WO2002102750A3 - Water-enhanced production of 1,1,1,3,3-pentachloropropane - Google Patents

Water-enhanced production of 1,1,1,3,3-pentachloropropane Download PDF

Info

Publication number
WO2002102750A3
WO2002102750A3 PCT/US2002/018253 US0218253W WO02102750A3 WO 2002102750 A3 WO2002102750 A3 WO 2002102750A3 US 0218253 W US0218253 W US 0218253W WO 02102750 A3 WO02102750 A3 WO 02102750A3
Authority
WO
WIPO (PCT)
Prior art keywords
water
pentachloropropane
production
alkane
enhanced production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2002/018253
Other languages
French (fr)
Other versions
WO2002102750A2 (en
Inventor
Lloyd B Branam
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vulcan Materials Co
Original Assignee
Vulcan Chemicals
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vulcan Chemicals filed Critical Vulcan Chemicals
Priority to DE60208676T priority Critical patent/DE60208676T2/en
Priority to EP02739794A priority patent/EP1397332B1/en
Priority to MXPA03011435A priority patent/MXPA03011435A/en
Priority to JP2003505295A priority patent/JP2004530712A/en
Publication of WO2002102750A2 publication Critical patent/WO2002102750A2/en
Publication of WO2002102750A3 publication Critical patent/WO2002102750A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/272—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions
    • C07C17/278—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions of only halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/272—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions
    • C07C17/275—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions of hydrocarbons and halogenated hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A process is provided by which addition of water is used to enhance the production of any hydrochlorocarbon feedstock through the use of Kharasch chemistry, i.e. the combination of a polychlorinated alkane with an olefin to produce a chlorinated or hydrochlorinated alkane with the use of a transition metal compound in homogeneous solution as catalyst. Preferably, water is added to increase the production of 1,1,1,3,3- pentachloropropane by the reaction of carbon tetrachloride and vinyl chloride in the presence of a catalyst mixture of organo phosphate solvent, iron metal and ferric chloride.
PCT/US2002/018253 2001-06-14 2002-06-12 Water-enhanced production of 1,1,1,3,3-pentachloropropane Ceased WO2002102750A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE60208676T DE60208676T2 (en) 2001-06-14 2002-06-12 WATER-INCREASED PRODUCTION OF 1,1,1,3,3-PENTACHLOROPROPANE
EP02739794A EP1397332B1 (en) 2001-06-14 2002-06-12 Water-enhanced production of 1,1,1,3,3-pentachloropropane
MXPA03011435A MXPA03011435A (en) 2001-06-14 2002-06-12 Water-enhanced production of 1,1,1,3,3-pentachloropropane.
JP2003505295A JP2004530712A (en) 2001-06-14 2002-06-12 Production of 1,1,1,3,3-pentachloropropane promoted by water

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/880,010 2001-06-14
US09/880,010 US6500995B1 (en) 2001-06-14 2001-06-14 Water-enhanced production of 1,1,1,3,3,-pentachloropropane

Publications (2)

Publication Number Publication Date
WO2002102750A2 WO2002102750A2 (en) 2002-12-27
WO2002102750A3 true WO2002102750A3 (en) 2003-03-27

Family

ID=25375335

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/018253 Ceased WO2002102750A2 (en) 2001-06-14 2002-06-12 Water-enhanced production of 1,1,1,3,3-pentachloropropane

Country Status (8)

