WO2006003930A1 - 発光装置並びにそれを用いた照明、ディスプレイ用バックライト及びディスプレイ - Google Patents
発光装置並びにそれを用いた照明、ディスプレイ用バックライト及びディスプレイ Download PDFInfo
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- WO2006003930A1 WO2006003930A1 PCT/JP2005/011939 JP2005011939W WO2006003930A1 WO 2006003930 A1 WO2006003930 A1 WO 2006003930A1 JP 2005011939 W JP2005011939 W JP 2005011939W WO 2006003930 A1 WO2006003930 A1 WO 2006003930A1
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- light emitting
- light
- emitted
- emitting unit
- emitting device
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Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/85—Packages
- H10H20/851—Wavelength conversion means
- H10H20/8511—Wavelength conversion means characterised by their material, e.g. binder
- H10H20/8512—Wavelength conversion materials
- H10H20/8513—Wavelength conversion materials having two or more wavelength conversion materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/85—Packages
- H10H20/852—Encapsulations
- H10H20/853—Encapsulations characterised by their shape
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/1336—Illuminating devices
- G02F1/133602—Direct backlight
- G02F1/133603—Direct backlight with LEDs
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/1336—Illuminating devices
- G02F1/133617—Illumination with ultraviolet light; Luminescent elements or materials associated to the cell
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/85—Packages
- H10H20/855—Optical field-shaping means, e.g. lenses
- H10H20/856—Reflecting means
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W72/00—Interconnections or connectors in packages
- H10W72/071—Connecting or disconnecting
- H10W72/075—Connecting or disconnecting of bond wires
- H10W72/07551—Connecting or disconnecting of bond wires characterised by changes in properties of the bond wires during the connecting
- H10W72/07554—Connecting or disconnecting of bond wires characterised by changes in properties of the bond wires during the connecting changes in dispositions
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W72/00—Interconnections or connectors in packages
- H10W72/50—Bond wires
- H10W72/541—Dispositions of bond wires
- H10W72/547—Dispositions of multiple bond wires
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W72/00—Interconnections or connectors in packages
- H10W72/50—Bond wires
- H10W72/551—Materials of bond wires
- H10W72/552—Materials of bond wires comprising metals or metalloids, e.g. silver
- H10W72/5522—Materials of bond wires comprising metals or metalloids, e.g. silver comprising gold [Au]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W72/00—Interconnections or connectors in packages
- H10W72/851—Dispositions of multiple connectors or interconnections
- H10W72/874—On different surfaces
- H10W72/884—Die-attach connectors and bond wires
Definitions
- the present invention relates to a light emitting device, and illumination, a backlight for display, and a display using the light emitting device.
- cold cathode fluorescent lamps and the like have been used as light sources such as lighting and backlights for liquid crystal displays.
- a pseudo-white light source that combines a light source that emits blue light and a substance that absorbs blue light and emits yellow light has been developed as an alternative light source.
- an InGaN light emitting diode force is used as a light source that emits blue light
- yttrium aluminate to which cerium is added is used as a substance that emits yellow light.
- the spectrum of light emitted from the pseudo white light source is essentially lacking in the green light component and the red light component. For this reason, the pseudo white light source has low color rendering and low color reproducibility. It was.
- the composition of yttrium aluminate (a substance that emits yellow light) is adjusted to emit yellow-green light, and in addition to this, a substance that absorbs blue light and emits red light It has been proposed to add to the yttrium aluminate to compensate for the shortage of the red component of the light emitted by the pseudo-white light source and to improve color rendering and color reproducibility.
- a substance that emits red light is not only blue light but also light having a longer wavelength than blue light but a shorter wavelength than red light, such as green and yellow. Many of them also absorb light. Examples of such materials include sulfides of alkaline earth metals activated with europium, alkaline earth metals and silicon nitrides activated with europium, alkaline earth metals and silicon oxynitrides activated with europium Such as things. These substances usually absorb light with a wavelength of 400 nm to 580 nm well and emit orange to red light having a peak at 580 nm to 680 nm.
- Substances that emit orange to red light as typified above absorb green to yellow light having a shorter wavelength than that, and therefore substances that emit orange to red light and green to red light. When used in combination with substances that emit yellow light, some of the light emitted by substances that emit green to yellow light is absorbed by substances that emit orange to red light! Reduce.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2004-71726
- a light emitting device such as a pseudo white light source having a light source that emits blue light and a substance that absorbs blue light and emits yellow light has high luminous efficiency, color rendering is not sufficient.
- the present invention was devised in view of the above problems, and improves the light emission efficiency and color rendering of a light-emitting device having two or more light-emitting substances that absorb light and emit light, and the light-emitting device.
- the purpose is to provide lighting, a display backlight and a display using the display.
- the gist of the present invention includes a light source and at least one luminescent material that emits light containing a component having a longer wavelength than the light emitted from the light source when excited by the light emitted from the light source.
- a light emitting device comprising: a light emitting unit; and a light emitting surface that emits light emitted from the light source, the first light emitting unit, and the second light emitting unit to the outside, wherein the first light emitting unit and the second light emitting unit Is opened at the light emitting surface, and the area of the boundary surface between the first light emitting portion and the second light emitting portion is 50% or less of the surface area of the first light emitting portion. (Claim 1).
- the amount of light emitted from the first light-emitting part that is absorbed by the second light-emitting part can be suppressed, and as a result, the light-emitting efficiency and color rendering of the light-emitting device can be improved.
- the boundary surface here is a surface on which light can be transmitted and received between the first light emitting unit and the second light emitting unit.
- the boundary between the first light emitting unit and the second light emitting unit is Even if there is a transparent region (specifically, a region where the first and second light-emitting substances are not present) between the surfaces facing the second light-emitting unit of the first light-emitting unit and the second light-emitting unit Of the surfaces facing the first light emitting part, the one having the smaller area is the boundary surface.
- the area of the boundary surface is preferably 50% or less of the total area of the light emitting surface.
- the light emitting surface is a surface from which light is emitted from the first light emitting unit and the second light emitting unit.
- the first light emitting unit is preferably closer to the light source than the second light emitting unit. That is, it is preferable that the distance between the portions where the light source and the first light emitting portion are closest to each other is smaller than the shortest distance between the portions where the light source and the second light emitting portion are closest. As a result, the amount of light emitted by the first light emitting unit force is absorbed by the second light emitting unit, and the color rendering properties of the emitted light can be further improved. wear.
- Another aspect of the present invention resides in illumination characterized by using the above light emitting device ( Claim 4).
- Still another subject matter of the present invention lies in a display backlight characterized by using the light emitting device described above (claim 5).
- Still another subject matter of the present invention lies in a display characterized by using the above-mentioned light emitting device (claim 6).
- the light emitting device of the present invention it is possible to obtain illumination, a display backlight, and a display that are excellent in luminous efficiency and color rendering.
- FIGS. 1 (a) to 1 (c) are schematic longitudinal sectional views of first and second light emitting sections for explaining a boundary surface.
- FIGS. 2 (a) to 2 (c) are schematic perspective views of the first and second light emitting sections and the frame for explaining the light emitting surface.
- FIG. 3 (a) and FIG. 3 (b) are diagrams schematically showing the main part of the light emitting device as the first embodiment of the present invention, and FIG. 3 (a) is a sectional view thereof. Fig. 3 (b) is a top view thereof.
- FIG. 4 (a) and FIG. 4 (b) are diagrams schematically showing a main part of a light emitting device as a second embodiment of the present invention, and FIG. 4 (a) is a sectional view thereof. Fig. 4 (b) is a top view thereof.
- FIG. 5 (a) and FIG. 5 (b) are diagrams schematically showing a main part of a light emitting device as a third embodiment of the present invention, and FIG. 5 (a) is a sectional view thereof. FIG. 5 (b) is a top view thereof.
- Figs. 6 (a) and 6 (b) are diagrams schematically showing a main part of a light emitting device as a fourth embodiment of the present invention, and Fig. 6 (a) is a sectional view thereof. Fig. 6 (b) is a top view thereof.
- FIG. 7 is a diagram schematically showing a cross section of a main part of a display for explaining an example of a backlight unit using the light emitting device of the present invention.
- FIG. 8 is a schematic cross-sectional view of the light emitting device of Comparative Example 1.
- the light-emitting device of the present invention includes a light source, a first light-emitting unit, and a second light-emitting unit, and the direction in which the first light-emitting unit and the second light-emitting unit attempt to emit light (hereinafter referred to as “predetermined direction” as appropriate).
- the light exit surface force is configured to emit light.
- the light emitting device includes a frame as a base for holding the light source, the first light emitting unit, and the second light emitting unit.
- the frame is a base that holds the light source, the first light emitting unit, and the second light emitting unit, and the shape, material, and the like thereof are arbitrary.
- a plate shape, a cup shape, or the like can be used according to the application.
- a cup-shaped frame is preferable because it can have directivity in the light emission direction and can effectively use light emitted from the light-emitting device.
- the material of the frame an appropriate material such as an inorganic material such as a metal, an alloy, glass or carbon, or an organic material such as a synthetic resin can be used.
- the surface of the frame that is exposed to light emitted from the light source, the first light emitting unit, and the second light emitting unit has a higher reflectivity of the incident light. More preferably, the rate is increased. Therefore, it is preferable that at least the surface that is exposed to light is formed of a material having high reflectance.
- the entire frame or the surface of the frame may be formed of a material containing a material having a high reflectance such as glass fiber, alumina powder, titania powder (such as injection molding resin).
- the specific method for increasing the reflectance of the frame surface is arbitrary.
- a metal having a high reflectance such as silver, platinum, and aluminum. It can be achieved by increasing the light reflectivity by plating or vapor deposition with metal or alloy.
- the part that increases the reflectivity may be the entire frame or a part of the frame, but usually the entire surface of the part that is irradiated with light emitted from the light source, the first light emitting part, and the second light emitting part. It is desirable that the reflectivity is increased.
- the frame is usually provided with electrodes for supplying power to the light source.
- the light source emits excitation light of the luminescent material contained in the first light emitting part and the second light emitting part, and also emits one component of light emitted from the light emitting device. That is, a part of the light emitted from the light source is absorbed as excitation light by the luminescent material in the first light emitting part and the second light emitting part, and another part is emitted in a predetermined direction from the light emitting device. It has become so.
- the type of the light source is arbitrary, and an appropriate one can be selected according to the use and configuration of the light emitting device.
- Examples of the light source include a light-emitting diode (hereinafter referred to as “LED” as appropriate), an edge-emitting or surface-emitting laser diode, an electroluminescence element, and the like, but an inexpensive LED is usually preferable.
- the emission wavelength of the light emitted from the light source is also arbitrary, and a light source that emits light having an appropriate emission wavelength may be used in accordance with the light emitted from the light emitting device.
