WO2005073659A1 - Brazed plate fin heat exchanger - Google Patents
Brazed plate fin heat exchanger Download PDFInfo
- Publication number
- WO2005073659A1 WO2005073659A1 PCT/US2005/001550 US2005001550W WO2005073659A1 WO 2005073659 A1 WO2005073659 A1 WO 2005073659A1 US 2005001550 W US2005001550 W US 2005001550W WO 2005073659 A1 WO2005073659 A1 WO 2005073659A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- heat exchanger
- tube
- fin
- plate fin
- collar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
- F28F21/081—Heat exchange elements made from metals or metal alloys
- F28F21/084—Heat exchange elements made from metals or metal alloys from aluminium or aluminium alloys
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/12—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
- F28F1/24—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending transversely
- F28F1/32—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending transversely the means having portions engaging further tubular elements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
- F28F21/081—Heat exchange elements made from metals or metal alloys
- F28F21/085—Heat exchange elements made from metals or metal alloys from copper or copper alloys
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2275/00—Fastening; Joining
- F28F2275/04—Fastening; Joining by brazing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2275/00—Fastening; Joining
- F28F2275/12—Fastening; Joining by methods involving deformation of the elements
- F28F2275/125—Fastening; Joining by methods involving deformation of the elements by bringing elements together and expanding
Definitions
- This invention is directed to heat exchanger fin collars, and more particularly to an improved fin collar for use in a brazed plate fin heat exchanger.
- Plate fin and tube heat exchangers are used in a wide variety of applications including, but not limited to, air conditioning and refrigeration where it is desired to exchange heat between two fluids, usually a pure liquid or a liquid undergoing a phase change to or from a gas, flowing in the heat exchanger tubes and a gas, usually air, flowing around the heat exchanger plate fins and tube exteriors.
- a plurality of thin plate fins are arranged parallel to each other between two tube sheets.
- Heat exchanger tubes pass through holes in the tube sheets and plate fins. There is a firm fit between the tubes and the plate fins so that the effective surface area, and thus the heat transfer area, of the heat exchanger tubes is increased by the area of the plate fins.
- a plate fin and tube heat exchanger offers improved heat transfer performance over a plain tube type heat exchanger of the same size.
- a common method of manufacturing this type of heat exchanger is to first assemble a plurality of plate fins between two tube sheets, then lace a plurality of hair pin tubes through selected holes in the plate fins and similar holes in each of the tube sheets. Next, bells are formed in the end of hairpin tubes, then the legs of the tubes are expanded to insure a tight mechanical fit between the tubes and plate fins.
- a brazed plate fin heat exchanger with an improved braze joint at the tube-to-fin joint .
- the present invention meets the above-described need by providing a fin collar having a shape that enhances flux application and brazing clad flow into the tube-to- fin joint to provide an improved thermal and structural bond.
- Figure 1 is a perspective view of a plate fin heat exchanger of the present invention
- Figure 2 is a perspective view of a tube of the present invention disposed through several plate fins
- Figure 3 is a perspective view of a fin collar of the present invention
- Figure 4 is a perspective view of an alternate embodiment of the fin collar of the present invention
- Figure 5 is a perspective view of another alternate embodiment of the fin collar of the present invention
- Figure 6 is a perspective view of the fin collar of the present invention shown with a representation of the air flow over the collar
- Figure 7 is a top plan view of the fin collar of Figure 6.
- Fig. 1 depicts a plate fin and tube heat exchanger 10 containing plate fins 12 that embody the present invention.
- Each plate fin has a plurality of holes 16.
- a common method of manufacturing heat exchanger 10 is to first assemble a plurality of plate fins 12 between two tube sheets 18, then lace a plurality of hairpin tubes 20 through selected holes 16 in the plate fins 12 and similar holes 16 in each of tube sheets 18.
- the heat exchanger assembly is completed by fitting up a plurality of return bends 22 to the ends of hairpin tubes 20 so as to form one or more closed fluid flow paths through the tubes of the heat exchanger.
- a first fluid such as a refrigerant
- a second fluid such as air
- a first fluid flows through heat exchanger 10 via a fluid flow path or paths defined by interconnected hairpin tubes 20 and return bends 22.
- a second fluid such as air
- a first fluid flows through heat exchanger 10 via a fluid flow path or paths defined by interconnected hairpin tubes 20 and return bends 22.