Country Link
US (1) US6500995B1 (en)
EP (1) EP1397332B1 (en)
JP (1) JP2004530712A (en)
AT (1) ATE315546T1 (en)
DE (1) DE60208676T2 (en)
ES (1) ES2252468T3 (en)
MX (1) MXPA03011435A (en)
WO (1) WO2002102750A2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7265082B2 (en) * 2004-08-04 2007-09-04 Honeywell International Inc. Azeotrope-like compositions of 1,1,1,3,3-pentachloropropane and carbon tetrachloride
US9738577B2 (en) * 2006-10-11 2017-08-22 Honeywell International Inc. Process for the manufacture of 1,1,1,3,3-pentachloropropane
CN101913982B (en) * 2010-09-07 2013-08-28 西安近代化学研究所 Preparation method of 1,1,1,3,3-pentafluorobutane
CN101913979A (en) * 2010-09-07 2010-12-15 西安近代化学研究所 Production method of 1,1,1,3,3-pentachlorobutane
US8835702B2 (en) 2011-06-03 2014-09-16 Honeywell International Inc. Method for mitigating the formation of by-products during the production of haloalkane compounds
US8889924B2 (en) * 2012-02-14 2014-11-18 Honeywell International Inc. Process for the production of 1,3,3,3-tetrafluoropropene
US8889930B2 (en) 2013-01-22 2014-11-18 Axiall Ohio, Inc. Process for producing chlorinated hydrocarbons
US9289758B2 (en) 2013-01-22 2016-03-22 Axiall Ohio, Inc. Processes for producing chlorinated hydrocarbons and methods for recovering polyvalent antimony catalysts therefrom
US9139497B2 (en) 2013-10-23 2015-09-22 Axiall Ohio, Inc. Process for producing chlorinated hydrocarbons in the presence of a polyvalent bismuth compound
US10717662B2 (en) * 2018-02-07 2020-07-21 Honeywell International Inc. Process for the removal of iron and phosphate ions from a chlorinated hydrocarbon waste stream
CN113329986A (en) * 2019-01-10 2021-08-31 西方化学股份有限公司 Photochlorination of partially chlorinated chloromethanes to carbon tetrachloride

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2658930A (en) * 1949-03-22 1953-11-10 Universal Oil Prod Co Production of polyhaloalkanes
EP0131561A1 (en) * 1983-07-06 1985-01-16 Monsanto Company Process for producing monoadducts of olefins and telogens reactive therewith
WO1997007083A1 (en) * 1995-08-14 1997-02-27 Alliedsignal Inc. Process for the preparation of halogenated alkanes
WO2001025176A1 (en) * 1999-10-06 2001-04-12 Solvay (Société Anonyme) Method for preparing halogenated hydrocarbons

