the silicate-containing material has a grain size ⁇ 0.1 mm.
- the silicate-containing material can be mechanically activated by washing with coarse-grained particles, preferably with a grain size> 0.1 mm.
- the coarser-grained particles are expediently also a silicate-containing material.
- the washing is conveniently done with water.
- the mechanical activation according to the invention takes place due to the stringing together of the various particles during washing. Such washing is carried out in particular in washing plants for aggregates of concrete or mortar products, in gravel washing plants, in sand washing plants and the like.
- the silicate-containing material falls as a by-product of a concrete aggregate washing system and / or aggregate aggregate washing system and / or gravel washing plant and / or sand washing plant and the silicate-containing material can be mechanically activated by the washing taking place in the washing plant.
- the mechanical activation of the silicate-containing material takes place here by washing with coarser particles of the concrete aggregate or mortar aggregate or the gravel or sand. These coarse-grained particles have a grain size> 0.063 mm or> 0.1 mm.
- the mechanical activation is brought about by the mechanical forces or by the frictional forces that occur during washing between the coarser-grained particles and the fine-grained silicate-containing material.
- the fine-grained constituents or the mineral fine constituents are obtained as waste materials, in particular as blowdown products and / or washing-up products in these washing systems. These by-products have so far been considered unsuitable for construction purposes.
- the slurried or slurrable fine-grained mineral washing products from concrete aggregate washing systems are unsuitable, for example, for the production of concrete because they have the shrinkage values, swelling values and Subsequently influence the strength values of a concrete.
- the invention is based on the knowledge that these by-products from concrete aggregate washing systems, mortar aggregate washing systems, gravel washing systems and sand washing systems, which accumulate in large quantities and have previously been costly to dispose of, can be used excellently for the production of the building materials according to the invention. It is within the scope of the invention that the silicate-containing materials used according to the invention can have small amounts of water, which come in particular from one of the abovementioned washing systems.
- At least 50% by weight of the silicate-containing material has a grain size ⁇ 0.1 mm.
- at least 70% by weight, preferably at least 80% by weight, very preferably at least 90% by weight, of the silicate-containing material has a grain size ⁇ 0.1 mm.
- 90 to 100% by weight of the silicate-containing material has a grain size ⁇ 0.1 mm. It is within the scope of the invention that at least 50% by weight of the silicate-containing material have a grain size ⁇ 0.063 mm.
- At least 70% by weight, preferably at least 80% by weight, very preferably at least 90% by weight, of the silicate-containing material has a grain size of ⁇ 0.063 mm.
- 90 to 100% by weight of the silicate-containing Material has a grain size ⁇ 0.063 mm.
- the proportion of the silicate-containing material which has a grain size ⁇ 0.1 mm or which has a grain size ⁇ 0.063 mm preferably consists of less than 40% by weight of a material which has a grain diameter ⁇ 0.005 mm.
- at least 50% by weight, preferably at least 70% by weight, very preferably at least 90% by weight, of the silicate-containing material consists of silt.
- At least 90 to 100% by weight of the silicate-containing material consists of silt.
- a silicate-containing material with less than 30% by weight, preferably with less than 20% by weight, of aluminosilicate constituents is used.
- the building material contains 40 to 90% by weight of the main component. If a component, for example a plate or a cuboid or cube-shaped component, is produced from the building material according to the invention, the building material advantageously contains 40 to 90% by weight of the main component. If a plaster or mortar is produced from the building material according to the invention, the building material preferably contains 10 to 60% by weight of the main component. The above, related to the main component Weight percentages refer to the building material without the addition of water.
- the building material preferably contains at least 2% by weight of a binder.
- the building material expediently contains 5 to 70% by weight, preferably 5 to 60% by weight, of at least one binder.
- a hydraulic binder for example a hydraulic binder of mineral origin, is used.
- At least one cement and / or lime and / or gypsum is preferably used as the hydraulic binder.
- ash preferably fly ash, as a binder.
- the above percentages by weight relating to the binder relate to the building material without the addition of water.
