WO2004085727A2

WO2004085727A2 - Composite press felt

Info

Publication number: WO2004085727A2
Application number: PCT/EP2004/050359
Authority: WO
Inventors: Robert L. Crook; Sanjay Patel; William Daniel Aldrich; Per Ola Lidar
Original assignee: Voith Fabrics Patent GmbH
Current assignee: Voith Fabrics Patent GmbH
Priority date: 2003-03-25
Filing date: 2004-03-24
Publication date: 2004-10-07
Anticipated expiration: 2005-09-25
Also published as: US7871672B2; US20070003760A1; EP1620598A2; WO2004085727A3; GB0306769D0

Abstract

There is provided an industrial fabric comprising a layer of batt of fibres optionally needled to a base cloth, whereby during manufacture of the fabric a dispersion of particulate, polymeric material has been applied to the layer of batt of fibres and thermally activated to provide a discontinuous layer containing a mixture of batt fibres and a polymer - baft fibre matrix.

Description

COMPOSITE PRESS FELT

The present invention relates to a press felt for use in the press section of a papermaking machine.

Paper is conventionally manufactured by conveying a paper furnish, usually consisting of an initial slurry of cellulosic fibres, on a forming fabric or between two forming fabrics in a forming section, the nascent sheet then being passed through a pressing section and ultimately through a drying section of a papermaking machine. In the case of standard tissue paper machines, the paper web is transferred from the press fabric to a Yankee dryer cylinder and then creped.

Papermachine clothing is essentially employed to carry the paper web through these various stages of the papermaking machine. In the forming section the fibrous furnish is wet-laid onto a moving forming wire and water is encouraged to drain from it by means of suction boxes and foils. The paper web is then transferred to a press fabric that conveys it through the pressing section, where it usually passes through a series of pressure nips formed by rotating cylindrical press rolls. Water is squeezed from the paper web and into the press fabric as the web and fabric pass through the nip together. In the final stage, the paper web is transferred either to a Yankee dryer, in the case of tissue paper manufacture, or to a set of dryer cylinders upon which, aided by the clamping action of the dryer fabric, the majority of the remaining water is evaporated.

A conventional press fabric comprises a batt of fibres needled to a base fabric. US 4,847,116 and US 4,571,359 relate to press fabrics in which a uniform layer of polymeric resin particles is applied to the surface of a woven textile base fabric. The resin particles are fused together to provide a porous elastic surface layer. A similar arrangement is described in EP 0653512A except in that a reinforcing structure, possibly a press felt, comprising a base cloth and a fibrous batt, is entirely embedded within the fused particulate material. These methods, involving sintering of fused particles, have limitations in practice as it is difficult to apply a large mass of particles of the required particle size, to a substrate and achieve controlled placement, porosity and application thickness.

US 4,772,504 describes a substantially impermeable press felt, provided with a layer of plastics material on the paper contacting surface to act as an anti-rewet layer.

US 6,017,583 relates to a process for the manufacture of a permeable strip material in which a plastics layer comprising soluble corpuscles is applied to a support and the soluble corpuscles are then leached out to provide through-flow passages. The plastics layer is initially applied as a powder and forms a planar outer surface plastic layer by heat and pressure treatment.

GB 2,200,687 describes the addition of additives to the needled batt layer of press felts in order to maximise the coated area between the press felt and the paper web. Such felts, when in use, are prone to rapid wear and a drastic reduction in felt porosity.

US 4,357,386 relates to a papermaker's press felt made up of a textile base layer, an intermediate layer of polymeric resin foam particles and a covering layer of non-woven staple fibres. The foam particles are included to improve wear and delamination, as well as to increase water removal capabilities. These particles, which are 0.3 to 2cm in diameter are not melted but are instead consolidated into the felt by needling.

EP 0987366A2 relates to a press felt in which a fibrous batt is needled to a woven base fabric. A substantially smooth and substantially uniformly porous layer is applied to the batt. This layer may comprise a woven fabric, a porous film sheet or a porous film obtained by heating a layer of at least partially fusible powder material.