- the light emission wavelength of the light emitted from the light source is usually 370 nm or more, preferably 380 mn or more, and usually 500 mn or less, preferably ⁇ or 480 mn or less. .
- the light source include LEDs using InGaN-based, GaAIN-based, InGaAIN-based, ZnSe S-based semiconductors, etc., which are grown on a substrate such as silicon carbide, sapphire, gallium nitride, etc. by a method such as MOCVD. Etc.
- a single light source may be used alone, or two or more light sources may be used in combination. Sarako, one light source may be used, or two or more light sources may be used in combination.
- the specific method is arbitrary.
- the light source can be attached using solder.
- solder For example, Au Sn, AgSn, or the like can be used.
- solder it is also possible to supply power from the electrode cover formed in the frame through the solder.
- solder exhibits excellent heat dissipation, so it is possible to use solder to install the light source. It is effective.
- an adhesive such as epoxy resin, imide resin, or acrylic resin may be used.
- the adhesive can be energized to supply power to the light source as in the case of using solder. It is also possible to scrape. Furthermore, it is preferable to mix these conductive fillers because heat dissipation is also improved.
- the method of supplying power to the light source is arbitrary, and in addition to energizing the above-mentioned solder adhesive, the light source and the electrode may be connected by wire bonding to supply power.
- the material, dimensions, and the like that limit the wire used at this time are arbitrary.
- metals such as gold and aluminum can be used as the material of the wire, and the force wire whose thickness can be normally set to 20 ⁇ m to 40 ⁇ m is not limited to this.
- Another example of a method for supplying power to the light source is a method for supplying power to the light source by flip chip mounting using bumps.
- the first light emitting unit is formed by including at least one kind of light emitting substance that is excited by light emitted from the light source and emits light including a component having a longer wavelength than the light emitted from the light source.
- the luminescent material used for the first light emitting unit will be described in detail later.
- the first light emitting unit receives the light emitted from the light source, and the light emitting material emits light using the received light as excitation light. Part of the emitted light is emitted to the outside of the light emitting device as a component of the light emitted by the light emitting device, and part of the light becomes excitation light of the luminescent material of the second light emitting unit.
- the second light emitting unit is excited by light emitted from the light source and light emitted from the first light emitting unit, and emits at least one kind of light including a component having a longer wavelength than the light emitted from the first light emitting unit. It is formed including a luminescent material. There is no particular limitation on the shape of the second light emitting part, and the second light emitting part can be provided alone at one place or divided into two or more places. Second light emission The luminescent material used for the part will also be described in detail later.
- the second light emitting unit receives the light emitted from the light source and the light emitted from the first light emitting unit, and the light emitting material emits light using the received light as excitation light.
- the emitted light is emitted outside the light emitting device as a component of light emitted by the light emitting device.
- both the first light emitting unit and the second light emitting unit are open to the outside on the light emitting surface.
- the light emitting surface means a surface from which the light emitting device emits light in a predetermined direction. Therefore, the light emitted from the light source, the first light emitting part, and the second light emitting part is also emitted in the predetermined direction with this light emitting surface force.
- the shape of the light exit surface is arbitrary, and it is desirable that the light exit surface has an appropriate shape such as a flat surface, a curved surface, or an uneven surface, depending on the application. Also, normally, even when light emitted by the light emitting device force is emitted in multiple directions, or even when emitted radially within a predetermined angular range, the strongest light is emitted in the predetermined direction. ! /
- the first light emitting unit and the second light emitting unit being open means that light emitted from the first and second light emitting units in a predetermined direction is not shielded by other members. It means being released. More specifically, the light emitted from the first light emitting unit in a predetermined direction is not blocked by the light source, the second light emitting unit, and the frame (in the case where the light emitting device includes a frame). The light emitted from the second light emitting unit in a predetermined direction is shielded by the light source, the first light emitting unit and the frame (if the light emitting device has a frame). This means that the light is emitted to the outside of the light emitting device without any trouble.
- first and second light emitting parts are opened if light emitted from other members such as a protective layer and a cover can be transmitted.
- the light emitting material absorbs light from the first light emitting unit as excitation light. Thereby, the light emitted from the first light emitting unit is consumed by the second light emitting unit. For this reason, the light intensity of the first light emitting unit force that would have been emitted to the outside of the light emitting device in the past is reduced, and thus the light is emitted from the light emitting device. As a result, the luminous flux was reduced and the luminous efficiency was reduced.
- the light emitted from the first light-emitting unit is consumed by the second light-emitting unit, so that the light-emitting device power also varies in the component of the emitted light, reducing the color reproducibility of the light-emitting device.
- the amount of light from the first light-emitting part absorbed by the second light-emitting part changes depending on the degree of sedimentation of the luminescent material, and thus the emission color. As a result, the color rendering performance tends to decrease.
- the light emitted from the first light emitting unit and the light emitted from the second light emitting unit are In other words, it is possible to reduce (or eliminate) the degree to which the intensity is weakened by being absorbed by other luminescent materials or shielded by other members. Therefore, variation in light components emitted from the light emitting device can be reduced, and both the light emission efficiency and color rendering of the light emitting device can be improved.
- the area of the boundary surface between the first light emitting part and the second light emitting part is usually 50% or less, preferably 30% or less, of the surface area of the first light emitting part.
- the total area of the boundary surface with respect to the total surface area of the first light emitting part should be within the above range.
- the light emitting material absorbs the light of the first light emitting unit force as excitation light, so that when the light emitted from the first light emitting unit enters the second light emitting unit, the light is emitted. Is the second Consumed in the light section. Therefore, the light emission efficiency of the light emitting device is reduced because the intensity of light from the first light emitting unit, which should have been emitted outside the light emitting device in the past, is reduced, and the light emitting device component of the emitted light As a result, the color rendering properties of the light-emitting device were reduced.
- the area of the boundary surface between the first light emitting unit and the second light emitting unit in the above range, it is possible to suppress the amount of light emitted by the first light emitting unit from being absorbed by the second light emitting unit. Therefore, the light emission efficiency of the light emitting device can be increased, and further, the color rendering property of the light emitting device can be improved by reducing the variation in the variation of light components emitted from the light emitting device.
- the boundary surface in the present specification refers to a surface on which light can be transmitted and received between the first light emitting unit and the second light emitting unit.
- the boundary surface may be a flat surface or a curved surface.
- the first light emitting unit and the second light emitting unit that exchange light are formed apart from each other, the surface of the first light emitting unit facing the second light emitting unit, and the second light emitting unit Of the faces facing the first light emitting part, the one with the force vj and the smaller area is the boundary face.
- the total area of the boundary surfaces of the respective portions is set within the above range.
- the first light emitting unit I and the second light emitting unit II having different sizes are in contact with each other, and a part of the right side surface of the first light emitting unit I in the drawing is shown.
- the area of the portion in contact with each other is the area of the boundary surface. Therefore, in the case shown in FIG. 1 (a), the area of the left side surface in the drawing of the second light emitting unit II is the area of the boundary surface X.
- the first light emitting unit I and the second light emitting unit II are provided apart from each other and face the second light emitting unit II of the first light emitting unit I. If the area of the side facing the first light emitting part I of the second light emitting part II is smaller than the area of the side, the first light emitting of the second light emitting part II, which is the surface with the smaller area, is used. The area of the side facing the part I is the area of the boundary surface X. The first light emitting unit I and the second light emitting unit II are provided apart from each other, and the area of the side surface of the first light emitting unit I facing the second light emitting unit II and the first light emitting unit II. If the area of the side facing part I is equal, any surface may be treated as a boundary surface.
- the second light emitting units II and II are provided on both sides of the first light emitting unit I.
- the light can travel between the first light emitting part I and the two second light emitting parts II and II on both sides.
- the total area of the boundary surface X between the first light emitting part I and the second light emitting part II on the left side in the figure is within the above range.
- the first light emitting part I and the second light emitting parts II and II are in contact with each other.
- the areas of the side surfaces are equal, and examples are given.
- FIGS. 1 (a) to 1 (c) substantially similar parts are denoted by the same reference numerals.
- the area of the boundary surface is usually 50% or less, preferably 30% or less of the total area of the light emitting surface.
- the light emitting surface is a surface in the light emitting device from which light is emitted from the first light emitting unit and the second light emitting unit toward the outside of the light emitting device.
- the direction in which light is emitted is not limited to the predetermined direction.
- FIGS. 2 (a) to 2 (c) a schematic perspective view of the first and second light emitting units and the frame is illustrated in FIGS. 2 (a) to 2 (c), and the light emission surface will be described in detail.
- the light emitting surface is the outermost peripheral surface of the first light emitting unit and the second light emitting unit, and the light emitting surface force is not blocked by a shielding object such as a frame, and emits light.
- a surface that is emitted to the outside of the device (not necessarily in a specific direction).
- a rectangular columnar first light-emitting portion I and a second light-emitting portion II are provided on a flat and opaque frame F so as to be in contact with side surfaces having the same area.
- the upper surface of the quadrangular prism formed by the first light emitting unit I and the second light emitting unit II that is, the upper surface la of the first light emitting unit I and the upper surface Ila of the second light emitting unit II
- the side surfaces that is, The side lb of the first light emitting part I and the side lib of the second light emitting part II, excluding the side surfaces that are in contact with each other, are the light emitting surfaces.
- the light emitted from the lower surface of the square pillar (that is, the lower surface Ic of the first light emitting unit I and the lower surface He of the second light emitting unit II) is shielded by the frame F and is emitted to the outside of the light emitting device. Therefore, the lower surface Ic, lie of the square column is not a light emitting surface.
- the first light emitting section I and the second light emitting section II formed in a rectangular shape similar to FIG.
- the upper surface la and all side surfaces lb of the first light emitting unit I and the upper surface Ila and all side surfaces I lb of the second light emitting unit II become light emitting surfaces.
- the light emitted from the lower surface Ic of the first light emitting unit I and the lower surface lie of the second light emitting unit II is shielded by the frame F and is therefore not emitted outside the light emitting device.
- the lower surface Ic of the part I and the lower surface lie of the second light emitting part II are not light emitting surfaces.
- the first and second light-emitting portions I and II are formed by a member such as transparent resin glass.
- the surfaces of the first and second light emitting parts I and II on which other members are formed also become light emitting surfaces.
- FIGS. 2 (a) to 2 (c) substantially similar parts are denoted by the same reference numerals.
- the first light emitting unit is closer to the light source than the second light emitting unit. That is, it is preferable that the distance between the portions where the light source and the first light emitting portion are closest to each other is smaller than the shortest distance between the portions where the light source and the second light emitting portion are closest.
- the second light emitting unit emits light using the light from the light source as excitation light.
- the intensity of the light that should be emitted from the first light emitting unit is insufficient, or the light emitted from the second light emitting unit is increased.
