WO2002072736A3 - Demulsification of water-in-oil emulsions - Google Patents

Demulsification of water-in-oil emulsions Download PDF

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Publication number
WO2002072736A3
WO2002072736A3 PCT/US2002/002022 US0202022W WO02072736A3 WO 2002072736 A3 WO2002072736 A3 WO 2002072736A3 US 0202022 W US0202022 W US 0202022W WO 02072736 A3 WO02072736 A3 WO 02072736A3
Authority
WO
WIPO (PCT)
Prior art keywords
demulsification
water
oil emulsions
emulsions
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2002/002022
Other languages
French (fr)
Other versions
WO2002072736A2 (en
Inventor
Ramesh Varadaraj
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Priority to CA2438167A priority Critical patent/CA2438167C/en
Priority to DE60226424T priority patent/DE60226424D1/en
Priority to AU2002251816A priority patent/AU2002251816A1/en
Priority to EP02720842A priority patent/EP1377653B1/en
Publication of WO2002072736A2 publication Critical patent/WO2002072736A2/en
Anticipated expiration legal-status Critical
Publication of WO2002072736A3 publication Critical patent/WO2002072736A3/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G33/00—Dewatering or demulsification of hydrocarbon oils
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T436/00—Chemistry: analytical and immunological testing
    • Y10T436/21—Hydrocarbon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T436/00—Chemistry: analytical and immunological testing
    • Y10T436/25—Chemistry: analytical and immunological testing including sample preparation
    • Y10T436/25375—Liberation or purification of sample or separation of material from a sample [e.g., filtering, centrifuging, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Colloid Chemistry (AREA)

Abstract

The invention includes a method for demulsification of water-in-oil emulsions by sonicating the emulsions.
PCT/US2002/002022 2001-03-09 2002-01-25 Demulsification of water-in-oil emulsions Ceased WO2002072736A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CA2438167A CA2438167C (en) 2001-03-09 2002-01-25 Demulsification of water-in-oil emulsions
DE60226424T DE60226424D1 (en) 2001-03-09 2002-01-25 WATER IN OIL EMULSION SPLITTING PROCESS
AU2002251816A AU2002251816A1 (en) 2001-03-09 2002-01-25 Demulsification of water-in-oil emulsions
EP02720842A EP1377653B1 (en) 2001-03-09 2002-01-25 Demulsification of water-in-oil emulsions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/803,575 US6555009B2 (en) 2001-03-09 2001-03-09 Demulsification of water-in-oil emulsions
US09/803,575 2001-03-09

Publications (2)

Publication Number Publication Date
WO2002072736A2 WO2002072736A2 (en) 2002-09-19
WO2002072736A3 true WO2002072736A3 (en) 2003-09-25

Family

ID=25186892

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/002022 Ceased WO2002072736A2 (en) 2001-03-09 2002-01-25 Demulsification of water-in-oil emulsions

Country Status (6)

Country Link
US (2) US6555009B2 (en)
EP (1) EP1377653B1 (en)
AU (1) AU2002251816A1 (en)
CA (1) CA2438167C (en)
DE (1) DE60226424D1 (en)
WO (1) WO2002072736A2 (en)