According to the present invention there is provided a industrial fabric comprising layer(s) of batt of fibres optionally needle punched to a base cloth, characterised in that during manufacture of the fabric a dispersion of particulate, polymeric material has been applied to the layer and thermally activated to provide a discontinuous layer containing a mixture of batt fibres and a polymer-batt fibre matrix. Solid polymer particles being applied as a dispersion remain discrete so that the polymer/fiber matrix structure remains permeable while improving surface smoothness, wear resistance and compaction resistance.

According to the invention the discontinuous layer containing a mixture of batt fibres and a polymer-batt fibre matrix is not only creating the surface of the fabric but also extends vertically into the fabric. Therefore the discontinuous layer exists in the x,y and z direction within the batt structure.

Further the polymeric layer formed is discontinuous, what means that there is no continuous matrix layer formed embedding the batt fibres. It is to be understood that the polymeric material in the discontinuous layer wets and impregnates the batt material only partially thereby creating areas in the layer which are not occupied with said polymeric material. Preferably the polymeric material impregnates the fibres along the axes of the fibres.

The thermal activation may comprise, for example, heating or applying incident radiation.

The resin-batt fibre matrix would comprise batt material with "cells" of polymer adhered to the surrounding fibres.

The industrial fabric according to the invention preferably is a paper machine clothing, whereby the paper machine clothing can be a forming fabric, a press felt, a dryer fabric or the like.

The industrial fabric can have a woven or an non-woven base cloth which is linked with the batt fibres.

It has been discovered that a significant impact on the fibre web structure can be realised using this technology with relatively small quantities of particles preferably in the range from 0,1% to 20% weight add on, most preferably in the range from 1% to 5% weight add on. This is important in providing process consistency, and is also much more cost effective than prior art methods. Multiple applications using relatively small amounts of particulate material in each pass, may be used to provide uniformity of surface.

To increase the performance in dynamic properties of the industrial fabric and to increase the durability of the industrial fabric the particulate polymeric material preferably can comprise thermoplastic elastomer particles. The resiliency and the wear resistance of the material is an important consideration. Elastomeric polyurethane is having excellent wear resistance and resiliency.

Surprisingly, the industrial fabric of the invention exhibits excellent resiliency, a smoother more planar surface and excellent abrasion resistance. Further the industrial fabric according to the invention is much easier to clean compared to fabrics known in the art.

Due to the discontinuous cellular structure of the added polymer, permeability and porosity remain high depending on the total solid add-on on a given substrate structure.

In the case that the industrial fabric is a paper machine clothing the fabric according to the invention further has an enhanced performance in sheet dewatering and rewet reduction.

In the case that the industrial fabric according to the invention is a press felt a enhanced uniform pressing interface for the paper web is achieved, particularly when under pressure, for example at a press nip.

The paper machine clothing according to the invention further exhibits excellent wear resistance, pressure uniformity, and air and water permeability.

The industrial fabric in accordance with the invention further exhibits excellent batt fibre bonding.

The industrial fabric may be made by depositing particles of polymeric material, optionally in combination with one or more binding agents, viscosity modifiers, anti-settling agents and/or wetting agents, into the fibrous fabric surface. The water is removed whilst the binder holds the particles in position. The modified surface is then heated in order to soften the particulate matter, whereupon the particulate material undergoes at least partial flow and fuses to itself as well as to the batt fibres and any matter in the vicinity. The resulting partially fused surface layer may then be calendered. E.g. in the case of an elastomeric polyurethane, the particles will thermally bond to each other and flow along the fibre axes thereby bonding the adjacent fibres. Consequently flow channels and porosity are maintained in the press felt structure and on its surface. Therefore the industrial fabric according to the invention surprisingly has approximately the same permeability as the fabric before applying the discontinuous layer.

The particles are ideally supplied as a suspension in a liquid, preferably water. The polymeric dispersion can be applied by a kiss roll or as a foam in which case a foaming agent is included in the formulation or by a precast thermoset film. Blade coating/spray techniques or electrostatic technique may also be used.

According to a second aspect of the present invention there is provided a method of making a industrial fabric in which a dispersion of particulate, polymeric material is applied to a batt of fibres, the batt being optionally needled to a base cloth, the particulate material then being thermally activated to bond the particulate material to the fibres and provide layer containing polymeric material and fibres.