- the light component emitted from the light-emitting device may vary from the target value and the color rendering may be deteriorated.
- the first light emitting unit at a position closer to the light source than the second light emitting unit, light that also emits light source power first enters the first light emitting unit.
- the first light emitting unit emits light using the light from the light source as excitation light
- the second light emitting unit emits light using the light from the first light emitting unit as excitation light, so that the first and second light emitting units emit light smoothly.
- the light emitted from the light emitting device Color variation is reduced, and color rendering can be further improved.
- the intensity of light emitted from the light source and incident on each of the first light emitting unit and the second light emitting unit is also related to the area of the light receiving surface of each of the first light emitting unit and the second light emitting unit. Therefore, the light source power distance to each of the first light emitting unit and the second light emitting unit, and the area of each light receiving surface, the light intensity received by the first light emitting unit is the light received by the second light emitting unit. It is preferable to set it so as to be greater than the intensity of.
- excitation light (mainly light of light source power) can be supplied to the first light emitting unit and the second light emitting unit, and further emitted from the light source, the first light emitting unit, and the second light emitting unit. If light can be emitted to the outside of the light emitting device, the arrangement, size, shape, and the like of each member constituting the light emitting device can be arbitrarily set.
- the first light emitting unit, the second light emitting unit, the light source, and the frame may be arranged at a distance so as to have a gap therebetween.
- a gap may be formed between the first light emitting unit and the second light emitting unit ⁇ see FIG. 1 (b) and FIG. 2 (c) ⁇ .
- a gap may be formed between one or both of the first light emitting unit and the second light emitting unit and the light source (see FIG. 6A).
- a distance is provided between the first light emitting unit and the second light emitting unit, one or both of the first light emitting unit and the second light emitting unit, and the light source so that they do not contact each other.
- other members may be provided between the two.
- a protective layer of transparent resin is formed on the entire circumference of the light source, the light from the light source is emitted as a luminous flux even though the distance between the light source and the first light emitting unit and the second light emitting unit is increased.
- the light source can be reliably supplied to the first light emitting unit and the second light emitting unit while keeping the light level high, so that the light source can be protected without reducing the intensity of the light emitted from the light emitting device. Become.
- the first light emitting unit and the second light emitting unit may have different sizes.
- the light emitting device of the present invention may include a member other than the light source, the first light emitting unit, the second light emitting unit, and the frame described above.
- a cover for protecting the light emitting device itself may be provided.
- a light guide member such as a mirror, a prism, a lens, or an optical fiber for changing the direction of the emitted light may also be provided.
- a heat sink or the like for releasing heat generated by the light emitting device may be provided.
- a light diffusion layer may be provided on the light emitting surface of the light emitting device in order to diffuse each component of light emitted from the light emitting device and prevent color unevenness of the visible light.
- the light-emitting substance used in the light-emitting device of the present invention absorbs excitation light and can emit light containing a longer wavelength component than the absorbed excitation light.
- the light emitting material is usually used in a mixture with a binder.
- the light-emitting substance a known substance can be appropriately selected and used according to the use of the light-emitting device.
- the emission itself is not limited by any mechanism such as fluorescence or phosphorescence.
- one kind of light emitting substance may be used alone, and two or more kinds may be used in any combination and ratio.
- the luminescent material used for the first light emitting unit is selected to emit light containing a component having a longer wavelength than the light emitted from the light source when excited by the light emitted from the light source
- the luminescent material used for the second light emitting unit is A light source that emits light including a component having a longer wavelength than the light emitted from the first light emitting unit when excited by the light emitted from the first light emitting unit is selected.
- the luminescent substance absorbs light having a wavelength of usually 350 nm or more, preferably 400 nm or more, more preferably 430 nm or more, and usually 600 nm or less, preferably 570 nm or less, more preferably 550 nm or less as excitation light. I want something to do! /
- the luminescent substance has a wavelength of emitted light of usually 400 nm or more, preferably 450 ⁇ m or more, more preferably 500 nm or more, and usually 750 nm or less, preferably 700 nm or less, more preferably 670 nm or less. Is desirable.
- the excitation light has a wavelength of usually 350 nm or more, preferably 400 nm or more, more preferably 430 nm or more, and usually 520 nm or less, Those that absorb light of preferably 500 nm or less, more preferably 480 nm or less are desirable.
- the light-emitting substance used in the first light-emitting portion has a wavelength of emitted light of usually 400 nm or more, preferably 450 nm or more, more preferably 500 nm or more, and usually 600 nm or less, preferably 570 nm or less, more preferably 550 nm or less. Something is desired!
- the wavelength of the excitation light is usually 400 nm or more, preferably 450 nm or more, more preferably 500 nm or more, and usually 600 nm or less, preferably 570 nm or less. More preferably, it absorbs light of 550 nm or less.
- the light-emitting substance used in the second light-emitting portion has a wavelength of emitted light of usually 550 nm or more, preferably 580 nm or more, more preferably 600 nm or more, and usually 750 nm or less, preferably 700 nm or less, more preferably 670 nm or less. Something is desired!
- the luminescent substance has a luminous efficiency of usually 40% or more, preferably 45% or more, more preferably 50% or more, still more preferably 55% or more, and most preferably 60% or more. It is preferable to use it.
- the luminous efficiency shown here is a value expressed as the product of quantum absorption efficiency and internal quantum efficiency.
- luminescent materials suitable for use in the light-emitting device of the present invention will be illustrated and described for each light-emitting portion.
- the light-emitting substance is not limited to the following examples, and it is within the scope of the present invention whether each exemplified light-emitting substance is used in the first light-emitting part or the second light-emitting part. Can be arbitrarily selected.
- a phosphor represented by the following formula (1) can be given.
- M 1 is a divalent metal element
- M 2 is a trivalent metal element
- M 3 is a tetravalent metal element
- a, b, c, and d are Each is a number in the following range.
- M 1 is a divalent metal element. From the viewpoint of luminous efficiency, etc., a group force consisting of Mg, Ca, Zn, Sr, Cd, and Ba is selected. Particularly preferred is Ca, which is more preferred to be Mg, Ca, or Zn. In this case, Ca may be a single system or a composite system with Mg. Basically, M 1 is
- the elemental power considered to be preferable but it may contain other divalent metal elements as long as the performance is not impaired.
- M 2 in the above formula (1) is from the same plane as the force M 1 that is a trivalent metal element, and from the group consisting of Al, Sc, Ga, Y, ⁇ , La, Gd, and Lu. Particularly preferred is Sc, which is more preferably Al, Sc, Y, or Lu, which is preferably at least one selected. In this case, Sc may be a single system or a complex system with Y or Lu. Basically, M 2 is preferably composed of the elements that are preferred in the above, but may contain other trivalent metal elements as long as the performance is not impaired.
- M 3 in the above formula (1) is a force that is a tetravalent metal element. From the same surface as M 2 , it is preferable to contain at least Si. Further, the tetravalent metal element represented by M 3 is usually 50 mol% or more, preferably 70 mol% or more, more preferably 80 mol% or more, particularly preferably 90 mol% or more of Si. Is desirable.
- tetravalent metal element M 3 other than Si examples include Ti, Ge
- a group force consisting of Zr, Sn, and Hf is preferred to be at least one selected.
- a group force consisting of Ti, Zr, Sn, and Hf is more preferred to be at least one selected.
- Particularly preferred is Sn.
- M 3 is preferably Si. Basically, M 3 is preferably composed of the elements that are considered preferable in the above description, but may contain other tetravalent metal elements as long as the performance is not impaired.
- the crystal structure of the phosphor is usually a garnet crystal structure, which is generally a in the above formula (1), a is 3, b is 2, c is 3, and d is 12 Body-centered cubic lattice crystal It is. However, here, the elemental force of the luminescent center ion is replaced by the position of the crystal lattice of one of the metal elements M ⁇ M 2 or M 3 or placed in the gap between the crystal lattices.
- a may be 3
- b 2, c is 3, and d may not be 12. Therefore, a, b, c, and d are 2. 7 ⁇ a ⁇ 3.3, 1.8 ⁇ b ⁇ 2. 2, 2. 7 ⁇ c ⁇ 3.3, 1 1. 0 ⁇ d ⁇ 13. A number in the range of 0 is preferred.
- the luminescent center ion contained in the compound matrix of this crystal structure contains at least Ce, and Cr, Mn, Fe, Co, Ni, Cu, Pr for fine adjustment of the luminescent properties.
- Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb can also contain one or more divalent to tetravalent elements.
- Mn, 2 to 3 valent Eu, or trivalent Tb can be particularly preferably used.
- This phosphor is usually excited with light of 420 nm to 480 nm.
- the emission spectrum has a peak at 500 to 510 nm and a wavelength component of 450 to 650 nm.
- a phosphor represented by the following formula (2) can be given.
- M 1 is an activator element containing at least Ce
- M 2 is a divalent metal element
- M 3 is a trivalent metal element
- a, b, c, and d are respectively It is a number in the following range.
- M 1 in the above formula (2) is an activator element contained in the crystal matrix described later, and contains at least Ce. Also, Cr, Mn, Fe, Co, Ni, Cu, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb for the purpose of phosphorescence and chromaticity adjustment It can contain at least one divalent to tetravalent element selected.
- the value a representing the content of the activator element M 1 is 0.0001 ⁇ a ⁇ 0.2. If the value of a is too small, the emission center intensity tends to decrease because there are too few emission center ions present in the crystal base of the phosphor.
- a is preferably 0.0005 or more, more preferably 0.002 or more, and preferably 0.1 or less, more preferably 0.04 or less.
- a is usually 0.004 or more, preferably 0.008 or more, more preferably 0.02 or more, and usually 0.15 or less, preferably 0.1 or less, more preferably 0.08 or less.
- M 2 in the above formula (2) is a divalent metal element.
- a group force consisting of Mg, Ca, Zn, Sr, Cd, and Ba is selected. It is particularly preferable that 50 mol% or more of the element of M 2 which is preferably Mg, Ca or Sr which is preferably one kind is Ca.
- M 3 in the formula (2) consists of the same surface as the force M 2 is a trivalent metal element, A1, Sc, Ga, Y , In, La, Gd, Yb, and Lu More preferred is Al, Sc, Yb, or Lu, which is preferably at least one selected from the group, and even more preferred is Sc, or Sc and Al, or Sc and Lu. It is particularly preferable that 50 mol% or more of the M 3 element is Sc.
- the host crystal of the phosphor is generally, M 2 is a divalent metal element to consist of M 3 and oxygen is a trivalent metal element, represented by the composition formula M 2 M 3 O Because it is a crystal, the chemical composition ratio is
- b is 1, c is 2, and d force.
- Ce which is an activator element, is replaced by the force of replacing M 2 or M 3 with the position of the crystal lattice of one of the metal elements, or disposed in the gap between the crystal lattices.
