WO2001007502A3 - Polymerisation method - Google Patents

Polymerisation method Download PDF

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Publication number
WO2001007502A3
WO2001007502A3 PCT/GB2000/002850 GB0002850W WO0107502A3 WO 2001007502 A3 WO2001007502 A3 WO 2001007502A3 GB 0002850 W GB0002850 W GB 0002850W WO 0107502 A3 WO0107502 A3 WO 0107502A3
Authority
WO
WIPO (PCT)
Prior art keywords
aromatic
monomer
heteroaromatic group
oligomer
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2000/002850
Other languages
French (fr)
Other versions
WO2001007502A2 (en
Inventor
Andrew Bruce Holmes
Florence Danielle Anni Geneste
Rainer Eugen Martin
Franco Cacialli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cambridge Display Technology Ltd
Original Assignee
Cambridge Display Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cambridge Display Technology Ltd filed Critical Cambridge Display Technology Ltd
Priority to EP00946212A priority Critical patent/EP1200504B1/en
Priority to DE60029450T priority patent/DE60029450T2/en
Priority to US10/048,097 priority patent/US7005484B1/en
Priority to AU60083/00A priority patent/AU6008300A/en
Priority to JP2001512779A priority patent/JP3403188B2/en
Publication of WO2001007502A2 publication Critical patent/WO2001007502A2/en
Publication of WO2001007502A3 publication Critical patent/WO2001007502A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00Electroluminescent light sources
    • H05B33/12Light sources with substantially two-dimensional [2D] radiating surfaces
    • H05B33/14Light sources with substantially two-dimensional [2D] radiating surfaces characterised by the chemical or physical composition or the arrangement of the electroluminescent material, or by the simultaneous addition of the electroluminescent material in or onto the light source
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/10Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aromatic carbon atoms, e.g. polyphenylenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00Luminescent materials, e.g. electroluminescent or chemiluminescent
    • C09K11/06Luminescent materials, e.g. electroluminescent or chemiluminescent containing organic luminescent materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10Organic polymers or oligomers
    • H10K85/111Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/114Poly-phenylenevinylene; Derivatives thereof
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10Organic polymers or oligomers
    • H10K85/151Copolymers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/40Organosilicon compounds, e.g. TIPS pentacene
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/10OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/11OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10Organic polymers or oligomers
    • H10K85/111Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10Organic polymers or oligomers
    • H10K85/111Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/115Polyfluorene; Derivatives thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/917Electroluminescent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Electroluminescent Light Sources (AREA)
  • Light Receiving Elements (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Devices For Conveying Motion By Means Of Endless Flexible Members (AREA)

Abstract

A method for making a polymer or oligomer comprising the steps of: (a) making a first monomer comprising a substituted aromatic or heteroaromatic group by: (i) providing an aromatic or heteroaromatic group substituted with first and second director groups; (ii) performing metalisation at a first position on the aromatic or heteroaromatic group; (iii) performing electrophilic substitution so as to provide a first substituent group at the first position; and (b) contacting in a reaction mixture the first monomer with at least two further monomers that independently are the same or different from the first monomer under conditions so as to form a polymer or oligomer; wherein the nature and positions of the first and second director groups regioselect the first position.
PCT/GB2000/002850 1999-07-24 2000-07-24 Polymerisation method Ceased WO2001007502A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP00946212A EP1200504B1 (en) 1999-07-24 2000-07-24 Polymerisation method
DE60029450T DE60029450T2 (en) 1999-07-24 2000-07-24 Polymerization
US10/048,097 US7005484B1 (en) 1999-07-24 2000-07-24 Polymerization method
AU60083/00A AU6008300A (en) 1999-07-24 2000-07-24 Polymerisation method
JP2001512779A JP3403188B2 (en) 1999-07-24 2000-07-24 Polymerization method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9917356.9 1999-07-24
GBGB9917356.9A GB9917356D0 (en) 1999-07-24 1999-07-24 Aromatic monomers and polymers for optoelectronic devices

Publications (2)

Publication Number Publication Date
WO2001007502A2 WO2001007502A2 (en) 2001-02-01
WO2001007502A3 true WO2001007502A3 (en) 2001-03-22

Family

ID=10857847

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2000/002850 Ceased WO2001007502A2 (en) 1999-07-24 2000-07-24 Polymerisation method

Country Status (10)

