WO2000049221A1 - Silicone coated fluid shield fabric - Google Patents

Silicone coated fluid shield fabric Download PDF

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Publication number
WO2000049221A1
WO2000049221A1 PCT/US2000/040036 US0040036W WO0049221A1 WO 2000049221 A1 WO2000049221 A1 WO 2000049221A1 US 0040036 W US0040036 W US 0040036W WO 0049221 A1 WO0049221 A1 WO 0049221A1
Authority
WO
WIPO (PCT)
Prior art keywords
fabric
fabric substrate
silicone
agent disposed
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2000/040036
Other languages
French (fr)
Inventor
William Carl Kimbrell
Christopher Todd Usher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Milliken and Co
Original Assignee
Milliken and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Milliken and Co filed Critical Milliken and Co
Priority to JP2000599938A priority Critical patent/JP2002537496A/en
Priority to BR0008392-5A priority patent/BR0008392A/en
Priority to EP00915029A priority patent/EP1161590A1/en
Priority to AU36331/00A priority patent/AU3633100A/en
Priority to KR1020017010656A priority patent/KR20020000767A/en
Priority to CA002363080A priority patent/CA2363080A1/en
Publication of WO2000049221A1 publication Critical patent/WO2000049221A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/186—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials one of the layers is on one surface of the fibrous web and the other layer is on the other surface of the fibrous web
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/04—Properties of the materials having electrical or magnetic properties
    • D06N2209/046—Anti-static
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/126—Permeability to liquids, absorption
    • D06N2209/128—Non-permeable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/147—Stainproof, stain repellent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1671—Resistance to bacteria, mildew, mould, fungi
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/14—Furniture, upholstery

Definitions

  • the present invention relates to a fabric useful in upholstery applications and
  • a method for forming such fabric is
  • vinyl coated fabrics are typically rather stiff to the touch and thereby lack the desired
  • the present invention overcomes these seemingly contradictory requirements
  • thin layer (preferably less than 2 oz/sq. yd.) of barrier material to be applied.
  • this barrier layer preferably possess
  • the present invention thus represents a useful advancement over
  • a fluid shield fabric is provided which may be transfer printed.
  • the fabric exhibits a
  • barrier material despite the use of an intermediate fiuorochemical composition.
  • a fabric substrate is
  • the fabric substrate is preferably a woven material although it is contemplated that tightly formed knitted materials and/or nonwovens as are known to those of skill in the art
  • Such fabric substrates are preferably formed from polyester
  • cotton-polyester blends such as nylon, and polypropylene may also be utilized.
  • Coating materials which may be
  • the polymeric material has such properties to allow
  • the fabric was scoured in a 180 - 200°F 7-8 pH bath.
  • the fabric was
  • the fabric is cured at a temperature of about 225 °F to 425 °F preferably
  • resist agent is thereafter passed through a calendering operation so as to flatten at least one
  • the calendering operation is preferably carried out at a pressure of about
  • a PDMS silicone composition is knife coated across the
  • surface for application is preferably calendered it may also be uncalendered.
  • the total weight of the applied barrier layer is less than about 2 oz/sq. yd., preferably less than 1.5 oz/sq. yd. and most preferably about 0.8 to 1 J
  • the fabric is then preferably passed through an oven
  • This operation preferably takes place at a temperature of
  • performance enhancing constituents may include, by way of example only and not limitation,
  • antimicrobial compositions flame retardants, antistats and/or ultraviolet stabilizing agents

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A fabric possessing both cleanability and fluid resistant properties is provided which can, if desired, be transfer printed. The fabric includes a textile substrate treated with a fluorochemical stain resist agent. The treated textile substrate is covered substantially on the back with a layer of coated silicone polymer. A process for forming the fluid shield fabric according to the present invention is also provided.

