WO2003078365A3 - Verfahren zur hydroformylierung von olefinen - Google Patents

Verfahren zur hydroformylierung von olefinen Download PDF

Info

Publication number
WO2003078365A3
WO2003078365A3 PCT/EP2003/002383 EP0302383W WO03078365A3 WO 2003078365 A3 WO2003078365 A3 WO 2003078365A3 EP 0302383 W EP0302383 W EP 0302383W WO 03078365 A3 WO03078365 A3 WO 03078365A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydroformylation
olefins
catalyst
separation
hydrogenation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2003/002383
Other languages
English (en)
French (fr)
Other versions
WO2003078365A2 (de
Inventor
Walter Toetsch
Detlef Arnoldi
Alfred Kaizik
Martin Trocha
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Oxeno Olefinchemie GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10227995A external-priority patent/DE10227995A1/de
Application filed by Oxeno Olefinchemie GmbH filed Critical Oxeno Olefinchemie GmbH
Priority to US10/506,603 priority Critical patent/US6960699B2/en
Priority to AU2003212316A priority patent/AU2003212316A1/en
Priority to EP03708195A priority patent/EP1485341A2/de
Priority to JP2003576374A priority patent/JP4068064B2/ja
Priority to BRPI0308432-9A priority patent/BR0308432A/pt
Publication of WO2003078365A2 publication Critical patent/WO2003078365A2/de
Publication of WO2003078365A3 publication Critical patent/WO2003078365A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Die Erfindung betrifft ein Verfahren zur Herstellung von Alkoholen durch Hydroformylierung von Olefinen oder Olefingemischen, Abtrennen des Katalysators und anschliessende Hydrierung, wobei nach der Abtrennung des Katalysators und vor der Hydrierung der Aldehyde eine Extraktion durchgeführt wird.
PCT/EP2003/002383 2002-03-15 2003-03-08 Verfahren zur hydroformylierung von olefinen Ceased WO2003078365A2 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US10/506,603 US6960699B2 (en) 2002-03-15 2003-03-08 Method for the hydroformylation of olefins
AU2003212316A AU2003212316A1 (en) 2002-03-15 2003-03-08 Method for the hydroformylation of olefins
EP03708195A EP1485341A2 (de) 2002-03-15 2003-03-08 Verfahren zur hydroformylierung von olefinen
JP2003576374A JP4068064B2 (ja) 2002-03-15 2003-03-08 オレフィン類のヒドロホルミル化法
BRPI0308432-9A BR0308432A (pt) 2002-03-15 2003-03-08 processo para a hidroformilação de olefinas

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE10211652 2002-03-15
DE10211652.0 2002-03-15
DE10227995A DE10227995A1 (de) 2002-03-15 2002-06-22 Verfahren zur Hydroformylierung von Olefinen
DE10227995.0 2002-06-22

Publications (2)

Publication Number Publication Date
WO2003078365A2 WO2003078365A2 (de) 2003-09-25
WO2003078365A3 true WO2003078365A3 (de) 2004-02-05

Family

ID=28042837

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/002383 Ceased WO2003078365A2 (de) 2002-03-15 2003-03-08 Verfahren zur hydroformylierung von olefinen

Country Status (7)

