WO2002034373A1 - Fibre membrane arrangement - Google Patents

Fibre membrane arrangement Download PDF

Info

Publication number
WO2002034373A1
WO2002034373A1 PCT/AU2001/001350 AU0101350W WO0234373A1 WO 2002034373 A1 WO2002034373 A1 WO 2002034373A1 AU 0101350 W AU0101350 W AU 0101350W WO 0234373 A1 WO0234373 A1 WO 0234373A1
Authority
WO
WIPO (PCT)
Prior art keywords
membranes
membrane
header
fibres
fibre
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/AU2001/001350
Other languages
French (fr)
Inventor
Roger Phelps
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
US Filter Wastewater Group Inc
Original Assignee
US Filter Wastewater Group Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by US Filter Wastewater Group Inc filed Critical US Filter Wastewater Group Inc
Priority to JP2002537414A priority Critical patent/JP2004516924A/en
Priority to CA002425598A priority patent/CA2425598A1/en
Priority to NZ525589A priority patent/NZ525589A/en
Priority to EP01978002A priority patent/EP1337318A4/en
Priority to AU2002210266A priority patent/AU2002210266A1/en
Publication of WO2002034373A1 publication Critical patent/WO2002034373A1/en
Priority to US10/423,044 priority patent/US20030226797A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/08—Prevention of membrane fouling or of concentration polarisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/18—Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02—Hollow fibre modules
    • B01D63/021—Manufacturing thereof
    • B01D63/0233—Manufacturing thereof forming the bundle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02—Hollow fibre modules
    • B01D63/031—Two or more types of hollow fibres within one bundle or within one potting or tube-sheet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2315/00—Details relating to the membrane module operation
    • B01D2315/06—Submerged-type; Immersion type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/28—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling by soaking or impregnating

Definitions

  • the present invention relates to membrane filtration systems and more particularly to such systems using porous hollow fibre membranes.
  • the membrane bioreactor process is used for the treatment of various waste waters.
  • the filtration module comes in contact with and filters a thickened concentration of mixed liquor that is developed in the process. Therefore it has been found that the filter module has an increased potential of solids fouling due to the thick nature of the material it is filtering.
  • the membrane reactor process typically uses aeration and/or mixed liquor flow in and around the filter modules to scrub the fibres and create fluid transfer around the fibres. This has the effect of reducing solids fouling. It is the movement of the fibres relative to the flow of mixed liquor within the module and around the fibres that minimises solids fouling.
  • the second mechanism that also works to cause solids fouling is the filtration process itself.
  • the process of filtration sucks the liquid out of the mixed liquor through the fibre membrane 6 and causes the mixed liquor to become thicker. With the effective gas scrubbing and fibre movement, the remaining solids are continuously mixed and diluted back into the bulk mixed liquor and moved away from the membrane surface by effective fluid transfer around the membranes 6. This mixing is achieved by a combination of aeration and/or mixed liquor flow within the process. If during filtration, mixing does not occur, solids are not removed from the membrane surface. In this case, the mixed liquor close to the membrane 6 will continue to thicken as water is sucked from it. A dehydrated sludge will begin to form around the membranes/fibres 6, and in combination with other similar fouled fibres, will cause solids fouling to the module 5.
  • the membranes are rendered inoperative by sealing the membrane pores in the portion of the membranes adjacent the header.
  • said porous membranes are hollow fibre membranes.
  • the hollow fibres extend between spaced opposed headers.
  • the portion of the membranes rendered inoperative extends for a predetermined distance from the interface between the header and the membranes.
  • the invention includes in another aspect, a filtration system modified in accordance with the method of the first aspect.
  • Figure 1 shows a schematic side elevation of a typical hollow fibre membrane module to which the present invention is applicable
  • Figures 2a and 2b show an enlarged side and plan view, respectively of the circled region of Figure 1 ;
  • Figure 3 shows an enlarged schematic side elevation view of the base of the module of Figure 1 illustrating solids fouling; and Figure 4 shows a similar view to Figure 1 with the membranes modified according to the invention.
  • this embodiment of the invention seeks to reduce or eliminate the second mechanism, filtration, from effecting the ends of the modules 5 by forming a limited non-operative fibre portion 10.
  • Figure 4 illustrates the portion 10 of the fibre 6, which is to be modified so filtration does not occur.
  • This portion 10 has limited mixing, fibre movement and fluid transfer around the fibres 6.
  • the two mechanisms described above are not able to work in unison to form a dehydrated sludge around the fibres 6. This serves to prevent clogging between the fibres 6 and eventual reduction in efficiency of the filtration process.
  • porous membranes are hollow fibre membranes extending between spaced opposed headers.
  • a membrane filtration system of the type having a plurality of membranes mounted, at least at one end, to a header and operable to withdraw permeate from multicomponent liquid substrate in which said porous membranes are immersed, wherein a portion of one or more of the membranes, adjacent the header, is rendered inoperative. 6.
  • a membrane filtration system according to claim 5 wherein the membrane pores in the portion of the membrane adjacent the header are sealed to render them inoperative.
  • a membrane filtration system according to claim 5 or claim 6 wherein said portion of the membranes rendered inoperative extends for a predetermined distance from the interface between the header and the membranes.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Manufacturing & Machinery (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

