WO2004017369A2 - Piezoelectric transducer with gas matrix - Google Patents
Piezoelectric transducer with gas matrix Download PDFInfo
- Publication number
- WO2004017369A2 WO2004017369A2 PCT/US2003/025334 US0325334W WO2004017369A2 WO 2004017369 A2 WO2004017369 A2 WO 2004017369A2 US 0325334 W US0325334 W US 0325334W WO 2004017369 A2 WO2004017369 A2 WO 2004017369A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- piezoelectric
- cylinders
- transducer
- faces
- frequency
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B06—GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS IN GENERAL
- B06B—METHODS OR APPARATUS FOR GENERATING OR TRANSMITTING MECHANICAL VIBRATIONS OF INFRASONIC, SONIC, OR ULTRASONIC FREQUENCY, e.g. FOR PERFORMING MECHANICAL WORK IN GENERAL
- B06B1/00—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency
- B06B1/02—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy
- B06B1/06—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy operating with piezoelectric effect or with electrostriction
- B06B1/0607—Methods or apparatus for generating mechanical vibrations of infrasonic, sonic, or ultrasonic frequency making use of electrical energy operating with piezoelectric effect or with electrostriction using multiple elements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S310/00—Electrical generator or motor structure
- Y10S310/80—Piezoelectric polymers, e.g. PVDF
Definitions
- This invention is in the field of piezoelectric transducers for ultrasound devices, more particularly, piezoelectric transducers comprising piezoelectric cylinders isolated from a support matrix by a gas or vacuum and arranged such that they are separated from each other by less than one wavelength in that matrix.
- Transducers are devices that transform input signals into output signals of a different form. In ultrasound devices, they transform signals of electrical energy into acoustic energy or produce electrical signals from absorbed sound waves. Piezoelectric ceramic materials are particularly effective for this type of electromechanical energy conversion and have found wide use in the transducer field. Many piezoelectric ceramics have very high electromechanical coupling coefficients, kx (approximately 0.5), which indicate how effective a material is at transferring electrical energy into mechanical energy.
- the source (transmitter) of ultrasound that is, the transducer device
- the receiver of ultrasoimd be very sensitive to detect even the minutest ultrasonic vibrations, irrespective of the medium or the mechanism by which they are generated.
- a second important property for effective ultrasound transducers is the acoustic impedance of the transducer material.
- Acoustic impedance describes the compressibility of a material and is found by taking the product of the density of a material arid the velocity of sound in that material.
- the size of the difference between the acoustic impedances of X and Y determines the amount of sound energy that is transmitted across the interface and the amount of sound energy that is reflected back into the first material. The greater the difference, the less sound energy that is received into the second material.
- the transmission of sound energy between two materials is termed acoustic coupling, higher coupling means higher transmission of sound energy.
- the size of the difference between the values of acoustic impedance is what determines the degree of acoustic coupling in that system.
- Systems with low differences in acoustic impedance exhibit the best coupling.
- Piezoelectric ceramics such as Pb(Zr, Ti)O 3 (PZT)
- Z acoustic impedances
- Z 410 Rayl.
- the large difference in acoustic impedance between the probe material (e.g., water) and the monolithic piece of ceramic results in a large proportion of reflected sound waves at the transducer surface.
- One solution to this problem of poor acoustic coupling is to create matching layers between the monolithic piece of ceramic and the sample and to use a backing medium behind the ceramic. These layers attenuate sound energy and still lose energy to reflection and are not a perfect solution to the problem.
- a second solution is to combine the strong piezoelectric characteristics of a ceramic with the better acoustic coupling properties of another material in a composite. Most early attempts to create composites involved loading ceramic particles into a polymer matrix to create a homogenous composite. These composites had low acoustic impedances, but the polymer shielded the piezoelectric ceramic particles from applied electric fields, preventing poling of the ceramic particles. In addition, the polymer acted to dampen waves generated by the ceramic.
- planar coupling in the piezoelectric cylinders generates vibrations that propagate through the polymer to other elements in the transducer creating noise, which is termed crosstalk in the art.
- This noise reduces the resolution of the device.
- This type of noise is especially troublesome in devices where one part of the array of cylinders is used to transmit ultrasound waves and another part is used to receive the reflected waves.