Country Link
US (1) US7005484B1 (en)
EP (1) EP1200504B1 (en)
JP (1) JP3403188B2 (en)
KR (1) KR100470952B1 (en)
CN (1) CN1243778C (en)
AT (1) ATE333482T1 (en)
AU (1) AU6008300A (en)
DE (1) DE60029450T2 (en)
GB (1) GB9917356D0 (en)
WO (1) WO2001007502A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100495740B1 (en) 1999-03-29 2005-06-17 세이코 엡슨 가부시키가이샤 Composition, method for preparing film, and functional element and method for preparing the same
US7074885B2 (en) 2001-05-03 2006-07-11 E.I. Du Pont De Nemours And Company Electroactive fluorene copolymers and devices made with such polymers
US7074886B2 (en) 2001-05-07 2006-07-11 E. I. Du Pont De Memours And Company Electroactive fluorene polymers having perfluoroalkyl groups, process for preparing such polymers and devices made with such polymers
US7049392B2 (en) 2003-02-12 2006-05-23 E. I. Du Pont De Nemour And Company Electroluminescent copolymers with multi-functional monomers and methods for use thereof
US7138483B2 (en) 2003-02-12 2006-11-21 E.I. Du Pont De Nemours And Company Monomers, conjugated polymers and electronic devices using such polymers
DE102008056391B4 (en) * 2008-09-26 2021-04-01 Osram Oled Gmbh Organic electronic component and process for its manufacture
US9608225B2 (en) * 2010-01-21 2017-03-28 Samsung Electronics Co., Ltd. Light emitting device and method of fabricating the same
AU2012286513A1 (en) * 2011-07-15 2014-02-20 The University Of Melbourne Process for the synthesis of conjugated polymers
KR102838359B1 (en) * 2020-04-03 2025-07-23 주식회사 엘지화학 Novel polymer and organic light emitting device comprising the same
CN114853985B (en) * 2022-06-06 2023-06-16 中国科学技术大学 Self-crosslinking anion exchange membrane without ether conjugated aromatic main chain and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09104732A (en) * 1995-07-31 1997-04-22 Samsung Electron Co Ltd Blue light emitting polymer and light emitting diode using the same
WO1998046652A1 (en) * 1997-04-17 1998-10-22 California Institute Of Technology Substituted poly(phenylenevinylene)s and poly(napthalenevinylene)s

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19509451A1 (en) * 1995-03-20 1996-09-26 Hoechst Ag Poly ((oligo-p-phenylene) vinylene) derivatives, process for their preparation and their use

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09104732A (en) * 1995-07-31 1997-04-22 Samsung Electron Co Ltd Blue light emitting polymer and light emitting diode using the same
WO1998046652A1 (en) * 1997-04-17 1998-10-22 California Institute Of Technology Substituted poly(phenylenevinylene)s and poly(napthalenevinylene)s

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 199726, Derwent World Patents Index; Class A25, AN 1997-285197, XP002152054 *
HWANG D -H ET AL: "ELECTROLUMINESCENT PROPERTIES OF NOVEL SILYL-DISUBSTITUTED SOLUBLE PPV DERIVATIVE", MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY. SECTION A. MOLECULAR CRYSTALS AND LIQUID CRYSTALS,GORDON AND BREACH PUBLISHERS, CH,CH, vol. 316, May 1998 (1998-05-01), pages 281 - 284, XP000941275, ISSN: 1058-725X *
J. F. BOWER: "Synthesis of 2-Substituted Dihydropyran 3-O-Carbamates via Combined Metalation-Suzuki-Miyaura Cross-Coupling Reactions", J. ORG. CHEM., vol. 63, no. 5, 1998, pages 1514 - 1518, XP000940872 *
LIAN-HUI WANG ET AL.: "Synthesis, spectrocopy and electrochemistry study on a novel di-silyl substituted poly(p-phenylenevinylene)", SYNTHETIC METALS, vol. 105, 9 July 1999 (1999-07-09), pages 85 - 89, XP000942715 *
M.R. ANDERSSON ET AL.: "Photoluminescence and electroluminescence of films from soluble PPV-polymers", SYNTHETIC METALS, vol. 85, 1997, pages 1275-1276, XP000942764 *
SNIECKUS V: "COMBINED DIRECTED ORTHO METALATION-CROSS COUPLING STRATEGIES. DESIGN FOR NATURAL PRODUCT SYNTHESIS", PURE & APPLIED CHEMISTRY,PERGAMON PRESS, OXFORD,GB, vol. 66, no. 10/11, 1994, pages 2155 - 2158, XP000919008, ISSN: 0033-4545 *
V. SNIECKUS: "Directed Ortho Metalation. Tertiary Amide and O-Carbamate Directors in Synthetic Strategies for Polysubstituted Aromatics", CHEMICAL REVIEWS, vol. 90, no. 6, 1990, pages 879 - 933, XP002152053 *

Also Published As

Publication number Publication date
GB9917356D0 (en) 1999-09-22
DE60029450T2 (en) 2006-12-28
KR100470952B1 (en) 2005-03-10
WO2001007502A2 (en) 2001-02-01
AU6008300A (en) 2001-02-13
JP3403188B2 (en) 2003-05-06
DE60029450D1 (en) 2006-08-31
CN1243778C (en) 2006-03-01
EP1200504A2 (en) 2002-05-02
ATE333482T1 (en) 2006-08-15
CN1364175A (en) 2002-08-14
US7005484B1 (en) 2006-02-28
JP2003505563A (en) 2003-02-12
EP1200504B1 (en) 2006-07-19
KR20020040760A (en) 2002-05-30

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