According to a preferred embodiment of the method a discontinuous layer is formed containing a mixture of batt fibres and a polymer-batt fibre matrix. According to another embodiment of the method a continuous polymer- batt fibre matrix layer is formed.

The method of the invention may be used to introduce any particulate (organic and/or inorganic) matter to a industrial fabric. Organic and/or inorganic matter could be mono/poly dispersed in the particulate matter, as could micro-fibres, bicomponent and/or splittable fibres, carbon fibres, nano-particles, alloys or blends of polymeric materials, and/or hollow micro-spheres. The polymeric material may be thermoplastic or thermoset. Multiple particle sizes and/or multiple types of particles having different hardnesses and melting points may be used to create unique surface and drainage effects. Additional micro-fibres are preferably added to the particulate material in that they aid bonding and they give the structure multi-directional strength and so reinforce the structure by enabling the layers of particulate matter to become more securely bonded to one another and to the batt fibres. The micro-fibres may be selected to have complex surface striations/morphology and may have a selected material property so as to facilitate wicking of moisture away from the paper web. This might also be achieved with a surface network or with micro-particles. Inorganic materials may be useful for static control and in providing sensor triggers for on-machine monitoring devices. Very hard or conductive inorganic particles, or time release capsules (such as are described in US 4,569,883) with surfactants or tracer material, etc. can be added utilising this technology.

The polymeric material preferably can comprise thermoplastic elastomers e.g. polyurethane (TPU). These particles will disperse and penetrate into the batt structure depending on the selected batt fineness and stratification, particle sizes and concentration, dispersion viscosity, temperature, use of vacuum, etc.. To form a porous structure (discontinuous layer) from 0,1 to 20% weight add on of polymeric material is preferably applied. Most preferably from 1% to 5% weight add on of polymeric material is applied. This is insufficient to form a continuous sheet layer. We would estimate that more than 20% weight add on would be required to form a continuous layer e.g. for a belt.

The diameter of the particles of the polymeric material is preferably in the range from 0,1 to 600 microns, most preferably in the range from 1 to 300 microns and ideally in the range from 20 to 150 microns.

The dispersion ideally comprises at least one binder to hold the particles in place on a given substrate e.g. the batt fibres of the fabric.

Bonding to the batt fibres is achieved via the binder system. The binder could be in liquid or solid form. The binder might be a permanent chemical adhesive. The binder is preferably included in an amount of 0,05% to 2%, most preferably 0.1 - 0.5% based on the dispersion volume. If the binder is in particulate form, then its melting point should be lower than that of the other particles and of the, typically polyamide, batt fibre. Preferred binders include any of the following either alone or in combination:- co-polyamides, co-polyesters, PVA's, PU's and nitrile latex rubbers.

The particulate dispersion ideally comprises at least one viscosity modifier to suit processing methods and equipment. Preferred viscosity modifiers include any of the following either alone or in combination:- Neutonian, Pseudo-plastic and/or strongly pseudo plastic types, based on PU, acrylic or PA's for water-borne systems. Guar and natural gums can also be used. The viscosity modifier is preferably included in an amount of 0,05% to 5%, most preferably 0,1% to 2% based on the dispersion volume. The particulate dispersion may include one or more anti-settling agents. Typical water soluble anit-settling agents are polyamides, polyacrylates and polyurethanes. The particulate dispersion preferably comprises from 0,1 - 2% of anti-settling agent and, more preferably from 0,2 -0,25% based on the dispersion volume.

The particulate dispersion may also include one or more wetting agents. Typical wetting agents include surfactants, ethoxylated ethers. The wetting agent is added in order to improve the wetting of the particles by lowering the surface tension. The particulate dispersion preferably comprises from 0,05% to 2% of wetting agent and, more preferably from 0,05 -0,25% based on the dispersion volume.

All of the components described above are selected such that the overall system is compatible with the relevant substrate.

Typically, any type of endless or seamed base can be used as the substrate. Alternatively, it may be the case that the combination of the binding particles and the polyamide nonwoven fibres alone may provide sufficient strength and stability, so that a standard textile type base can be omitted. The surface structure is preferably needle punched fibrous non- woven, but could be any other non-woven as well such as point bonded, spun bonded, etc.

