WO2003048098A3 - Process for preparing monochloroacetic acid - Google Patents

Process for preparing monochloroacetic acid Download PDF

Info

Publication number
WO2003048098A3
WO2003048098A3 PCT/EP2002/012944 EP0212944W WO03048098A3 WO 2003048098 A3 WO2003048098 A3 WO 2003048098A3 EP 0212944 W EP0212944 W EP 0212944W WO 03048098 A3 WO03048098 A3 WO 03048098A3
Authority
WO
WIPO (PCT)
Prior art keywords
acid
stream
peroxycarboxylic acid
mca
monochloroacetic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2002/012944
Other languages
French (fr)
Other versions
WO2003048098A2 (en
Inventor
Cornelis Kooijman
Jacobus Theodorus Jo Aaldering
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Akzo Nobel NV
Original Assignee
Akzo Nobel NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo Nobel NV filed Critical Akzo Nobel NV
Priority to DE60236617T priority Critical patent/DE60236617D1/en
Priority to AT02804179T priority patent/ATE469876T1/en
Priority to AU2002356676A priority patent/AU2002356676A1/en
Priority to US10/495,367 priority patent/US7030270B2/en
Priority to JP2003549293A priority patent/JP4210600B2/en
Priority to EP02804179A priority patent/EP1451136B1/en
Publication of WO2003048098A2 publication Critical patent/WO2003048098A2/en
Publication of WO2003048098A3 publication Critical patent/WO2003048098A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention relates to a process for preparing monochloroacetic acid (MCA) comprising a chlorination step and a hydrogenation step and is characterized in that said process comprises the removal of aldehydes from a process stream by peroxidation using a peroxycarboxylic acid. A preferred peroxycarboxylic acid comprises peracetic acid. Preferably, the process is carried out at a temperature of 60-100 °C, most preferably at atmospheric pressure. Preferably, an about equimolar amount of peroxycarboxylic acid is used relative to the molar amount of aldehydes present in the process stream. A practical choice for the process stream is the acetic acid recycle stream. The invention process provides a clear and colourless MCA end product.
PCT/EP2002/012944 2001-12-04 2002-11-19 Process for preparing monochloroacetic acid Ceased WO2003048098A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
DE60236617T DE60236617D1 (en) 2001-12-04 2002-11-19 PROCESS FOR THE PREPARATION OF MONOCLOROACTIC ACID
AT02804179T ATE469876T1 (en) 2001-12-04 2002-11-19 METHOD FOR PRODUCING MONOCHLOROACETIC ACID
AU2002356676A AU2002356676A1 (en) 2001-12-04 2002-11-19 Process for preparing monochloroacetic acid
US10/495,367 US7030270B2 (en) 2001-12-04 2002-11-19 Process for preparing monochloroacetic acid
JP2003549293A JP4210600B2 (en) 2001-12-04 2002-11-19 Monochloroacetic acid production method
EP02804179A EP1451136B1 (en) 2001-12-04 2002-11-19 Process for preparing monochloroacetic acid

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP01204651.2 2001-12-04
EP01204651 2001-12-04

Publications (2)

Publication Number Publication Date
WO2003048098A2 WO2003048098A2 (en) 2003-06-12
WO2003048098A3 true WO2003048098A3 (en) 2004-03-04

Family

ID=8181341

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/012944 Ceased WO2003048098A2 (en) 2001-12-04 2002-11-19 Process for preparing monochloroacetic acid

Country Status (9)

Country Link
US (1) US7030270B2 (en)
EP (1) EP1451136B1 (en)
JP (1) JP4210600B2 (en)
CN (1) CN1242974C (en)
AT (1) ATE469876T1 (en)
AU (1) AU2002356676A1 (en)
DE (1) DE60236617D1 (en)
ES (1) ES2345768T3 (en)
WO (1) WO2003048098A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2391331C2 (en) * 2008-08-13 2010-06-10 Общество с ограниченной ответственностью "Синтез-2" Method of obtaining monochloracetic acid
WO2013057125A1 (en) * 2011-10-20 2013-04-25 Akzo Nobel Chemicals International B.V. Process for the purification of a liquid feed comprising mca and dca
DK2748139T3 (en) 2011-10-20 2017-08-07 Akzo Nobel Chemicals Int Bv METHOD FOR HYDRODECHLORINATION OF A LIQUID SUPPLY INCLUDING DICHLORO ACETIC ACID
AR104892A1 (en) * 2015-06-12 2017-08-23 Akzo Nobel Chemicals Int Bv PROCESS FOR HYDRODECLORATION OF A FOOD THAT INCLUDES DICHLOROACETIC ACID
PL243218B1 (en) * 2020-06-28 2023-07-17 Pcc Mcaa Spolka Z Ograniczona Odpowiedzialnoscia Colorless monochloroacetic acid and method of its preparation

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3393235A (en) * 1964-07-22 1968-07-16 Rhone Poulenc Sa Process for the preparation of monochloracetic acid
GB1456057A (en) * 1973-11-16 1976-11-17 Elektrokemiska Ab Method of removing odourous substances from gases
JPH04338357A (en) * 1991-05-16 1992-11-25 Daicel Chem Ind Ltd Method for purifying acetic acid
US5756840A (en) * 1995-12-11 1998-05-26 Hoechst Aktiengesellschaft Process for the preparation of a particularly pure monochloroacetic

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2323777C2 (en) * 1973-05-11 1975-01-16 Farbwerke Hoechst Ag, Vormals Meister Lucius & Bruening, 6000 Frankfurt Process for the continuous purification of crude monochloroacetic acid
JP3766708B2 (en) 1994-12-26 2006-04-19 三菱瓦斯化学株式会社 Method for producing high purity terephthalic acid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3393235A (en) * 1964-07-22 1968-07-16 Rhone Poulenc Sa Process for the preparation of monochloracetic acid
GB1456057A (en) * 1973-11-16 1976-11-17 Elektrokemiska Ab Method of removing odourous substances from gases
JPH04338357A (en) * 1991-05-16 1992-11-25 Daicel Chem Ind Ltd Method for purifying acetic acid
US5756840A (en) * 1995-12-11 1998-05-26 Hoechst Aktiengesellschaft Process for the preparation of a particularly pure monochloroacetic

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 199302, Derwent World Patents Index; Class E13, AN 1993-012163, XP002197250 *

Also Published As

Publication number Publication date
EP1451136B1 (en) 2010-06-02
DE60236617D1 (en) 2010-07-15
JP4210600B2 (en) 2009-01-21
WO2003048098A2 (en) 2003-06-12
ES2345768T3 (en) 2010-10-01
JP2005511678A (en) 2005-04-28
ATE469876T1 (en) 2010-06-15
AU2002356676A1 (en) 2003-06-17
US20050148794A1 (en) 2005-07-07
US7030270B2 (en) 2006-04-18
CN1242974C (en) 2006-02-22
EP1451136A2 (en) 2004-09-01
AU2002356676A8 (en) 2003-06-17
CN1599709A (en) 2005-03-23

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