WO2003043018A1 - Magnetoresistance random access memory for improved scalability - Google Patents

Magnetoresistance random access memory for improved scalability Download PDF

Info

Publication number
WO2003043018A1
WO2003043018A1 PCT/US2002/031946 US0231946W WO03043018A1 WO 2003043018 A1 WO2003043018 A1 WO 2003043018A1 US 0231946 W US0231946 W US 0231946W WO 03043018 A1 WO03043018 A1 WO 03043018A1
Authority
WO
WIPO (PCT)
Prior art keywords
magnetic
layer
ferromagnetic
electrically insulating
magnetic moment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2002/031946
Other languages
French (fr)
Inventor
Bradley N. Engel
Leonid Savtchenko
Jason Allen Janesky
Nicholas D. Rizzo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Motorola Solutions Inc
Original Assignee
Motorola Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Motorola Inc filed Critical Motorola Inc
Priority to EP02773722A priority Critical patent/EP1449219A1/en
Priority to KR1020047006283A priority patent/KR100924443B1/en
Priority to JP2003544760A priority patent/JP2005510048A/en
Publication of WO2003043018A1 publication Critical patent/WO2003043018A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/02Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
    • G11C11/14Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using thin-film elements
    • G11C11/15Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using thin-film elements using multiple magnetic layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y25/00Nanomagnetism, e.g. magnetoimpedance, anisotropic magnetoresistance, giant magnetoresistance or tunneling magnetoresistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/02Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
    • G11C11/16Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/02Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
    • G11C11/16Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
    • G11C11/161Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect details concerning the memory cell structure, e.g. the layers of the ferromagnetic memory cell
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F10/00Thin magnetic films, e.g. of one-domain structure
    • H01F10/32Spin-exchange-coupled multilayers, e.g. nanostructured superlattices
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F10/00Thin magnetic films, e.g. of one-domain structure
    • H01F10/32Spin-exchange-coupled multilayers, e.g. nanostructured superlattices
    • H01F10/324Exchange coupling of magnetic film pairs via a very thin non-magnetic spacer, e.g. by exchange with conduction electrons of the spacer
    • H01F10/3254Exchange coupling of magnetic film pairs via a very thin non-magnetic spacer, e.g. by exchange with conduction electrons of the spacer the spacer being semiconducting or insulating, e.g. for spin tunnel junction [STJ]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F10/00Thin magnetic films, e.g. of one-domain structure
    • H01F10/32Spin-exchange-coupled multilayers, e.g. nanostructured superlattices
    • H01F10/324Exchange coupling of magnetic film pairs via a very thin non-magnetic spacer, e.g. by exchange with conduction electrons of the spacer
    • H01F10/3268Exchange coupling of magnetic film pairs via a very thin non-magnetic spacer, e.g. by exchange with conduction electrons of the spacer the exchange coupling being asymmetric, e.g. by use of additional pinning, by using antiferromagnetic or ferromagnetic coupling interface, i.e. so-called spin-valve [SV] structure, e.g. NiFe/Cu/NiFe/FeMn
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F41/00Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
    • H01F41/14Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for applying magnetic films to substrates
    • H01F41/30Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for applying magnetic films to substrates for applying nanostructures, e.g. by molecular beam epitaxy [MBE]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F41/00Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
    • H01F41/14Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for applying magnetic films to substrates
    • H01F41/30Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for applying magnetic films to substrates for applying nanostructures, e.g. by molecular beam epitaxy [MBE]
    • H01F41/302Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for applying magnetic films to substrates for applying nanostructures, e.g. by molecular beam epitaxy [MBE] for applying spin-exchange-coupled multilayers, e.g. nanostructured superlattices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N50/00Galvanomagnetic devices
    • H10N50/10Magnetoresistive devices