A method of reducing solids fouling between porous membranes in a membrane filtration system of the type having a plurality of membranes mounted, at least at one end, to a header and operable to withdraw permeate from multicomponent liquid substrate in which said porous membranes are immersed, the method including rendering a portion of one or more of the membranes, adjacent the header, inoperative.

Description

TITLE: Fibre Membrane Arrangement"
FIELD OF THE INVENTION
The present invention relates to membrane filtration systems and more particularly to such systems using porous hollow fibre membranes.
The invention will be described with respect to its application to a membrane bioreactor (MBR) process, however, it will be appreciated that the invention is not limited to such an application and may be equally useful in other processes using hollow fibre membranes or the like. The term "porous" is intended to include "permeable" membranes. BACKGROUND ART
Any discussion of the prior art throughout the specification should in no way be considered as an admission that such prior art is widely known or forms part of common general knowledge in the field.
The membrane bioreactor process is used for the treatment of various waste waters. Within this process the filtration module comes in contact with and filters a thickened concentration of mixed liquor that is developed in the process. Therefore it has been found that the filter module has an increased potential of solids fouling due to the thick nature of the material it is filtering.
The membrane reactor process typically uses aeration and/or mixed liquor flow in and around the filter modules to scrub the fibres and create fluid transfer around the fibres. This has the effect of reducing solids fouling. It is the movement of the fibres relative to the flow of mixed liquor within the module and around the fibres that minimises solids fouling.
When solids fouling does occur within a module it typically starts from either of its ends. Once started, the solids fouling may grow from the ends towards the centre of the module and may cause the module to become inoperable. There are a number of mechanisms that influence this. Two of these are described below.
The first mechanism is created by the nature of the module construction. As shown in the example of Figures 1 , 2a and 2b, at each end of the module 5, the fibre 6 is held by the material 7 it is potted into and hence is restricted in movement. As there is no or limited movement of fibre 6 in this area, fluid transfer is poor. As shown in Figure 3, the fibre 6 is unable to shake loose any solids 8 that may become caught between the fibres 6 and hence they become trapped and begin the fouling process. The collective trapped solids at this point are still quite soft and well hydrated.
The second mechanism that also works to cause solids fouling is the filtration process itself. The process of filtration sucks the liquid out of the mixed liquor through the fibre membrane 6 and causes the mixed liquor to become thicker. With the effective gas scrubbing and fibre movement, the remaining solids are continuously mixed and diluted back into the bulk mixed liquor and moved away from the membrane surface by effective fluid transfer around the membranes 6. This mixing is achieved by a combination of aeration and/or mixed liquor flow within the process. If during filtration, mixing does not occur, solids are not removed from the membrane surface. In this case, the mixed liquor close to the membrane 6 will continue to thicken as water is sucked from it. A dehydrated sludge will begin to form around the membranes/fibres 6, and in combination with other similar fouled fibres, will cause solids fouling to the module 5.
Hence, at the ends of the modules 5, both mechanisms occur. There is limited mixing and fibre movement, which encourages solids entrapment, and combined ith the filtration process, dehydrates the mixed liquor that is trapped between the fibres 6. A thick sludge then forms around the fibres 6 leaving them bound together by a dehydrated sludge. DISCLOSURE OF THE INVENTION
The present invention seeks to overcome or at least ameliorate one or more of the disadvantages of the prior art described above or at least provide the public with a useful alternative. According to a first aspect, the present invention provides a method of reducing solids fouling between porous membranes in a membrane filtration system of the type having a plurality of membranes mounted, at least at one end, to a header and operable to withdraw permeate from multicomponent liquid substrate in which said porous membranes are immersed, the method including rendering a portion of one or more of the membranes, adjacent the header, inoperative.