Description

Description
SILICONE COATED FLUID SHIELD FABRIC
Technical Field
This application is a continuation-in-part of our copending prior Application
Serial No. 08/799,790 entitled FLUID SHIELD FABRIC having a filing date of
February 12, 1997.
The present invention relates to a fabric useful in upholstery applications and
more particularly to a fabric having antimicrobial and stain resistant properties in
combination with a fluid barrier coating suitable for transfer printing which does not
adversely affect the tactile hand of the fabric. A method for forming such fabric is
also provided.
Background Art
Heretofore, a number of approaches have been taken to making fabrics both
cleanable and liquid resistant so as to be more useful in environments where liquid
staining is likely to occur. Vinyl coated fabrics have been most broadly accepted for
these purposes due to relatively easy cleanability and fairly low cost. However, such
vinyl coated fabrics are typically rather stiff to the touch and thereby lack the desired
appearance and feel for use in environments such as restaurants, nursing homes, and
the like where pleasing tactile and visual perceptions by the user are considered
important. Surface laminated fabrics have been utilized to enhance the aesthetic
characteristics of the fabrics, but due to the generally disjunctive adherence between the laminate film and the fabric itself, these products tend to peel, crack, and
delaminate after long periods of use. Such laminated products also tend to lack the
generally desirable feel of standard upholstery products. Adherence of a liquid barrier
film or coating to a fabric substrate is made all the more difficult when fiuorochemical
stain-resist treatments are applied, since such compositions by their nature tend to
repel an applied coating.
The present invention overcomes these seemingly contradictory requirements
of fluorochemically based stain resistance in combination with a strongly adherent
fluid barrier shield through proper selection of the base textile material in combination
with the selection of coating materials and application processes so as to permit a very
thin layer (preferably less than 2 oz/sq. yd.) of barrier material to be applied.
Moreover, the actual material making up this barrier layer preferably possess
dyeability and elastomeric properties which tend to conform substantially to those of
the fabric substrate. The present invention thus represents a useful advancement over
present practices.
Objects and Summary of the Invention
In light of the foregoing, it is a general object of the present invention to
provide a fabric which possesses both stain resist and fluid barrier properties but
which also exhibits a soft fabric hand as in traditional untreated upholstery fabrics
where a soft fabric hand is understood to mean flexibility and/or lack of stiffness in
the fabric itself. It is a more particular object of the present invention to provide a fabric
wherein a barrier coating of polymeric material is adhered in stable relation to a
fluorochemically treated surface.
It is yet a more particular object of the present invention to provide a fluid shield
fabric useful in upholstery applications possessing a barrier coating of silicone polymer
material in stable relation to a fluorochemically treated surface of a woven, knitted, or
nonwoven fabric substrate.
Other objects, advantages and features of the present invention will, no doubt, occur
to those skilled in the art upon reading of the following specification. Thus, while the
invention will be described and disclosed in connection with certain preferred embodiments
and procedures, it is by no means intended to limit the invention to such specific
embodiments and procedures. Rather, it is intended to cover all such alternative
embodiments, procedures, and modifications thereto as may fall within the true spirit and
scope of the invention as defined only by the appended claims and equivalents thereto.
A fluid shield fabric is provided which may be transfer printed. The fabric exhibits a
good hand while maintaining intimate adhesion between the base fabric and the polymeric
barrier material despite the use of an intermediate fiuorochemical composition.
In the potentially preferred practice of the present invention, a fabric substrate is
treated with a fiuorochemical stain resist agent and thereafter coated substantially on the back
side (i.e. the surface which is not to undergo printing) with a layer of polymeric material so as
to yield a final construction which exhibits both fluid and stain resistant properties.
The fabric substrate is preferably a woven material although it is contemplated that tightly formed knitted materials and/or nonwovens as are known to those of skill in the art
may likewise be used if desired. Such fabric substrates are preferably formed from polyester
yarns although it is contemplated that other materials including, by way of example only and
not limitation, cotton-polyester blends, nylon, and polypropylene may also be utilized.
In one particularly preferred embodiment, it has been found that the use of a
calendering procedure to flatten the fabric on the side to be coated reduces the required
amount of polymeric material to achieve the desired barrier properties when knife coating is
used to apply the polymeric material across the woven fabric substrate. It has been further
found that through the use of an appropriate silicone polymer that high degrees of flexibility
can be achieved without the occurrence of delamination. Coating materials which may be
preferred include by way of example only, PDMS silicone compositions sold by Wacker
Chemical in Adrian Michigan including a cross-linking agent and inhibitor as a two
component kit under the trade designation LR3003-10A and B.
The use of a tightly woven fabric with albi yarn enhances adhesion between the fabric
substrate and the polymeric material. The polymeric material has such properties to allow
heat transfer printing at temperatures ranging from 350°F to 450°F without damage to the
polymeric coating. The invention may be further understood and illustrated through reference
to the following non limiting example.
SPECIFIC EXAMPLE 1
The following example describes the preparation of fabric according to the present
invention intended for dye application. A woven fabric having a weave density of about 68 ends per inch by 46 picks per inch
was formed from two ply textured albi polyester yarn to yield a 100% plain weave polyester
woven fabric. The fabric was scoured in a 180 - 200°F 7-8 pH bath. The fabric was
thereafter padded to a pick-up of 50% on both sides with a solution containing about 1% -
40% (about 6.6% preferred) of a fiuorochemical such as MILLIGUARD™ BK 96 a
fluoroacrylate copolymer emulsion from Milliken Chemical in Spartanburg, South Carolina;
about 0.5% - 5.0% (about 3.0% preferred) ULTRA-FRESH™ NM; about 0.05% - 1.0%
(about 1.0% preferred) ULTRA-FRESH™ 40 available from Thompson Research; and 0.5%-
5.0% (3.0% preferred) of an anti-static such as Antistat 993, an ester salt from Sybron
Chemical, in Welford, South Carolina.
While in the preferred practice, this solution will include both antimicrobial and anti¬
static components, it is to be understood and appreciated that one or more of these additional
components may be eliminated if desired. Following the padding application of this
preparation solution, the fabric is cured at a temperature of about 225 °F to 425 °F preferably
about 350°F for 60 seconds. The woven fabric substrate with applied fiuorochemical stain
resist agent is thereafter passed through a calendering operation so as to flatten at least one
side of the fabric. The calendering operation is preferably carried out at a pressure of about
200N/mm with a calendering roll temperature of about 392°F.
In the preferred practice, a PDMS silicone composition is knife coated across the
calendered surface of the fabric thereby forming an effective barrier layer. Although the
surface for application is preferably calendered it may also be uncalendered.
In the preferred practice, the total weight of the applied barrier layer is less than about 2 oz/sq. yd., preferably less than 1.5 oz/sq. yd. and most preferably about 0.8 to 1 J
oz/sq. yd.
Following the coating procedure the fabric is then preferably passed through an oven
to set the silicone barrier layer. This operation preferably takes place at a temperature of
about 390°F for a period of about 80 seconds.
It is contemplated that additional performance enhancing constituents may be
incorporated within the polymeric materials which are coated onto the fabric substrate. These
performance enhancing constituents may include, by way of example only and not limitation,
antimicrobial compositions; flame retardants, antistats and/or ultraviolet stabilizing agents
such as are known to those of skill in the art.
In light of the above disclosure of potentially preferred embodiments and processes, it
will be appreciated that the general principal of invention disclosed herein may be applied in
a variety of ways. Therefore, it is contemplated by the appended claims to cover any such
modifications and other embodiment as incorporate the features of this invention within the
broadest allowable scope thereof.