- the waves resulting from planar coupling in the transmitting cylinders are propagated through the polymer to the receiving cylinders creating noise and reduce the image quality. Therefore, the object of the present invention is to overcome deficiencies in the prior art.
- the current ultrasonic transducer devices utilize a piezoelectric material, the front and back faces of which are bonded with a variety of materials that modify the resonance and frequency characteristics of the piezoelectric material with respect to ultrasound transmission in a given medium.
- the piezoelectric materials used are: Lead Zirconate- Lead Titanate solid solutions, Lead meta Niobates, Lead Titanates, Lead Magnesium Niobate, Lithium Niobate, Zinc Oxide, Quartz, Barium Titanate, polymer-based homogeneous materials, polymer matrix solid piezoelectric materials, etc.
- Materials used on the back, front, and on the sides of the piezoelectric materials are: rigid, porous, monolithic or composite, particulate, or fibrous metals, alloys, ceramics, polymers, etc.
- the devices according to the current art can be made to generate high transduction in the medium of ultrasound transmission. See Bhardwaj U.S. PatentNo. 6,311,573.
- the devices according to the current art are to be used for certain applications, such as for power generation or for high transduction in attenuative media (gases, coarse grained, open or closed cell materials) particularly in high frequency range, say from 100 kHz to greater than 1 MHz, then one has to apply relatively high electrical power to the devices. Whereas some applications can be successfully executed by doing so, yet there are others that cannot. The reason for this being high power excitation of transducers results in the heating of the piezoelectric material, subsequently destroying the entire device. Besides this, too high electrical power can be dangerous and more cumbersome to handle in a practical manner. Therefore, it is necessary to develop a piezoelectric device that is inherently characterized by transduction efficiency higher than those that are produced according to the current art.
- the present invention has been shown to overcome the limitations of the prior art.
- a piezoelectric transducer defined by two faces.
- the transducer comprises a plurality of piezoelectric cylinders.
- the axial length and composition of the piezoelectric cylinders determine the frequency of the transducers when excited.
- the axial ends of the piezoelectric cylinders are aligned with the faces.
- the piezoelectric cylinders are separated from each other in a manner to substantially reduce or substantially eliminate crosstalk.
- the piezoelectric cylinders or fibers may be separated from each other by a space that is empty or a space that is partially empty of matrix material resulting in a gap between the cylinders and the material so that cylinders and material are substantially entirely unconnected.
- the piezoelectric cylinders are separated from each other by a distance that is preferably less than the acoustic wavelength at the frequency of the piezoelectric cylinders or fibers in the space between the cylinders. Electrodes are provided at the faces of the transducer for simultaneously exciting the piezoelectric cylinders.
- a piezoelectric transducer is defined by two substantially parallel faces and a support structure provides mechanical strength to the transducer between the faces.
- Piezoelectric cylinders are arranged between the parallel faces with cylindrical axes substantially perpendicular to the parallel faces. The axial length and composition of the piezoelectric cylinders determine the frequency of the transducers when excited.
- the piezoelectric cylinders are separated from each other by a space and there is a gap in the space free of solid or liquid material.
- the piezoelectric cylinders are separated from each other by a distance that is preferably less than the acoustic wavelength at the frequency of the piezoelectric cylinders in the space therebetween.
- Electrodes are provided at the parallel faces of the transducer for simultaneously exciting the cylinders.
- the piezoelectric cylinders may have one or more of the following cross sections: circular, rectangular, hexagonal, or any other polygon, with a width preferably less than one wavelength of the frequency in the piezoelectric material.
- the material may comprise a solidified foam, fiber batting or honeycomb, for example, which material is not electrically conductive.
- the gap in the space between the piezoelectric cylinders may be filled with a gas at atmospheric pressure, gas below atmospheric pressure, or a vacuum.