- b may be 1, c force ⁇ , and d may not be 4.
- b is usually a number of 0.8 or more, preferably 0.9 or more, and usually 1.2 or less, preferably 1.1 or less.
- C is usually 1.6 or more, preferably 1.8 or more, and usually 2.4 or less, preferably 2.2 or less. That's right.
- d is usually a number of 3.2 or more, preferably 3.6 or more, and usually 4.8 or less, preferably 4.4 or less.
- M 2 and M 3 represent divalent and trivalent metal elements, respectively, but there are essential differences in light emission characteristics and crystal structure.
- a small part of M 2 and Z or M 3 can be a monovalent, tetravalent, or pentavalent metal element, and the charge balance can be adjusted.
- Ions for example, halogen elements (F, Cl, Br, 1), nitrogen, sulfur, selenium and the like may be contained in the compound.
- This phosphor is excited by light of 420 nm to 480 nm, and is most efficient particularly at 440 to 470 nm.
- the emission spectrum has a peak at 490 to 550 nm and a wavelength component of 450 to 700 nm.
- light emitting materials suitable for the first light emitting part include (Ba, Ca, Sr) MgAl O: Eu, (Ba, Mg, Ca, Sr) (PO) Cl: Eu, (Ba, Ca, Sr) MgSi O: Eu etc.
- Examples include, but are not limited to, substances having an emission peak at 500 nm to 600 nm, such as ⁇ -sialon activated by Eu represented by ⁇ n ⁇ 1.5).
- ⁇ -sialon activated by Eu represented by ⁇ n ⁇ 1.5.
- a plurality of the above-described phosphors may be used.
- a phosphor represented by the following formula (3) can be given.
- M is Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm,
- D represents one or more elements selected from the group consisting of tetravalent metal elements Represents two or more elements, E represents one or more elements selected from trivalent metal element forces, X represents a force selected from groups consisting of 0, N, and F forces 1 Species or two or more elements.
- a, b, c, d, and e are numbers in the following ranges, respectively.
- M includes at least Eu, and Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb force are also selected. 2 or more elements.
- Eu is preferred to be one or more elements selected from the group consisting of Mn, Ce, Sm, Eu, Tb, Dy, Er, and Yb. More preferably.
- A is a group force that is a divalent metal element force other than the M element.
- Mg, Ca, Ca is more preferable, and one or more elements selected from the group consisting of Sr and Ba are more preferable.
- D is one or more elements selected from the group consisting of tetravalent metal elements, among which Si, Ge, Sn, Ti, Zr, Hf It is more preferable that Si is one or more elements selected from the group consisting of Si.
- E is one or more elements selected from the group consisting of trivalent metal elements, among which B, Al, Ga, More preferably, Al is preferably one or more elements selected from the group force consisting of In, Sc, Y, La, Gd, and Lu.
- X is one or more elements selected from the group consisting of 0, N, and F. Among them, N, or N and O and O forces are also preferable.
- a represents the content of the element M serving as the emission center
- Ratio of M and (M + A) number of atoms a ⁇ where a (number of M atoms) Z (number of M atoms + number of A atoms)) force ⁇ 0. 00001 or more and 0.1 or less Good power to be.
- c is the content of D element such as Si, and is an amount represented by 0.5 ⁇ c ⁇ 4.
- d is the content of E element such as A1, and is an amount represented by 0.5 ⁇ d ⁇ 8.
- compositions with high emission luminance. At least, the composition contains Eu in the M element, Ca in the A element, Si in the D element, A1 in the E element, X element contains N.
- an inorganic compound in which the M element is Eu, the A element is Ca, the D element is Si, the E element is A1, and the X element is N or a mixture of N and O is desirable.
- This phosphor is excited by at least light of 580 nm or less, and is particularly efficient at 400 nm to 550 nm, and therefore absorbs light emitted from the first light emitting part well.
- the emission spectrum has a peak at 580 nm to 720 nm.
- M represents at least one element selected from Ba, Mg, and Zn
- a, b, c, d, and e are numbers in the following ranges, respectively.
- the preferred range of a in the above formula (4) is usually 0.0002 or more, preferably 0.0004 or more, and usually 0.02 or less.
- the preferable range of a in the above formula (4) is usually 0.0004 or more, usually 0.01 or less, preferably 0.007 or less, more preferably 0.005.
- a in the above formula (4) is usually 0.0004 or more, usually 0.01 or less, preferably 0.007 or less, more preferably 0.005.
- more preferably 0.004 or less is usually 0.0004 or more, usually 0.01 or less, preferably 0.007 or less, more preferably 0.005.
- the preferable range of a in the above formula (4) is usually 0.004 or more, preferably 0.001 or more, and usually 0.02 or less, preferably 0.08 or less is desirable.
- the content of the luminescent center ion Eu 2+ is smaller than the above range, the luminescence intensity tends to decrease.
- concentration quenching is there.
- the preferred range of a in the above formula (4) which has all of thermal stability, temperature characteristics, and light emission intensity. A range of 0.004 or less is desirable.
- M representing at least one element selected from Ba, Mg, and Zn is not necessarily an essential element in the present invention, but the molar ratio d of M is 0 ⁇ d ⁇ Even if it is contained in the chemical substance of the formula (4) at a ratio of 0.1, the object of the present invention is achieved. Can do.
- This phosphor is excited by light of 600 nm or less, and has the highest efficiency, particularly at 400 nm to 550 nm. Therefore, the phosphor emits light emitted from the first light emitting part well.
- the emission spectrum is 620 ⁇ ! Has a peak at ⁇ 680 nm.
- the luminescent material suitable for use in the second light emitting part are not particularly limited as long as the emission wavelength is 550 nm to 750 nm and the emission wavelength is longer than that of the first light emitting part.
- CaSi N Eu
- a fluorescent europium complex or the like can be used. Also on
- the luminescent material is usually used in the form of particles.
- the particle diameter of the luminescent material particles is usually 150 ⁇ m or less, preferably 50 ⁇ m or less, more preferably 20 ⁇ m or less, further preferably 10 m or less, and most preferably 5 m or less.
- the emission color variation of the light emitting device increases, and when the light emitting material and the sealing material are mixed, it may be difficult to uniformly apply the light emitting material.
- it is usually 0.001 ⁇ m or more, preferably 0.01 ⁇ m or more, more preferably 0.1 ⁇ m or more, further preferably 1 ⁇ m or more, and most preferably 2 m or more. Below this range, the luminous efficiency decreases.
- the volume ratio of the light emitting material of the second light emitting unit to the light emitting material of the first light emitting unit is arbitrary, but is usually 0.05 or more, preferably 0.1 or more, more preferably 0.2 or more, Usually, it is 1 or less, preferably 0.8 or less, more preferably 0.5 or less. It is preferable if this ratio is too large or too small. It is difficult to obtain white light emission.
- a light emitting material is fired to produce a fired body, and the fired body is directly used as the first light emitting part or the first light emitting part. It can be used for two light emitting parts.
- a binder is used for the first light emitting part and the second light emitting part. It is possible to produce without. Even when the binder is not used, other components such as additives can be coexisted in the first light emitting part and the second light emitting part.
- the second light emitting unit includes a light emitting substance that emits light including a component having a longer wavelength than the light emitted from the first light emitting unit when excited by the light emitted from the light source and the first light emitting unit, and a binder.
- the light emitting material of the first light emitting unit may be mixed.
- the concentration of the luminescent material of the first light-emitting part contained in the second light-emitting part is low V, and the light-emitting substance of the first light-emitting part is contained in the second light-emitting part. It's more preferable!
- the light emitting material of the second light-emitting unit is not usually contained in the first light-emitting unit, but the light-emitting power of the second light-emitting unit is sufficient if the luminous flux power of the light emitted by the first light-emitting unit is not reduced. Even if the substance is contained, it is more desirable that the light emitting substance of the second light emitting part, which is usually 40% by volume or less, is not contained at all. That is, even though the light emitting material in the second light emitting unit is excited by the light emitted from the first light emitting unit, the light emitted from the light emitting material in the first light emitting unit in the first light emitting unit is secondly emitted.
- the luminescent material in each light emitting part should be selected so that the luminescent material in the light emitting part does not absorb too much.
- the first light emitting unit and the second light emitting unit may contain a binder in addition to the light emitting substance.
- Noinda is usually used to collect powdered or particulate luminescent materials or attach them to a frame.
- a binder used in the light emitting device of the present invention Any known one without any limitation can be used.
- the light emitting device is of a transmissive type, that is, the light emitted from the light source, the first light emitting unit, and the second light emitting unit is transmitted through the first light emitting unit or the second light emitting unit and emitted to the outside of the light emitting device.
- inorganic materials such as glass can be used in addition to rosin and the like.
- the resin include organic synthetic resins such as epoxy resin and silicon resin, and inorganic materials such as polysiloxane gel and glass.
- the viscosity of the resin is arbitrary. It is desirable to use a binder having an appropriate viscosity according to the particle size and specific gravity of the luminescent material, particularly the specific gravity per surface area. For example, when epoxy resin is used as a binder, if the particle size of the luminescent material particles is 2 ⁇ m to 5 ⁇ m and the specific gravity is 2 to 5, usually 1 to: an epoxy having a viscosity of LOPas The use of rosin is preferable because the phosphor particles can be well dispersed.
- Binders may be used alone or in combination of two or more in any combination and ratio.
- the ratio between the luminescent material and the binder is not limited, but the ratio of the luminescent material to the binder is usually 0.01 or more, preferably 0.05 or more, more preferably, by weight. It is desirable that it is 0.1 or more, usually 5 or less, preferably 1 or less, more preferably 0.5 or less.
- the light-emitting device is a transmission type, it is desirable that the light-emitting substance is appropriately dispersed in the first light-emitting portion and the second light-emitting portion in order to obtain a higher luminous flux.
- the light emitting device is of a reflective type (that is, light emitted from the light source, the first light emitting unit, and the second light emitting unit is emitted outside the light emitting device without passing through the first light emitting unit or the second light emitting unit).
- the luminescent material is filled with high density. Therefore, the composition of the luminescent material should be set in accordance with the use of the light-emitting device, the type and physical properties of the luminescent material, the type and viscosity of the noinda, etc., taking these into consideration.
- the emission color of the light emitted from the light emitting device can be arbitrarily changed by adjusting the ratio of the light emitting materials of the first light emitting unit and the second light emitting unit and the use weight of the light emitting material. wear.
- the light emitting material may contain other components, and the first light emitting portion and the second light emitting portion may be formed of the light emitting material, a binder used as appropriate, and other components.
- any other known additive with no particular limitation can be used.
- a diffusing agent such as alumina or yttria
- a binder such as calcium pyrophosphate or barium calcium borate as the other component.
- the first light-emitting part and the second light-emitting part can be manufactured by any method without particular limitation.