Claims

ClaimsWHAT IS CLAIMED IS:
1. A fluid shield fabric comprising:
a fabric substrate, a fiuorochemical stain resist agent substantially covering
said fabric substrate, and a layer of thermosetting silicone substantially covering said
fabric substrate so as to provide a barrier layer against liquid passage.
2. The invention as in Claim 1, wherein said fabric substrate is polyester.
3. The invention as in Claim 1, wherein said fabric substrate is nylon.
4. The invention as in Claim 1, wherein said fabric substrate is polypropylene.
5. The invention as in Claim 1, wherein said fabric substrate is a woven fabric.
6. The invention as in Claim 1, wherein said fabric substrate is a knit fabric.
7. The invention as in Claim 1, wherein said fabric substrate is a nonwoven fabric.
8. The invention as in Claim 1 , wherein said fabric substrate comprises a smooth
calendered surface.
9. The invention as in Claim 1 , further including a flame retarding agent disposed across
said fabric substrate.
10. The invention as in Claim 1, further including an antimicrobial agent disposed across
said fabric substrate.
11. The invention as in Claim 1 , wherein said silicone includes a flame retarding agent
disposed therein.
12. The invention as in Claim 1, wherein said silicone includes an ultraviolet stabilizing
agent disposed therein.
13. The invention as in Claim 1, wherein said silicone includes an antimicrobial agent
disposed therein.
14. The invention as in Claim 1, wherein said silicone includes an antistatic agent
disposed therein.
15. The invention as in Claim 1 , wherein said silicone is present at a level of about 2 oz/sq. yd. or less.
PCT/US2000/040036 1999-02-22 2000-02-22 Silicone coated fluid shield fabric Ceased WO2000049221A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2000599938A JP2002537496A (en) 1999-02-22 2000-02-22 Silicone coated fluid shielding fabric
BR0008392-5A BR0008392A (en) 1999-02-22 2000-02-22 Fluid protective fabric, silicone coated
EP00915029A EP1161590A1 (en) 1999-02-22 2000-02-22 Silicone coated fluid shield fabric
AU36331/00A AU3633100A (en) 1999-02-22 2000-02-22 Silicone coated fluid shield fabric
KR1020017010656A KR20020000767A (en) 1999-02-22 2000-02-22 Silicone coated fluid shield fabric
CA002363080A CA2363080A1 (en) 1999-02-22 2000-02-22 Silicone coated fluid shield fabric