- Fig. 1 A is a schematic drawing of the perforated foam material
- Fig. IB is a schematic drawing of a honeycomb core suitable as a support matrix
- Figs. 2A and 2B are schematic drawings of a perforated foam material and a honeycomb core, respectively, supporting piezoelectric ceramic cylinders;
- Fig. 3 is a drawing showing the relationship between the support matrix and the piezoelectric cylinders, preferably the width of the cylinder dl and the distance between the cylinders d2 are less than one wavelength in the piezoelectric material at a specified frequency;
- Fig. 4 is a section view of the transducer according to this invention with the surface fully electroded, the spacing between the cylinders and the width of the cylinders being less than one wavelength at a specified frequency, and t is the thickness of the transducer;
- Fig. 5 is a section view of the transducer according to this invention with the alternative method of electroding individual cylinders rather than the entire surface for reduction of the penetration of conducting material into the support matrix, the spacing between the cylinders and the width of the cylinders being less than one wavelength at a specified frequency, and t is the thickness of the composite;
- FIGs. 6 A and 6B show a schematic drawing. of an array with electrodes applied to rows of cylinders in two different ways;
- Fig. 7 is a schematic illustration of an arrangement of equal length piezoelectric cylinders arranged for focusing
- FIG. 8 is a schematic illustration of ah arrangement of piezoelectric cylinders of variable lengths to produce a broadband transducer
- FIG. 9 is a schematic cross-sectional view through a transducer assembly according to this invention.
- Fig. 10 is an oscilloscope trace showing a signal reflected through air from a surface to a comparative polymer matrix transducer
- Fig. 11 is an oscilloscope trace showing a signal reflected through air from a surface to a gas matrix transducer made according to this invention
- Fig 12 is an oscilloscope display showing a reflected signal through air from a surface to a polymer matrix transducer with the top trace being the entire signal and the bottom trace the amplified reflected signal;
- Fig 13 is an oscilloscope display showing a reflected signal through air from a surface to a gas matrix transducer according to this invention with the top trace being the entire signal and the bottom trace the amplified reflected signal;
- Fig. 14 is an oscilloscope display showing the crosstalk between two gas matrix transducers according to this invention in physical contact with each other;
- Fig. 15 is an oscilloscope display showing the crosstalk between two comparative polymer matrix transducers in physical contact with each other;
- Fig. 16 is an oscilloscope display showing fully resolved multiple reflected signals through air from a surface to a gas matrix transducer according to this invention
- Fig. 17 is an oscilloscope display showing poorly resolved multiple reflected signals through air to a comparative polymer matrix transducer
- Fig. 18 is a schematic cross section of an array of transducers according to one embodiment of this invention.
- Fig. 19 is a schematic plan view of a linear array of transducers according to this invention.
- Fig. 20 is a schematic plan view of a two-dimensional array according to this invention.
- the transducer of the present invention uses piezoelectric cylinders with a preferred diameter of less than one wavelength of the frequency in the piezoelectric ceramic. These cylinders are preferably set apart by a distance less than one wavelength of the frequency in the support matrix.
- the support matrix may consist, of foams, ceramics, polymers, fiber batting, or other materials that allow for voids into which the piezoelectric cylinders may be inserted.
- the piezoelectric cylinders are separated, except for incidental brushing contact, from the matrix material by a layer of gas or a vacuum, isolating the piezoelectric elements from the support matrix.
- This invention improves on the prior art performance of these arrays of piezoelectric cylinders, which are normally embedded and bonded to some type of polymer matrix, by isolating them in a support matrix which provides mechanical strength of the overall transducer assembly and protects the array of piezoelectric cylinders.
- the deformation of the matrix along with the piezoelectric elements was the essential feature of the composite's operation.
- the current design instead focuses on mechanically isolating the piezoelectric elements to prevent electromechanical crosstalk between adjacent cylinders. This isolation also serves to reduce the effects of planar coupling on resolution and sensitivity.
- the composite still benefits from the lowered overall dielectric constant, which allows high voltages to be obtained when ultrasound waves are received as compared to a monolithic piezoelectric ceramic.
- the design also lowers the overall transducer acoustic impedance allowing for better coupling between the transducer and air or other low impedance materials.
- the transducer of the current design may be constructed by taking a support matrix, such as a foam with holes drilled in it (as shown in Fig. 1 A) or a honeycomb structure (Fig. IB), and inserting a piezoelectric ceramic (e.g., LiNbO 3 , Pb(Zr, Ti)O 3 , Pb,Mg(NbO3), Pb(Zr, Ln, Ti)O 3 ) cylinders into the holes (as shown in Fig. 2A) or cells of a honeycomb structure (Fig. 2B).