- a second fluid such as air
- a first fluid flows through heat exchanger 10 via a fluid flow path or paths defined by interconnected hairpin tubes 20 and return bends 22.
- a second fluid such as air
- a second fluid flows over and around plate fins 12 and tubes 20. If there is a temperature differential between the two fluids, then heat transfer from the warmer to the cooler of the two takes place through the tube walls and plate fins.
- a single tube 20 is shown disposed through a plurality of plate fins 12.
- Each plate fin 12 is provided with an upstanding fin collar 30 disposed around the openings 16. As shown, the collar 30 may be curved so
- the number of plate fins 12 that can be placed around the tube 20 is determined by the height of the collar 30.
- the tube 20 to fin 12 joint is brazed in a controlled atmosphere braze furnace.
- the brazing temperatures will range between 1070°F and 1120°F depending on the clad used.
- the tube 20 may be constructed of an aluminum alloy that is clad or unclad.
- the tube 20 may be roll formed with a welded seam or a lock seam.
- the tube 20 may be extruded.
- the tube 20 may have a wall thickness of 0.016" to 0.05" depending on the tube diameter and the working pressure.
- the tube 20 may have a cross-sectional shape that is round, circular, oval, or the like.
- the tube material is a long life, high strength, corrosion resistant alloy.
- a 3003 aluminum alloy may be used.
- an Alcan X-1000 may be used.
- the clad alloys may be 4045 or 4343 aluminum alloys.
- the fins 12 and fin collar 30 may be constructed out of an aluminum alloy 3003 with a 4045 or 4343 alloy clad. If unclad, the fin may be constructed from an 1100 aluminum alloy.
- the fins may be constructed with a thickness of 0.003" to 0.016".
- the present invention may be used for brazing a copper fin to copper tubing or brazing an aluminum fin to copper tubing, as will be evident to those of ordinary skill in the art. In Fig.
- a first embodiment of the fin collar 30 of the present invention is shown.
- a plurality of slits 32 are disposed around the circumference of the fin collar 30.
- the slits 32 may be formed by removing material from the collar and may be disposed equidistantly around the perimeter of the collar 30.
- the slit may extend from the top 43 of the collar 30 and terminate at a point approximately 0.02" from the underside of the fin.
- the slit 32 is defined by a pair of opposed walls 34 and 36.
- the walls 34 and 36 may be angled such that the width 40 across the slit 32 gradually increases from the bottom 42 of the slit 32 to the top 43 of the collar 30.
- the slit 32 may range from 0.015" to 0.15" in width depending on the collar height and the number of slits.
- the slits 32 improve the tube- to-fin joint both thermally and structurally.
- the fin collar 30 of the present invention enhances the flux application and the brazing clad flow because the slits 32 allow the cladding to flow through on both sides of the collar 30.
- the split fin collar 30 increases heat transfer between the air and tube surfaces.
- the slits 32 open access to a portion of the surface of the primary tube 20 for the air flow allowing direct heat transfer from air to the tube 20 without the resistance from secondary sources. Ordinarily these portions of the primary tube 20 would be covered by a solid fin collar.
- Fin collar 40 has a rectangular-shaped slit 42.
- the slit 42 is defined by a bottom wall 44 and opposed side walls 46 and 48.
- the bottom wall 44 may extend to a point approximately 0.02" from the underside of the fin 12.
- the collars 40 may have a curvature such that they have a convex shape on the side that faces the tubes 20.
- Fin collar 60 is elongated in the longitudinal (tube axis) direction.
- the collar 60 has a plurality of slits 62 defined therein.
- the slits 62 also have a rectangular shape and are defined by a bottom wall 64 and a pair of opposed side walls 66, 68.
- the bottom wall 64 may extend to a point approximately 0.02" from the underside of the fin 12.
- arrows 70 representing air flow around the collar 30 during use.