- the building material contains at least 0.2% by weight, preferably at least 0.5% by weight, of chips and / or fibers. It is within the scope of the invention that the building material contains 0.5% by weight to 25% by weight, preferably 0.5% by weight to 20% by weight, of chips and / or fibers.
- the above percentages by weight relating to the chips and / or fibers mean the building material or the building material mixture without the addition of water.
- the building material contains natural fibers and / or plastic fibers and / or glass fibers. Natural fibers means in particular wood fibers and / or coconut fibers and / or sisal fibers and / or hemp fibers and / or straw fibers.
- Plastic fibers mean in particular plastic fibers with hydrophilic Characteristics.
- Polyalkene fibers and / or polyacrylonitrile fibers and / or polyvinyl acetate fibers can be used as plastic fibers.
- Polypropylene fibers are expediently used as polyalkene fibers.
- the building material contains wood fibers and / or wood chips.
- the fiber length of the wood fibers and / or wood chips is expediently 5 to 10 mm or 5 to 20 mm.
- the diameter of the wood fibers and / or wood chips is 0.2 to 3 mm, preferably 0.3 to 2 mm.
- the addition of fibers and / or chips can very effectively increase the standard tensile strength of the end product made from the building material according to the invention.
- the invention further teaches a method for producing a building material, wherein a mechanically activated silicate-containing material, which has at least 50% by weight of a grain size ⁇ 0.1 mm, is mixed with at least one additive.
- a mechanically activated silicate-containing material which has at least 50% by weight of a grain size ⁇ 0.1 mm
- the mechanically activated silicate-containing material is additionally treated mechanically and / or chemically and / or biologically before it is used in the building material according to the invention.
- the mechanically activated silicate-containing material is subjected to at least one post-activation before mixing with the at least one additive. It is within the scope of the invention that the post-activation is caused by moisture and / or air.
- the mechanically activated silicate-containing material before mixing with the at least one additive.
- the mechanically activated silicate-containing material is stored outdoors, advantageously at least two weeks, preferably several months. Weathering, ie storing the silicate-containing material outdoors, can take, for example, 1 to 15 months. It has been shown that the silicate-containing material weathered according to this preferred embodiment is particularly suitable for the building material according to the invention.
- the mechanically activated silicate-containing material is rolled before mixing with the at least one additive of a koller device.
- coarser constituents still present in the starting material are expediently comminuted.
- a further post-activation namely a further mechanical activation of the silicate-containing material takes place during the rolling.
- the friction between the particles that occurs during the rolling causes a further physico-chemical activation of the particle surfaces.
- the rolled silicate-containing material is particularly suitable for the building material according to the invention. It is within the scope of the invention that the mechanically activated silicate-containing material is fed to the koller device in the earth-moist state.
- Water in particular rainwater, can be added during rolling and other additives, such as high molecular weight polyelectrolytes, can be added.
- this is mechanical activated silicate-containing material first weathered and rolled after weathering.
- the mechanically activated silicate-containing material is rolled off before mixing with the at least one additive.
- the material is crushed to a desired grain size. Only one fine rolling mill can be used, or several fine rolling mills can be arranged one behind the other, expediently a stepwise comminution of coarser components takes place.
- post-activation in particular mechanical activation of the silicate-containing material takes place during fine rolling. Additional additives such as high molecular weight polyelectrolytes can be added during fine rolling.
- the fine rolling expediently takes place after an upstream rolling mill.
- the mechanically activated silicate-containing material is first weathered, then rolled and then finely rolled.
- At least one additive is preferably added to the silicate-containing material after weathering and / or rolling and / or fine rolling.
- At least one binder preferably a hydraulic binder, is expediently added.
- the binder may be cement and / or lime and / or gypsum and / or ash.
- Water in particular rainwater, is added before, during or after mixing with the at least one additive.
- Fibers and / or chips are also mixed in according to the invention. It has already been explained above which fibers and / or chips are particularly suitable in this connection.
- a wide variety of inorganic, organic and / or biological additives can be mixed in, in particular to improve the processability and / or to produce certain properties of the building material.