- the width of the cylinder preferably should be less than one wavelength of a specified frequency in the piezoelectric material.
- the holes or cells in the support matrix material must be spaced such that the distance between them is preferably less than one wavelength in the matrix material. • The reason for the width and spacing in the transducer is to reduce or eliminate the problems with acoustic nodes.
- Fig. 3 illustrates the relationship between the matrix and the piezoelectric cylinders.
- the diameter dl of the cylinders is preferably less than one wavelength of the piezoelectric material.
- the spacing d2 between adjacent piezoelectric cylinders is less than one wavelength of the matrix gas and structure at the frequency of the transducer.
- Fig. 4 illustrates a common electrode sheet for exciting all piezoelectric cylinders at one time.
- Fig. 5 illustrates lead wires to each individual piezoelectric cylinder. The latter arrangement, while more difficult to fabricate, will be less susceptible to crosstalk between cylinders.
- Figs. 6A and 6B illustrate alternate arrangements for attaching strips of conductive material across the ends of the piezoelectric cylinders.
- honeycomb materials are commercially available, for example, from Hexal Composites, Duxford, Cambridge CB2 4QD, United Kingdom.
- These honeycomb materials have thin walls comprised of various materials, such as glass fabric reinforced with phenolic resin and paper reinforced with phenolic resin. The walls divide off the cells, which may have a hexagonal cross section.
- One suitable honeycomb structure is formed of abutting corrugated layers wherein the peaks . of one layer are attached to the grooves of the other layer.
- honeycomb structures See, for example, Dixon et al. U.S. Patent No. 5,571,369.
- the piezoelectric cylinders are not attached to the support matrix material, though there can be some contact between the support matrix and the cylinders.
- a key feature is that the gaps between the cylinders and the support matrix are filled with some gas, mixture of gases, or a vacuum. While the prior art has relied on surface contact and attachment between the cylinders and the matrix material to transfer energy between the matrix and the ceramic, the current invention makes use of this gap to isolate the cylinders minimizing mechanical crosstalk and noise between the piezoelectric elements.
- the gas or vacuum between the support matrix and the rods allows for improved coupling with air in non-contact applications, while still being able to take advantage of the larger piezoelectric voltages and improved sensitivity offered by the piezoelectric cylinders in a 1-3 arrangement over a monolithic ceramic.
- the focus was on the matrix properties and finding a matrix arrangement that would optimize overall composite properties, such as dielectric constant or acoustic impedance.
- the focus is on the piezoelectric elements, their arrangement, and isolation to optimize their performance.
- improved performance is realized by combining ceramic element size and shape, which effectively eliminates planar coupling coefficients and raises piezoelectric voltages in the overall transducer arrangement, with the benefits of mechanical isolation, such as reduced noise and crosstalk between elements in the transducer.
- the support matrix used in one embodiment of the current invention serves primarily to impart mechanical strength or flexibility to the piezoelectric array.
- better performance may be realized by taking the isolation a step further by removing the support matrix material entirely and leaving only gas or vacuum between the piezoelectric cylinders.
- This configuration would take advantage of the complete mechanical isolation of the piezoelectric cylinders to provide for better resolution of the reflected ultrasound waves.
- the cylinders may be held in place by placing them between two horizontal metal plates and bonding the plates to the top and bottom faces of the cylinders.
- the other important feature is the electroding on the surface of the composite, which provides electrical connection to the control and measuring devices.
- the electroding can either be on the full surface of the composite or the individual faces of the piezoelectric cylinders. When the surface is fully electroded, care must be taken to prevent the conductive material (Cu, Al, Au, Ag, Ni, Pt, etc.) from penetrating into the matrix material.
- Gas matrix piezoelectric material is characterized by the following highly desired characteristics: extremely high thickness mode coupling, which is equal to that of the solid piezoelectric material; practically zero planar coupling, which is usually very high for high coupling piezoelectric materials; very low dielectric constant; very low density; and very low pyroelectric charge development.
- Fig. 7 shows the cross section of equal length piezoelectric cylinders arranged between two faces that are curved in order to generate a geometric focus.