- the first light-emitting part and the second light-emitting part are prepared by dispersing a light-emitting substance and appropriately used binder and other components in a dispersion medium, and applying the prepared slurry to a substrate such as a frame. Thereafter, the slurry can be dried to form.
- the slurry is prepared by mixing the light-emitting substance and other components such as binders and additives that are used as appropriate in a dispersion medium.
- the name of the slurry may be changed to a paste, a pellet, or the like depending on the type of the binder.
- dispersion medium used for slurry preparation there is no limitation on the dispersion medium used for slurry preparation, and any known dispersion medium can be used arbitrarily. Specific examples thereof include chain hydrocarbons such as n-hexane, n-heptane, and solvesso, aromatic hydrocarbons such as toluene and xylene, halogenated hydrocarbons such as trichloroethylene and perchloroethylene, and methanol.
- chain hydrocarbons such as n-hexane, n-heptane, and solvesso
- aromatic hydrocarbons such as toluene and xylene
- halogenated hydrocarbons such as trichloroethylene and perchloroethylene
- methanol methanol
- Alcohols such as ethanol, isopropanol and n-butanol, ketones such as acetone, methyl ethyl ketone and methyl isobutyl ketone, esters such as ethyl acetate and n -butyl acetate, ethers such as cellosolve, butylsolve and cellosolveacetate And aqueous solvents such as water and arbitrary aqueous solutions.
- ketones such as acetone, methyl ethyl ketone and methyl isobutyl ketone
- esters such as ethyl acetate and n -butyl acetate
- ethers such as cellosolve, butylsolve and cellosolveacetate
- aqueous solvents such as water and arbitrary aqueous solutions.
- the prepared slurry is applied to a substrate such as a frame.
- the application method is arbitrary, but for example, a method such as dispensation or potting can be used.
- coating with the slurry used as a 1st light emission part and the slurry used as a 2nd light emission part is arbitrary, and you may apply any first. Moreover, you may apply
- the dispersion medium is dried to produce the first light-emitting portion and the second light-emitting portion.
- Any drying method can be used. For example, natural drying, heat drying, vacuum drying, baking, ultraviolet irradiation, electron beam irradiation, or the like may be used. Among them, baking at a temperature of several tens of degrees centigrade to one hundred and several tens of degrees centigrade is preferable because the dispersion medium can be easily and reliably removed with inexpensive equipment.
- the first light-emitting part and the second light emitting part can be produced by mixing a light-emitting substance with a binder and other components that are used as appropriate and kneading them.
- molding for example, press molding, extrusion molding (T-die extrusion, inflation extrusion, pro-molding, melt spinning, profile extrusion, etc.), injection molding, etc. are performed. .
- the binder is a thermosetting material such as epoxy resin or silicon resin
- the binder before curing, the luminescent material, and other components used as appropriate are mixed and molded, and thereafter
- the first light emitting part and the second light emitting part can be produced by curing the binder by heating.
- the binder is UV curable
- the first and second light emitting parts can be produced by curing the binder resin by irradiating UV light instead of heating in the above method. .
- the first light emitting unit and the second light emitting unit may be manufactured in a series of steps when manufacturing the light emitting device, but the first light emitting unit and the second light emitting unit are separately prepared in advance.
- the light emitting device may be completed by later being incorporated into a frame or the like. It is also possible to prepare a unit that combines the frame and one of the first light emitting part and the second light emitting part, and to complete the light emitting device by combining these units. It is.
- FIG. 3 (a) and 3 (b) are diagrams schematically showing the main part of the light emitting device as the first embodiment of the present invention, and FIG. 3 (a) is a cross-sectional view thereof, FIG. (b) is a top view thereof.
- the light emitting device 1 of the present embodiment includes a frame 2, a blue LED (blue light emitting unit) 3 as a light source, and a green light emitting unit as a first light emitting unit. And a red light emitting part 5 as a second light emitting part.
- the frame 2 is a resin base for holding the blue LED 3, the green light emitting unit 4, and the red light emitting unit 5.
- a trapezoidal concave section (dent) 2A having an opening on the upper side in the figure is formed.
- the dimensions of the recess 2A of the light emitting device 1 allow the light emitting device 1 to emit light in a predetermined direction (here, upward in the figure). It is set to such a dimension.
- an electrode (not shown) that is supplied with external power of the light emitting device 1 is provided at the bottom of the recess 2A, and power can be supplied to the blue LED 3 from this electrode.
- the inner surface of the concave portion 2A of the frame 2 is enhanced in the reflectance of light in the entire visible light region by metal plating, so that the light hitting the inner surface of the concave portion 2A of the frame 2 is also predetermined from the light emitting device 1. It can be released in the direction. It goes without saying that metal plating does not short the electrode!
- a blue LED 3 is installed as a light source.
- the blue LED 3 is an LED that emits blue light when supplied with electric power. Part of the blue light emitted from the blue LED 3 is emitted from the green light emitting part 4 and the red light emitting part 5 (here In this case, the fluorescent material) is absorbed as excitation light, and another part is emitted from the light emitting device 1 in a predetermined direction (here, upward in the figure).
- the blue LED 3 is installed at the bottom of the recess 2A of the frame 2, but here, a silver paste (silver particles on the adhesive is used between the frame 2 and the blue LED 3).
- the blue LED 3 is installed in the frame 2 by this. Sarakuko, this silver paste 6 also plays a role in dissipating the heat generated by the blue LED3.
- a gold wire 7 for supplying power to the blue LED 3 is attached to the frame 2.
- the blue LED 3 and the electrode (not shown) provided at the bottom of the recess 2A of the frame 2 are connected by wire bonding using the wire 7, and when the wire 7 is energized, the blue LED 3 is energized. Supplied, blue LED 3 emits blue light.
- the recess 2A of the frame 2 is provided with a green light emitting part 4 as a first light emitting part and a red light emitting part 5 as a second light emitting part.
- the concave portion 2A is filled with the green light emitting portion 4 and the red light emitting portion 5, and the green light emitting portion 4 and the red light emitting portion 5 face the outside of the light emitting device 1 through the opening of the concave portion 2A.
- 1 functions as a light emitting surface 1A that emits light in a predetermined direction. That is, the blue light emitted from the blue LED 3, the green light emitted from the green light emitting unit 4, and the red light emitted from the red light emitting unit 5 are emitted from the light emitting surface 1A in a predetermined direction. It has become.
- the light emitting surface 1A is the only surface from which light is emitted from the light emitting device 1. Therefore, the light emitting surface 1A of the light emitting device 1 also functions as the light emitting surface Y of the light emitting device 1. -ing
- the green light emitting section 4 is formed of a green phosphor and transparent resin.
- the green phosphor is a luminescent material of the green light emitting section 4 and is a fluorescent material that is excited by blue light emitted from the blue LED 3 and emits green light having a longer wavelength than blue light.
- the transparent resin is a binder of the green light emitting unit 4, and here, an epoxy resin which is a synthetic resin capable of transmitting visible light over the entire wavelength region is used.
- the green light emitting part 4 fills the left part in the figure from the bottom of the recess 2A to the opening. It is formed so that. Further, the green light emitting part 4 is formed so as to cover the entire circumference of the blue LED 3, and therefore the green light emitting part 4 is formed closer to the blue LED 3 than the red light emitting part 5. Become. Therefore, the blue light emitted from the blue LED 3 first passes through the green light emitting unit 4 and then reaches the outside of the light emitting device 1 and the red light emitting unit 5.
- the green light emitting section 4 has a first light exit surface 4A at the opening of the recess 2A.
- the first light exit surface 4A is an upper surface in the drawing of the green light emitting section 4 formed in a planar shape, and overlaps the plane formed by the upper surface of the frame 2.
- the first light emitting surface 4A is a surface that emits light emitted from the green light emitting unit 4 in a predetermined direction outside the light emitting device 1. Blue light emitted from the blue LED 3 is emitted from the first light emitting surface 4A. Are also released.
- the first light exit surface 4A together with a second light exit surface 5A described later, constitutes a light exit surface 1A that emits light emitted from the light emitting device 1 to the outside.
- the green light emitting unit 4 is opened on the light emitting surface 1A.
- the red light emitting section 5 is formed of a red phosphor and transparent resin.
- the red phosphor is a luminescent material of the red light emitting unit 5 and is excited by blue light emitted from the blue LED 3 and green light emitted from the green light emitting unit 4 to emit red light having a longer wavelength than that of green light. It is a phosphor that emits light.
- the transparent resin is a binder of the red light emitting unit 5, and here, like the green light emitting unit 4, an epoxy resin that can transmit visible light is used.
- the red light emitting portion 5 is formed so as to fill the right portion in the figure from the bottom of the recess 2A to the opening. As described above, the green light emitting portion 4 is also formed from the bottom of the recess 2A to the opening. Therefore, in the light emitting device 1, the thickness of the green light emitting portion 4 (the distance in the vertical direction in the figure) and the red light emitting portion are It is formed to be approximately equal to the thickness of 5!
- the red light emitting portion 5 is formed farther from the blue LED 3 than the green light emitting portion 4!
- the red light emitting unit 5 also has a second light emitting surface 5A at the opening of the recess 2A, as with the green light emitting unit 4.
- the second light emission surface 5A is the upper surface in the figure of the red light emitting section 5 formed in a planar shape, and overlaps the plane formed by the upper surface of the frame 2.
- the second light exit surface 5A allows the light emitted from the red light emitting unit 5 to be emitted outside the light emitting device 1. This is a surface that emits in a fixed direction. Blue light emitted from the blue LED 3 from this second light emitting surface 5A and, in some cases, green light emitting part 4 is emitted and enters the red light emitting part 5 from the boundary surface ⁇ .
- Green light is also emitted.
- the second light emitting surface 5A together with the first light emitting surface 4A, constitutes a light emitting surface 1A that emits light emitted from the light emitting device 1 to the outside.
- the red light emitting unit 5 is open at the light exit surface 1A.
- the right side surface 4B of the green light emitting unit 4 in the drawing and the left side surface 5B of the red light emitting unit 5 in the drawing are in direct contact with each other over the entire surface.
- the right side surface 4B of the green light emitting unit 4 and the left side surface 5B of the red light emitting unit 5 form the same surface in contact with each other.
- this The surface forms a boundary surface X between the green light emitting portion 4 and the red light emitting portion 5.
- the area of the boundary surface X is the surface area of the green light emitting unit 4 (here, the surface where the green light emitting unit 4 is in contact with the frame 2, the blue LED 3, the red light emitting unit 5, and the wire 7).
- the area and the total area of the first light exit surface 4A with the green light emitting part 4 open to the outside) are usually 50% or less, preferably 30% or less! RU
- boundary surface X is configured so that its area is usually 50% or less, preferably 30% or less, of the area of the light emitting surface Y of the light emitting device 1 (here, coincides with the light emitting surface 1A). !