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US25514199A 1999-02-22 1999-02-22
US09/255,141 1999-02-22

Publications (1)

Publication Number Publication Date
WO2000049221A1 true WO2000049221A1 (en) 2000-08-24

Family

ID=22967017

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/040036 Ceased WO2000049221A1 (en) 1999-02-22 2000-02-22 Silicone coated fluid shield fabric

Country Status (8)

Country Link
EP (1) EP1161590A1 (en)
JP (1) JP2002537496A (en)
KR (1) KR20020000767A (en)
CN (1) CN1340120A (en)
AU (1) AU3633100A (en)
BR (1) BR0008392A (en)
CA (1) CA2363080A1 (en)
WO (1) WO2000049221A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1397247A4 (en) * 2001-05-23 2006-12-20 Milliken & Co Release barrier fabrics
US9534343B2 (en) 2012-10-18 2017-01-03 The Chemours Company Fc, Llc Partially fluorinated copolymer emulsions containing fatty acids and esters

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6833335B2 (en) * 2002-11-27 2004-12-21 Milliken & Company Barrier fabric
WO2011083879A1 (en) * 2010-01-07 2011-07-14 Dow Corning Toray Co., Ltd. Cured organopolysiloxane resin film having gas barrier properties and method of producing the same
KR102238956B1 (en) 2014-06-24 2021-04-13 삼성전자주식회사 Fluid Analysis Sheet, Fluid Analysis Cartridge Having the Same and Method of Manufacturing the Fluid Analysis Cartridge
CN104674554B (en) * 2015-03-06 2016-08-24 苏州爱立方服饰有限公司 A kind of fabric waterproof finishing agent and preparation method thereof
CN108611868A (en) * 2018-05-04 2018-10-02 嘉兴市卡秋莎服装股份有限公司 A kind of antibacterial fabric and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
UST896018I4 (en) * 1971-02-01 1972-03-07 Defensive publication
EP0177364A2 (en) * 1984-10-05 1986-04-09 HIRAOKA & CO. LTD Process for preparation of water-proof sheets
US4695484A (en) * 1984-12-07 1987-09-22 Dai-Ichi Kogyo Seiyaku Co., Ltd. Process for forming moisture-permeable waterproof coating on fabrics
WO1989008553A1 (en) * 1988-03-14 1989-09-21 Sili-Tex, Inc. Silicone polymer fiber encapsulated webs
WO1998035831A1 (en) * 1997-02-12 1998-08-20 Milliken Research Corporation Fluid shield fabric
EP0890673A1 (en) * 1997-07-11 1999-01-13 DHJ International Process for the preparation of a textile to be printed, printed textile and its use

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
UST896018I4 (en) * 1971-02-01 1972-03-07 Defensive publication
EP0177364A2 (en) * 1984-10-05 1986-04-09 HIRAOKA & CO. LTD Process for preparation of water-proof sheets
US4695484A (en) * 1984-12-07 1987-09-22 Dai-Ichi Kogyo Seiyaku Co., Ltd. Process for forming moisture-permeable waterproof coating on fabrics
WO1989008553A1 (en) * 1988-03-14 1989-09-21 Sili-Tex, Inc. Silicone polymer fiber encapsulated webs
WO1998035831A1 (en) * 1997-02-12 1998-08-20 Milliken Research Corporation Fluid shield fabric
EP0890673A1 (en) * 1997-07-11 1999-01-13 DHJ International Process for the preparation of a textile to be printed, printed textile and its use

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1397247A4 (en) * 2001-05-23 2006-12-20 Milliken & Co Release barrier fabrics
US9534343B2 (en) 2012-10-18 2017-01-03 The Chemours Company Fc, Llc Partially fluorinated copolymer emulsions containing fatty acids and esters

Also Published As

Publication number Publication date
EP1161590A1 (en) 2001-12-12
KR20020000767A (en) 2002-01-05
AU3633100A (en) 2000-09-04
CN1340120A (en) 2002-03-13
CA2363080A1 (en) 2000-08-24
BR0008392A (en) 2002-09-24
JP2002537496A (en) 2002-11-05

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