Particles bonded to the surface of typically round fibres and yarns may provide surprising influences on improving or controlling water or air flow and/or sheet release at extremely high speeds anticipated for newer generation of paper machines.

In a preferred embodiment of the invention a complex, unique composite matrix is created using a relatively coarse nonwoven staple fibre. These fibres are bonded together using polymeric particles for increased long- term resiliency and also improved fibre bonding and strength. Nearer the surface an application of finer, perhaps harder particles can be made, interbonded with each other, the polyamide fibres and the interior particles to form a resilient interconnected network with a high degree of overall uniformity on the pressing surface, while still providing excellent porosity for sheet dewatering, and a far tougher surface, immune to fibre shedding than is achievable with fine diameter staple fibres.

Application of the dispersion could also be on the interior roll side surface as well to make the fabric tough and resist high degree of inside wear for certain applications.

In order that the present invention may be more readily understood, specific embodiments will now be described with reference to the accompanying representations in which:-

Fig. 1 is an SEM of the surface of one press felt in accordance with the invention at 10X magnification; and

Fig. 2 is an SEM of the same surface at 20X magnification.

Example 1

A press felt was manufactured by needling a batt of polyamide fibres to a woven base cloth.

A particulate dispersion was prepared, the constituents of which are listed below. - 9 g/l - viscosity modifier

- 5 g/l - binder

- 78.75 g/l - polyurethane particles (20-150 microns in diameter)

- water

The viscosity modifier, binder and polyurethane particles were added to the water to provide the particulate dispersion. The dispersion was then applied by a kiss roll method. This was applied in multiple revolutions, leading to uniformity of the particulate matter within the felt/batt fibre surface. The treated fabric was then dried for example by hot air or infra- red radiation.

The treated fabric was then heated to the softening temperature of the polyurethane particles. Whilst the particulate material is in a quasi-molten state, the fabric surface was compacted using a compaction roll which pushed the material in to the interstices within the batt, whilst also smoothing the fabric surface. This results in a porous, composite with high resiliency and a smooth surface.

Tests have proven that the press fabric made in this way provides increased smoothness in the nip, thus reducing the possibility of marking of the paper web.

In the following examples a press felt was treated in like manner to Example 1. Example 2

Dispersion formulation

- 1g/l - wetting agent

- 10Og/l - polyurethane particles (50-150 microns in diameter)

- 2,4g/l - anti settling agent 1

- 1 ,6g/l - anti settling agent 2

- 5g/l - viscosity modifier 1

- 2g/l - viscosity modifier 2

- 2.5g/l - binder

- water

The above were all applied using a kiss roll applicator.

The photographs of Figs. 1 and 2 show that the particulate material is melted (and not sintered) and is present as a non-continuous treatment.

The melted thermoplastic material fills the interstices between the batt fibres, whilst fusing around the batt. The treatment fills the undulations in the batt to give a smoother and more planar surface, after calendering, which does not close down the permeability of the fabric.

It is to be understood that the above described examples may be subject to various modifications.

Claims

Patent Claims

1. Industrial fabric comprising a layer of batt of fibres optionally needled to a base cloth, cha racte rized i n , that during manufacture of the fabric a dispersion of particulate, polymeric material has been applied to the layer of batt of fibres and thermally activated to provide a discontinuous layer containing a mixture of batt fibres and a polymer - batt fibre matrix.

2. Industrial fabric according to claim 1 , ch a ra cte ri zed i n , that the discontinuous layer exists in x,y and z direction within the batt structure.

3. Industrial fabric according to one of the preceding claims, cha ra cte rized i n , that the fabric with the discontinuous layer substantially has the same permeability as the fabric before applying the discontinuous layer.

4. Industrial fabric according to one of the preceding claims, cha ra cte rized in , that the discontinuous layer further comprises organic and / or inorganic matter.

5. Industrial fabric according to one of the preceding claims, c h a ra cte ri zed i n , that at least one of the organic and / or inorganic matter is in the form of micro-fibres or micro particles or nano-particles or alloy or blend.