- the light-emitting device 1 of the present embodiment is configured as described above. Therefore, when blue light is emitted from the blue LED 3, a part of the blue light is used as excitation light by the green light emitting unit 4, and green light is emitted from the green light emitting unit 4. The other part of the blue light emitted from the blue LED 3 is used as excitation light by the red light emitting unit 5, and red light is emitted from the red light emitting unit 5. Furthermore, part of the green light emitted from the green light emitting unit 4 is absorbed by the red light emitting unit 5 and used as excitation light. Then, the blue light, green light, and red light emitted in this way are each emitted in a predetermined direction from the light exit surface 1A.
- the light-emitting device 1 can exhibit high luminous efficiency and color rendering. That is, the green light emitting part 4 and the red light emitting part 5 are opened at the light emitting surface 1A, and the area of the boundary surface X is set to a predetermined value (50%) or less with respect to the total surface area of the green light emitting part 4. Therefore, the amount of light emitted from the green light emitting unit 4 is suppressed by the red light emitting unit 5. Thereby, the light emission efficiency of the light emitting device 1 can be increased. In addition, since it is possible to suppress variations in light components emitted from the light emitting device 1, it is possible to improve color reproducibility and color rendering of the light emitting device 1.
- FIG. 4 (a) and 4 (b) are diagrams schematically showing a main part of the light emitting device as the second embodiment of the present invention, and FIG. 4 (a) is a cross-sectional view thereof. (b) is a top view thereof.
- the light emitting device 11 of this embodiment includes a frame 12, a blue LED (blue light emitting part) 13 as a light source, and a green light emitting as a first light emitting part. And a red light emitting portion 15 as a second light emitting portion.
- the frame 12 is a base made of resin for holding the blue LED 13, the green light emitting part 14, and the red light emitting part 15.
- the frame 12 is formed in a flat plate shape, and a blue LED 13, a green light emitting unit 14, and a red light emitting unit 15 are provided on the upper surface thereof.
- the surface of the frame 12 is provided with an electrode (not shown) to which power is also supplied from the external force of the light emitting device 11, and the blue LED 13 can be supplied with power from this electrode.
- the reflectance of light in the entire visible light range has been increased by metal plating, so that light hitting the surface of the frame 12 can also be directed from the light emitting device 11 in a predetermined direction (here, upward in the figure). It has become possible to release towards.
- a blue LED 13 is installed as a light source.
- the blue LED 13 is the same as the blue LED 3 of the first embodiment, and functions in the same manner, so the description thereof is omitted here.
- the blue LED 13 is fixed to the frame 12 by the silver paste 16 and is supplied with electric power through the electrode by the wire 17.
- the silver paste 16 and the wire 17 of the light emitting device 11 are the same as the silver paste 6 and the wire 7 of the first embodiment, respectively.
- a green light-emitting part 14 as a first light-emitting part is provided so as to cover the entire circumference of the blue LED 13, and furthermore, the green light-emitting part 14 is provided at both the left and right ends in the drawing.
- the green light-emitting part 14 and the red light-emitting part 15 are combined to form a rectangular parallelepiped as a whole, The red light emitting portion 15 is formed, and the green light emitting portion 14 is formed in the other portions.
- the light emitting device 11 is set so that the predetermined direction in which light is emitted is the upward direction in the figure. Therefore, the light emitting device 11 is formed by the upper surface 14A of the green light emitting unit 14 and the upper surface 15A of the red light emitting unit 15.
- the surface 11A to be operated functions as a light emitting surface 11A from which the light emitting device 11 emits light in a predetermined direction. That is, the light emitting surface 11A emits blue light emitted from the blue LED 13, green light emitted from the green light emitting unit 14, and red light emitted from the red light emitting unit 15 in a predetermined direction. It has become.
- the light emitting surface 11A formed by the upper surface 14A of the green light emitting portion 14 and the upper surface 15A of the red light emitting portion 15 is formed as a single plane!
- the green light emitting portion 14 is formed of the same material as the green light emitting portion 4 of the first embodiment. Further, since the green light emitting portion 14 covers the entire circumference of the blue LED 13, the green light emitting portion 14 is formed closer to the blue LED 13 than the red light emitting portion 15. Therefore, as in the first embodiment, the blue light emitted from the blue LED 13 first passes through the green light emitting unit 14 and then reaches the outside of the light emitting device 11 and the red light emitting unit 15. Further, as described above, the green light emitting portion 14 has an upper surface 14A facing the outside of the light emitting device 11, and emits green light from the upper surface 14A in a predetermined direction. Therefore, the green light emitting portion 14 is opened on the upper surface 14A, that is, on the light emitting surface 11A including the upper surface 14A. The blue light emitted from the blue LED 13 is also emitted from the upper surface 14A.
- the red light emitting portion 15 is formed of the same material as the red light emitting portion 5 of the first embodiment. Further, since the red light emitting unit 14 covers the entire circumference of the blue LED 13, the red light emitting unit 15 is formed farther from the blue LED 13 than the green light emitting unit 14.
- the upper surface 15A of the red light emitting unit 15 also faces the outside of the light emitting device 11, and red light is emitted from the upper surface 15A in a predetermined direction. Therefore, the red light emitting unit 15 is opened on the upper surface 15A, that is, on the light emitting surface 11A including the upper surface 15A. From this top surface 15A, the blue LED 13 is The emitted blue light and, in some cases, the green light emitting part 14 emits red light from the boundary surface X.
- Green light incident on the light section 15 is also emitted.
- the green light emitting unit 14 and the red light emitting unit 15 are in direct contact with each other. Specifically, the entire inner side surface 15B and lower surface 15C of the red light emitting unit 15 are in direct contact with the corresponding surface 14B of the green light emitting unit 14. Therefore, the inner side surfaces 15B and the lower surface 15C of both the left and right red light emitting portions 15 and the surface 14B of the green light emitting portion 14 are in contact with each other to form a force boundary surface XI1.
- the area of the boundary surface XI I (that is, the total area of the surfaces where the inner side surface 15B and the lower surface 15C contact the surface 14B) is the surface area of the green light emitting unit 14 (here, green light emission).
- it is configured to be 50% or less, preferably 30% or less.
- the boundary surface X has an area force of the light emitting surface Y of the light-emitting device 11 which is usually 50 times the area.
- the light emitting surface Y is defined as the light emitting surface 11A (that is, the upper surface 14A of the green light emitting unit 14 and the upper surface of the red light emitting unit 15).
- the light-emitting device 11 of the present embodiment is configured as described above. Therefore, when blue light is emitted from the blue LED 13, a part of the blue light is used as excitation light in the green light emitting part 14, and the green light emitting part 14 also emits green light. Further, another part of the blue light emitted from the blue LED 13 is used as excitation light in the red light emitting unit 15, and red light is emitted from the red light emitting unit 5. Further, part of the green light emitted from the green light emitting unit 14 is absorbed by the red light emitting unit 15 and used as excitation light. Then, the blue light, green light and red light emitted in this way are emitted from the light exit surface 11A in a predetermined direction, respectively.
- the light emitting device 11 can exhibit high luminous efficiency and color rendering. That is, the green light emitting portion 14 and the red light emitting portion 15 are opened at the light exit surface 11A.
- the area of the boundary surface X is set to a predetermined value (50%) with respect to the total surface area of the green light emitting part 14.
- the amount of light emitted by the green light-emitting unit 14 can be suppressed by the red light-emitting unit 15, thereby improving the light emission efficiency and color rendering of the light-emitting device 11.
- the color rendering properties and color reproducibility of the light emitting device 11 can be improved.
- the same operations and effects as the light emitting device 1 of the first embodiment can be obtained.
- FIGS. 5 (a) and 5 (b) are diagrams schematically showing a main part of a light emitting device as a third embodiment of the present invention, and FIG. 5 (a) is a cross-sectional view thereof. (b) is a top view thereof. However, in FIG. 5B, illustration of the sealing portion is omitted for the sake of explanation.
- the light emitting device 21 of the present embodiment includes a frame 22, a blue LED (blue light emitting part) 23 as a light source, and a green light emitting as a first light emitting part.
- the frame 22 is a base made of resin for holding the blue LED 23, the green light emitting unit 24, the red light emitting unit 25, and the sealing unit 29.
- the frame 22 is formed in a flat plate shape, and a blue LED 23, a green light emitting unit 24, a red light emitting unit 25, and a sealing unit 29 are provided on the upper surface thereof.
- the frame 22 has an electrode (not shown), and the light hitting the surface of the frame 22 due to the metal plating is also transmitted from the light emitting device 21 in a predetermined direction (here Then, it can discharge
- a blue LED 23 is installed as a light source.
- the blue LED 23 is the same as the blue LEDs 3 and 13 of the first and second embodiments, and functions in the same manner, so the description thereof is omitted here.
- the blue LED 23 is fixed by flip bonding using the solder bump 26, and power is supplied from the electrode through the solder bump 26.
- a reflection plate 28 having a lower surface as a mirror surface is attached to the upper portion of the blue LED 23.
- blue LED 23 emits upward in the figure.
- the reflected light is reflected by the reflecting plate 28 and is incident on either side of the green light emitting unit 24 and the red light emitting unit 25.
- the frame 22 is provided with a sealing portion 29 that covers the entire upper side of the frame 22.
- the sealing portion 29 is made of a material that transmits at least blue light emitted from the blue LED 23, green light emitted from the green light emitting portion 24, and red light emitted from the red light emitting portion 25.
- a green light-emitting part 24 as a first light-emitting part and a red light-emitting part 25 as a second light-emitting part are formed in a film shape having the same film thickness.
- the entire upper surface of the frame 22 is covered with the green light emitting part 24 and the red light emitting part 25.
- the light emitting device 21 is set so that a predetermined direction in which light is emitted is an upward direction in the figure, and therefore, a surface 21A formed by the upper surface 24A of the green light emitting unit 24 and the upper surface 25A of the red light emitting unit 25.
- the light emitting device 21 functions as a light emitting surface 21A from which light is emitted in a predetermined direction. That is, the light emitting surface 21A emits blue light emitted from the blue LED 23, green light emitted from the green light emitting unit 24, and red light emitted from the red light emitting unit 25 in a predetermined direction. It has become.
- the light emitting surface 21A formed by the upper surface 24A of the green light emitting unit 24 and the upper surface 25A of the red light emitting unit 25 is formed as a single plane.
- the light emitted from the blue LED 23 is not directly emitted in a predetermined direction because of the reflector 28, and is reflected by the frame 22 and emitted to the outside! .