- the type of curvature can be spherical to produce a point focus, it can be parabolic to create a cylindrical focus, or it can be a combination of the two to create a compound focus.
- Fig. 8 shows the cross section of variable length piezoelectric cylinders arranged between a plane face and a curved face.
- Fig. 9 shows the details of a transducer device based upon gas matrix piezoelectric materials.
- FC the frequency constant (mm*MHz)
- t the thickness of the gas matrix composite in millimeters.
- abutting the piezoelectric materials have a composition that determines the efficiency of ultrasound transmission in the medium in which propagation of ultrasound is desired.
- the total thickness of this layer individually or collectively (if multiple), preferably should be one-quarter of the wavelength in the Z matching layer.
- the Z matching layer materials may comprise single or multiple layers of homogeneous or particulate or fibrous metals, ceramics, polymers, or their combinations.
- this material modifies the pulse shape and the frequency characteristics of the ultrasound device.
- the thickness of tins material is less than one-eighth of the wavelength or more, preferably, one quarter of the wavelength.
- the damping materials may comprise single or multiple layers of homogeneous or particulate or fibrous metals, ceramics, polymers, or their combinations.
- Electrically conductive wires 4 are bonded to the faces of the piezoelectric material and to a suitable coaxial cable or connector 8.
- the transducer housing 5 may comprise metal, ceramic, polymer, or a composite.
- the sides 6 of the transducer may be encapsulated with a material, such as non-electrically conductive epoxy, rubber, or inorganic cement. If desired, an electrically tuning network 7 may be installed between the -ve and +ve faces of the piezoelectric composite.
- a comparison between the polymer matrix and gas matrix piezoelectric transducers is informative.
- the testing was conducted at a frequency of about 125 kHz.
- the active area of the transducers was 50 x 50 mm.
- the transducers were excited with a 220 volt negative spike pulse.
- a steel plate was placed 180 mm away from the transducer in ambient air.
- the gain of the receiver was 20 dB.
- Fig. 10 is an oscilloscope display recording the reflected pulse for a polymer matrix transducer.
- the amplitude of the reflected pulse is 0.52 volts.
- Fig. 11 is an oscilloscope trace recording the reflected pulse for a gas matrix transducer according to this invention.
- the amplitude of the reflected pulse is 1.33 volts.
- the reflected signal of the latter is more than 60% or more than 8 dB greater than that of the former. Similar improvement is observed when the devices made for operation in water and in contact with solid materials are tested.
- FIG. 12 shows that the polymer matrix piezoelectric transducer had a low signal-to- noise ratio and a definitely noisy time base. The reflected signal amplitude was 0.5 volts.
- Fig. 13 shows that the gas matrix piezoelectric transducer has a very high signal-to-noise ratio and a very clean time base. The reflected signal amplitude was 1 volt which is 6 dB (50%) higher than the polymer matrix piezoelectric transducer. It should be noted that the conditions of transducer excitation and signal amplification in Figs. 12 and 13 are the same. By comparison, the gas matrix piezoelectric transducer according to this invention is excellent. The improved signal-to-noise ratio is due to the substantial elimination of the radial component of the piezoelectric materials. A further benefit of the substantial elimination of the radial- components is that adjacent transducers do not transfer radial components.
- the gas matrix based piezoelectric transducers offer a significant advantage.
- This advantage pertains to the fact that gas matrix piezoelectric material is virtually free from the deleterious effects of planar coupling. Therefore, multiple transducers based upon this invention can be closely placed against each other without practically any crosstalk between them.
- Figs. 14 and 15 illustrate the crosstalk between two abutting gas matrix transducers and two adjacent polymer matrix transducers, respectively.
- Figs. 16 and 17 illustrate relative signal-to-noise ratio of multiple reflections from a flat target at 60 mm. The reflected signal for the gas matrix transducer is fully resolved upon receipt of the first reflection. The noise prevents full resolution until a much later time.
- Figs. 18 and 19 show the schematics of a linear array.
- Fig. 20 shows the schematics of a matrix array. Individual transducers in the array design can be of any desired shape. With two-dimensional arrays, instant sonic pictures are possible.