- high molecular weight polyelectrolytes and / or high molecular weight polywaxes can be added.
- inorganic additives such as silica and / or soda can be added.
- fillers such as brick powder and / or stone powder, are added.
- organic additives such as glycol and / or alcoholates and / or glycerin can be added.
- at least one biological additive from the group "casein, urea, sugar derivative, tannin, lignm, whey, molasses, liquid manure" is added. - Mixing with the at least one additive is preferably carried out in a forced batch mixer.
- the compulsory batch mixer transfers sufficient shear forces to the mix to effectively break up agglomerates and conglomerates.
- the batch of mixed material can be separated for buffering and ripening the mixed material.
- the type and / or the amount of the additive or additives is selected as a function of how the building material according to the invention is used should be, ie for the production of components or as mortar, plaster, spatula, screed, adhesive or the like.
- the mixture is preferably precompressed and homogenized first.
- the mixed material is expediently pressed thereafter, and the shaping into a component shaped strand is then preferably carried out.
- the shaped strand can then be cut into segments.
- the segments are then expediently dried. Thereafter, the segments are preferably trimmed to form the components.
- a preferred method according to the invention for producing components by listing the individual method steps is given below:
- the respective Intermediate product is processed into mortars, plasters, spatulas, screeds or adhesives using known measures.
- molds for relief and hollow bodies can also be produced from the intermediate product.
- the components obtained can be processed further, for example by edge profiling and / or by grinding the surface and / or by means of a surface coating.
- the components produced using the method according to the invention can in principle have a wide variety of shapes and, for example, be plate-shaped, cuboid, cube-shaped or cylindrical.
- the components can have profiled surfaces and / or cavities, such as air channels.
- plate-shaped components are used for floors and the surface of the plate-shaped components has channel-like profiles, into which lines or pipes from floor heating systems can be inserted.
- the invention is based on the knowledge that building materials or components can be produced in a simple and inexpensive manner, if the teaching according to the invention is used. Building materials and components are obtained which are characterized by high moisture resistance and frost resistance and which meet all requirements with regard to their mechanical properties. The building materials and components meet all ecological, building physics and building physiology requirements. If the building materials and components for manufacturing according to the invention of buildings, for example residential and office spaces, they surprisingly contribute to an increased well-being of the people staying in these buildings or rooms. The building materials and components according to the invention are distinguished by excellent properties with regard to fire protection, thermal insulation and with regard to impact sound insulation. It should also be emphasized that the building materials are environmentally friendly and can be easily disposed of.
- the building materials or components to be disposed of can be easily prepared in such a way that they can be used again to produce a building material according to the invention.
- the components produced in the context of the invention can be used in a variety of ways, for example for wall construction, ceiling construction and floor construction of buildings.
- the components can be used, for example, as thermal insulation panels or lightweight panels.
- the invention is explained in more detail below on the basis of exemplary embodiments:
- thermal insulation board 80 weight points of a mechanically activated silicate-containing material from a concrete aggregate washing system with 20 weight points of cement and water were mixed in the forced batch mixer. The amount of water was chosen so that the water / solids ratio was 0.45. After sufficient mixing of the aforementioned components, 20 parts by weight of finely comminuted wood chips with a fiber length of up to 10 mm and a diameter of about 0.3 mm to 2 mm were added. The mixture in the batch mixer was followed by a phase of buffering, calming and maturing of the mix. The mix was then pre-compressed and homogenized in a pre-press.
- the mix was then passed through a working press with a pre-compression stage with a twin-shaft mixing system and a screw press connected to it, and was pressed by a press head arranged at the end of the working press for shaping.
- the exchangeable press head of the working press gives the component the desired contour on the one hand and on the other hand it can also be used to create cavities, in particular air channels, inside the component or the plate.
- segments were then separated from the continuous component molding strand produced. After intermediate storage or drying, the segment was trimmed to the desired shape. After appropriate comminution, the resulting sections could be returned to the starting material for the production of the building material.