- the green light emitting part 24 is formed by depositing the same material as the green light emitting parts 4 and 14 of the first and second embodiments on the frame 22. Further, the green light emitting portion 24 is formed so that the left end force in the figure of the frame 22 extends from the blue LED 23 to the right side of the figure so as to surround the entire portion where the blue LED 23 and the frame 22 are bonded by flip bonding. . Therefore, the green light emitting unit 24 is formed closer to the blue LED 23 than the red light emitting unit 25. Therefore, most of the blue light emitted from the blue LED 23 is incident on the green light emitting portion 24.
- the green light emitting unit 24 can emit green light from its upper surface 24A in a predetermined direction outside the light emitting device 21. Therefore, the green light emitting unit 24 is open on the upper surface 24A, that is, on the light emitting surface 21A including the upper surface 24A. become. From this upper surface 24A, blue light emitted from the blue LED 23 and reflected by the frame 22 is also emitted.
- the red light emitting section 25 is formed by depositing the same material as the red light emitting sections 5 and 15 of the first and second embodiments on the frame 22.
- the red light emitting unit 25 has a green light emitting unit 24 that is formed so that the left end force in the drawing of the frame 22 extends from the blue LED 23 to the right side of the drawing. It will be formed in the distance.
- the red light emitting unit 25 can emit red light from its upper surface 25A in a predetermined direction outside the light emitting device 21. Therefore, the red light emitting portion 25 is opened on the upper surface 25A, that is, on the light emitting surface 21A including the upper surface 25A.
- the green light incident on 5 is also emitted.
- the green light emitting unit 24 and the red light emitting unit 25 are in direct contact with each other.
- the right side surface 24B of the green light emitting unit 24 in the drawing and the left side surface 25B of the red light emitting unit 25 in the drawing are in direct contact with each other over the entire surface.
- the right side surface 24B of the green light emitting part 24 and the left side surface 25B of the red light emitting part 25 that are in contact with each other are forces that form the same surface.
- this surface is the green light emitting part 24.
- the red light emitting part 25 is formed as an interface X.
- the area of the boundary surface X is equal to the surface area of the green light emitting part 24, and the green light emitting part 24
- the total area of 21 side surfaces 24C is usually 50% or less, preferably 30% or less.
- the boundary surface X has an area force of the light emitting surface Y of the light emitting device 21 and is usually 50 times the area.
- the light emitting surface Y is the light emitting surface 21A (that is, the upper surface 24A of the green light emitting unit 24 and the upper surface of the red light emitting unit 25).
- the light emitting device 21 of the present embodiment is configured as described above. Accordingly, when blue light is emitted from the blue LED 23, a part of the blue light is used as excitation light by the green light emitting unit 24, and green light is emitted from the green light emitting unit 24. The other part of the blue light emitted from the blue LED 23 is used as excitation light by the red light emitting unit 25, and red light is emitted from the red light emitting unit 25. Furthermore, a part of the green light emitted from the green light emitting unit 24 is absorbed by the red light emitting unit 25 and used as excitation light. Then, the blue light, the green light, and the red light emitted in this way are each emitted from the light emitting surface 21A in a predetermined direction.
- the light-emitting device 21 can exhibit high luminous efficiency and color rendering. That is, the green light emitting part 24 and the red light emitting part 25 are opened at the light emitting surface 21A, and the area of the boundary surface X is set to a predetermined value (50%) with respect to the total surface area of the green light emitting part 24.
- the amount of light emitted from the green light emitting unit 24 is absorbed by the red light emitting unit 25, and thereby the luminous efficiency and color rendering of the light emitting device 21 can be improved.
- the color rendering properties and color reproducibility of the light emitting device 21 can be improved.
- the same operation and effect as the light emitting devices 1 and 11 of the first and second embodiments can be achieved.
- FIGS. 6 (a) and 6 (b) are diagrams schematically showing the main part of the light emitting device as the fourth embodiment of the present invention, and FIG. 6 (a) is a cross-sectional view thereof. (b) is a top view thereof.
- the light emitting device 31 of the present embodiment includes a first frame 32, a blue LED (blue light emitting unit) 33 as a light source, and a first light emitting unit.
- a green light emitting unit 34, a red light emitting unit 35 as a second light emitting unit, and a second frame 39 are provided.
- the first frame 32 is a resin base for holding the blue LED 33, the green light emitting unit 34, and the red light emitting unit 35, similar to the frame 2 of the first embodiment.
- a trapezoidal recess (dimple) 32A having an opening on the upper side is formed. Therefore, first Similar to the embodiment, the light emitted from the light emitting device 31 can have directivity, and the emitted light can be used effectively.
- the first frame 32 is configured such that the light hitting the surface of the first frame 32 due to the metal plating on the surface of the recess 32A is also directed from the light emitting device 31 in a predetermined direction (here, upward in the figure). Can now be released! /
- a second frame 39 is provided on the upper part of the first frame 32.
- the second frame 39 is preferably formed of a material that transmits at least the blue light emitted from the blue LED 33, the green light emitted from the green light emitting portion 34, and the red light emitted from the red light emitting portion 35.
- the second frame 39 is formed of a material that transmits the blue light, the green light, and the red light.
- the second frame 39 has an electrode (not shown), and power can be supplied to the blue LED 33 through this electrode.
- a blue LED 33 is installed as a light source in the center of the lower surface of the second frame 39.
- the blue LED 33 is the same as the blue LEDs 3, 13, and 23 in the first to third embodiments, and functions in the same manner, so the description thereof is omitted here.
- the blue LED 33 is fixed to the second frame 39 by silver paste 36 and is supplied with electric power through an electrode by a wire 37.
- the silver paste 36 and the wire 37 of the light emitting device 31 are the same as the silver paste 6, 16, 26 and the wires 7, 17, 27 of the first to third embodiments, respectively.
- the space from the bottom of the recess 32A of the first frame 32 to the lower surface of the second frame 39 is at least blue light emitted by the blue LED 33, green light emitted by the green light emitting part 34, and red light emitted by the red light emitting part 35. Molded with a transparent material (not shown).
- a green light emitting part 34 as a first light emitting part and a red light emitting part 35 as a second light emitting part are formed in a film shape having the same film thickness.
- the green light emitting portion 34 and the red light emitting portion 35 cover the entire inner surface of the recess 32A of the first frame 32.
- the light emitting device 31 is set so that the predetermined direction in which light is emitted is the upward direction in the figure. Therefore, the upper surface 34A of the green light emitting part 34 and the concave part 32A in the opening of the concave part 32A are shown in the figure.
- the light emitting device 31 has a predetermined surface 31A formed by the upper surface 35B of the red light emitting portion 35 on the right slope in the drawing of the upper surface 35A and the concave portion 32A, and the upper surface 35C of the red light emitting portion 35 on the bottom surface of the concave portion 32A. It functions as a light exit surface 31A that emits light in the direction.
- the blue light emitted from the blue LED 33, the green light emitted from the green light emitting unit 34, and the red light emitted from the red light emitting unit 35 are emitted from the light emitting surface 31A in a predetermined direction. ing.
- the light emitted from the blue LED 33 is not directly emitted in a predetermined direction because of the silver paste 36, and is reflected by the first frame 32 and emitted to the outside.
- the light emitting surface 31A serves as the light emitting surface Y of the light emitting device 31 because the light emitting surface 31A is the only surface from which the light is emitted from the light emitting device 31. It is doing.
- the green light emitting part 34 is formed by depositing the same material as the green light emitting parts 4, 14, 24 of the first to third embodiments on the surface of the recess 32 A of the first frame 32. Further, the green light emitting portion 34 is formed from the left end of the surface of the recess 32A to the right side in the figure from the central portion (here, the right side from the position corresponding to the right end of the blue LED 33). For this reason, the green light emitting part 34 is formed closer to the blue LED 33 than the red light emitting part 35. Therefore, at least half or more of the blue light emitted from the blue LED 33 is incident on the green light emitting unit 34.
- the green light emitting portion 34 includes an upper surface 34A of the green light emitting portion 34 in the opening of the concave portion 32A, an upper surface 34B of the green light emitting portion 34 on the left slope in the drawing of the concave portion 32A, and a bottom surface of the concave portion 32A.
- the upper surface 34C force of the green light emitting part 34 in FIG. 5 can also emit green light in a predetermined direction outside the light emitting device 31. Therefore, the green light emitting portion 34 is opened on these surfaces 34A, 34B, 34C, that is, on the light emitting surface 31A including the surfaces 34A, 34B, 34C.
- the forces of these surfaces 34A, 34B, and 34C are also emitted from the blue LED 33 and reflected by the first frame 32.
- the red light emitting portion 35 is formed by depositing the same material as the red light emitting portions 5, 15, and 25 of the first to third embodiments on the surface of the recess 32A of the first frame 32. .
- the red light emitting portion 35 is formed in a portion of the recess 32A where the green light emitting portion 34 is not formed. Yes. Therefore, since the green light emitting portion 34 is formed from the left end of the recess 32A of the first frame 32 to the right side in the drawing rather than the central portion, the red light emitting portion 35 is more in comparison with the green light emitting portion 34. It is formed far away from the blue LED33. Therefore, the blue light emitted from the blue LED 33 is more incident on the green light emitting part 34 than on the red light emitting part 35.
- the red light emitting portion 35 is formed on the upper surface 35A of the red light emitting portion 35 in the opening of the concave portion 32A, the upper surface 35B of the red light emitting portion 35 on the right slope in the drawing of the concave portion 32A, and the bottom surface of the concave portion 32A. Red light can be emitted from the upper surface 35C of the red light emitting unit 35 toward a predetermined direction outside the light emitting device 31. Therefore, the red light emitting unit 35 is good on these surfaces 35A, 35B, and 35C, and is open on the light emitting surface 31A including the surfaces 35A, 35B, and 35C.
- the green light emitting unit 34 and the red light emitting unit 35 are in direct contact with each other.
- the right side surface 34D in the drawing of the green light emitting unit 34 and the left side surface 35D in the drawing of the red light emitting unit 35 are in direct contact with each other over the entire surface. 1.
- the right side surface 34D of the green light emitting unit 34 and the left side surface 35D of the red light emitting unit 35 that are in contact with each other have the same surface. In the light emitting device 31 of this embodiment, this surface is the green light emitting unit 34.
- the red light emitting portion 35 is formed as an interface X.
- the area of the boundary surface X is the surface area of the green light emitting portion 34 (here, the opening of the recess 32A is
- the total right side surface 34D and the total area of the surfaces where the green light emitting portion 34 and the first frame 32 are in contact with each other) are usually 50% or less, preferably 30% or less.
- the boundary surface X has an area equal to the light emission surface Y of the light emitting device 31 (here, the light emission surface).
- the surface area is generally 50% or less, preferably 30% or less. ing.