- Gas matrix piezoelectrics are lighter ' by more than 50% relative to polymer based piezoelectric composites and more than lighter relative to solid piezoelectric materials, have higher resolution, have zero crosstalk, and can have complex shapes. Pyroelectric effects are much lower, therefore, much lower surface temperatures of transducers, therefore, easier to handle, have longer life, and are more robust.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Transducers For Ultrasonic Waves (AREA)
- Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)
Abstract
Description
Claims
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2003256409A AU2003256409A1 (en) | 2002-08-14 | 2003-08-12 | Piezoelectric transducer with gas matrix |
| EP03788434A EP1550151A2 (en) | 2002-08-14 | 2003-08-12 | Piezoelectric transducer with gas matrix |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US40349402P | 2002-08-14 | 2002-08-14 | |
| US60/403,494 | 2002-08-14 | ||
| US10/337,531 | 2003-01-07 | ||
| US10/337,531 US7382082B2 (en) | 2002-08-14 | 2003-01-07 | Piezoelectric transducer with gas matrix |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2004017369A2 true WO2004017369A2 (en) | 2004-02-26 |
| WO2004017369A3 WO2004017369A3 (en) | 2004-05-06 |
Family
ID=31720294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2003/025334 Ceased WO2004017369A2 (en) | 2002-08-14 | 2003-08-12 | Piezoelectric transducer with gas matrix |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US7382082B2 (en) |
| EP (1) | EP1550151A2 (en) |
| AU (1) | AU2003256409A1 (en) |
| WO (1) | WO2004017369A2 (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7084552B2 (en) * | 2003-01-16 | 2006-08-01 | The Ultran Group, Inc. | Anisotropic acoustic impedance matching material |
| JP2005027752A (en) * | 2003-07-08 | 2005-02-03 | Toshiba Corp | Piezoelectric vibrator, piezoelectric vibrator manufacturing method, ultrasonic probe, and ultrasonic diagnostic apparatus |
| US7703327B2 (en) * | 2004-09-16 | 2010-04-27 | The Boeing Company | Apparatus and method for area limited-access through transmission ultrasonic inspection |
| US20070055182A1 (en) * | 2005-07-20 | 2007-03-08 | Ust, Inc. | Thermally enhanced ultrasound transducer method |
| WO2006088708A2 (en) * | 2005-02-15 | 2006-08-24 | The Ultran Group, Inc. | Multi-layer gas matrix piezoelectric composite transducer |
| US8237335B2 (en) * | 2005-07-20 | 2012-08-07 | Ust, Inc. | Thermally enhanced ultrasound transducer means |
| US8446071B2 (en) * | 2005-07-20 | 2013-05-21 | Ust, Inc. | Thermally enhanced ultrasound transducer system |
| US7405510B2 (en) * | 2005-07-20 | 2008-07-29 | Ust, Inc. | Thermally enhanced piezoelectric element |
| US7378779B2 (en) * | 2005-07-20 | 2008-05-27 | Ust, Inc. | Thermally enhanced piezoelectric composite system and method |
| US7755254B2 (en) * | 2006-12-04 | 2010-07-13 | Ngk Insulators, Ltd. | Honeycomb-type piezoelectric/electrostrictive element |
| NO330292B1 (en) * | 2007-09-12 | 2011-03-21 | Det Norske Veritas As | Acoustic thickness paints using gas as a coupling medium |
| US8179026B2 (en) * | 2008-09-04 | 2012-05-15 | University Of Massachusetts | Nanotubes, nanorods and nanowires having piezoelectric and/or pyroelectric properties and devices manufactured therefrom |
| EP2244489A1 (en) * | 2009-04-24 | 2010-10-27 | Bayer MaterialScience AG | Method for producing an electromechanical converter |
| FR2965249B1 (en) * | 2010-09-28 | 2013-03-15 | Eurocopter France | IMPROVED DEFROSTING SYSTEM FOR FIXED OR ROTATING SAIL OF AN AIRCRAFT |
| DE102010043108A1 (en) * | 2010-10-29 | 2012-05-03 | Robert Bosch Gmbh | Piezoelectric surface acoustic transducer |