Country Link
US (1) US6960699B2 (de)
EP (1) EP1485341A2 (de)
JP (1) JP4068064B2 (de)
CN (1) CN100503542C (de)
AU (1) AU2003212316A1 (de)
BR (1) BR0308432A (de)
WO (1) WO2003078365A2 (de)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10058383A1 (de) * 2000-11-24 2002-05-29 Oxeno Olefinchemie Gmbh Neue Phosphininverbindungen und deren Metallkomplexe
CA2455191C (en) * 2001-09-26 2011-03-15 Oxeno Olefinchemie Gmbh Alkyl phthalate mixtures with controlled viscosity
DE10149348A1 (de) 2001-10-06 2003-04-10 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefin mit Palladiumcarbenverbindungen
DE10220801A1 (de) * 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
DE10225565A1 (de) 2002-06-10 2003-12-18 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen
BR0313866A (pt) 2002-08-31 2005-07-05 Oxeno Olefinchemie Gmbh Processo para a hidroformilação de compostos olefinicamente insaturados, especialmente olefinas na presença de ésteres de ácido carbÈnico cìclicos
AU2003250219A1 (en) 2002-08-31 2004-04-30 Oxeno Olefinchemie Gmbh Method for producing aldehydes by means of hydroformylation of olefinically unsaturated compounds, said hydroformylation being catalysed by unmodified metal complexes in the presence of cyclic carbonic acid esters
PL377038A1 (pl) * 2002-11-19 2006-01-23 Ciba Specialty Chemicals Holding Inc. Amfoteryczne fluorescencyjne wybielacze optyczne
DE10257499A1 (de) 2002-12-10 2004-07-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefinen durch katalytische Spaltung von 1-Alkoxyalkanen
DE10329042A1 (de) * 2003-06-27 2005-01-13 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Octen aus Crack-C4
DE10359628A1 (de) * 2003-12-18 2005-07-21 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Herstellung von 1-Olefinen aus 2-Hydroxyalkanen
DE10360771A1 (de) * 2003-12-23 2005-07-28 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von dreiwertigen Organophosphor-Verbindungen
DE10360772A1 (de) * 2003-12-23 2005-07-28 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Organoacylphosphiten
DE102004033410A1 (de) * 2004-02-14 2005-09-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Olefinen mit 8 bis 12 Kohlenstoffatomen
DE102004013514A1 (de) * 2004-03-19 2005-10-06 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen
DE102004021128A1 (de) * 2004-04-29 2005-11-24 Oxeno Olefinchemie Gmbh Vorrichtung und Verfahren für die kontinuierliche Umsetzung einer Flüssigkeit mit einem Gas an einem festen Katalysator
DE102005036039A1 (de) 2004-08-28 2006-03-02 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 2,7-Octadienylderivaten
DE102004059292A1 (de) * 2004-12-09 2006-06-14 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Alkoholen aus Olefinen durch Hydroformylierung und Hydrierung
DE102004059293A1 (de) * 2004-12-09 2006-06-14 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen
DE102004063673A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas
DE102005035816A1 (de) * 2005-07-30 2007-02-01 Oxeno Olefinchemie Gmbh Verfahren zur Hydrierung von Oxo-Aldehyden mit hohen Estergehalten
DE102005042464A1 (de) * 2005-09-07 2007-03-08 Oxeno Olefinchemie Gmbh Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen
DE102006031964A1 (de) * 2006-07-11 2008-01-17 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 3-Methylbut-1-en
WO2008147129A1 (en) * 2007-05-29 2008-12-04 Lg Chem, Ltd. Method for the hydroformylation of olefins and apparatus using the same
DE102007061649A1 (de) * 2007-12-20 2009-07-02 Evonik Oxeno Gmbh Einstufiges kontinuierliches Verfahren zur Hydroformylierung von höheren Olefinen oder Olefingemischen
DE102007061648A1 (de) * 2007-12-20 2009-07-02 Evonik Oxeno Gmbh Mehrstufiges kontinuierliches Verfahren zur Hydroformylierung von höheren Olefinen oder Olefingemischen
EP2321246B1 (de) * 2008-08-29 2015-06-10 ExxonMobil Chemical Patents Inc. Abgasreinigung in olefin-hydroformylierungen
US20120123079A1 (en) 2009-07-23 2012-05-17 Evonik Fibres Gmbh Polyimide membranes made of polymerization solutions
DE102009047351A1 (de) 2009-12-01 2011-06-09 Evonik Goldschmidt Gmbh Komposit-Siliconmembranen mit hoher Trennwirkung
CN102741210B (zh) 2009-12-22 2016-02-24 陶氏技术投资有限责任公司 控制混合配体加氢甲酰化工艺中的正构∶异构醛比率
DE102012202779A1 (de) 2012-02-23 2013-08-29 Evonik Oxeno Gmbh Verfahren und Vorrichtung zur technischen Hydroformylierung von Isobuten und zum Auftrennen des Produktgemisches
EP2906573B1 (de) 2012-10-12 2016-11-23 Evonik Degussa GmbH Gemisch von bisphosphiten und dessen verwendung als katalysatorgemisch in der hydroformylierung
DE102012223572A1 (de) 2012-12-18 2014-06-18 Evonik Industries Ag Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2816933A (en) * 1952-02-09 1957-12-17 Exxon Research Engineering Co Catalyst regeneration in oxo alcohol synthesis
WO1993024437A1 (en) * 1992-05-29 1993-12-09 Exxon Chemical Patents Inc. Catalyst regeneration
DE19939491A1 (de) * 1999-08-20 2001-02-22 Basf Ag Kontinuierliches Verfahren zur Hydroformylierung von Olefinen mit 6 bis 20 Kohlenstoffatomen
EP1172349A2 (de) * 2000-07-14 2002-01-16 Oxeno Olefinchemie GmbH Mehrstufiges Verfahren zur Herstellung von Oxo-Aldehyden und/oder Alkoholen