6. Industrial fabric according to one of the preceding claims, c h a ra cte ri zed i n , that at least two of the organic and / or inorganic matters having different particle sizes and / or different melting points and / or different hardnesses.

7. Industrial fabric according to one of the preceding claims, c h a ra cte ri zed i n , that the thermal activation comprises heating and / or applying incident irradiation.

8. Industrial fabric according to claim 7, c h a ra cte ri zed i n , that the thermal activation affects a chemical reaction and / or a phase change.

9. Industrial fabric according to one of the preceding claims, ch a ra cte rized i n , that the particulate polymeric material comprises thermoplastic and / or thermoset particles.

10. Industrial fabric according to one of the preceding claims, c h a ra cte rized i n , that thermoplastic particles are thermoplastic elastomer particles, preferably elatomeric polyurethane.

11. Industrial fabric according to one of the preceding claims, ch a ra cte ri ze d i n , that the industrial fabric is a paper machine clothing, preferably a forming fabric or a press felt or a dryer fabric.

12. Method of making a industrial fabric comprising the following steps:

- applying a dispersion of particulate polymeric material to a batt of fibres, whereby the batt being optionally needled to a base cloth,

- thermally activating the dispersion of particulate polymeric material to bond the particulate material to the fibres and to provide a layer.

13. Method according to claim 12, ch a ra cte ri zed i n , that the layer is a continuous polymer - batt fibre matrix layer.

14. Method according to claim 13, ch a ra cte ri zed i n , that more than 20% weight add on of polymeric material is applied.

15. Method according to claim 12, ch a ra cte rized in , that the layer is a discontinuous layer containing a mixture of batt fibres and a polymer - batt fibre matrix.

16. Method according to claim 15, ch a ra cte ri zed i n , that 0,1% to 20% weight add on, preferably 1% to 5% weight add on of polymeric material is applied.

17. Method according to one of the preceding claims, ch a ra cteri ze d i n , that the diameter of the polymeric particles applied is in the range from 0,1 to 600 microns, preferably in the range from 1 to 300 microns and ideally in the range from 20 to 150 microns.

18. Method according to one of the preceding claims, ch a ra cteri zed i n , that the dispersion comprises at least one binder in liquid and / or solid form.

19. Method according to claim 18, ch a ra cteri ze d i n , that binder includes any of the following either alone or in combination:- co-polyamides, co-polyesters, PVA's, PU's and nitrile latex rubbers.

20. Method according to claim 18 or 19, ch a ra cte ri zed i n , that the binder is included in an amount of 0,05% to 2%, preferably in an amount of 0,1% to 0,5% based on the dispersion volume.

21. Method according to one of the preceding claims, cha ra cterized i n , that the dispersion comprises at least one viscosity modifier.

22. Method according to claim 21 , ch a ra cte ri ze d i n , that the viscosity modifier includes any of the following either alone or in combination:- Neutonian, Pseudo-plastic and/or strongly pseudo plastic types, based on PU, acrylic or PA's for water-borne systems, guar or natural gums.

23. Method according to claim 21 or 22, ch a ra cte ri zed i n , that the viscosity modifier is included in an amount of 0,05% to 5%, preferably 0,1 % to 2%, based on the dispersion volume.

24. Method according to one of the preceding claims, ch a ra cterized i n , that the dispersion comprises at least one anti-settling agent.

25. Method according to claim 24, c h a ra cte rize d i n , that the anti-settling agent is water soluble and comprises polyamide and / or polyacrylate ans / or polyurethane.

26. Method according to claim 25, ch a ra cte rized i n , that the anti- settling agent is included in an amount of 0,1 % to 2%, preferably 0,2% to 0,25%, based on the dispersion volume.

27. Method according to one of the preceding claims, ch a ra cte rize d i n , that the dispersion comprises at least one wetting agent.

28. Method according to claim 27, ch a ra cte ri zed i n , that the wetting agent includes at lest one of: surfactants, ethoxylated ether.

29. Method according to claim 27 or 28, ch a ra cte rized i n , that the wetting agent is included in an amount of 0,05% to 2%, preferably 0,05% to 0,25%, based on the dispersion volume.

30. Method according to one of the preceding claims, cha ra cterized i n , that after the thermal activation the fabric is calendered.