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US7871512B2 (en) * 2001-05-10 2011-01-18 Petrosonics, Llc Treatment of crude oil fractions, fossil fuels, and products thereof
US7081196B2 (en) * 2001-05-10 2006-07-25 Mark Cullen Treatment of crude oil fractions, fossil fuels, and products thereof with sonic energy
US7014773B2 (en) * 2003-02-21 2006-03-21 Exxonmobil Research And Engineering Company Demulsification of emulsions by socillatory mixing
US7323342B2 (en) * 2003-04-04 2008-01-29 Exxonmobil Research And Engineering Company Method for improving oil desalting by forming unstable water-in-oil emulsions
US6795484B1 (en) 2003-05-19 2004-09-21 Johns Manville International, Inc. Method and system for reducing a foam in a glass melting furnace
US7776930B2 (en) * 2004-06-16 2010-08-17 Champion Technologies, Inc. Methods for inhibiting naphthenate salt precipitates and naphthenate-stabilized emulsions
US7383828B2 (en) * 2004-06-24 2008-06-10 Emission & Power Solutions, Inc. Method and apparatus for use in enhancing fuels
US7428896B2 (en) * 2004-06-24 2008-09-30 Emission & Power Solutions, Inc. Method and apparatus for use in enhancing fuels
US7736518B2 (en) * 2005-02-14 2010-06-15 Total Separation Solutions, Llc Separating mixtures of oil and water
US20060180500A1 (en) * 2005-02-15 2006-08-17 Sulphco, Inc., A Corporation Of The State Of Nevada Upgrading of petroleum by combined ultrasound and microwave treatments
FR2883571B1 (en) * 2005-03-23 2007-07-06 Petroleo Brasileiro Sa PROCESS FOR REDUCING THE NAPHTHENIC ACIDITY OF OIL OILS OR THEIR FRACTIONS
US7588682B2 (en) * 2005-10-04 2009-09-15 Kevin Norman Process and apparatus for enhanced recovery of oil from oily particulate material
CA2658780C (en) * 2006-08-16 2014-05-13 Exxonmobil Upstream Research Company Oil/water separation of well stream by flocculation-demulsification process
CA2658791C (en) * 2006-08-16 2014-09-30 Exxonmobil Upstream Research Company Core annular flow of heavy crude oils in transportation pipelines and production wellbores
WO2008020909A2 (en) * 2006-08-16 2008-02-21 Exxonmobil Upstream Research Company Demulsification of water-in-oil emulsion
US9115851B2 (en) 2006-08-16 2015-08-25 Exxonmobil Upstream Research Company Core annular flow of crude oils
BRPI0700642B1 (en) * 2007-03-07 2015-04-14 Petroleo Brasileiro S.A. - Petrobras Method for treating water / oil emulsions with microwaves
US20090038932A1 (en) * 2007-08-08 2009-02-12 Battelle Memorial Institute Device and method for noninvasive ultrasonic treatment of fluids and materials in conduits and cylindrical containers
EP2225350B1 (en) * 2007-11-14 2020-01-08 Saudi Arabian Oil Company Microwave-promoted desulfurization of crude oil
US8197673B2 (en) * 2008-11-19 2012-06-12 Saudi Arabian Oil Company Converting heavy sour crude oil/emulsion to lighter crude oil using cavitations and filtration based systems
BRPI0905253B1 (en) * 2009-12-28 2020-02-18 Petroleo Brasileiro S.A. - Petrobras PROCESS FOR THE TREATMENT OF WATER / OIL EMULSIONS
US8570497B2 (en) * 2010-02-08 2013-10-29 Phillips 66 Company Oil in water analyzer
US8926825B2 (en) * 2010-03-19 2015-01-06 Mark Cullen Process for removing sulfur from hydrocarbon streams using hydrotreatment, fractionation and oxidation
EP2705113B1 (en) 2011-05-06 2015-07-08 Nalco Company Low dosage polymeric naphthenate inhibitors
CN103813842B (en) 2011-07-26 2016-03-23 沙特阿拉伯石油公司 Dynamic Demulsification System for Oil-Gas Separation Plant
CA3012433C (en) * 2016-03-04 2020-04-28 Halliburton Energy Services, Inc. Improved performance non-emulsifiers that employ branched alcohols and a new high-solvency carrier oil
CA3012434C (en) 2016-03-04 2023-01-03 Halliburton Energy Services, Inc. Alkyl unsaturated fatty acid ester oil as an oil component in the formulation and application of surfactant flowback aids for subterranean stimulation
CA3116538C (en) 2018-11-21 2023-09-12 Halliburton Energy Services, Inc. Treatment fluids for demulsifying production fluids
US11105722B2 (en) 2019-01-03 2021-08-31 Saudi Arabian Oil Company Screening demulsifiers for crude live oil-water emulsions
US11262281B2 (en) 2019-01-03 2022-03-01 Saudi Arabian Oil Company Screening demulsifiers for crude oil-water emulsions
RU2724745C1 (en) * 2019-08-06 2020-06-25 Общество с ограниченной ответственностью "Газпромнефть Научно-Технический Центр" (ООО "Газпромнефть НТЦ") Method of ultrasonic dispersion of demulsifier in water-oil emulsion
US10968402B1 (en) 2019-10-08 2021-04-06 Saudi Arabian Oil Company Method and system for the control of water concentration in crude oil entering the dehydrators
US11008521B1 (en) * 2019-10-08 2021-05-18 Saudi Arabian Oil Company Control of demulsifier injection into crude oil entering separators
US11414327B2 (en) * 2020-06-15 2022-08-16 Chevron U.S.A. Inc. Sonication for separation of materials in fluids
US11591880B2 (en) 2020-07-30 2023-02-28 Saudi Arabian Oil Company Methods for deployment of expandable packers through slim production tubing
US11421148B1 (en) 2021-05-04 2022-08-23 Saudi Arabian Oil Company Injection of tailored water chemistry to mitigate foaming agents retention on reservoir formation surface
US11548784B1 (en) 2021-10-26 2023-01-10 Saudi Arabian Oil Company Treating sulfur dioxide containing stream by acid aqueous absorption
US11926799B2 (en) 2021-12-14 2024-03-12 Saudi Arabian Oil Company 2-iso-alkyl-2-(4-hydroxyphenyl)propane derivatives used as emulsion breakers for crude oil
US12179129B2 (en) 2021-12-14 2024-12-31 Saudi Arabian Oil Company Synergetic solvent for crude oil emulsion breakers
US12065921B2 (en) 2021-12-15 2024-08-20 Saudi Arabian Oil Company Standalone demulsifier testing for crude oil
CN114988627A (en) * 2022-05-24 2022-09-02 中国船舶重工集团公司第七0三研究所无锡分部 Efficient ship oil-sewage separation system and method
US11993746B2 (en) 2022-09-29 2024-05-28 Saudi Arabian Oil Company Method of waterflooding using injection solutions containing dihydrogen phosphate