For preference, the membranes are rendered inoperative by sealing the membrane pores in the portion of the membranes adjacent the header. Preferably, said porous membranes are hollow fibre membranes. For further preference, the hollow fibres extend between spaced opposed headers. Preferably, the portion of the membranes rendered inoperative extends for a predetermined distance from the interface between the header and the membranes.
The invention includes in another aspect, a filtration system modified in accordance with the method of the first aspect. BRIEF DESCRIPTION OF DRAWINGS A preferred embodiment of the invention ill now be described, by way of example only, with reference to the accompanying drawings in which:
Figure 1 shows a schematic side elevation of a typical hollow fibre membrane module to which the present invention is applicable;
Figures 2a and 2b show an enlarged side and plan view, respectively of the circled region of Figure 1 ;
Figure 3 shows an enlarged schematic side elevation view of the base of the module of Figure 1 illustrating solids fouling; and Figure 4 shows a similar view to Figure 1 with the membranes modified according to the invention. DESCRIPTION OF PREFERRED EMBODIMENT
Referring to Figure 4, this embodiment of the invention seeks to reduce or eliminate the second mechanism, filtration, from effecting the ends of the modules 5 by forming a limited non-operative fibre portion 10. Figure 4 illustrates the portion 10 of the fibre 6, which is to be modified so filtration does not occur. This portion 10 has limited mixing, fibre movement and fluid transfer around the fibres 6. Hence by modifying the fibres 6 in this portion 10 so they do not filter, the two mechanisms described above are not able to work in unison to form a dehydrated sludge around the fibres 6. This serves to prevent clogging between the fibres 6 and eventual reduction in efficiency of the filtration process.
It will be appreciated that further embodiments and exemplifications of the invention are possible, without departing from the spirit or scope of the invention described.
CLAIMS:
1. A method of reducing solids fouling between porous membranes in a membrane filtration system of the type having a plurality of membranes mounted, at least at one end, to a header and operable to withdraw permeate from multicomponent liquid substrate in which said porous membranes are immersed, the method including rendering a portion of one or more of the membranes, adjacent the header, inoperative.
2. A method according to claim 1 wherein the membranes are rendered inoperative by sealing the membrane pores in the portion of the membrane adjacent the header. 3. A method according to claim 1 or claim 2 wherein said portion of the membranes rendered inoperative extends for a predetermined distance from the interface between the header and the membrane.
4. A method according to claim 1 wherein said porous membranes are hollow fibre membranes extending between spaced opposed headers. 5. A membrane filtration system of the type having a plurality of membranes mounted, at least at one end, to a header and operable to withdraw permeate from multicomponent liquid substrate in which said porous membranes are immersed, wherein a portion of one or more of the membranes, adjacent the header, is rendered inoperative. 6. A membrane filtration system according to claim 5 wherein the membrane pores in the portion of the membrane adjacent the header are sealed to render them inoperative.
7. A membrane filtration system according to claim 5 or claim 6 wherein said portion of the membranes rendered inoperative extends for a predetermined distance from the interface between the header and the membranes.
8. A membrane filtration system according to claim 5 wherein said porous membranes are hollow fibre membranes extending between spaced opposed headers. 9. A membrane filtration system substantially as herein described with reference to any one of the embodiments of the invention illustrated in the accompanying drawings.
PCT/AU2001/001350 2000-10-23 2001-10-22 Fibre membrane arrangement Ceased WO2002034373A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2002537414A JP2004516924A (en) 2000-10-23 2001-10-22 Fiber membrane arrangement
CA002425598A CA2425598A1 (en) 2000-10-23 2001-10-22 Fibre membrane arrangement
NZ525589A NZ525589A (en) 2000-10-23 2001-10-22 Fibre membrane arrangement
EP01978002A EP1337318A4 (en) 2000-10-23 2001-10-22 Fibre membrane arrangement
AU2002210266A AU2002210266A1 (en) 2000-10-23 2001-10-22 Fibre membrane arrangement
US10/423,044 US20030226797A1 (en) 2000-10-23 2003-04-23 Fibre membrane arrangement