- the thermal insulation board obtained had a dry bulk density (28d) of 0.9 kg / dm 3 , a standard compressive strength (28d) of 6 N / mm 2 , a standard tensile strength (28d) of 3 N / mm 2 and a thermal conductivity of 0.3 W. / mK on.
- Example 2
- a lightweight board which had a dry bulk density (28d) of 1 kg / dm 3 and the following parameters: standard compressive strength (28d) of 16 N / mm 2 and a standard tensile strength (28d) of 8 N / mm 2 without loss of mass or a compressive and bending tensile strength of up to 80 cycles / 12 h at temperatures from -30 ° C to +30 ° C.
- a frost- and thaw-stable component in the form of a prism 70 parts by weight of the silicate-containing material according to embodiment 2 were mixed with 30 parts by weight of cement and water. The water-solid ratio was 0.4. After the starting components mentioned had been mixed, 6.2 parts by weight of short-cut coconut fibers with a length of 0.5 to 3 cm were mixed in. Then the same procedural steps as carried out in the embodiments 1 and 2.
- a prism of high bending tensile strength was obtained with the following parameters: dry bulk density (28d) 1.2 kg / dm 3 , standard compressive strength (28d) 14 N / mm 2 , bending tensile strength of 14 N / mm 2 . At temperatures from -30 ° C to +30 ° C, such a component has a constant compressive and bending strength up to 80 cycles / 12 h without loss of mass.
- the building material obtained had the following parameters: dry bulk density (28d) of 1.6 kg / dm 3 , standard compressive strength (28d) 2.5 N / mm 2 , standard bending tensile strength (28d) of 1.4 N / mm 2 , reversible water absorption and removal of 30 wt. -%.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Laminated Bodies (AREA)
- Finishing Walls (AREA)
- Rod-Shaped Construction Members (AREA)
Abstract
Description
Claims
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT00902637T ATE228979T1 (de) | 1999-02-02 | 2000-01-27 | Baustoff, verfahren zur herstellung eines baustoffes und bauelement |
| EP00902637A EP1070026B1 (de) | 1999-02-02 | 2000-01-27 | Baustoff, verfahren zur herstellung eines baustoffes und bauelement |
| DE10080210T DE10080210D2 (de) | 1999-02-02 | 2000-01-27 | Baustoff, Verfahren zur Herstellung eines Baustoffes und Bauelement |
| AU24403/00A AU2440300A (en) | 1999-02-02 | 2000-01-27 | Building material, method for producing a building material and structural member |
| DE50000858T DE50000858D1 (de) | 1999-02-02 | 2000-01-27 | Baustoff, verfahren zur herstellung eines baustoffes und bauelement |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19905131.3 | 1999-02-02 | ||
| DE1999105131 DE19905131A1 (de) | 1999-02-02 | 1999-02-02 | Baustoff und Bauelemente sowie Verfahren zu ihrer Herstellung |
| DE19938382 | 1999-08-06 | ||
| DE19938382.0 | 1999-08-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2000046163A1 true WO2000046163A1 (de) | 2000-08-10 |
Family
ID=26051734
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2000/000635 Ceased WO2000046163A1 (de) | 1999-02-02 | 2000-01-27 | Baustoff, verfahren zur herstellung eines baustoffes und bauelement |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP1070026B1 (de) |
| AT (1) | ATE228979T1 (de) |
| AU (1) | AU2440300A (de) |
| DE (2) | DE50000858D1 (de) |