Definitions

  • This invention relates to semiconductor memory devices .
  • the present invention relates to semiconductor random access memory devices that utilize a magnetic field.
  • SRAM Serial RAM
  • DRAM Dynamic RAM
  • FLASH the major nonvolatile memory device in use today. Typical non-volatile memory devices use charges trapped in a floating oxide layer to store information.
  • FLASH memory has a poor write endurance of 10 4 -10 6 cycles before memory failure.
  • the thickness of the gate oxide has to stay above the threshold that allows electron tunneling, thus restricting FLASH'S scaling trends.
  • MRAM magnetoresistive RAM
  • a memory state in MRAM is not maintained by power, but rather by the direction of the magnetic moment vector.
  • Storing data is accomplished by applying magnetic fields and causing a magnetic material in a cell to be magnetized into either of two possible memory states. Recalling data is accomplished by sensing the electrical resistance, which differs for the two states .
  • the magnetic fields for programming are created by passing currents through conductive lines external to the magnetic structure or through the magnetic structures themselves .
  • a scalable magnetoresistive tunneling junction memory (hereinafter referred to as "MRAM”) device.
  • the MRAM device includes a substrate onto which a fixed magnetic region is positioned.
  • An electrically insulating material of sufficient thickness to act as a electron tunneling barrier is then positioned on the fixed magnetic region and a free magnetic region is positioned on the electrically insulating material .
  • the fixed magnetic region adjacent to the tunneling barrier has a resultant magnetic moment vector that is fixed in a preferred direction.
  • the free magnetic region includes a synthetic anti-ferromagnetic (hereinafter referred to as "SAF”) layer material.
  • SAF synthetic anti-ferromagnetic
  • the synthetic anti-ferromagnetic layer material includes N anti-ferromagnetically coupled layers of a ferromagnetic material where N is an integer greater than or equal to two. Further, the N layers define a magnetic switching volume that can be adjusted by changing N. In the preferred embodiment, the N ferromagnetic layers are anti-ferromagnetically coupled by sandwiching an anti- ferromagnetic coupling spacer layer between each adjacent ferromagnetic layer.
  • the total net magnetic moment vector is comprised of the vector sum of the each N sub-layer magnetic moment vectors. Because each sublayer is anti-ferromagnetically coupled to its neighboring layer, there are two antiparallel directions the sub-layer moments can point in zero magnetic field. The total moment is therefore determined by the difference of M 1 and M 2 , where M 1 and M 2 are the total sublayer moments in each direction, respectively.
  • the magnetic moment vectors are usually oriented anti- parallel by the coupling of the anti-ferromagnetic coupling spacer layer. Anti-ferromagnetic coupling is also generated by the magnetostatic fields of the layers in the MRAM structure. Therefore, the spacer layer need not necessarily provide any additional antiferromagnetic coupling beyond eliminating the ferromagnetic coupling between the two magnetic layers .
  • the magnetic moment vectors in the ferromagnetic layers can have different magnitudes to provide a
  • M b — , where M total - M 1 + M 2 is the total
  • the resultant magnetic moment vector of the ⁇ -layer structure is free to rotate with an applied magnetic field. In zero field the resultant magnetic moment vector will be stable in a direction, determined by the magnetic anisotropy, which is either parallel or anti-parallel with respect to the resultant magnetic moment vector of the fixed magnetic region.
  • the current through the MRAM device depends on the tunneling magnetoresistance, which is governed by the relative orientation of the magnetic moment vectors of the free and fixed magnetic regions directly adjacent to the tunneling barrier. If the magnetic moment vectors are parallel, then the MRAM device resistance is low and a voltage bias will induce a larger current through the device. This state is defined as a "1". If the magnetic moment vectors are anti-parallel, then the MRAM device resistance is high and an applied voltage bias will induce a smaller current through the device. This state is defined as a "0". It will be understood that these definitions are arbitrary and could be reversed, but are used in this example for illustrative purposes. Thus, in magnetoresistive memory, data storage is accomplished by applying magnetic fields that cause the magnetic moment vectors in the MRAM device to be orientated either one of parallel and anti-parallel directions relative to the magnetic moment vector in the fixed reference layer.
  • the number N of ferromagnetic layers can be adjusted to increase the magnetic switching volume of the free magnetic region.
  • the energy barrier required to inadvertently reverse the magnetic moment vectors is increased.
  • the effect of the increased energy barrier is to decrease the data retention error rate due to inadvertent reversals caused by thermal fluctuations. Consequently, the stability of the memory state is increased.
  • the addition of ferromagnetic layers can be such that there is no change in the sub-layer magnetic moment balance ratio M ⁇ r and the switching field remains constant for a circular bit shape.
  • the total energy barrier is increased since each anti-ferromagnetically coupled ferromagnetic layer must overcome its intrinsic anisotropy to reverse, thereby increasing the magnetic switching volume without increasing the required switching current. Therefore, the MRAM device can be scaled to smaller lateral dimensions and the magnetic switching volume can be kept constant or adjusted to a desired value by adding more anti-ferromagnetically coupled ferromagnetic layers while maintaining a constant sub-layer moment balance ratio.
  • the MRAM device is circular in shape so that there is no contribution to the switching field from shape anisotropy.
  • a parameter that predominantly sets a switching field is the material's induced magnetic anisotropy, H k .
  • H k is only about 20 Oe, which is undesirable for MRAM device operation.
  • M % , M are the total sub-layer magnetic moments in each direction of the N-layer structure, respectively.
  • the increase in the switching field is a result of the smaller resultant magnetic moment vector becoming a smaller handle for the external magnetic field to rotate all of the spins in the N ferromagnetic layers.
  • the closer in magnitude that the opposing magnetic moments are to each other the higher the effective switching field.
  • the switching field can be adjusted to a reasonable value through the control of the induced H k and the sub-layer magnetic moment balance ratio
  • the shape sensitivity is decreased since the circular shape is not the main source of the switching field. Also, the diminished resultant magnetic moment vector further reduces the effect of shape variations since the effective magnetic charges at the shape edges are much smaller than for a single layer film of comparable thickness.
  • FIG. 1 is a sectional view of a magnetoresistive random access memory device with improved scalability
  • FIG. 2 is a graph illustrating the coercivity of a bulk free layer film verses the thickness of one ferromagnetic layer in a N-layer structure with the other layer held at a constant thickness of 40 A.
  • FIG. 1 illustrates a simplified sectional view of a scalable magnetoresistive tunneling junction memory cell 5 in accordance with the present invention.
  • the scalable magnetoresistive tunneling junction memory cell 5 includes a supporting substrate 10 onto which a seed layer 20 is positioned.
  • Supporting substrate 10 may be, for example, a semiconductor substrate or wafer and semiconductor control devices may then be formed thereon.
  • Seed layer 20 is formed on supporting substrate 10 to aid in the formation and operation of the remaining layers of material.
  • An anti- ferromagnetic layer 30 is then positioned on seed layer 20 and includes, for example Ni, Fe, Mn, Co or combinations thereof. It will be understood that seed layer 20 is optional and is included in this preferred embodiment for illustrative purposes. Also, the positioning of anti-ferromagnetic layer 30 is for fabrication convenience with many other possible configurations available.
