WO2003015902A3 - High strength asymmetric cellulosic membrane - Google Patents
High strength asymmetric cellulosic membrane Download PDFInfo
- Publication number
- WO2003015902A3 WO2003015902A3 PCT/US2002/025367 US0225367W WO03015902A3 WO 2003015902 A3 WO2003015902 A3 WO 2003015902A3 US 0225367 W US0225367 W US 0225367W WO 03015902 A3 WO03015902 A3 WO 03015902A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- high strength
- cellulosic membrane
- membranes
- strength asymmetric
- asymmetric cellulosic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0093—Chemical modification
- B01D67/00931—Chemical modification by introduction of specific groups after membrane formation, e.g. by grafting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/145—Ultrafiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/147—Microfiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
- B01D67/0013—Casting processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
- B01D67/0018—Thermally induced processes [TIPS]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/08—Polysaccharides
- B01D71/12—Cellulose derivatives
- B01D71/14—Esters of organic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/08—Polysaccharides
- B01D71/12—Cellulose derivatives
- B01D71/14—Esters of organic acids
- B01D71/16—Cellulose acetate
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07K—PEPTIDES
- C07K1/00—General methods for the preparation of peptides, i.e. processes for the organic chemical preparation of peptides or proteins of any length
- C07K1/14—Extraction; Separation; Purification
- C07K1/34—Extraction; Separation; Purification by filtration, ultrafiltration or reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07K—PEPTIDES
- C07K16/00—Immunoglobulins [IG], e.g. monoclonal or polyclonal antibodies
- C07K16/06—Immunoglobulins [IG], e.g. monoclonal or polyclonal antibodies from serum
- C07K16/065—Purification, fragmentation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/12—Specific ratios of components used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/30—Cross-linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/20—Specific permeability or cut-off range
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Water Supply & Treatment (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Biochemistry (AREA)
- Biophysics (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Molecular Biology (AREA)
- Immunology (AREA)
- Inorganic Chemistry (AREA)
- Transplantation (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Analytical Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2002329724A AU2002329724A1 (en) | 2001-08-14 | 2002-08-08 | High strength asymmetric cellulosic membrane |
| CA002454856A CA2454856A1 (en) | 2001-08-14 | 2002-08-08 | High strength asymmetric cellulosic membrane |
| JP2003520850A JP2004538143A (en) | 2001-08-14 | 2002-08-08 | High strength asymmetric cellulosic membrane |
| EP02765968A EP1425085A2 (en) | 2001-08-14 | 2002-08-08 | High strength asymmetric cellulosic membrane |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/929,821 | 2001-08-14 | ||
| US09/929,821 US20030038081A1 (en) | 2001-08-14 | 2001-08-14 | High strength asymmetric cellulosic membrane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2003015902A2 WO2003015902A2 (en) | 2003-02-27 |
| WO2003015902A3 true WO2003015902A3 (en) | 2003-11-13 |
Family
ID=25458509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2002/025367 Ceased WO2003015902A2 (en) | 2001-08-14 | 2002-08-08 | High strength asymmetric cellulosic membrane |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20030038081A1 (en) |
| EP (1) | EP1425085A2 (en) |
| JP (1) | JP2004538143A (en) |
| AU (1) | AU2002329724A1 (en) |
| CA (1) | CA2454856A1 (en) |
| WO (1) | WO2003015902A2 (en) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6045899A (en) * | 1996-12-12 | 2000-04-04 | Usf Filtration & Separations Group, Inc. | Highly assymetric, hydrophilic, microfiltration membranes having large pore diameters |