Family Cites Families (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1015546A (en) 1963-03-08 1966-01-05 Ici Ltd Stabilisation of vinylidene chloride
GB1135314A (en) 1965-03-12 1968-12-04 Edison Soc Process for stabilizing halogenated hydrocarbons particularly trichloroethylene and tetrachloroethylene against decomposition
LU51496A1 (en) 1965-07-14 1966-09-07
US3862978A (en) 1967-08-24 1975-01-28 Dow Chemical Co Catalytic synthesis of organic halogen compounds from an ethylenically unsaturated compound and a halogenated organic compound
GB1288565A (en) 1969-03-24 1972-09-13
GB1265567A (en) 1969-07-22 1972-03-01
US3696050A (en) 1970-08-03 1972-10-03 Eastman Kodak Co Polymerization inhibitors for vinyl monomers and unsaturated polyesters
DE2148185C3 (en) 1971-09-27 1975-05-28 Wacker-Chemie Gmbh, 8000 Muenchen POLYMERIZATION INHIBITOR FOR POLYMERIZABLE VINYL-BASED ALIPHATIC, AROMATIC AND HETEROCYCLIC COMPOUNDS
JPS4892310A (en) 1972-03-18 1973-11-30
JPS5088007A (en) 1973-12-08 1975-07-15
FR2297213A1 (en) 1975-01-10 1976-08-06 Rhone Poulenc Ind Trioxane stabilised with phenolic cpds. - also chlorohydrocarbons, pref. 1,1,1- trichloroethane stabilised with this mixture
JPS5259103A (en) * 1975-11-10 1977-05-16 Shin Etsu Chem Co Ltd Process for preparation of tetrachloroalkane
US4307261A (en) 1980-02-19 1981-12-22 Vulcan Materials Company Process for separating ferric iron from chlorinated hydrocarbons
US4412086A (en) 1980-02-19 1983-10-25 Vulcan Materials Company Process for separating ferric iron from chlorinated hydrocarbons
US4605802A (en) 1982-04-01 1986-08-12 Halocarbon Products Corp. Production of 1,1,1,3-tetrachloropropane
US4471096A (en) 1982-08-03 1984-09-11 Tenneco Polymers, Incorporated Process for the production of vinyl chloride polymers in the presence of a chain-transfer agent that is a mercapto organic compound having at least one beta-ether linkage
US4480121A (en) 1982-08-26 1984-10-30 The Dow Chemical Company Preparation of 2-halo-1-alkenes and acrylate esters from hydrocarbon streams
US5017718A (en) 1983-01-26 1991-05-21 Sagami Chemical Research Center Process for preparing polyfluoroalkyl-substituted compounds
US4542231A (en) 1983-07-05 1985-09-17 Celanese Corporation Stabilized ethylenically unsaturated organic compositions
US4650914A (en) 1983-07-06 1987-03-17 Monsanto Company Process for producing 1,1,2,3-tetrachloropropene
US4535194A (en) 1983-07-06 1985-08-13 Monsanto Co. Process for producing 1,1,2,3-tetrachloropropene
US4803009A (en) 1988-02-02 1989-02-07 E. I. Du Pont De Nemours And Company Stabilized azeotrope or azeotrope-like composition of 1,1,2-trichloro-1,2,2-trifluoroethane, methanol and 1,2-dichloroethylene
US4804493A (en) 1988-05-24 1989-02-14 E. I. Du Pont De Nemours And Company Stabilized azeotrope or azeotrope-like composition of 1,1,2-trichloro-1,2,2-trifluoroethane and trans-1,2-dichloroethylene
ES2054034T3 (en) 1988-11-30 1994-08-01 Rhone Poulenc Spec Chim A PROCESS FOR THE PRODUCTION OF ACRYLILOXY CHLORIDE (SUBSTITUTED) HYDROXYPROPILTRIALKYLAMMONIUM.
US4961870A (en) 1989-12-14 1990-10-09 Allied-Signal Inc. Azeotrope-like compositions of 1,1,2-trichloro-1,2,2-trifluoroethane,1,2-dichloroethylene, and alkanol having 3 to 7 carbon atoms
US5087791A (en) 1990-11-19 1992-02-11 The B. F. Goodrich Company Process for the preparation of ethylene and vinyl chloride from ethane in the presence of water
FR2689885B1 (en) 1992-04-14 1994-10-21 Atochem North America Elf Process for inhibiting the decomposition of 1,1-dichloro-1-fluorethane.
US5656137A (en) 1994-03-25 1997-08-12 Elf Atochem North America, Inc. F141B crude stabilization
US5569794A (en) 1994-05-24 1996-10-29 Alliedsignal Inc. Vapor phase process for producing hydroflourocarbons from perchloroethylene having a phenolic inhibitor
CZ7197A3 (en) 1994-07-11 1998-02-18 Alliedsignal Inc. Process for preparing 1,1,1,3,3-pentafluoropropane
EP0729932A1 (en) 1995-03-03 1996-09-04 Central Glass Company, Limited Method of producing halopropane
ES2166901T3 (en) 1995-08-01 2002-05-01 Du Pont PROCESS FOR THE MANUFACTURE OF HALOGENATED HYDROCARBONS.
WO1997005089A1 (en) 1995-08-01 1997-02-13 E.I. Du Pont De Nemours And Company Process for the manufacture of halocarbons and selected compounds and azeotropes with hf
US5633413A (en) 1995-08-08 1997-05-27 Alliedsignal Inc. Continuous process for the production of vinylidene chloride telomers
FR2740132B1 (en) 1995-10-23 1997-12-19 Solvay PROCESS FOR THE PREPARATION OF 1,1,1,3,3-PENTAFLUOROPROPANE
US5714651A (en) 1995-12-28 1998-02-03 Elf Atochem North America, Inc. Use of polymerization inhibitor to prolong the life of a Lewis acid catalyst
US5696310A (en) 1996-04-12 1997-12-09 Jackson; Andrew Purification of 1,1,1,3,3-pentafluoropropane
US5792893A (en) 1996-07-09 1998-08-11 Vulcan Materials Company Method for the manufacture of 1,1,1,3,3,3-hexachloropropane
US6040487A (en) 1996-07-31 2000-03-21 E. I. Du Pont De Nemours And Company Process for the manufacture of halocarbons
DE69823189T2 (en) 1997-05-05 2005-04-21 Solvay Sa Bruessel Bruxelles METHOD FOR PRODUCING HALOGENATED HYDROCARBONS
JP2000086545A (en) 1998-09-18 2000-03-28 Asahi Glass Co Ltd Method for producing 1,1,1,3,3-pentachloropropane
US6300532B1 (en) * 1998-12-15 2001-10-09 Alliedsignal Inc. Process for addition of haloalkanes to alkenes catalyzed by an organophosphite compound
US6187978B1 (en) 1999-05-12 2001-02-13 Alliedsignal Inc. Continuous process for manufacturing halogenated compounds
JP2001213820A (en) * 2000-01-31 2001-08-07 Central Glass Co Ltd Method of producing 1,1,1,3,3-pentachloro-propane
JP2001297139A (en) 2000-04-12 2001-10-26 Hudson Soft Co Ltd Baggage management system
US6313360B1 (en) * 2000-09-29 2001-11-06 Vulcan Materials Company Process for the manufacture of 1, 1, 1, 3, 3-pentachloropropane