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AUPR0946A AUPR094600A0 (en) 2000-10-23 2000-10-23 Fibre membrane arrangement
AUPR0946 2000-10-23

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/423,044 Continuation US20030226797A1 (en) 2000-10-23 2003-04-23 Fibre membrane arrangement

Publications (1)

Publication Number Publication Date
WO2002034373A1 true WO2002034373A1 (en) 2002-05-02

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/AU2001/001350 Ceased WO2002034373A1 (en) 2000-10-23 2001-10-22 Fibre membrane arrangement

Country Status (8)

Country Link
US (1) US20030226797A1 (en)
EP (1) EP1337318A4 (en)
JP (1) JP2004516924A (en)
CN (1) CN1213796C (en)
AU (2) AUPR094600A0 (en)
CA (1) CA2425598A1 (en)
NZ (1) NZ525589A (en)
WO (1) WO2002034373A1 (en)

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WO2011039111A1 (en) * 2009-09-30 2011-04-07 Membrana Gmbh Hollow fiber membrane mats with fluid impermeable segments and related methods
US8999454B2 (en) 2012-03-22 2015-04-07 General Electric Company Device and process for producing a reinforced hollow fibre membrane
US9022229B2 (en) 2012-03-09 2015-05-05 General Electric Company Composite membrane with compatible support filaments
US9061250B2 (en) 2009-06-26 2015-06-23 Bl Technologies, Inc. Non-braided, textile-reinforced hollow fiber membrane
US9132390B2 (en) 2009-03-26 2015-09-15 Bl Technologies Inc. Non-braided reinforced holow fibre membrane
US9221020B2 (en) 2010-09-15 2015-12-29 Bl Technologies, Inc. Method to make yarn-reinforced hollow fiber membranes around a soluble core
US9227362B2 (en) 2012-08-23 2016-01-05 General Electric Company Braid welding
US9321014B2 (en) 2011-12-16 2016-04-26 Bl Technologies, Inc. Hollow fiber membrane with compatible reinforcements
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US20030226797A1 (en) 2003-12-11
AUPR094600A0 (en) 2000-11-16
AU2002210266A1 (en) 2002-05-06
EP1337318A4 (en) 2004-12-22
JP2004516924A (en) 2004-06-10
CA2425598A1 (en) 2002-05-02
EP1337318A1 (en) 2003-08-27
NZ525589A (en) 2004-09-24
CN1471424A (en) 2004-01-28

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