| DE10326741B4 (en) * | 2003-06-13 | 2017-07-27 | Sartorius Stedim Biotech Gmbh | A process for producing a cellulose-based microporous membrane and a cellulose-based microporous membrane obtained by the process |
| JP2005095003A (en) * | 2003-09-03 | 2005-04-14 | Fuji Photo Film Co Ltd | Method for separating and purifying nucleic acid |
| DE10354571B4 (en) * | 2003-11-21 | 2011-05-05 | Sartorius Stedim Biotech Gmbh | Process for the production of spirits |
| JP2006083292A (en) * | 2004-09-16 | 2006-03-30 | Fuji Photo Film Co Ltd | Method for stable production of microporous membrane and use thereof in nucleic acid separation and purification method |
| RU2008129719A (en) * | 2005-12-21 | 2010-01-27 | Конинклейке Филипс Электроникс Н.В. (Nl) | SENSOR OF BIOMOLECULES AND METHOD OF ITS PRODUCTION AND APPLICATION |
| JP2007245107A (en) * | 2006-03-20 | 2007-09-27 | Daicel Chem Ind Ltd | Hollow fiber porous membrane |
| US8123945B2 (en) * | 2007-05-09 | 2012-02-28 | The United States of America as represented by the Secretary of the Interior, The Bereau of Reclamation | Method for making high flux, high salt rejection cellulose desalting membranes |
| EP2150356A4 (en) * | 2007-05-26 | 2012-05-30 | Stonybrook Water Purification | HIGH FLOW FLUID SEPARATION MEMBRANES COMPRISING A CELLULOSE LAYER OR CELLULOSE DERIVATIVE |
| DE102008055821A1 (en) * | 2008-04-14 | 2009-10-15 | Sartorius Stedim Biotech Gmbh | Cellulose hydrate membrane, process for its preparation and use thereof |
| DE102008018732B4 (en) | 2008-04-14 | 2022-06-09 | Sartorius Stedim Biotech Gmbh | Process for separating substances using a cellulose hydrate membrane in size exclusion chromatography |
| DE102008018734B4 (en) * | 2008-04-14 | 2013-03-21 | Sartorius Stedim Biotech Gmbh | Hydrophobic cellulose membrane, process for its preparation and its use in hydrophobic interaction chromatography |
| US9055752B2 (en) * | 2008-11-06 | 2015-06-16 | Intercontinental Great Brands Llc | Shelf-stable concentrated dairy liquids and methods of forming thereof |
| UA112972C2 (en) | 2010-09-08 | 2016-11-25 | Інтерконтінентал Грейт Брендс ЛЛС | LIQUID DAIRY CONCENTRATE WITH A HIGH CONTENT OF DRY SUBSTANCES |
| US8585806B2 (en) * | 2011-01-11 | 2013-11-19 | Hydration Systems, Llc | Gas separation membrane |
| US20120175300A1 (en) * | 2011-01-11 | 2012-07-12 | Herron John R | Two-layer membrane |
| CN106661263B (en) * | 2014-07-22 | 2020-07-10 | 株式会社大赛璐 | Manufacturing method of porous cellulose medium |
| JP6422032B2 (en) * | 2015-11-04 | 2018-11-14 | 日本特殊膜開発株式会社 | Flow separation type pore diffusion membrane separation module for concentration |
| TWI577562B (en) * | 2016-02-05 | 2017-04-11 | 大江生醫股份有限公司 | Bio-cellulose membrane and the production method thereof |
| KR102247345B1 (en) * | 2019-07-12 | 2021-05-03 | 한국화학연구원 | Hollow fiber membrane with improved mechanical strength, and method for manufacturing the same |
| DE102019005373A1 (en) | 2019-07-30 | 2021-02-04 | Sartorius Stedim Biotech Gmbh | Mechanically stable ultrafiltration membrane and process for its manufacture |
| GB202009004D0 (en) | 2020-06-12 | 2020-07-29 | Norwegian Univ Of Science And Technology (Ntnu) | Carbon hollow fibre membrane |
| CN113877439B (en) * | 2020-07-03 | 2024-04-16 | 杭州科百特科技有限公司 | Polymer filter membrane mixed by coarse and fine fibers and preparation method and application thereof |
| CN113117532B (en) * | 2021-05-06 | 2022-07-15 | 贝源新材料科技(广东)有限公司 | Ultrafiltration membrane for double adsorption of heavy metal and dye and preparation method thereof |
| CN113171686A (en) * | 2021-05-12 | 2021-07-27 | 安徽建筑大学 | A kind of preparation method of cellulose acetate reverse osmosis membrane modified with quaternary ammonium salt surface |
| CN115025630A (en) * | 2021-06-02 | 2022-09-09 | 赛普(杭州)过滤科技有限公司 | Preparation method and product of hollow cellulose virus removal filtering membrane |
| CN115041024A (en) * | 2021-06-02 | 2022-09-13 | 赛普(杭州)过滤科技有限公司 | Preparation method of asymmetric regenerated cellulose virus-removing flat filter membrane and product |
