WO2004004893A3 - Catalyseurs comprenant une couche d’oxyde de tungstene sur un support zircone et/ou oxyde de titane - Google Patents

Catalyseurs comprenant une couche d’oxyde de tungstene sur un support zircone et/ou oxyde de titane Download PDF

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Publication number
WO2004004893A3
WO2004004893A3 PCT/FR2003/002040 FR0302040W WO2004004893A3 WO 2004004893 A3 WO2004004893 A3 WO 2004004893A3 FR 0302040 W FR0302040 W FR 0302040W WO 2004004893 A3 WO2004004893 A3 WO 2004004893A3
Authority
WO
WIPO (PCT)
Prior art keywords
zirconia
catalysts
oxide layer
support
tungsten oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2003/002040
Other languages
English (en)
Other versions
WO2004004893A2 (fr
Inventor
Francois Figueras
Nadine Essayem
Cyril Feche
Stefane Loridant
Jorge Palomeque
Georges Gelbard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Original Assignee
Centre National de la Recherche Scientifique CNRS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS filed Critical Centre National de la Recherche Scientifique CNRS
Priority to DE60320995T priority Critical patent/DE60320995D1/de
Priority to AU2003259316A priority patent/AU2003259316A1/en
Priority to EP03762721A priority patent/EP1519785B1/fr
Priority to US10/519,498 priority patent/US7851401B2/en
Publication of WO2004004893A2 publication Critical patent/WO2004004893A2/fr
Publication of WO2004004893A3 publication Critical patent/WO2004004893A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

L'invention concerne des solides comprenant une monocouche d'oxyde de tungstène sur un support zircone et/ou dioxyde de titane, caractérisé en ce que le tungstène présente une coordination tétraédrique, avant et après calcination.L'invention concerne également le procédé de préparation des solides, ainsi que leurs utilisations comme catalyseurs de réactions à catalyse acide.
PCT/FR2003/002040 2002-07-03 2003-07-01 Catalyseurs comprenant une couche d’oxyde de tungstene sur un support zircone et/ou oxyde de titane Ceased WO2004004893A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE60320995T DE60320995D1 (de) 2002-07-03 2003-07-01 Katalysator bestehend aus einer wolframoxidmonoschicht auf einem zirkon- und/oder titandioxidträger
AU2003259316A AU2003259316A1 (en) 2002-07-03 2003-07-01 Catalysts comprising a tungsten oxide layer on a zirconia and/or titanium oxide support
EP03762721A EP1519785B1 (fr) 2002-07-03 2003-07-01 Catalyseurs comprenant une monocouche d'oxyde de tungstene sur un support zircone et/ou oxyde de titane
US10/519,498 US7851401B2 (en) 2002-07-03 2003-07-01 Tungsten catalysts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR02/08318 2002-07-03
FR0208318A FR2841797B1 (fr) 2002-07-03 2002-07-03 Catalyseurs a base de tungstene

Publications (2)

Publication Number Publication Date
WO2004004893A2 WO2004004893A2 (fr) 2004-01-15
WO2004004893A3 true WO2004004893A3 (fr) 2004-04-15

Family

ID=29725119

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2003/002040 Ceased WO2004004893A2 (fr) 2002-07-03 2003-07-01 Catalyseurs comprenant une couche d’oxyde de tungstene sur un support zircone et/ou oxyde de titane

Country Status (7)