- the shape of the fin collar 30 provides interruptions around the circumference of the fin collar 30 perpendicular to air flow. The interruptions will provide turbulence, which is indicated by curved lines 80, in the boundary layer of air along the fin collar 30 which will increase the rate of heat transfer between the air and the tube 20.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Geometry (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Details Of Heat-Exchange And Heat-Transfer (AREA)
Abstract
Description
Claims
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05705853A EP1714100B1 (en) | 2004-01-20 | 2005-01-13 | Method of forming a brazed plate fin heat exchanger |
| CN200580005954.0A CN1961192B (en) | 2004-01-20 | 2005-01-13 | Brazed radiating fin heat exchanger |
| JP2006551197A JP5296990B2 (en) | 2004-01-20 | 2005-01-13 | Brazed plate fin heat exchanger |
| AT05705853T ATE556285T1 (en) | 2004-01-20 | 2005-01-13 | METHOD FOR MAKING A BRAZED FIN TUBE HEAT EXCHANGER |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/761,448 US20050155750A1 (en) | 2004-01-20 | 2004-01-20 | Brazed plate fin heat exchanger |
| US10/761,448 | 2004-01-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2005073659A1 true WO2005073659A1 (en) | 2005-08-11 |
Family
ID=34750171
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2005/001550 Ceased WO2005073659A1 (en) | 2004-01-20 | 2005-01-13 | Brazed plate fin heat exchanger |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US20050155750A1 (en) |
| EP (1) | EP1714100B1 (en) |
| JP (1) | JP5296990B2 (en) |
| CN (1) | CN1961192B (en) |
| AT (1) | ATE556285T1 (en) |
| WO (1) | WO2005073659A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2185900A1 (en) * | 2007-08-29 | 2010-05-19 | Micro Motion, Inc. | Brace bar with tabbed apertures for brazing to a flow tube |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2299300B1 (en) * | 2005-08-01 | 2009-04-16 | Jose Maria Vergara Uranga | HEAT EXCHANGER MANUFACTURED IN COPPER AND BRASS ALLOYS OF VERY HIGH TEMPERATURE OF RECOGNITION AND HIGH HARDNESS RESISTANT TO HIGH INTERNAL PRESSURES. |
| TWI320300B (en) * | 2005-11-18 | 2010-02-01 | Dissipating heat device of fin-type | |
| USD566824S1 (en) * | 2006-03-20 | 2008-04-15 | Ishikawajima-Harima Heavy Industries Co., Ltd. | Plate fin for a heat exchanger |
| EP1890101B1 (en) * | 2006-08-08 | 2009-10-28 | Behr GmbH & Co. KG | Fin for heat exchanger, heat exchanger with such a fin and method for producing the heat exchanger |
| US8152047B2 (en) * | 2007-04-16 | 2012-04-10 | Luvata Franklin, Inc. | Method of producing a corrosion resistant aluminum heat exchanger |
| US20100212868A1 (en) * | 2008-02-15 | 2010-08-26 | Yang Chien-Lung | Assembled configuration of cooling fins and heat pipes |
| US20090218073A1 (en) * | 2008-02-28 | 2009-09-03 | Asia Vital Components Co., Ltd. | Cooling fin |
| US8037699B2 (en) | 2008-04-24 | 2011-10-18 | Mitsubishi Electric Corporation | Heat exchanger and air conditioner using the same |
| CN101850501A (en) * | 2009-04-01 | 2010-10-06 | 富准精密工业(深圳)有限公司 | Radiator and method of manufacturing the same |
| CN102116586B (en) * | 2009-12-30 | 2013-11-06 | 富准精密工业(深圳)有限公司 | Heat dissipating device |
| ES2744883T3 (en) * | 2010-07-26 | 2020-02-26 | Carrier Corp | Aluminum fin and tube heat exchanger |
| JP2012202560A (en) * | 2011-03-23 | 2012-10-22 | Sanwa Thermotech Co Ltd | Heat exchanger and method of manufacturing the same |
| JP5511778B2 (en) * | 2011-12-16 | 2014-06-04 | 株式会社デンソー | Manufacturing method of heat exchanger, and heat exchanger manufactured by the manufacturing method |