  • a first magnetic region 55 having a resultant magnetic moment vector 57 is positioned on the anti- ferromagnetic layer 30.
  • An electrically insulating layer 70 is placed on first magnetic region 55 and a second magnetic region 135 having a resultant magnetic moment vector 87 is positioned on electrically insulating layer 70.
  • Electrically insulating layer 70 behaves as a tunneling barrier junction. It will be understood that electrically insulating layer 70 can include multiple insulating layers, but is shown as one layer for illustrative purposes.
  • Anti-ferromagnetic layer 30 pins resultant magnetic moment vector 57 unidirectionally along a preferred magnetic axis unless sufficient magnetic field is supplied to overcome the pinning action of layer 30. Generally, anti-ferromagnetic layer 30 is thick enough to insure that spurious signals and normal cell writing signals will not switch resultant magnetic moment vector 57.
  • fixed magnetic region In the preferred embodiment, fixed magnetic region
  • magnetic region 55 includes a synthetic anti-ferromagnetic layer material which includes a tri-layer structure of an anti- ferromagnetic coupling spacer layer 50 sandwiched between a ferromagnetic layer 60 and a ferromagnetic layer 40.
  • magnetic region 55 can include a synthetic anti-ferromagnetic layer material other than a tri-layer structure and the use of a tri- layer structure in this embodiment is for illustrative purposes only.
  • magnetic region 55 is a fixed ferromagnetic region, meaning that resultant magnetic moment vector 57 is not free to rotate in the presence of a moderate applied magnetic field and is used as the reference layer.
  • a free magnetic region 135 includes a synthetic anti-ferromagnetic layer material which includes N ferromagnetic layers that are anti-ferromagnetically coupled, wherein N is a integer number greater than or equal to two .
  • N is chosen to be equal to two so that magnetic region includes a tri-layer structure which has an anti-ferromagnetic coupling spacer layer 90 sandwiched between a ferromagnetic layer 80 and a ferromagnetic layer 100.
  • Ferromagnetic layers 80 and 100 each have thicknesses 81 and 101, respectively.
  • anti- ferromagnetic coupling spacer layer 90 has a thickness 86.
  • the synthetic anti- ferromagnetic layer material in magnetic region 135 can include other structures with a different number of ferromagnetic layers and the use of a tri-layer structure in this embodiment is for illustrative purposes only.
  • a five-layer stack of a ferromagnetic layer/ anti-ferromagnetic coupling spacer layer/ ferromagnetic layer /anti-ferromagnetic coupling spacer layer/ ferromagnetic layer could be used, wherein N is equal to three .
  • anti-ferromagnetic coupling spacer layers 50 and 90 include elements Ru, Os, Re, Cr, Rh, and Cu, or combinations thereof.
  • ferromagnetic layers 40, 60, 80, and 100 generally include alloys of Ni, Fe, Mn, Co, or combinations thereof.
  • Ferromagnetic layers 80 and 100 each have a magnetic moment vector 85 and 105, respectively, that are usually held anti-parallel by coupling of anti-ferromagnetic coupling spacer layer 90.
  • magnetic region 135 has a resultant magnetic moment vector 87. Resultant magnetic moment vectors 57 and 87 are oriented along an anisotropy easy-axis in a preferred direction. Further, magnetic region 135 is a free ferromagnetic region, meaning that resultant magnetic moment vector 87 is free to rotate in the presence of an applied magnetic field.
  • anti-ferromagnetic coupling layers are illustrated between the ferromagnetic layers in magnetic regions 55 and 135, it will be understood that the ferromagnetic layers could be anti-ferromagnetically coupled through other means such as magnetostatic fields or other features.
  • the ferromagnetic layers are anti-parallel coupled from magnetostatic flux closure. In this case, any nonmagnetic spacer layer that breaks the ferromagnetic exchange between layers will suffice.
  • the adjacent ferromagnetic layers are anti-ferromagnetically coupled by sandwiching anti-ferromagnetic coupling material between each adjacent ferromagnetic layer.
  • One advantage of using a synthetic anti-ferromagnetic layer material is that the anti-parallel coupling of the magnetic moment vectors prevents a vortex from forming at a given thickness where a vortex would be formed if using a single layer.
  • each succeeding layer i.e. 20, 30, 40, etc.
  • each cell may be defined by selective deposition, photolithography processing, etching, etc. in any of the techniques known in the semiconductor industry.
  • a magnetic field is provided to set an easy magnetic axis for these layers (induced anisotropy) .
  • This anisotropy axis can also be set subsequent to deposition by annealing in the presence of a magnetic field.
  • the number N of ferromagnetic layers in free region 135 can be adjusted such that the magnetic switching volume of free region 135 remains substantially constant or increases as the device is scaled laterally to smaller dimensions.
  • the magnetic switching volume of MRAM device 5 can be controlled and, consequently, the bit error rate can be minimized.
  • Thicknesses 81 and 101 and/or the materials of the layers are chosen so that a magnetic field needed to switch magnetic moments 85 and 105 remains substantially constant (the term "substantially constant" is intended to include moderate increases) as the device is scaled laterally. Because the N ferromagnetic layers can be chosen such that there is no change in the magnetic moment balance ratio M br , the switching field H sw remains constant for a circular plan.
  • magnetoresistive tunneling junction memory cell 5 has magnetic regions 55 and 135 that each have a length/width ratio in a range of
  • MRAM device 5 is circular in shape (generally in a cross-section parallel to substrate 10) so that there is no contribution to the switching field from shape anisotropy and also because it is easier to use photolithography processing to scale the device to smaller dimensions laterally.
  • MRAM device 5 can have other shapes, such as square, rectangular, elliptical, or diamond but is illustrated as being circular for simplicity.
  • H k the material's induced magnetic anisotropy
  • H k the material's induced magnetic anisotropy
  • H sw the effective anisotropy and switching field
  • M 8 s, M 105 are the magnitude of the magnetic moment vectors in ferromagnetic layers 80 and 100, respectively.
  • FIG. 2 a graph illustrates the effective switching field, H sw , of a tri-layer structure verses thickness 101 of ferromagnetic layer 100.
  • the graph of the data in FIG. 2 was generated from a bulk, unpatterned material film, and as such it is representative of the trend in H sw of circular bit patterns.
  • FIG. 2 provides direct evidence of the amplification effect of an unbalanced synthetic anti- ferromagnetic structure.
  • thickness 86 of anti- ferromagnetic coupling spacer layer 90 is chosen to be 7 A and thickness 81 of ferromagnetic layer 80 is chosen to be 40 A.
  • anti-ferromagnetic spacer layer 90 includes Ru and ferromagnetic layers 80 and 100 include NiFeCo .
  • thickness 101 of ferromagnetic layer 100 is varied from approximately 30 A to 75 A, H sw varies dramatically in the range of approximately 35 A to 45 A. For optimal MRAM device operation, H sw should be approximately in the range between 50 Oe and 150 Oe . H sw can be set in this range by varying thickness 101 as illustrated. If thickness 101 is set at 40 A, then H sw will be approximately 225
  • H sw will be approximately 75
  • H sw can be adjusted to a desired value.
  • the scalable magnetoresistive memory device has a magnetic switching volume that can be controlled by varying N.
  • N the magnetic switching volume can be increased as the MRAM device is scaled laterally to smaller dimensions. Consequently, the bit error rate due to thermal fluctuations is reduced.
  • H sw can be controlled by varying the thicknesses and/or materials of the ferromagnetic layers. By controlling H sw , the switching field can be adjusted to a desired value sufficient for MRAM device operation as the device is scaled laterally to smaller dimensions.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Nanotechnology (AREA)
  • Power Engineering (AREA)
  • Computer Hardware Design (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Mram Or Spin Memory Techniques (AREA)
  • Semiconductor Memories (AREA)
  • Hall/Mr Elements (AREA)

