WO2001042143A3 - Method and device for electrochemically disinfecting fluids - Google Patents

Method and device for electrochemically disinfecting fluids Download PDF

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Publication number
WO2001042143A3
WO2001042143A3 PCT/US2000/042584 US0042584W WO0142143A3 WO 2001042143 A3 WO2001042143 A3 WO 2001042143A3 US 0042584 W US0042584 W US 0042584W WO 0142143 A3 WO0142143 A3 WO 0142143A3
Authority
WO
WIPO (PCT)
Prior art keywords
stream
cell
electrodialytic
electrodes
flowing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2000/042584
Other languages
French (fr)
Other versions
WO2001042143A2 (en
Inventor
Alan H Molof
Raul C Cardenas
Edward J Mignone
David Livshits
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gemma Industrial Ecology Ltd
Original Assignee
Gemma Industrial Ecology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gemma Industrial Ecology Ltd filed Critical Gemma Industrial Ecology Ltd
Priority to AU45178/01A priority Critical patent/AU4517801A/en
Priority to CA002394859A priority patent/CA2394859A1/en
Priority to EP00992643A priority patent/EP1409415A2/en
Publication of WO2001042143A2 publication Critical patent/WO2001042143A2/en
Publication of WO2001042143A3 publication Critical patent/WO2001042143A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • C02F1/4674—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation with halogen or compound of halogens, e.g. chlorine, bromine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Disinfection or sterilisation of materials or objects, in general; Accessories therefor
    • A61L2/02—Disinfection or sterilisation of materials or objects, in general; Accessories therefor using physical processes
    • A61L2/03—Electric current
    • A61L2/035—Electrolysis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/30—Treatment of water, waste water, or sewage by irradiation
    • C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/46109—Electrodes
    • C02F2001/46152—Electrodes characterised by the shape or form
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/42—Nature of the water, waste water, sewage or sludge to be treated from bathing facilities, e.g. swimming pools
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4611—Fluid flow
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/46115—Electrolytic cell with membranes or diaphragms
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4612—Controlling or monitoring
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4612—Controlling or monitoring
    • C02F2201/46145—Fluid flow
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4618—Supplying or removing reactants or electrolyte
    • C02F2201/46185—Recycling the cathodic or anodic feed
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/003—Downstream control, i.e. outlet monitoring, e.g. to check the treating agents, such as halogens or ozone, leaving the process
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/04—Oxidation reduction potential [ORP]
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/06—Controlling or monitoring parameters in water treatment pH
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00—General aspects of water treatment
    • C02F2301/02—Fluid flow conditions
    • C02F2301/022—Laminar
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/04—Disinfection
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00—Multistage treatment of water, waste water or sewage

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

A method for treating fluids operates on a continuously flowing stream of fluid. The stream is acted upon in a continuous flow process to generate a disinfectant species (e.g., chlorine) in the stream and to simultaneously lower the pH of the stream below approximately 4.0. The stream is passed through and electrodialytic cell and an electric potential difference is applied across electrodes of the cell during the passage of the stream through the cell. Relative to its flow through a channel upstream of the cell, the stream is accelerated when flowing through the cell. The stream at an outlet of the electrodialytic cell to raise the pH of the stream to a neutral range, thus producing a disinfected solution. This step may be implemented by passing the effluent stream between differentially charged electrodes, for example, of the same electrodialytic cell. A chemical disinfecting method is also disclosed.
PCT/US2000/042584 1999-12-02 2000-12-04 Method and device for electrochemically disinfecting fluids Ceased WO2001042143A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU45178/01A AU4517801A (en) 1999-12-02 2000-12-04 Method and device for electrochemically disinfecting fluids
CA002394859A CA2394859A1 (en) 1999-12-02 2000-12-04 Method and device for electrochemically disinfecting fluids
EP00992643A EP1409415A2 (en) 1999-12-02 2000-12-04 Method and device for electrochemically disinfecting fluids

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US45310699A 1999-12-02 1999-12-02
US09/453,106 1999-12-02

Publications (2)

Publication Number Publication Date
WO2001042143A2 WO2001042143A2 (en) 2001-06-14
WO2001042143A3 true WO2001042143A3 (en) 2001-11-01

Family

ID=23799227

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/042584 Ceased WO2001042143A2 (en) 1999-12-02 2000-12-04 Method and device for electrochemically disinfecting fluids

Country Status (4)