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2658930A (en) * 1949-03-22 1953-11-10 Universal Oil Prod Co Production of polyhaloalkanes
EP0131561A1 (en) * 1983-07-06 1985-01-16 Monsanto Company Process for producing monoadducts of olefins and telogens reactive therewith
WO1997007083A1 (en) * 1995-08-14 1997-02-27 Alliedsignal Inc. Process for the preparation of halogenated alkanes
WO2001025176A1 (en) * 1999-10-06 2001-04-12 Solvay (Société Anonyme) Method for preparing halogenated hydrocarbons

Also Published As

Publication number Publication date
DE60208676D1 (en) 2006-04-06
US6500995B1 (en) 2002-12-31
EP1397332B1 (en) 2006-01-11
JP2004530712A (en) 2004-10-07
EP1397332A2 (en) 2004-03-17
ES2252468T3 (en) 2006-05-16
DE60208676T2 (en) 2006-07-13
US20030009066A1 (en) 2003-01-09
MXPA03011435A (en) 2004-07-01
ATE315546T1 (en) 2006-02-15
WO2002102750A2 (en) 2002-12-27

Similar Documents

Publication Publication Date Title
Yuan et al. Recent advances in FeCl3-photocatalyzed organic reactions via hydrogen-atom transfer
WO2002102750A3 (en) Water-enhanced production of 1,1,1,3,3-pentachloropropane
US9334205B2 (en) Process for the production of chlorinated propanes and propenes
WO2005023984A3 (en) Method for producing 1,1,1,3-tetrachloropropane and other haloalkanes using a copper catalyst
CA2004312A1 (en) Production of allyl chloride
EA199800322A1 (en) METHOD OF OBTAINING 1,1,1,3,3-PENTAFTORPROPANE
AU2002348228A1 (en) Photochlorination of 1,1,1,3,3-pentafluoropropane
MY107702A (en) A process for the production of a mixture of ethylene and mixtures containing ethylene
WO2002066378A3 (en) Methods of producing substantially anatase-free titanium dioxide with silicon halide addition
JP2015506346A (en) Chlorinating agent containing sulfuryl chloride
De Campo et al. New and improved catalysts for transition metal catalysed radical reactions
ES2108296T3 (en) PROCEDURE TO CONVERT 1,1,2-TRICHLOROETHANE TO VINYL AND / OR ETHYLENE CHLORIDE.
EP0913380A4 (en)
Wei et al. Substoichiometric TiCl4-mediated vicinal difunctionalization of α, β-acetylenic ketones for the synthesis of β-halo Baylis–Hillman olefins
AU2003232761A1 (en) Methods for producing chlorine from hydrogen chloride
Iranpoor et al. A facile conversion of thiols to alkyl halides by triphenylphosphine/N-halosuccinimides
EP1140746A1 (en) Process for addition of haloalkanes to alkenes catalyzed by an organophosphite compound
WO2013090421A1 (en) Process for the production of chlorinated propanes and propenes
Uemura et al. The chlorination of norbornene by metal chlorides and the product isomerization.
US5396006A (en) Preparation of alkenes and of cyclopentane and cyclohexane
WO2001021565A3 (en) Process for producing 3-bromobenzoyl halides
GB1186557A (en) Improvements in or relating to the manufacture of Chlorinated Hydrocarbons
KR960017504A (en) Hydrogen chloride oxidation method
GB1170149A (en) Chlorination of Chloroalkanes.
GB1441457A (en) Reactors

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): JP MX

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2002739794

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: PA/a/2003/011435

Country of ref document: MX

WWE Wipo information: entry into national phase

Ref document number: 2003505295

Country of ref document: JP

WWP Wipo information: published in national office

Ref document number: 2002739794

Country of ref document: EP

WWG Wipo information: grant in national office

Ref document number: 2002739794

Country of ref document: EP