Abstract

A scalable magnetoresistive tunneling junction memory cell (5) comprising a fixed ferromagnetic region (55) having a magnetic moment vector fixed in a preferred direction in the absence of an applied magnetic field, an electrically insulating material (70) positioned on the fixed ferromagnetic region to form a magnetoresistive tunneling junction, and a free ferromagnetic region (135) having a magnetic moment vector oriented in a position parallel or anti-parallel to that of the fixed ferromagnetic region. The free ferromagnetic region includes N ferromagnetic layers (80,100) that are anti-ferromagnetically coupled, where N is an integer greater than or equal to two. The number N of ferromagnetic layers can be adjusted to increase the effective magnetic switching volume of the MRAM device.

Description

Magnetoresistance Random Access Memory for Improved Scalability
FIELD OF THE INVENTION
This invention relates to semiconductor memory devices .
More particularly, the present invention relates to semiconductor random access memory devices that utilize a magnetic field.
BACKGROUND OF THE INVENTION
Memory devices are an extremely important component in electronic systems. The three most important commercial high-density memory technologies are SRAM, DRAM, and FLASH. Each of these memory devices uses an electronic charge to store information and each has its own advantages. SRAM has fast read and write speeds, but it is volatile and requires large cell area. DRAM has high density, but it is also volatile and requires a refresh of the storage capacitor every few milliseconds . This requirement increases the complexity of the control electronics . FLASH is the major nonvolatile memory device in use today. Typical non-volatile memory devices use charges trapped in a floating oxide layer to store information.
Drawbacks to FLASH include high voltage requirements and slow program and erase times. Also, FLASH memory has a poor write endurance of 104-106 cycles before memory failure. In addition, to maintain reasonable data retention, the thickness of the gate oxide has to stay above the threshold that allows electron tunneling, thus restricting FLASH'S scaling trends.
To overcome these shortcomings, new magnetic memory devices are being evaluated. One such device is magnetoresistive RAM (hereinafter referred to as "MRAM"). MRAM has the potential to have speed performance similar to DRAM. To be commercially viable, however, MRAM must have comparable memory density to current memory technologies, be scalable for future generations, operate at low voltages, have low power consumption, and have competitive read/write speeds.
For an MRAM device, the stability of the memory state, the repeatability of the read/write cycles, and the memory element-to-element switching field uniformity are three of the most important aspects of its design characteristics. A memory state in MRAM is not maintained by power, but rather by the direction of the magnetic moment vector. Storing data is accomplished by applying magnetic fields and causing a magnetic material in a cell to be magnetized into either of two possible memory states. Recalling data is accomplished by sensing the electrical resistance, which differs for the two states . The magnetic fields for programming are created by passing currents through conductive lines external to the magnetic structure or through the magnetic structures themselves .
Conventional MRAM devices rely on the bit shape with aspect ratio to create a shape anisotropy that provides the switching field. As the bit dimension shrinks, three problems occur. First, the switching field increases for a given shape and film thickness, requiring more current to switch. Second, the total switching volume is reduced so that the energy barrier for reversal, which is proportional to volume and switching field, is also reduced. The energy barrier refers to the amount of energy needed to switch the magnetic moment vector from one state to the other. The energy barrier determines the data retention and error rate of the MRAM device and unintended reversals can occur due to thermal fluctuations if the barrier is too small. Finally, because the switching field is produced by shape, the switching field becomes more sensitive to shape variations as the bit shrinks in size. With photolithography scaling becoming more difficult at smaller dimensions, MRAM devices will have difficulty maintaining tight switching distributions.
It would be highly advantageous, therefore, to remedy the foregoing and other deficiencies inherent in the prior art .
Accordingly, it is an object of the present invention to provide a new and improved magnetoresistive random access memory device.
It is an object of the present invention to provide a new and improved magnetoresistive random access memory device which can be scaled while keeping the switching field nearly constant.
It is another object of the present invention to provide a new and improved magnetoresistive random access memory device which has a controllable magnetic switching volume .
It is a further object of the present invention to provide a new and improved magnetoresistive random access memory device which has a controllable energy barrier to minimize the bit error rate of the device. It is an object of the present invention to provide a new and improved magnetoresistive random access memory device which can be fabricated using conventional photolithography processing.
It is another object of the present invention to provide a new and improved magnetoresistive random access memory device which has a switching field that is less dependant on shape.
SUMMARY OF THE INVENTION
To achieve the objects and advantages specified above and others, a scalable magnetoresistive tunneling junction memory (hereinafter referred to as "MRAM") device is disclosed. The MRAM device includes a substrate onto which a fixed magnetic region is positioned. An electrically insulating material of sufficient thickness to act as a electron tunneling barrier is then positioned on the fixed magnetic region and a free magnetic region is positioned on the electrically insulating material . The fixed magnetic region adjacent to the tunneling barrier has a resultant magnetic moment vector that is fixed in a preferred direction. In the preferred embodiment, the free magnetic region includes a synthetic anti-ferromagnetic (hereinafter referred to as "SAF") layer material. The synthetic anti-ferromagnetic layer material includes N anti-ferromagnetically coupled layers of a ferromagnetic material where N is an integer greater than or equal to two. Further, the N layers define a magnetic switching volume that can be adjusted by changing N. In the preferred embodiment, the N ferromagnetic layers are anti-ferromagnetically coupled by sandwiching an anti- ferromagnetic coupling spacer layer between each adjacent ferromagnetic layer.
In the preferred embodiment, the total net magnetic moment vector is comprised of the vector sum of the each N sub-layer magnetic moment vectors. Because each sublayer is anti-ferromagnetically coupled to its neighboring layer, there are two antiparallel directions the sub-layer moments can point in zero magnetic field. The total moment is therefore determined by the difference of M1 and M2, where M1 and M2 are the total sublayer moments in each direction, respectively. The magnetic moment vectors are usually oriented anti- parallel by the coupling of the anti-ferromagnetic coupling spacer layer. Anti-ferromagnetic coupling is also generated by the magnetostatic fields of the layers in the MRAM structure. Therefore, the spacer layer need not necessarily provide any additional antiferromagnetic coupling beyond eliminating the ferromagnetic coupling between the two magnetic layers .
The magnetic moment vectors in the ferromagnetic layers can have different magnitudes to provide a
resultant magnetic moment vector given by ΔM = (N2-Nι ) and a sub-layer magnetic moment fractional balance ratio,
(M2 - M.) ΔM .
Mb — = , where Mtotal - M1 + M2 is the total
(M2 + M ) Mlolαl