Country Link
EP (1) EP1409415A2 (en)
AU (1) AU4517801A (en)
CA (1) CA2394859A1 (en)
WO (1) WO2001042143A2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7393522B2 (en) 2000-01-12 2008-07-01 Novabay Pharmaceuticals, Inc. Physiologically balanced, ionized, acidic solution and methodology for use in wound healing
GR1004118B (en) * 2001-10-11 2003-01-21 Electrochemical sewage wet oxidation method.
JP3768160B2 (en) 2001-12-25 2006-04-19 三洋電機株式会社 Water treatment equipment
CN101360686A (en) * 2005-12-09 2009-02-04 肯尼思·罗兰·瓦尔科 Continuous Hypochlorite Generator
ATE501285T1 (en) * 2006-09-22 2011-03-15 Wen-Shing Shyu ELECTROLYZER
DE102007033445A1 (en) * 2007-07-18 2009-01-22 Monopharm Handelsgesellschaft Mbh Diaphragmalyse method and use of the products obtained by the method
US20100078331A1 (en) * 2008-10-01 2010-04-01 Scherson Daniel A ELECTROLYTIC DEVICE FOR GENERATION OF pH-CONTROLLED HYPOHALOUS ACID AQUEOUS SOLUTIONS FOR DISINFECTANT APPLICATIONS
KR101144820B1 (en) * 2009-10-21 2012-05-11 한국에너지기술연구원 Apparatus for seprarating carbon dioxide, and method for seprarating carbon dioxide with the same
US8641874B2 (en) * 2010-12-09 2014-02-04 Rayne Guest Compact closed-loop electrolyzing process and apparatus
ES2373601B1 (en) * 2011-10-14 2013-02-08 I.D. Electroquímica, S.L. WATER CLEANING PROCEDURE WITHOUT SALT CONTRIBUTION AND WATER CLEANING REACTOR.
DE102013010950B4 (en) 2012-06-28 2016-09-01 Hochschule Anhalt Electrolytic cell and process for the electrolytic production of chlorine dioxide
DE102014014188A1 (en) 2014-09-24 2016-03-24 Hochschule Anhalt (Fh) Process for the chemical production of chlorine dioxide from chlorite ion and ozone
US12193623B2 (en) 2016-03-02 2025-01-14 Z Intellectual Property Holding Company, Llc Systems and methods for cleaning surfaces
EP3422919B1 (en) 2016-03-02 2022-07-20 Z Intellectual Property Holding Company, LLC Systems and methods for providing a wand for a floor cleaning appartatus
JP6974444B2 (en) 2016-05-17 2021-12-01 ディバーシー，インコーポレーテッド Alkaline and chlorine solutions produced using electrochemical activation
AU2018212642B2 (en) 2017-01-26 2021-02-04 Diversey, Inc. Neutralization in electro-chemical activation systems
ES1197058Y (en) 2017-10-16 2018-01-29 I D Electroquimica S L Reactor for integral water treatment
WO2019165474A1 (en) * 2018-02-26 2019-08-29 SHUPE, William Systems and methods for producing electrolyzed alkaline water and/or electrolyzed oxidizing water
KR102191049B1 (en) 2019-02-22 2020-12-15 엘지전자 주식회사 water dispensing apparatus
KR102267887B1 (en) * 2019-02-22 2021-06-23 엘지전자 주식회사 water dispensing apparatus
KR102194595B1 (en) 2019-02-22 2020-12-23 엘지전자 주식회사 water dispensing apparatus
EP3962541B1 (en) 2019-04-29 2025-03-26 Spa Logic, Inc. Water sanitation system and method
CN113277603B (en) * 2020-02-19 2022-09-06 重庆昕晟环保科技有限公司 Water quality safety management control system of newly-built building secondary water supply water tank
CN118125560A (en) * 2024-03-22 2024-06-04 汤姆生电解技术(广州)有限公司 Ultrasonic diaphragm electrolytic tank

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5207877A (en) * 1987-12-28 1993-05-04 Electrocinerator Technologies, Inc. Methods for purification of air
US5759489A (en) * 1995-01-17 1998-06-02 Miura-Denshi Kabushiki-Kaisha Washing and disinfecting method and apparatus for artificial dialyzer using acid water electrolytically made
US5858201A (en) * 1994-07-29 1999-01-12 Toto, Ltd. Strong acid sterilizing liquid containing hypochlorous acid at a low concentration, method and apparatus for generating same, and apparatus for generating and dispensing same
US5858202A (en) * 1996-01-30 1999-01-12 Zenkoku-Mokko-Kikai-Kan, Inc. Method for producing electrolytic water and apparatus for producing the same
US5965009A (en) * 1996-04-24 1999-10-12 Permelec Electrode Ltd. Method of producing acid water and electrolytic cell therefor
US6056866A (en) * 1995-08-17 2000-05-02 Kaigen Co., Ltd. Sterilizing apparatus and method for medical instruments
US6139714A (en) * 1997-12-02 2000-10-31 Gemma Industrial Ecology Ltd. Method and apparatus for adjusting the pH of a liquid

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5207877A (en) * 1987-12-28 1993-05-04 Electrocinerator Technologies, Inc. Methods for purification of air
US5858201A (en) * 1994-07-29 1999-01-12 Toto, Ltd. Strong acid sterilizing liquid containing hypochlorous acid at a low concentration, method and apparatus for generating same, and apparatus for generating and dispensing same
US5759489A (en) * 1995-01-17 1998-06-02 Miura-Denshi Kabushiki-Kaisha Washing and disinfecting method and apparatus for artificial dialyzer using acid water electrolytically made
US6056866A (en) * 1995-08-17 2000-05-02 Kaigen Co., Ltd. Sterilizing apparatus and method for medical instruments
US5858202A (en) * 1996-01-30 1999-01-12 Zenkoku-Mokko-Kikai-Kan, Inc. Method for producing electrolytic water and apparatus for producing the same
US5965009A (en) * 1996-04-24 1999-10-12 Permelec Electrode Ltd. Method of producing acid water and electrolytic cell therefor
US6139714A (en) * 1997-12-02 2000-10-31 Gemma Industrial Ecology Ltd. Method and apparatus for adjusting the pH of a liquid

Also Published As

Publication number Publication date
WO2001042143A2 (en) 2001-06-14
AU4517801A (en) 2001-06-18
CA2394859A1 (en) 2001-06-14
EP1409415A2 (en) 2004-04-21

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