| US20150075760A1 (en) * | 2012-04-12 | 2015-03-19 | Carrier Corporation | Aluminum alloy tube-fin heat exchanger |
| US9154008B2 (en) * | 2012-10-02 | 2015-10-06 | Siemens Industry, Inc. | Hybrid rotor bar assemblies, electric motors including hybrid rotor bar assemblies, and methods of assemblying same |
| US10006662B2 (en) * | 2013-01-21 | 2018-06-26 | Carrier Corporation | Condensing heat exchanger fins with enhanced airflow |
| KR20140094126A (en) * | 2013-01-21 | 2014-07-30 | 엘지전자 주식회사 | A heat exchanger and a method for manufacturing the same |
| US20140262188A1 (en) * | 2013-03-15 | 2014-09-18 | Ramana Venkato Rao Sistla | Fin Spacing On An Evaporative Atmospheric Water Condenser |
| JP2013238610A (en) * | 2013-07-16 | 2013-11-28 | Micro Motion Inc | Flow tube assembly and method for forming the same |
| JP5752199B2 (en) * | 2013-09-13 | 2015-07-22 | 株式会社Uacj | Refrigerator refrigerator heat exchanger |
| KR20150053135A (en) * | 2013-11-07 | 2015-05-15 | 엘지전자 주식회사 | Heat exchanger and Manufacturing method fo the same |
| KR101550212B1 (en) * | 2014-04-24 | 2015-09-07 | (주)한국이에스테크 | Fin and tube heat exchanger with enamel layer |
| WO2015178684A1 (en) * | 2014-05-20 | 2015-11-26 | 조한용 | Fin tube heat exchanger having shrink ring and manufacturing method therefor |
| CN109219723A (en) * | 2016-06-07 | 2019-01-15 | 三菱电机株式会社 | The outdoor unit of air-conditioning device |
| US12070756B2 (en) | 2016-06-30 | 2024-08-27 | Adey Holdings (2008) Limited | Magnetic rod guide for a filter |
| GB2551830B (en) | 2016-06-30 | 2020-09-23 | Adey Holdings 2008 Ltd | Magnetic rod guide for a filter |
| WO2018139162A1 (en) * | 2017-01-24 | 2018-08-02 | 三菱電機株式会社 | Heat exchanger |
| CN107401861A (en) * | 2017-08-17 | 2017-11-28 | 河南科隆集团有限公司 | A kind of evaporator fin and its manufacture method |
| WO2019062493A1 (en) * | 2017-09-30 | 2019-04-04 | 杭州三花微通道换热器有限公司 | Heat exchanger and fin |
| JP2020076531A (en) * | 2018-11-07 | 2020-05-21 | ダイキン工業株式会社 | Heat exchanger and air conditioner including the same |
| JP6888697B2 (en) * | 2020-01-22 | 2021-06-16 | ダイキン工業株式会社 | How to make a heat exchanger |
| KR102793502B1 (en) * | 2021-12-28 | 2025-04-14 | 주식회사 경동나비엔 | Fin and heat exchanger including the same |
| WO2023113362A1 (en) * | 2021-12-14 | 2023-06-22 | 주식회사 경동나비엔 | Fins and heat exchanger comprising same |
| KR102793501B1 (en) * | 2021-12-14 | 2025-04-14 | 주식회사 경동나비엔 | Fin and heat exchanger including the same |
| DE202022105382U1 (en) | 2022-09-26 | 2022-10-05 | Dipak Debbarma | Heat sink with microchannels |
| JP7464872B1 (en) | 2022-09-30 | 2024-04-10 | ダイキン工業株式会社 | Heat exchanger |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5396556A (en) * | 1977-02-02 | 1978-08-23 | Hitachi Ltd | Cooling fin |
| GB2110811A (en) * | 1981-11-28 | 1983-06-22 | Salter & Co Ltd G | Finned tube heat exchanger members |
| JPH02154992A (en) * | 1988-12-05 | 1990-06-14 | Sumitomo Light Metal Ind Ltd | Heat exchanger employing flat tube |
| US5117905A (en) * | 1987-08-29 | 1992-06-02 | Sueddeutsche Kuehlerfabrik Julius Fr. Behr Gmbh & Co. Kg | Heat exchanger with fins |
| JP2003161589A (en) * | 2001-11-21 | 2003-06-06 | Toyo Radiator Co Ltd | Air conditioning plate fin type heat exchanger |
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| US1634110A (en) * | 1926-03-17 | 1927-06-28 | Wolverine Tube Company | Radiating device |
| US2089340A (en) * | 1932-01-19 | 1937-08-10 | Moore Dry Kiln Co | Extended fin surface for conduits |
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| US3190353A (en) * | 1962-05-22 | 1965-06-22 | Storfer Robert | Heat transfer fin |