| WO (1) | WO2000046163A1 (de) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10024678A1 (de) * | 2000-02-14 | 2001-11-29 | Wki Isoliertechnik Gmbh Berlin | Wärmedämmplatte aus Polystyrol (EPS/XPS) oder Polyurethan (PUR) mit niedriger Wasserdampfdiffusionszahl kleiner 10mu mit äußerer Beschichtung |
| AT512883A1 (de) * | 2012-04-18 | 2013-11-15 | Hubert Edmund Kern | Getrockneter, ungebrannter, diffusionsfähiger, wasserresistenter und frostresistenter, ökonomischer, ökologischer Mergel und/oder Ton und/oder Lehm und/oder Mischformen davon |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0470948A2 (de) * | 1990-08-08 | 1992-02-12 | Köhler-Pavlik, Johann Dipl.-Ing. | Baustoffgemisch zur Herstellung von Form- und Fertigteilen sowie Verfahren zur Herstellung der Baustoffgemische |
| DE19548645A1 (de) * | 1995-12-14 | 1997-06-19 | Witega Angewandte Werkstoff Forschung Gemeinnuetzige Gmbh Adlershof | Verfahren zur Herstellung von hochwertigen Sekundärrohstoffen aus sortenreinem Abbruchmaterial von Bauwerken |
| DE19637680A1 (de) * | 1996-09-05 | 1998-03-12 | Werec Gmbh Berlin Wertstoff Re | Verwertbare Stoffe aus bislang zu deponierenden Kieselglas- und Al¶2¶O¶3¶-Keramikabfällen, wie sie beim Recycling von Entladungslampen anfallen, und Verfahren zu ihrer Herstellung |
-
2000
- 2000-01-27 AT AT00902637T patent/ATE228979T1/de not_active IP Right Cessation
- 2000-01-27 WO PCT/EP2000/000635 patent/WO2000046163A1/de not_active Ceased
- 2000-01-27 DE DE50000858T patent/DE50000858D1/de not_active Expired - Fee Related
- 2000-01-27 AU AU24403/00A patent/AU2440300A/en not_active Abandoned
- 2000-01-27 EP EP00902637A patent/EP1070026B1/de not_active Expired - Lifetime
- 2000-01-27 DE DE10080210T patent/DE10080210D2/de not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0470948A2 (de) * | 1990-08-08 | 1992-02-12 | Köhler-Pavlik, Johann Dipl.-Ing. | Baustoffgemisch zur Herstellung von Form- und Fertigteilen sowie Verfahren zur Herstellung der Baustoffgemische |
| DE19548645A1 (de) * | 1995-12-14 | 1997-06-19 | Witega Angewandte Werkstoff Forschung Gemeinnuetzige Gmbh Adlershof | Verfahren zur Herstellung von hochwertigen Sekundärrohstoffen aus sortenreinem Abbruchmaterial von Bauwerken |
| DE19637680A1 (de) * | 1996-09-05 | 1998-03-12 | Werec Gmbh Berlin Wertstoff Re | Verwertbare Stoffe aus bislang zu deponierenden Kieselglas- und Al¶2¶O¶3¶-Keramikabfällen, wie sie beim Recycling von Entladungslampen anfallen, und Verfahren zu ihrer Herstellung |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10024678A1 (de) * | 2000-02-14 | 2001-11-29 | Wki Isoliertechnik Gmbh Berlin | Wärmedämmplatte aus Polystyrol (EPS/XPS) oder Polyurethan (PUR) mit niedriger Wasserdampfdiffusionszahl kleiner 10mu mit äußerer Beschichtung |
| AT512883A1 (de) * | 2012-04-18 | 2013-11-15 | Hubert Edmund Kern | Getrockneter, ungebrannter, diffusionsfähiger, wasserresistenter und frostresistenter, ökonomischer, ökologischer Mergel und/oder Ton und/oder Lehm und/oder Mischformen davon |
| AT512883B1 (de) * | 2012-04-18 | 2017-09-15 | Edmund Kern Hubert | Getrockneter, ungebrannter, diffusionsfähiger, wasserresistenter und frostresistenter, ökonomischer, ökologischer Mergel und/oder Ton und/oder Lehm und/oder Mischformen davon |
Also Published As
| Publication number | Publication date |
|---|---|
| DE50000858D1 (de) | 2003-01-16 |
| EP1070026B1 (de) | 2002-12-04 |
| ATE228979T1 (de) | 2002-12-15 |
| DE10080210D2 (de) | 2001-09-13 |
| EP1070026A1 (de) | 2001-01-24 |
| AU2440300A (en) | 2000-08-25 |
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