Country Link
US (1) US7851401B2 (fr)
EP (1) EP1519785B1 (fr)
AT (1) ATE395131T1 (fr)
AU (1) AU2003259316A1 (fr)
DE (1) DE60320995D1 (fr)
FR (1) FR2841797B1 (fr)
WO (1) WO2004004893A2 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1938085B (zh) * 2004-03-29 2011-05-25 昭和电工株式会社 用于制备含氧化合物的钯、钨和锆基催化剂，该催化剂的制备方法和利用该催化剂制备含氧化合物的方法
FR2888131B1 (fr) * 2005-07-08 2008-04-04 Total France Sa Catalyseur d'ouverture de cycles hydrocarbones.
FR2907445B1 (fr) * 2006-10-20 2010-09-03 Rhodia Recherches & Tech Composition a acidite elevee a base d'oxyde de zirconium, d'oxyde de titane et d'oxyde de tungstene,procede de preparation et utilisation dans le traitement des gaz d'echappement
DE102007004350A1 (de) * 2007-01-29 2008-07-31 Evonik Degussa Gmbh Verfahren zur Regenerierung eines Katalysators
US20090242459A1 (en) * 2008-03-26 2009-10-01 General Electric Company Oxidative desulfurization of fuel oil
KR20110055533A (ko) * 2009-10-06 2011-05-25 미츠비시 쥬고교 가부시키가이샤 고온 배기 가스용 탈질 촉매 및 그 제조 방법, 고온 배기 가스 탈질 방법
FR2956114B1 (fr) 2010-02-11 2012-03-23 Inst Francais Du Petrole Procede de transformation de biomasse lignocellulosique ou de cellulose par des acides solides de lewis a base de tungstene
FR2963346B1 (fr) 2010-07-29 2013-03-15 IFP Energies Nouvelles Procede de transformation de biomasse lignocellulosique ou de cellulose par des catalyseurs acides solides de lewis a base d'oxyde de tungstene et d'un metal choisi dans les groupes 8 a 11
US8790508B2 (en) 2010-09-29 2014-07-29 Saudi Arabian Oil Company Integrated deasphalting and oxidative removal of heteroatom hydrocarbon compounds from liquid hydrocarbon feedstocks
US10262763B2 (en) * 2016-09-19 2019-04-16 Radium Incorporated Systems, devices, and/or methods for managing radiation shielding
US20240367996A1 (en) * 2020-10-16 2024-11-07 Zhejiang University Composite Oxide Containing Tungstate Nanoclusters, And Preparation Method And Application Thereof
CN115138371B (zh) * 2021-03-29 2024-03-12 昆明理工大学 一种还原性硫污染物选择性催化氧化催化剂及其制备方法和应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2739132A (en) * 1952-08-25 1956-03-20 Universal Oil Prod Co Manufacture of supported catalysts
US3474042A (en) * 1965-12-24 1969-10-21 Montedison Spa Process for the production of catalysts containing molybdenum and/or tungsten
GB1249079A (en) * 1969-04-02 1971-10-06 Shell Int Research A process for epoxidizing olefins with organic hydroperoxides
US5543036A (en) * 1993-07-22 1996-08-06 Mobil Oil Corporation Process for hydrotreating
WO2001048119A1 (fr) * 1999-12-28 2001-07-05 Elf Antar France Procede de desulfuration des derives du thiophene contenus dans des carburants

Family Cites Families (1)

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FR2684899B1 (fr) * 1991-12-16 1994-03-25 Rhone Poulenc Chimie Catalyseur de reduction selective des oxydes d'azote contenus dans un flux gazeux et application desdits catalyseurs.

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2739132A (en) * 1952-08-25 1956-03-20 Universal Oil Prod Co Manufacture of supported catalysts
US3474042A (en) * 1965-12-24 1969-10-21 Montedison Spa Process for the production of catalysts containing molybdenum and/or tungsten
GB1249079A (en) * 1969-04-02 1971-10-06 Shell Int Research A process for epoxidizing olefins with organic hydroperoxides
US5543036A (en) * 1993-07-22 1996-08-06 Mobil Oil Corporation Process for hydrotreating
WO2001048119A1 (fr) * 1999-12-28 2001-07-05 Elf Antar France Procede de desulfuration des derives du thiophene contenus dans des carburants

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
JONG RACK SOHN ET AL.: "Characterization of zirconia-supported tungsten oxide catalyst", LANGMUIR, vol. 14, no. 21, 1998, pages 6140 - 6145, XP002234339 *
M.A. VUURMAN ET I.E. WACHS: "Structural determination of supported V2O5-WO3/TiO2 catalysts by in situ Raman spectrometry and X-ray photoelectron spectroscopy", JOURNAL OF PHYSICAL CHEMISTRY, vol. 95, no. 24, 1991, pages 9928 - 9937, XP002234340 *
PARERA J M ET AL: "n-butane isomerization on tungsten oxide supported on zirconia", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 163, no. 1-2, 5 December 1997 (1997-12-05), pages 165 - 175, XP004338258, ISSN: 0926-860X *

Also Published As

Publication number Publication date
DE60320995D1 (de) 2008-06-26
ATE395131T1 (de) 2008-05-15
US7851401B2 (en) 2010-12-14
AU2003259316A8 (en) 2004-01-23
US20060091045A1 (en) 2006-05-04
FR2841797B1 (fr) 2005-08-05
FR2841797A1 (fr) 2004-01-09
EP1519785A2 (fr) 2005-04-06
EP1519785B1 (fr) 2008-05-14
WO2004004893A2 (fr) 2004-01-15
AU2003259316A1 (en) 2004-01-23

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