moment of the N layers . The resultant magnetic moment vector of the Ν-layer structure is free to rotate with an applied magnetic field. In zero field the resultant magnetic moment vector will be stable in a direction, determined by the magnetic anisotropy, which is either parallel or anti-parallel with respect to the resultant magnetic moment vector of the fixed magnetic region.
The current through the MRAM device depends on the tunneling magnetoresistance, which is governed by the relative orientation of the magnetic moment vectors of the free and fixed magnetic regions directly adjacent to the tunneling barrier. If the magnetic moment vectors are parallel, then the MRAM device resistance is low and a voltage bias will induce a larger current through the device. This state is defined as a "1". If the magnetic moment vectors are anti-parallel, then the MRAM device resistance is high and an applied voltage bias will induce a smaller current through the device. This state is defined as a "0". It will be understood that these definitions are arbitrary and could be reversed, but are used in this example for illustrative purposes. Thus, in magnetoresistive memory, data storage is accomplished by applying magnetic fields that cause the magnetic moment vectors in the MRAM device to be orientated either one of parallel and anti-parallel directions relative to the magnetic moment vector in the fixed reference layer.
The number N of ferromagnetic layers can be adjusted to increase the magnetic switching volume of the free magnetic region. By increasing the magnetic switching volume, the energy barrier required to inadvertently reverse the magnetic moment vectors is increased. The effect of the increased energy barrier is to decrease the data retention error rate due to inadvertent reversals caused by thermal fluctuations. Consequently, the stability of the memory state is increased. The addition of ferromagnetic layers can be such that there is no change in the sub-layer magnetic moment balance ratio M^r and the switching field remains constant for a circular bit shape. Hence, the total energy barrier is increased since each anti-ferromagnetically coupled ferromagnetic layer must overcome its intrinsic anisotropy to reverse, thereby increasing the magnetic switching volume without increasing the required switching current. Therefore, the MRAM device can be scaled to smaller lateral dimensions and the magnetic switching volume can be kept constant or adjusted to a desired value by adding more anti-ferromagnetically coupled ferromagnetic layers while maintaining a constant sub-layer moment balance ratio.
In the preferred embodiment, the MRAM device is circular in shape so that there is no contribution to the switching field from shape anisotropy. In this configuration, a parameter that predominantly sets a switching field is the material's induced magnetic anisotropy, Hk. For typical materials such as NiFeCo, Hk is only about 20 Oe, which is undesirable for MRAM device operation. If a SAF N-layer structure is included in the free region, then the anisotropy and switching field, Hsw, is amplified depending on the sub-layer magnetic moment fractional balance ratio M^r such that:
H = (Λf2+Λf,) H = H^_ sw (Λf2-M.) k Mhr '
where M% , M are the total sub-layer magnetic moments in each direction of the N-layer structure, respectively. The increase in the switching field is a result of the smaller resultant magnetic moment vector becoming a smaller handle for the external magnetic field to rotate all of the spins in the N ferromagnetic layers. Hence, the closer in magnitude that the opposing magnetic moments are to each other, the higher the effective switching field. Thus, the switching field can be adjusted to a reasonable value through the control of the induced Hk and the sub-layer magnetic moment balance ratio
Mbr. The shape sensitivity is decreased since the circular shape is not the main source of the switching field. Also, the diminished resultant magnetic moment vector further reduces the effect of shape variations since the effective magnetic charges at the shape edges are much smaller than for a single layer film of comparable thickness.
BRIEF DESCRIPTION OF THE DRAWINGS
The foregoing and further and more specific objects and advantages of the instant invention will become readily apparent to those skilled in the art from the following detailed description of a preferred embodiment thereof taken in conjunction with the following drawings
FIG. 1 is a sectional view of a magnetoresistive random access memory device with improved scalability; and FIG. 2 is a graph illustrating the coercivity of a bulk free layer film verses the thickness of one ferromagnetic layer in a N-layer structure with the other layer held at a constant thickness of 40 A.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
Turn now to FIG. 1, which illustrates a simplified sectional view of a scalable magnetoresistive tunneling junction memory cell 5 in accordance with the present invention. The scalable magnetoresistive tunneling junction memory cell 5 includes a supporting substrate 10 onto which a seed layer 20 is positioned. Supporting substrate 10 may be, for example, a semiconductor substrate or wafer and semiconductor control devices may then be formed thereon. Seed layer 20 is formed on supporting substrate 10 to aid in the formation and operation of the remaining layers of material. An anti- ferromagnetic layer 30 is then positioned on seed layer 20 and includes, for example Ni, Fe, Mn, Co or combinations thereof. It will be understood that seed layer 20 is optional and is included in this preferred embodiment for illustrative purposes. Also, the positioning of anti-ferromagnetic layer 30 is for fabrication convenience with many other possible configurations available.
A first magnetic region 55 having a resultant magnetic moment vector 57 is positioned on the anti- ferromagnetic layer 30. An electrically insulating layer 70 is placed on first magnetic region 55 and a second magnetic region 135 having a resultant magnetic moment vector 87 is positioned on electrically insulating layer 70. Electrically insulating layer 70 behaves as a tunneling barrier junction. It will be understood that electrically insulating layer 70 can include multiple insulating layers, but is shown as one layer for illustrative purposes.
Anti-ferromagnetic layer 30 pins resultant magnetic moment vector 57 unidirectionally along a preferred magnetic axis unless sufficient magnetic field is supplied to overcome the pinning action of layer 30. Generally, anti-ferromagnetic layer 30 is thick enough to insure that spurious signals and normal cell writing signals will not switch resultant magnetic moment vector 57.
In the preferred embodiment, fixed magnetic region
55 includes a synthetic anti-ferromagnetic layer material which includes a tri-layer structure of an anti- ferromagnetic coupling spacer layer 50 sandwiched between a ferromagnetic layer 60 and a ferromagnetic layer 40. However, it will be understood that magnetic region 55 can include a synthetic anti-ferromagnetic layer material other than a tri-layer structure and the use of a tri- layer structure in this embodiment is for illustrative purposes only. Further, magnetic region 55 is a fixed ferromagnetic region, meaning that resultant magnetic moment vector 57 is not free to rotate in the presence of a moderate applied magnetic field and is used as the reference layer.
A free magnetic region 135 includes a synthetic anti-ferromagnetic layer material which includes N ferromagnetic layers that are anti-ferromagnetically coupled, wherein N is a integer number greater than or equal to two . In the embodiment shown here for simplicity, N is chosen to be equal to two so that magnetic region includes a tri-layer structure which has an anti-ferromagnetic coupling spacer layer 90 sandwiched between a ferromagnetic layer 80 and a ferromagnetic layer 100. Ferromagnetic layers 80 and 100 each have thicknesses 81 and 101, respectively. Further, anti- ferromagnetic coupling spacer layer 90 has a thickness 86. It will be understood that the synthetic anti- ferromagnetic layer material in magnetic region 135 can include other structures with a different number of ferromagnetic layers and the use of a tri-layer structure in this embodiment is for illustrative purposes only.