| FR3029815B1 (en) * | 2014-12-10 | 2020-03-13 | Thales | PIEZOELECTRIC HYDROPHONE WITH PERFORATIONS AND ANTENNA COMPRISING A PLURALITY OF HYDROPHONES |
| US11090688B2 (en) | 2016-08-10 | 2021-08-17 | The Ultran Group, Inc. | Gas matrix piezoelectric ultrasound array transducer |
| US10702615B2 (en) | 2016-10-19 | 2020-07-07 | The Ultran Group, Inc. | Non-contact ultrasound germicide apparatus |
| US12397178B2 (en) | 2020-05-01 | 2025-08-26 | Secondwave Systems, Inc. | Wearable focused phased array device for modulation |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4330593A (en) * | 1980-11-13 | 1982-05-18 | The United States Of America As Represented By The Secretary Of The Navy | PZT/Polymer composites and their fabrication |
| US4412148A (en) * | 1981-04-24 | 1983-10-25 | The United States Of America As Represented By The Secretary Of The Navy | PZT Composite and a fabrication method thereof |
| US4658176A (en) * | 1984-07-25 | 1987-04-14 | Hitachi, Ltd. | Ultrasonic transducer using piezoelectric composite |
| US4728845A (en) * | 1987-06-30 | 1988-03-01 | The United States Of America As Represented By The Secretary Of The Navy | 1-3-0 Connectivity piezoelectric composite with void |
| JP2794720B2 (en) * | 1988-08-23 | 1998-09-10 | 松下電器産業株式会社 | Composite piezoelectric vibrator |
| US5065068A (en) * | 1989-06-07 | 1991-11-12 | Oakley Clyde G | Ferroelectric ceramic transducer |
| MX9204071A (en) * | 1991-07-12 | 1993-04-01 | Hexcel Corp | METHOD AND APPARATUS FOR MAKING THERMOPLASTIC ALVEOLAR STRUCTURES, THERMALLY CAST. |
| US5325011A (en) * | 1993-06-09 | 1994-06-28 | The United States Of America As Represented By The Asecretary Of The Navy | Transducers and method for making same |
| US5376859A (en) * | 1994-02-07 | 1994-12-27 | The United States Of America As Represented By The Secretary Of The Navy | Transducers with improved signal transfer |
| NO308264B1 (en) * | 1994-03-22 | 2000-08-21 | Western Atlas Int Inc | Well log probe with approximately cylindrical arrangement of piezoelectric acoustic transducers for electronic control and focusing of acoustic signals |
| US5655276A (en) * | 1995-02-06 | 1997-08-12 | General Electric Company | Method of manufacturing two-dimensional array ultrasonic transducers |
| US5552004A (en) * | 1995-04-03 | 1996-09-03 | Gen Electric | Method of making an acoustic composite material for an ultrasonic phased array |
| US5698928A (en) * | 1995-08-17 | 1997-12-16 | Motorola, Inc. | Thin film piezoelectric arrays with enhanced coupling and fabrication methods |
| US6311573B1 (en) * | 1997-06-19 | 2001-11-06 | Mahesh C. Bhardwaj | Ultrasonic transducer for high transduction in gases and method for non-contact ultrasound transmission into solid materials |
| JPH11155859A (en) * | 1997-09-24 | 1999-06-15 | Toshiba Corp | Ultrasonic probe and ultrasonic diagnostic apparatus using the same |
| US6255761B1 (en) * | 1999-10-04 | 2001-07-03 | The United States Of America As Represented By The Secretary Of The Navy | Shaped piezoelectric composite transducer |
| US6720712B2 (en) * | 2000-03-23 | 2004-04-13 | Cross Match Technologies, Inc. | Piezoelectric identification device and applications thereof |
-
2003
- 2003-01-07 US US10/337,531 patent/US7382082B2/en active Active
- 2003-08-12 AU AU2003256409A patent/AU2003256409A1/en not_active Abandoned
- 2003-08-12 WO PCT/US2003/025334 patent/WO2004017369A2/en not_active Ceased
- 2003-08-12 EP EP03788434A patent/EP1550151A2/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| AU2003256409A1 (en) | 2004-03-03 |
| EP1550151A2 (en) | 2005-07-06 |
| US20040032188A1 (en) | 2004-02-19 |
| AU2003256409A8 (en) | 2004-03-03 |
| US7382082B2 (en) | 2008-06-03 |
| WO2004017369A3 (en) | 2004-05-06 |
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