| CN114653214A (en) * | 2022-03-29 | 2022-06-24 | 赛普(杭州)过滤科技有限公司 | Preparation method of regenerated cellulose ultrafiltration membrane with controllable product performance and product |
| CA3247043A1 (en) * | 2022-04-15 | 2023-10-19 | Siemens Healthcare Diagnostics Inc. | Creatinine lateral flow assay devices and methods of production and use thereof |
| CN116099385B (en) * | 2022-09-09 | 2024-06-14 | 杭州科百特过滤器材有限公司 | A high-throughput cellulose virus removal filter membrane and its preparation process |
| CN116272430A (en) * | 2023-02-28 | 2023-06-23 | 杭州科百特过滤器材有限公司 | A kind of cellulose virus removal film and its preparation process |
| CN116272431A (en) * | 2023-04-10 | 2023-06-23 | 赛普(杭州)过滤科技有限公司 | Preparation method of ultrafiltration membrane with controllable thickness of humidity sensing small pore layer and ultrafiltration equipment |
| CN116712869B (en) * | 2023-08-07 | 2023-11-24 | 赛普(杭州)过滤科技有限公司 | Regenerated cellulose virus-removing filtering membrane and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3883626A (en) * | 1972-11-21 | 1975-05-13 | Asahi Chemical Ind | Porous cellulose acetate membrane and a process for the manufacture of same |
| EP0042766A2 (en) * | 1980-06-25 | 1981-12-30 | Puropore, Inc. | Highly anisotropic membranes and process for making same |
| US4543221A (en) * | 1979-12-17 | 1985-09-24 | Cd Medical, Inc. | Method for making cellulose semipermeable hollow fibers |
| JPS6230502A (en) * | 1985-03-04 | 1987-02-09 | Toyobo Co Ltd | Hollow yarn type separation membrane |
| JPH04250834A (en) * | 1991-01-07 | 1992-09-07 | Fuji Photo Film Co Ltd | Precision filter membrane |
| DE19750527A1 (en) * | 1997-11-14 | 1999-05-27 | Akzo Nobel Nv | Production of stable and storable cellulosic separation membrane |
| WO2000072950A1 (en) * | 1999-05-31 | 2000-12-07 | Daicel Chemical Industries, Ltd. | Cellulose derivative hollow fiber membrane |
| WO2001089673A2 (en) * | 2000-05-24 | 2001-11-29 | Millipore Corporation | Process of forming multilayered structures |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1495887A (en) * | 1923-09-24 | 1924-05-27 | George W Crane | Drill-setting device |
| US3227510A (en) * | 1958-03-04 | 1966-01-04 | Tee Pak Inc | Dyeing substrates ionically binding in localized areas catalysts for the predyeing olefin polymerization thereon |
| US3580841A (en) * | 1969-07-31 | 1971-05-25 | Us Interior | Ultrathin semipermeable membrane |
| BE759589A (en) * | 1969-11-28 | 1971-04-30 | Eastman Kodak Co | PROCESS FOR THE MANUFACTURE OF MEMBRANES SPECIFIC TO REVERSE OSMOSIS |
| US3682318A (en) * | 1970-06-10 | 1972-08-08 | Amicon Corp | Tubular ultrafiltration membrane and support |
| US3762566A (en) * | 1971-08-03 | 1973-10-02 | Abcor Inc | Supported semipermeable membranes and process for preparing same |
| DE2522979A1 (en) * | 1974-05-24 | 1975-12-04 | Fuji Photo Film Co Ltd | METHOD OF MANUFACTURING A MICROPOROUS FILM |
| US4026978A (en) * | 1975-07-17 | 1977-05-31 | The United States Of America As Represented By The Secretary Of The Interior | Method of making asymmetric cellulose triacetate membranes |
| US4309247A (en) * | 1976-03-15 | 1982-01-05 | Amf Incorporated | Filter and method of making same |
| US4159251A (en) * | 1976-09-29 | 1979-06-26 | Pharmaco, Inc. | Ultrafiltration membranes based on heteroaromatic polymers |
| US4145295A (en) * | 1977-08-15 | 1979-03-20 | Canadian Patents And Development Limited | Cellulose ester ultra-filtration membranes and their manufacture |
| CA1148872A (en) * | 1979-04-06 | 1983-06-28 | Eugene A. Ostreicher | Filter with inorganic cationic colloidal silica |
| US4629563B1 (en) * | 1980-03-14 | 1997-06-03 | Memtec North America | Asymmetric membranes |
| US4473474A (en) * | 1980-10-27 | 1984-09-25 | Amf Inc. | Charge modified microporous membrane, process for charge modifying said membrane and process for filtration of fluid |