For example, a five-layer stack of a ferromagnetic layer/ anti-ferromagnetic coupling spacer layer/ ferromagnetic layer /anti-ferromagnetic coupling spacer layer/ ferromagnetic layer could be used, wherein N is equal to three .
Generally, anti-ferromagnetic coupling spacer layers 50 and 90 include elements Ru, Os, Re, Cr, Rh, and Cu, or combinations thereof. Further, ferromagnetic layers 40, 60, 80, and 100 generally include alloys of Ni, Fe, Mn, Co, or combinations thereof. Ferromagnetic layers 80 and 100 each have a magnetic moment vector 85 and 105, respectively, that are usually held anti-parallel by coupling of anti-ferromagnetic coupling spacer layer 90. Also, magnetic region 135 has a resultant magnetic moment vector 87. Resultant magnetic moment vectors 57 and 87 are oriented along an anisotropy easy-axis in a preferred direction. Further, magnetic region 135 is a free ferromagnetic region, meaning that resultant magnetic moment vector 87 is free to rotate in the presence of an applied magnetic field.
While anti-ferromagnetic coupling layers are illustrated between the ferromagnetic layers in magnetic regions 55 and 135, it will be understood that the ferromagnetic layers could be anti-ferromagnetically coupled through other means such as magnetostatic fields or other features. For example, when the aspect ratio of a cell is reduced to five or less, the ferromagnetic layers are anti-parallel coupled from magnetostatic flux closure. In this case, any nonmagnetic spacer layer that breaks the ferromagnetic exchange between layers will suffice. However, in the preferred embodiment, the adjacent ferromagnetic layers are anti-ferromagnetically coupled by sandwiching anti-ferromagnetic coupling material between each adjacent ferromagnetic layer. One advantage of using a synthetic anti-ferromagnetic layer material is that the anti-parallel coupling of the magnetic moment vectors prevents a vortex from forming at a given thickness where a vortex would be formed if using a single layer.
Further, during fabrication of scalable magnetoresistive tunneling junction memory cell 5, each succeeding layer (i.e. 20, 30, 40, etc.) is deposited or otherwise formed in sequence and each cell may be defined by selective deposition, photolithography processing, etching, etc. in any of the techniques known in the semiconductor industry. During deposition of at least the ferromagnetic layers 80 and 100, a magnetic field is provided to set an easy magnetic axis for these layers (induced anisotropy) . This anisotropy axis can also be set subsequent to deposition by annealing in the presence of a magnetic field.
The number N of ferromagnetic layers in free region 135 can be adjusted such that the magnetic switching volume of free region 135 remains substantially constant or increases as the device is scaled laterally to smaller dimensions. Thus, the magnetic switching volume of MRAM device 5 can be controlled and, consequently, the bit error rate can be minimized. Thicknesses 81 and 101 and/or the materials of the layers are chosen so that a magnetic field needed to switch magnetic moments 85 and 105 remains substantially constant (the term "substantially constant" is intended to include moderate increases) as the device is scaled laterally. Because the N ferromagnetic layers can be chosen such that there is no change in the magnetic moment balance ratio Mbr, the switching field Hsw remains constant for a circular plan. The total energy barrier for magnetic moment vector reversal increases since each individual ferromagnetic layer must overcome its induced anisotropy to reverse, thereby increasing the effective volume without increasing Hsw. For a bit shape with aspect ratio greater than one, the volume can be increased while minimizing the increase in switching field by appropriate choice of moment balance in the adjacent ferromagnetic layers. In an alternate embodiment, magnetoresistive tunneling junction memory cell 5 has magnetic regions 55 and 135 that each have a length/width ratio in a range of
1 to 5 for a non-circular plan. When the aspect ratio of free and fixed regions 135 and 55 is less than five, magnetic moment vectors 85 and 105 in magnetic region 135 have a strong tendency to align anti-parallel solely from magnetostatic fringing fields. This magnetostatic coupling therefore allows the replacement of the anti- ferromagnetic coupling layer with a spacer layer that does not allow interlayer exchange. In the preferred embodiment, MRAM device 5 is circular in shape (generally in a cross-section parallel to substrate 10) so that there is no contribution to the switching field from shape anisotropy and also because it is easier to use photolithography processing to scale the device to smaller dimensions laterally. However, it will be understood that MRAM device 5 can have other shapes, such as square, rectangular, elliptical, or diamond but is illustrated as being circular for simplicity.
In a circular plan, a parameter that predominantly sets the switching field is the material's induced magnetic anisotropy, Hk . For typical materials such as NiFeCo, Hk is only about 20 Oe, which is undesirable for MRAM device operation. If a N-layer structure is included in the free magnetic region, then the effective anisotropy and switching field, Hsw, is amplified depending on the sub-layer magnetic moment balance ratio of the individual sub-layer moments such that:
_( 85+ 105) (Mg5 -M]05)
where M8s, M105 are the magnitude of the magnetic moment vectors in ferromagnetic layers 80 and 100, respectively.
Turn now to FIG. 2 in which a graph illustrates the effective switching field, Hsw, of a tri-layer structure verses thickness 101 of ferromagnetic layer 100. The graph of the data in FIG. 2 was generated from a bulk, unpatterned material film, and as such it is representative of the trend in Hsw of circular bit patterns. Hence, FIG. 2 provides direct evidence of the amplification effect of an unbalanced synthetic anti- ferromagnetic structure.
In this particular example, thickness 86 of anti- ferromagnetic coupling spacer layer 90 is chosen to be 7 A and thickness 81 of ferromagnetic layer 80 is chosen to be 40 A. Also, in this example, anti-ferromagnetic spacer layer 90 includes Ru and ferromagnetic layers 80 and 100 include NiFeCo . As thickness 101 of ferromagnetic layer 100 is varied from approximately 30 A to 75 A, Hsw varies dramatically in the range of approximately 35 A to 45 A. For optimal MRAM device operation, Hsw should be approximately in the range between 50 Oe and 150 Oe . Hsw can be set in this range by varying thickness 101 as illustrated. If thickness 101 is set at 40 A, then Hsw will be approximately 225
Oersteds, which is probably too high. If thickness 101 is set at around 43 A, then Hsw will be approximately 75
Oersteds, which is a more ideal value. The important point is that by adjusting the thicknesses, 81, 86, and 101, Hsw can be adjusted to a desired value.
Thus, the scalable magnetoresistive memory device has a magnetic switching volume that can be controlled by varying N. By adjusting N, the magnetic switching volume can be increased as the MRAM device is scaled laterally to smaller dimensions. Consequently, the bit error rate due to thermal fluctuations is reduced. Also, Hsw can be controlled by varying the thicknesses and/or materials of the ferromagnetic layers. By controlling Hsw, the switching field can be adjusted to a desired value sufficient for MRAM device operation as the device is scaled laterally to smaller dimensions.
Various changes and modifications to the embodiments herein chosen for purposes of illustration will readily occur to those skilled in the art. To the extent that such modifications and variations do not depart from the spirit of the invention, they are intended to be included within the scope thereof which is assessed only by a fair interpretation of the following claims.
Having fully described the invention in such clear and concise terms as to enable those skilled in the art to understand and practice the same, the invention claimed is:

Claims

1. A scalable magnetoresistive tunneling junction memory cell comprising: an electrically insulating material designed to form a magnetoresistive tunneling barrier; a first magnetic region positioned on one side of the electrically insulating material, the first magnetic region having a magnetic moment vector adjacent the electrically insulating material; a second magnetic region positioned on an opposite side of the electrically insulating material, the second magnetic region having a magnetic moment vector adjacent the insulating material and oriented in a position parallel or anti-parallel to the magnetic moment vector of the first magnetic region, the electrically insulating material and the first and second magnetic regions forming a magnetoresistive tunneling junction device, and at least one of the first and second magnetic regions including a synthetic anti-ferromagnetic layer material that has a magnetic switching volume, the synthetic anti-ferromagnetic layer material includes N ferromagnetic layers which are anti-ferromagnetically coupled, where N is an integer greater than or equal to two, and the magnetic switching volume is adjustable by changing N to maintain a sufficient energy barrier to switching for nonvolatile memory operation as the magnetoresistive memory element is scaled laterally to smaller dimensions.
2. A scalable magnetoresistive tunneling junction memory cell as claimed in claim 1 wherein the magnetic switching volume is adjusted by increasing N such that the volume remains substantially constant or increases as the magnetoresistive memory element is scaled laterally to smaller dimensions.
3. A scalable magnetoresistive tunneling junction memory cell as claimed in claim 1 wherein a sub-layer magnetic moment fractional balance ratio of the one of the first and second magnetic regions remains constant as the magnetoresistive memory element is scaled laterally to smaller dimensions.
4. A scalable magnetoresistive tunneling junction memory cell comprising: an electrically insulating material designed to form a magnetoresistive tunneling barrier; a first magnetic region positioned on one side of the electrically insulating material, the first magnetic region having a magnetic moment vector adjacent the electrically insulating material; a second magnetic region positioned on an opposite side of the electrically insulating material, the second magnetic region having a magnetic moment vector adjacent the insulating material and oriented in a position parallel or anti-parallel to the magnetic moment vector of the first magnetic region, the electrically insulating material and the first and second magnetic regions forming a magnetoresistive tunneling junction device, and at least one of the first and second magnetic regions including N ferromagnetic layers which are anti- ferromagnetically coupled, where N is an integer number greater than or equal to two, and has a sub-layer magnetic moment fractional balance ratio and the switching field of at least the one of the first and second magnetic regions is adjusted by changing the sub-layer magnetic moment fractional balance ratio such that the magnetoresistive memory element is scalable laterally to smaller dimensions.
5. A scalable magnetoresistive tunneling junction memory cell comprising: a first magnetic region having a resultant magnetic moment vector fixed in a preferred direction in the absence of an applied magnetic field; an electrically insulating material positioned on the first magnetic region to form a magnetoresistive tunneling barrier; and a second magnetic region positioned on the insulating material and having a resultant magnetic moment vector switchable between positions parallel and anti- parallel to the resultant magnetic moment vector of the first magnetic region, the electrically insulating material and the first and second magnetic regions forming a magnetoresistive tunneling junction device, and at least one of the first and second magnetic regions include N ferromagnetic layers which are anti- ferromagnetically coupled, where N is an integer greater than or equal to two, and the at least one of the first and second magnetic regions including a sub-layer magnetic moment fractional balance ratio designed to set a switching field.
6. A scalable magnetoresistive tunneling junction memory cell as claimed in claim 5 wherein the N ferromagnetic layers are anti-ferromagnetically coupled by sandwiching a layer of anti-ferromagnetic coupling material between each adjacent pair of ferromagnetic layers.
7. A scalable magnetoresistive tunneling junction memory cell as claimed in claim 5 wherein at least one of the first and second magnetic regions has a magnetic switching volume that remains substantially constant or increases as the device is scaled laterally to smaller dimensions.
8. A scalable magnetoresistive tunneling junction memory cell comprising: a substrate; an anti-ferromagnetic material supported on the substrate; a fixed magnetic region positioned on the anti- ferromagnetic material which includes a synthetic anti- ferromagnetic layer material, having a resultant magnetic moment vector which is fixed in a preferred direction in the absence of an applied magnetic field; an electrically insulating layer positioned on the fixed magnetic region; and a free magnetic region positioned on the electrically insulating layer to form a magnetoresistive tunneling junction device in cooperation with the electrically insulating layer and the fixed magnetic region, the free magnetic region including a synthetic anti-ferromagnetic layer material that includes N layers of a ferromagnetic material, where N is an integer number greater than or equal to two, and wherein each layer of the N layers of the ferromagnetic material has a magnetic moment vector where the magnetic moment vectors of each adjacent layer of the N layers of the ferromagnetic material are oriented anti- parallel such that they are anti-ferromagnetically coupled, and a magnetic switching volume of the free magnetic region that is scalable by increasing N such that the volume remains substantially constant or increases to maintain a sufficient energy barrier to switching for nonvolatile memory operation and a moment fractional balance ratio of the free magnetic region that remains substantially constant as the scalable magnetoresistive memory element is scaled laterally to smaller dimensions.
9. A method of fabricating a scalable magnetoresistive tunneling junction memory cell comprising the steps of: providing a substrate defining a surface; supporting a fixed magnetic region having a magnetic switching volume and also having a resultant magnetic moment vector on the substrate, wherein the resultant magnetic moment vector is oriented in a preferred direction; positioning an electrically insulating tunneling junction layer on the fixed magnetic region; positioning a free magnetic region having a resultant magnetic moment vector and a magnetic switching volume on the .electrically insulating tunneling junction layer, wherein the resultant magnetic moment vector can be oriented one of parallel and anti-parallel with respect to the resultant magnetic moment vector of the fixed magnetic region, the free magnetic region includes a synthetic anti- ferromagnetic layer material which includes N ferromagnetic layers that are anti-ferromagnetically coupled, where N is an integer number greater than two and where each N ferromagnetic layer has a magnetic moment vector and the magnetic moment vectors of each adjacent N layer of ferromagnetic material are oriented anti-parallel; and adjusting the number of N ferromagnetic layers and their magnetic moment to optimize the magnetic switching volume as the lateral dimensions of the device are changed and a sub-layer magnetic moment fractional balance ratio of the free magnetic region is chosen to provide a magnetic switching field so that as the device is scaled laterally to different dimensions, a sufficient energy barrier to switching is maintained for nonvolatile memory operation.
PCT/US2002/031946 2001-10-16 2002-09-24 Magnetoresistance random access memory for improved scalability Ceased WO2003043018A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP02773722A EP1449219A1 (en) 2001-10-16 2002-09-24 Magnetoresistance random access memory with adjustable scalability
KR1020047006283A KR100924443B1 (en) 2001-10-16 2002-09-24 Magnetoresistive random access memory with improved scaling
JP2003544760A JP2005510048A (en) 2001-10-16 2002-09-24 Magnetoresistive random access memory with improved shrinkability