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4255279A (en) * 1979-07-20 1981-03-10 Exxon Research & Engineering Co. Dual demetalling of oxo products with catalyst recycle
US5237105A (en) * 1992-05-29 1993-08-17 Exxon Chemical Patents Inc. Method for removing hydroformylation catalyst
DE19654340A1 (de) 1996-12-24 1998-08-06 Huels Chemische Werke Ag Verfahren zur Herstellung von höheren Oxo-Alkoholen
DE19842368A1 (de) 1998-09-16 2000-03-23 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von höheren Oxoalkoholen aus Olefingemischen durch zweistufige Hydroformylierung
DE19842371A1 (de) 1998-09-16 2000-03-23 Oxeno Oelfinchemie Gmbh Verfahren zur Herstellung von höheren Oxo-Alkoholen aus Olefingemischen
DE10009207A1 (de) 2000-02-26 2001-08-30 Oxeno Olefinchemie Gmbh Verbessertes Verfahren zur Hydroformylierung von Olefinen durch Reduzierung der Ameisensäurekonzentration
DE10135906A1 (de) 2001-07-24 2003-02-06 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von höheren Olefinen mit Kobaltverbindungen als Katalysator

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2816933A (en) * 1952-02-09 1957-12-17 Exxon Research Engineering Co Catalyst regeneration in oxo alcohol synthesis
WO1993024437A1 (en) * 1992-05-29 1993-12-09 Exxon Chemical Patents Inc. Catalyst regeneration
DE19939491A1 (de) * 1999-08-20 2001-02-22 Basf Ag Kontinuierliches Verfahren zur Hydroformylierung von Olefinen mit 6 bis 20 Kohlenstoffatomen
EP1172349A2 (de) * 2000-07-14 2002-01-16 Oxeno Olefinchemie GmbH Mehrstufiges Verfahren zur Herstellung von Oxo-Aldehyden und/oder Alkoholen

Also Published As

Publication number Publication date
JP2005529853A (ja) 2005-10-06
US20050171389A1 (en) 2005-08-04
BR0308432A (pt) 2006-06-06
WO2003078365A2 (de) 2003-09-25
JP4068064B2 (ja) 2008-03-26
EP1485341A2 (de) 2004-12-15
AU2003212316A8 (en) 2003-09-29
CN1649815A (zh) 2005-08-03
AU2003212316A1 (en) 2003-09-29
CN100503542C (zh) 2009-06-24
US6960699B2 (en) 2005-11-01

Similar Documents

Publication Publication Date Title
WO2003078365A3 (de) Verfahren zur hydroformylierung von olefinen
MX256050B (es) Metodo para mejorar la selectividad de un catalizador y un proceso de epoxidacion de una olefina.
EG24126A (en) Method for producing 1-olefins by catalytically splitting 1-alkoxyalkanes
ZA995926B (en) Process for preparing higher oxo alcohols from olefin mixtures by two-stage hydroformylation.
TW200942525A (en) Process for producing epichlorohydrin
ZA200006513B (en) Process for the preparation of aldehydes from olefins by hydroformylation.
WO2002048126A3 (en) Process for preparing oxirane compounds
MX257124B (es) Metodo para iniciar un proceso de epoxidacion, catalizador y proceso de epoxidacion de una olefina.
SG123664A1 (en) Process for preparing alcohols from olefins by hydroformylation and hydrogenation
WO2005094320A3 (en) Method of separating layers of material using a laser beam
PL349832A1 (en) Method of obtaining aldehydes by hydroformylation of olefins in presence of stabilised rhodium catalysts
WO2005031182A3 (en) Brake caliper for disc brake assembly and method and apparatus for producing same
PL2041049T3 (pl) Proces wytwarzania 3-metylobut-1-enu
DE60125884D1 (de) Verfahren zur oligomerisierung von olefinen sowie die hydrierungsprodukte der hergestellten olefine
WO2008051758A3 (en) A method for making a dressing
AU2001242333A1 (en) Method for producing anhydrous formic acid
WO2008111282A1 (ja) カルボニル化合物の製造方法
AU2001240616A1 (en) Method for processing a liquid hydroformylation discharge
WO2005037751A3 (en) Preparation of branched aliphatic alcohols using a process stream from an isomerization unit with recycle to a dehydrogenation unit
EA200400270A1 (ru) Выделение диметилового эфира из потока олефинов под низким давлением
WO2003068980A3 (en) Method for extracting a macrolide from biomatter
WO2005009934A3 (de) Zweistufiges hydroformylierungsverfahren
WO2003020678A3 (en) Method of separating dimethyl ether from an olefin stream
MXPA05014144A (es) Metodo de fabricacion de cemento portland de adquisicion temprana de alta resistencia.
EP1694440A4 (de) Verfahren zur herstellung eines mischmetalloxidkatalysators zur herstellung von ungesättigten aldehyden aus olefinen

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2003708195

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2003576374

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 20038099454

Country of ref document: CN

WWP Wipo information: published in national office

Ref document number: 2003708195

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWE Wipo information: entry into national phase

Ref document number: 10506603

Country of ref document: US

ENP Entry into the national phase

Ref document number: PI0308432

Country of ref document: BR

WWR Wipo information: refused in national office

Ref document number: 2003708195

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 2003708195

Country of ref document: EP