| US4432875A (en) * | 1981-05-29 | 1984-02-21 | Brunswick Corporation | Semi-permeable membranes and processes for making the same |
| US4413074A (en) * | 1982-01-25 | 1983-11-01 | Brunswick Corporation | Hydrophilic surfaces and process for making the same |
| CH660852A5 (en) * | 1982-11-23 | 1987-05-29 | Aligena Ag | DYNAMIC MEMBRANES THAT ARE THIN THIN POLYMER LAYERS ON POROUS, POLYMER CARRIER MATERIALS. |
| US4512896A (en) * | 1983-02-07 | 1985-04-23 | Yale University | Transfer of macromolecules from a chromatographic substrate to an immobilizing matrix |
| US4609465A (en) * | 1984-05-21 | 1986-09-02 | Pall Corporation | Filter cartridge with a connector seal |
| US4606824A (en) * | 1984-10-26 | 1986-08-19 | Chaokang Chu | Modified cellulose separation matrix |
| IL78169A0 (en) * | 1986-03-17 | 1986-07-31 | Weizmann Kiryat Membrane Prod | Novel membranes and process for making them |
| US4814082A (en) * | 1986-10-20 | 1989-03-21 | Memtec North America Corporation | Ultrafiltration thin film membranes |
| US4902422A (en) * | 1988-12-06 | 1990-02-20 | Board Regents The University Of Texas System | Defect-free ultrahigh flux asymmetric membranes |
| NL9000113A (en) * | 1990-01-17 | 1991-08-16 | X Flow Bv | METHOD FOR MANUFACTURING A FLAT POROUS PRODUCT AND ITS APPLICATION IN THE FIELD OF PHARMACY, MEDICINE, DENTISTRY OR COSMETICS. |
| US5098569A (en) * | 1990-12-13 | 1992-03-24 | Monsanto Company | Surface-modified support membrane and process therefor |
| IL104670A (en) * | 1993-02-09 | 1998-04-05 | Travenol Lab Israel Ltd | Leukocyte removal method and filter unit for same |
| DE4309845C2 (en) * | 1993-03-26 | 1996-10-31 | Seitz Filter Werke | Filter material and process for its manufacture |
| US6045899A (en) * | 1996-12-12 | 2000-04-04 | Usf Filtration & Separations Group, Inc. | Highly assymetric, hydrophilic, microfiltration membranes having large pore diameters |
-
2001
- 2001-08-14 US US09/929,821 patent/US20030038081A1/en not_active Abandoned
-
2002
- 2002-08-08 JP JP2003520850A patent/JP2004538143A/en not_active Withdrawn
- 2002-08-08 AU AU2002329724A patent/AU2002329724A1/en not_active Abandoned
- 2002-08-08 WO PCT/US2002/025367 patent/WO2003015902A2/en not_active Ceased
- 2002-08-08 CA CA002454856A patent/CA2454856A1/en not_active Abandoned
- 2002-08-08 EP EP02765968A patent/EP1425085A2/en not_active Withdrawn
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3883626A (en) * | 1972-11-21 | 1975-05-13 | Asahi Chemical Ind | Porous cellulose acetate membrane and a process for the manufacture of same |
| US4543221A (en) * | 1979-12-17 | 1985-09-24 | Cd Medical, Inc. | Method for making cellulose semipermeable hollow fibers |
| EP0042766A2 (en) * | 1980-06-25 | 1981-12-30 | Puropore, Inc. | Highly anisotropic membranes and process for making same |
| JPS6230502A (en) * | 1985-03-04 | 1987-02-09 | Toyobo Co Ltd | Hollow yarn type separation membrane |
| JPH04250834A (en) * | 1991-01-07 | 1992-09-07 | Fuji Photo Film Co Ltd | Precision filter membrane |
| DE19750527A1 (en) * | 1997-11-14 | 1999-05-27 | Akzo Nobel Nv | Production of stable and storable cellulosic separation membrane |
| WO2000072950A1 (en) * | 1999-05-31 | 2000-12-07 | Daicel Chemical Industries, Ltd. | Cellulose derivative hollow fiber membrane |
| EP1127608A1 (en) * | 1999-05-31 | 2001-08-29 | Daicel Chemical Industries, Ltd. | Cellulose derivative hollow fiber membrane |
| WO2001089673A2 (en) * | 2000-05-24 | 2001-11-29 | Millipore Corporation | Process of forming multilayered structures |
Non-Patent Citations (2)
| Title |
|---|
| PATENT ABSTRACTS OF JAPAN vol. 011, no. 206 (C - 433) 3 July 1987 (1987-07-03) * |
| PATENT ABSTRACTS OF JAPAN vol. 017, no. 030 (C - 1018) 20 January 1993 (1993-01-20) * |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2454856A1 (en) | 2003-02-27 |
| US20030038081A1 (en) | 2003-02-27 |
| JP2004538143A (en) | 2004-12-24 |
| AU2002329724A1 (en) | 2003-03-03 |
| WO2003015902A2 (en) | 2003-02-27 |
| EP1425085A2 (en) | 2004-06-09 |
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