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2257997A (en) * 1940-11-27 1941-10-07 American Cyanamid Co Breaking petroleum emulsions
US2864502A (en) * 1954-04-26 1958-12-16 H2 Oil Engineering Corp Methods and means for the treatment of oil, gas and water emulsions
US3255571A (en) * 1963-05-14 1966-06-14 Nat Tank Co Method and means for treating oil well emulsions
US3699051A (en) * 1970-08-27 1972-10-17 Nalco Chemical Co Compositions and processes for breaking petroleum emulsions
WO1996005272A2 (en) * 1994-08-12 1996-02-22 Nalco/Exxon Energy Chemicals, L.P. Oil treatment and compositions therefor
US5885424A (en) * 1994-06-15 1999-03-23 Mobil Oil Corporation Method and apparatus for breaking hydrocarbon emulsions

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US3640894A (en) * 1970-07-09 1972-02-08 Nalco Chemical Co Compositions and processes for breaking petroleum emulsions
US4283290A (en) * 1977-07-06 1981-08-11 Davy International (Oil & Chemicals) Ltd. Purification utilizing liquid membrane with electrostatic coalescence
US4384977A (en) * 1981-06-11 1983-05-24 Marathon Oil Company Polyalkyloxyamines as demulsifying agents
US4737265A (en) * 1983-12-06 1988-04-12 Exxon Research & Engineering Co. Water based demulsifier formulation and process for its use in dewatering and desalting crude hydrocarbon oils
US4734205A (en) * 1986-09-08 1988-03-29 Exxon Research And Engineering Company Hydrophobically associating polymers for oily water clean-up
US5251488A (en) * 1991-02-14 1993-10-12 Texaco Inc. Multiphase volume and flow test instrument
US5333498A (en) * 1992-06-19 1994-08-02 W. L. Walker Co., Inc. Apparatus and method for measuring physical characteristics of a liquid
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US5538628A (en) * 1993-12-16 1996-07-23 Logan; James R. Sonic processor
USH1568H (en) * 1994-05-26 1996-08-06 Exxon Production Research Company Acoustic separation of liquid hydrocarbons from wastewater
US5951456A (en) * 1997-05-16 1999-09-14 Scott; Harold W. Ultrasonic methods and apparatus for separating materials in a fluid mixture

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2257997A (en) * 1940-11-27 1941-10-07 American Cyanamid Co Breaking petroleum emulsions
US2864502A (en) * 1954-04-26 1958-12-16 H2 Oil Engineering Corp Methods and means for the treatment of oil, gas and water emulsions
US3255571A (en) * 1963-05-14 1966-06-14 Nat Tank Co Method and means for treating oil well emulsions
US3699051A (en) * 1970-08-27 1972-10-17 Nalco Chemical Co Compositions and processes for breaking petroleum emulsions
US5885424A (en) * 1994-06-15 1999-03-23 Mobil Oil Corporation Method and apparatus for breaking hydrocarbon emulsions
WO1996005272A2 (en) * 1994-08-12 1996-02-22 Nalco/Exxon Energy Chemicals, L.P. Oil treatment and compositions therefor

Also Published As

Publication number Publication date
US20020185445A1 (en) 2002-12-12
DE60226424D1 (en) 2008-06-19
US20030155307A1 (en) 2003-08-21
US6555009B2 (en) 2003-04-29
US6716358B2 (en) 2004-04-06
CA2438167A1 (en) 2002-09-19
AU2002251816A1 (en) 2002-09-24
WO2002072736A2 (en) 2002-09-19
EP1377653B1 (en) 2008-05-07
CA2438167C (en) 2011-01-18
EP1377653A2 (en) 2004-01-07

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