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/978,860 2001-10-16
US09/978,860 US6531723B1 (en) 2001-10-16 2001-10-16 Magnetoresistance random access memory for improved scalability

Publications (1)

Publication Number Publication Date
WO2003043018A1 true WO2003043018A1 (en) 2003-05-22

Family

ID=25526460

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/031946 Ceased WO2003043018A1 (en) 2001-10-16 2002-09-24 Magnetoresistance random access memory for improved scalability

Country Status (7)

Country Link
US (1) US6531723B1 (en)
EP (1) EP1449219A1 (en)
JP (1) JP2005510048A (en)
KR (1) KR100924443B1 (en)
CN (1) CN100476997C (en)
TW (1) TW574687B (en)
WO (1) WO2003043018A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005129801A (en) * 2003-10-24 2005-05-19 Sony Corp Magnetic storage element and magnetic memory
WO2005086170A1 (en) * 2004-03-05 2005-09-15 Nec Corporation Toggle type magnetic random access memory
CN1637927B (en) * 2003-10-24 2010-05-12 三星电子株式会社 Magnetic random access memory and manufacturing method thereof

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6979586B2 (en) * 2000-10-06 2005-12-27 Headway Technologies, Inc. Magnetic random access memory array with coupled soft adjacent magnetic layer
US6545906B1 (en) * 2001-10-16 2003-04-08 Motorola, Inc. Method of writing to scalable magnetoresistance random access memory element
US7390584B2 (en) * 2002-03-27 2008-06-24 Nve Corporation Spin dependent tunneling devices having reduced topological coupling
US6826077B2 (en) * 2002-05-15 2004-11-30 Hewlett-Packard Development Company, L.P. Magnetic random access memory with reduced parasitic currents
US7095646B2 (en) * 2002-07-17 2006-08-22 Freescale Semiconductor, Inc. Multi-state magnetoresistance random access cell with improved memory storage density
US6714446B1 (en) * 2003-05-13 2004-03-30 Motorola, Inc. Magnetoelectronics information device having a compound magnetic free layer
US8471263B2 (en) * 2003-06-24 2013-06-25 Sang-Yun Lee Information storage system which includes a bonded semiconductor structure
US6956763B2 (en) * 2003-06-27 2005-10-18 Freescale Semiconductor, Inc. MRAM element and methods for writing the MRAM element
US6967366B2 (en) * 2003-08-25 2005-11-22 Freescale Semiconductor, Inc. Magnetoresistive random access memory with reduced switching field variation
US6842365B1 (en) 2003-09-05 2005-01-11 Freescale Semiconductor, Inc. Write driver for a magnetoresistive memory
US6987691B2 (en) * 2003-12-02 2006-01-17 International Business Machines Corporation Easy axis magnetic amplifier
US7088608B2 (en) * 2003-12-16 2006-08-08 Freescale Semiconductor, Inc. Reducing power consumption during MRAM writes using multiple current levels
DE102005004126B4 (en) * 2004-02-06 2008-05-08 Qimonda Ag MRAM memory cell with weak intrinsically anisotropic memory layer
US7436700B2 (en) * 2004-02-06 2008-10-14 Infineon Technologies Ag MRAM memory cell having a weak intrinsic anisotropic storage layer and method of producing the same
KR100541558B1 (en) * 2004-04-19 2006-01-11 삼성전자주식회사 Magnetic tunnel junction structures with tips bent at both ends, magnetic ram cells employing them and photomasks used to form them
US7129098B2 (en) * 2004-11-24 2006-10-31 Freescale Semiconductor, Inc. Reduced power magnetoresistive random access memory elements
US7088611B2 (en) * 2004-11-30 2006-08-08 Infineon Technologies Ag MRAM with switchable ferromagnetic offset layer
US7200033B2 (en) * 2004-11-30 2007-04-03 Altis Semiconductor MRAM with coil for creating offset field
CN100438115C (en) * 2004-12-02 2008-11-26 北京科技大学 Magnetic tunnel junction having high magnetoresistance effect and method for making same
US20060171197A1 (en) * 2005-01-31 2006-08-03 Ulrich Klostermann Magnetoresistive memory element having a stacked structure
US7154771B2 (en) * 2005-02-09 2006-12-26 Infineon Technologies Ag Method of switching an MRAM cell comprising bidirectional current generation
US7099186B1 (en) * 2005-02-10 2006-08-29 Infineon Technologies Ag Double-decker MRAM cells with scissor-state angled reference layer magnetic anisotropy and method for fabricating
US7180113B2 (en) * 2005-02-10 2007-02-20 Infineon Technologies Ag Double-decker MRAM cell with rotated reference layer magnetizations
US7298597B2 (en) * 2005-03-29 2007-11-20 Hitachi Global Storage Technologies Netherlands B.V. Magnetoresistive sensor based on spin accumulation effect with free layer stabilized by in-stack orthogonal magnetic coupling
US7205596B2 (en) * 2005-04-29 2007-04-17 Infineon Technologies, Ag Adiabatic rotational switching memory element including a ferromagnetic decoupling layer
JP2006332527A (en) * 2005-05-30 2006-12-07 Renesas Technology Corp Magnetic storage element
US7313043B2 (en) * 2005-11-29 2007-12-25 Altis Semiconductor Snc Magnetic Memory Array
US7280389B2 (en) * 2006-02-08 2007-10-09 Magic Technologies, Inc. Synthetic anti-ferromagnetic structure with non-magnetic spacer for MRAM applications
US20080055792A1 (en) * 2006-03-07 2008-03-06 Agency For Science, Technology And Research Memory cells and devices having magnetoresistive tunnel junction with guided magnetic moment switching and method
JP5003109B2 (en) * 2006-11-14 2012-08-15 富士通株式会社 Ferromagnetic tunnel junction device, manufacturing method thereof, magnetic head using the same, and magnetic memory
US7539047B2 (en) * 2007-05-08 2009-05-26 Honeywell International, Inc. MRAM cell with multiple storage elements
US20090034321A1 (en) 2007-08-01 2009-02-05 Honeywell International Inc. Magnetoresistive Element with a Biasing Layer
KR101446334B1 (en) 2008-05-07 2014-10-01 삼성전자주식회사 Magnetic resistance element
US7880209B2 (en) * 2008-10-09 2011-02-01 Seagate Technology Llc MRAM cells including coupled free ferromagnetic layers for stabilization
GB2465370A (en) * 2008-11-13 2010-05-19 Ingenia Holdings Magnetic data storage comprising a synthetic anti-ferromagnetic stack arranged to maintain solitons
GB201015497D0 (en) 2010-09-16 2010-10-27 Cambridge Entpr Ltd Magnetic data storage
GB201020727D0 (en) 2010-12-07 2011-01-19 Cambridge Entpr Ltd Magnetic structure
CN102074266A (en) * 2010-12-17 2011-05-25 电子科技大学 Spin valve storage cell for stabilizing residual magnetism state
US8339843B2 (en) 2010-12-17 2012-12-25 Honeywell International Inc. Generating a temperature-compensated write current for a magnetic memory cell
US9281168B2 (en) * 2014-06-06 2016-03-08 Everspin Technologies, Inc. Reducing switching variation in magnetoresistive devices
WO2016198886A1 (en) 2015-06-10 2016-12-15 The University Of Nottingham Magnetic storage devices and methods
CN110235201A (en) * 2016-12-27 2019-09-13 艾沃思宾技术公司 Including the data storage in the synthetic anti-ferromagnet in magnetic tunnel-junction
EP4362650B1 (en) * 2022-10-31 2025-08-06 Commissariat à l'Energie Atomique et aux Energies Alternatives Magnetic tunnel junction, array of magnetic tunnel junctions, and associated fabrication method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000090418A (en) * 1998-09-16 2000-03-31 Toshiba Corp Magnetoresistive element and magnetic recording device
DE19830343C1 (en) * 1998-07-07 2000-04-06 Siemens Ag Artificial antiferromagnetic layer manufacturing method for MR sensor, involves affecting symmetry of antiferromagnetic layer partially by mask to adjust orientation of magnetization of bias layer
EP1109168A2 (en) * 1999-12-17 2001-06-20 Motorola, Inc. Magnetic dual element with dual magnetic states and fabricating method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19836567C2 (en) * 1998-08-12 2000-12-07 Siemens Ag Memory cell arrangement with memory elements with a magnetoresistive effect and method for their production
DE19840823C1 (en) * 1998-09-07 2000-07-13 Siemens Ag Magnetoresistive element and its use as a memory element in a memory cell arrangement
US6205052B1 (en) * 1999-10-21 2001-03-20 Motorola, Inc. Magnetic element with improved field response and fabricating method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19830343C1 (en) * 1998-07-07 2000-04-06 Siemens Ag Artificial antiferromagnetic layer manufacturing method for MR sensor, involves affecting symmetry of antiferromagnetic layer partially by mask to adjust orientation of magnetization of bias layer
JP2000090418A (en) * 1998-09-16 2000-03-31 Toshiba Corp Magnetoresistive element and magnetic recording device
EP1109168A2 (en) * 1999-12-17 2001-06-20 Motorola, Inc. Magnetic dual element with dual magnetic states and fabricating method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE INSPEC [online] INSTITUTE OF ELECTRICAL ENGINEERS, STEVENAGE, GB; UHM Y R ET AL: "Computer simulation of switching characteristics in magnetic tunnel junctions exchange-biased by synthetic antiferromagnets", XP002226080, Database accession no. 7286478 *
INTERNATIONAL SYMPOSIUM ON PHYSICS OF MAGNETIC MATERIALS/ INTERNATIONAL SYMPOSIUM ON ADVANCED MAGNETIC TECHNOLOGIES (ISPMM/ISAMT2001), TAIPEI, TAIWAN, 13-16 MAY 2001, vol. 239, no. 1-3, Journal of Magnetism and Magnetic Materials, Feb. 2002, Elsevier, Netherlands, pages 123 - 125, ISSN: 0304-8853 *
PATENT ABSTRACTS OF JAPAN vol. 2000, no. 06 22 September 2000 (2000-09-22) *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005129801A (en) * 2003-10-24 2005-05-19 Sony Corp Magnetic storage element and magnetic memory
CN1637927B (en) * 2003-10-24 2010-05-12 三星电子株式会社 Magnetic random access memory and manufacturing method thereof
WO2005086170A1 (en) * 2004-03-05 2005-09-15 Nec Corporation Toggle type magnetic random access memory
US7440314B2 (en) 2004-03-05 2008-10-21 Nec Corporation Toggle-type magnetoresistive random access memory

Also Published As

Publication number Publication date
US6531723B1 (en) 2003-03-11
EP1449219A1 (en) 2004-08-25
KR20040058245A (en) 2004-07-03
CN100476997C (en) 2009-04-08
TW574687B (en) 2004-02-01
KR100924443B1 (en) 2009-11-02
JP2005510048A (en) 2005-04-14
CN1589478A (en) 2005-03-02

Similar Documents

Publication Publication Date Title
US6531723B1 (en) Magnetoresistance random access memory for improved scalability
US6545906B1 (en) Method of writing to scalable magnetoresistance random access memory element
US10707410B2 (en) Magnetoresistive stacks with an unpinned, fixed synthetic anti-ferromagnetic structure and methods of manufacturing thereof
US5966323A (en) Low switching field magnetoresistive tunneling junction for high density arrays
KR101405854B1 (en) Magnetic stack with spin torque switching having a layer assisting said switching
US6633498B1 (en) Magnetoresistive random access memory with reduced switching field
US7235408B2 (en) Synthetic antiferromagnetic structure for magnetoelectronic devices
US6654278B1 (en) Magnetoresistance random access memory
EP1038299B1 (en) Low switching field magnetic tunneling junction usable for multi-state magnetic memory cell
US6956764B2 (en) Method of writing to a multi-state magnetic random access memory cell
KR102363995B1 (en) Semiconductor device and method for fabricating the same
KR101247255B1 (en) Reduced power magnetoresistive random access memory elements
GB2539102A (en) Voltage-controlled magnetic anisotropy switching device using an external ferromagnetic biasing film
WO2005048262A2 (en) Mram architecture with a flux closed data storage layer
US7622784B2 (en) MRAM device with improved stack structure and offset field for low-power toggle mode writing
US6936903B2 (en) Magnetic memory cell having a soft reference layer
KR20240143574A (en) Magnetic tunneling junction device capable of field-free switching and memory device including the same
HK1075321B (en) A method of switching a magnetoresistive memory device and magnetoresistive array

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SD SE SG SI SK SL TJ TM TN TR TT TZ UA UG UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LU MC NL PT SE SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2003544760

Country of ref document: JP

Ref document number: 1020047006283

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 2002773722

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 20028228065

Country of ref document: CN

WWP Wipo information: published in national office

Ref document number: 2002773722

Country of ref document: EP