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| US4449581A (en) * | 1982-08-30 | 1984-05-22 | Chromalloy American Corporation | Heat exchanger fin element with dog-bone type pattern of corrugations |
| JPH02217158A (en) * | 1988-10-28 | 1990-08-29 | Showa Alum Corp | Heat exchanger |
| US4949543A (en) * | 1989-09-12 | 1990-08-21 | Modine Manufacturing Company | Tube and fin assembly for heat exchangers in power plants |
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| US5111876A (en) * | 1991-10-31 | 1992-05-12 | Carrier Corporation | Heat exchanger plate fin |
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| US5582246A (en) * | 1995-02-17 | 1996-12-10 | Heat Pipe Technology, Inc. | Finned tube heat exchanger with secondary star fins and method for its production |
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| US6178292B1 (en) * | 1997-02-06 | 2001-01-23 | Denso Corporation | Core unit of heat exchanger having electric heater |
| US5956846A (en) * | 1997-03-21 | 1999-09-28 | Livernois Research & Development Co. | Method and apparatus for controlled atmosphere brazing of unwelded tubes |
| JPH10318695A (en) * | 1997-05-19 | 1998-12-04 | Zexel Corp | Heat exchanger |
| JP3823584B2 (en) * | 1999-02-15 | 2006-09-20 | 日産自動車株式会社 | Heat exchanger |
| US6266882B1 (en) * | 1999-05-20 | 2001-07-31 | Carrier Corporation | Fin collar and method of manufacturing |
| CA2434826C (en) * | 2001-01-16 | 2011-03-29 | Pechiney Rhenalu | Brazing sheet and method |
| US6644394B1 (en) * | 2002-06-25 | 2003-11-11 | Brazeway, Inc. | Braze alloy flow-barrier |
-
2004
- 2004-01-20 US US10/761,448 patent/US20050155750A1/en not_active Abandoned
-
2005
- 2005-01-13 AT AT05705853T patent/ATE556285T1/en active
- 2005-01-13 EP EP05705853A patent/EP1714100B1/en not_active Expired - Lifetime
- 2005-01-13 CN CN200580005954.0A patent/CN1961192B/en not_active Expired - Fee Related
- 2005-01-13 WO PCT/US2005/001550 patent/WO2005073659A1/en not_active Ceased
- 2005-01-13 JP JP2006551197A patent/JP5296990B2/en not_active Expired - Fee Related
-
2007
- 2007-02-06 US US11/702,793 patent/US20070163767A1/en not_active Abandoned
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5396556A (en) * | 1977-02-02 | 1978-08-23 | Hitachi Ltd | Cooling fin |
| GB2110811A (en) * | 1981-11-28 | 1983-06-22 | Salter & Co Ltd G | Finned tube heat exchanger members |
| US5117905A (en) * | 1987-08-29 | 1992-06-02 | Sueddeutsche Kuehlerfabrik Julius Fr. Behr Gmbh & Co. Kg | Heat exchanger with fins |
| JPH02154992A (en) * | 1988-12-05 | 1990-06-14 | Sumitomo Light Metal Ind Ltd | Heat exchanger employing flat tube |
| JP2003161589A (en) * | 2001-11-21 | 2003-06-06 | Toyo Radiator Co Ltd | Air conditioning plate fin type heat exchanger |
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| Title |
|---|
| PATENT ABSTRACTS OF JAPAN vol. 002, no. 128 (M - 037) 26 October 1978 (1978-10-26) * |
| PATENT ABSTRACTS OF JAPAN vol. 014, no. 404 (M - 1018) 31 August 1990 (1990-08-31) * |
| PATENT ABSTRACTS OF JAPAN vol. 2003, no. 10 8 October 2003 (2003-10-08) * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2185900A1 (en) * | 2007-08-29 | 2010-05-19 | Micro Motion, Inc. | Brace bar with tabbed apertures for brazing to a flow tube |
Also Published As
| Publication number | Publication date |
|---|---|
| US20070163767A1 (en) | 2007-07-19 |
| CN1961192A (en) | 2007-05-09 |
| ATE556285T1 (en) | 2012-05-15 |
| EP1714100B1 (en) | 2012-05-02 |
| JP5296990B2 (en) | 2013-09-25 |
| US20050155750A1 (en) | 2005-07-21 |
| CN1961192B (en) | 2013-01-09 |
| EP1714100A1 (en) | 2006-10-25 |
| JP2007518962A (en) | 2007-07-12 |
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