- the light emitting device 31 of the present embodiment is configured as described above. Accordingly, when blue light is emitted from the blue LED 33, a part of the blue light is used as excitation light by the green light emitting unit 34, and green light is emitted from the green light emitting unit 34. The other part of the blue light emitted from the blue LED 33 is used as excitation light by the red light emitting unit 35, and red light is emitted from the red light emitting unit 35. Furthermore, part of the green light emitted from the green light emitting unit 34 is absorbed by the red light emitting unit 35 and used as excitation light. The blue light, green light, and red light thus emitted are respectively emitted from the light emission surface 31A (that is, the light emission surface Y).
- the light emitting device 31 can exhibit high luminous efficiency and color rendering. That is, the green light emitting portion 34 and the red light emitting portion 35 are opened at the light emitting surface 31A, and the area of the boundary surface X is set to a predetermined value (50%) with respect to the total surface area of the green light emitting portion 34.
- the amount of light emitted from the green light emitting unit 34 is absorbed by the red light emitting unit 35, and thus the light emission efficiency of the light emitting device 31 can be increased.
- the color rendering properties and color reproducibility of the light emitting device 31 can be improved.
- the same operations and effects as the light emitting devices 1, 11, and 21 of the first to third embodiments can be obtained.
- the application of the light emitting device of the present invention is not limited, and can be applied to any application using light. Specific examples of applications include lighting, a backlight unit for display, and a display.
- the light-emitting device of the present invention is used as illumination, there is no particular limitation.
- it can be used in various modes as illumination, such as a camera flash, a video camera light, and indoor and outdoor lighting fixtures.
- the light emitting device of the present invention has different wavelengths (that is, colors) of light emitted from the first light emitting unit and the second light emitting unit, but the light emitted from the light emitting device is emitted from the light emitting device.
- the light emitted from the light source, the first light-emitting part, and the second light-emitting part is sufficiently mixed, so when visually observed The light will be perceived as the target color without being separated into components. If the light-emitting device of the present invention is used as illumination, light with high color rendering properties can be irradiated with high luminous efficiency.
- the light-emitting device of the present invention can be used as a knocklight unit by combining with an optical member such as a light guide plate.
- a display backlight unit is attached to a display of a mobile phone to illuminate the liquid crystal display unit from the back side.
- the light-emitting device of the present invention is attached to the display backlight unit. Can be used.
- FIG. 7 is a diagram schematically showing a cross-section of the main part of the display 41 of the mobile phone in order to explain an example of a backlight unit using the light emitting device of the present invention.
- a light guide plate 43 having a size corresponding to the entire back surface of the liquid crystal display unit 42 is attached to the back surface of the liquid crystal display unit 42.
- the light guide plate 43 is formed as a flat optical member formed of a transparent material that transmits all light in the visible region, and a light emitting device 44 is attached to the side thereof.
- the light emitting device 44 is attached so that emitted light can be incident on the light guide plate 43, and the light guide plate 43 and the light emitting device 44 constitute a display backlight unit 45.
- the light emitted from the light emitting device 44 enters the light guide plate 43 and is emitted toward the surface force liquid crystal display portion facing the liquid crystal display portion 42 of the light guide plate 43.
- the liquid crystal display unit 42 can be illuminated brightly.
- the wavelengths (that is, colors) of the light emitted from the first light emitting unit and the second light emitting unit of the light emitting device 44 are different, but the light emitted from the light emitting device 44 is contained in the light guide plate 43. As it mixes and becomes uniform, there is no wrinkle that causes uneven color when illuminating the LCD 42
- the light-emitting device of the present invention When the light-emitting device of the present invention is used for a relatively large display or the like, the light-emitting device of the present invention may be used as a backlight that directly illuminates the liquid crystal display unit with a backlight power. Even in such a case, the light emitted from the light emitting device is mixed and made uniform before reaching the liquid crystal display portion, so there is no possibility of uneven color.
- the light emitted from the light emitting device in order to mix each component of the light emitted from the light emitting device, if the light emitted from the light emitting device is diffused using a diffusion plate, a light diffusing layer, etc., the light is more evenly distributed. be able to. Such a method is preferably used so as not to leave even a slight unevenness in emission color, such as an indicator of an audio device.
- the light emitting device of the present invention when used as a backlight or a backlight unit of a display, it is possible to provide a display having good color reproducibility and high luminous efficiency (luminance).
- Example 1 a light emitting device having the same configuration as that of the above-described light emitting device of the first embodiment of the present invention was manufactured, and the light emission efficiency and the color rendering properties were evaluated.
- the parts corresponding to FIG. 3 (a) and FIG. 3 (b) are drawn with appropriate reference numerals. Is shown.
- a frame (2) having a cup-shaped recess (2A) with an electrode patterned on the bottom is prepared, and a light emitting diode (3) is used as a light source for emitting light at a wavelength of 450 nm to 470 nm on the bottom of the recess (2A).
- a light emitting diode (3) is used as a light source for emitting light at a wavelength of 450 nm to 470 nm on the bottom of the recess (2A).
- silver paste (6) used for die bonding was applied thinly and uniformly in consideration of heat dissipation of the heat generated in the light emitting diode (3). This was heated at 150 ° C. for 2 hours to harden the silver paste, and then the light emitting diode and the frame electrode were wire bonded.
- the wire (7) was a gold wire with a diameter of 25 ⁇ m.
- the luminescent material of the first light emitting section (4) is represented by Ca Ce ScSiO.
- the phosphor used was used. This phosphor absorbs light emitted from the light emitting diode (3) and emits light having a wavelength of 470 nm to 690 nm.
- the light emitting material of the second light emitting part (5) is represented by Ca AlSiEu N 2 O 3.
- a phosphor of 0.99 0. 008 2. 85 0.15 was used. This phosphor absorbs the light emitted from the light emitting diode (3) and the light emitted from the first light emitting section (4), and has a wavelength of 540 ⁇ ! It emits light at ⁇ 760nm.
- the light emitting substance (that is, Ca Ce ScSiO) of the first light emitting section (4) is epoxy resin.
- the ratio of the luminescent material to the silicone resin was 15:85 (weight ratio).
- the light emitting material (ie, Ca AlSiEu NO) of the second light emitting part (5) A second slurry was prepared by kneading in the coconut oil. In this second slurry, the ratio of luminescent material to silicone resin was 5:95 (weight ratio).
- the first light emitting part (4) and the light emitting part (4) A second light emitting part (5) was formed, and the first light emitting part (4) covered the entire circumference of the light emitting diode (3). Therefore, the first light emitting part (4) is located closer to the light emitting diode (3) than the second light emitting part (5).
- the ratio of the luminescent material of the first light emitting unit (4) and the luminescent material of the second light emitting unit (5) was set so that the light emitted from the light emitting device force was white light.
- the light emitting device was manufactured by the above operation.
- the first light-emitting portion (4) and the second light-emitting portion (5) face the outside of the light-emitting device through the openings of the recesses (2A), respectively. Further, the surfaces of the first light emitting unit (4) and the second light emitting unit (5) facing the outside form the light emitting surface (1A) of the light emitting device of this example. Therefore, the first light emitting part (4) and the second light emitting part (5) are opened at the light emitting surface (1A).
- This light-emitting device was made to emit light by supplying power of 0.07 W to the light-emitting diode (3).
- the total luminous flux, chromaticity, and color rendering were measured by measuring the emission spectrum of the light emitted by the light emitting device using an integrating sphere.
- the results are shown in Table 1.
- the average value Ra of R1 to R8 calculated according to “J IS Z 8726” was used.
- V and chromaticity (xZy) represent color coordinates.
- the luminescent material of the first light emitting part (4) a phosphor represented by Ca Ce ScO is used.
- the light emitting device was manufactured in the same manner as in Example 1, and the area of the boundary surface (X) between the first light emitting part (4) and the second light emitting part (5), the first light emitting part (4)
- the surface area, the area of the light emitting surface (Y) of the light emitting device, and the total luminous flux, chromaticity, and color rendering of the light emitted from the light emitting device when the light emitting device was caused to emit light were measured. The results are shown in Table 1.
- the first light emitting portion (4) and the second light emitting portion (5) face the outside of the light emitting device through the openings of the recesses (2A), respectively, and the first light emitting portion (4) And the surface of the second light emitting unit (5) facing the outside forms the light emitting surface (1A) of the light emitting device of this embodiment, so the first light emitting unit (4) and the second light emitting unit (5) Each is opened at the light exit surface (1A).
- a light emitting diode is formed at the bottom of the recess (2A).
- the second light emitting part (5) is formed so as to cover the whole, and the second light emitting part (5) is formed on the upper part ⁇ that is, the opening side of the concave part (2 A) ⁇ of the second light emitting part (5).
- the light emitting device was manufactured in the same manner as in Example 1 except that the first light emitting part (4) was formed so as to cover the entire upper part.
- FIG. 8 is a schematic cross-sectional view of the light emitting device of Comparative Example 1.
- the parts corresponding to the components shown in FIGS. 3 (a) and 3 (b) are shown in FIG. 3 (a), The same reference numerals as those in Fig. 3 (b) are attached.
- the area of the interface (X) between the first light emitting part (4) and the second light emitting part (5), the surface area of the first light emitting part (4), And the area of the light emitting surface (Y) of the light emitting device, and the total luminous flux, chromaticity, and color rendering of the light emitted from the light emitting device when the light emitting device emitted light The results are shown in Table 1.
- the light emitting device was manufactured in the same manner as in Example 1 except that a single light emitting part was formed.
- the area of the light emission surface of the light-emitting device, and the total luminous flux, chromaticity, and color rendering of the light emitted by the light-emitting device when the light-emitting device was caused to emit light Sex was measured.
- the results are shown in Table 1. Note that the light emitting device of Comparative Example 2 has only one light emitting portion, and therefore the boundary surface and the area of the first light emitting portion cannot be measured.
- the first light emitting unit and the second light emitting unit are opened at the light emitting surface, and the area of the boundary surface between the first light emitting unit and the second light emitting unit is the first.
- the light emitting devices of Examples 1 and 2 that are 50% or less of the surface area of the light emitting part can emit a higher luminous flux than the light emitting device of Comparative Example 1. Therefore, it can be seen that the light emitting device has higher luminous efficiency than the light emitting device of Comparative Example 1.
- the conventional technology has been unable to provide a light-emitting device excellent in both light emission efficiency and color rendering, but according to Examples 1 and 2, the present invention provides light emission efficiency and color rendering. It was confirmed that a light emitting device excellent in both can be realized.
- the present invention can be used in any field where light is used.
- image display of various electronic devices such as mobile phones, household appliances, outdoor installation displays, etc. It is suitable for use in an apparatus.
Landscapes
- Led Device Packages (AREA)
- Planar Illumination Modules (AREA)
- Led Devices (AREA)
- Liquid Crystal (AREA)
- Non-Portable Lighting Devices Or Systems Thereof (AREA)
Abstract
Description
Claims
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/631,396 US7474050B2 (en) | 2004-06-30 | 2005-06-29 | Light emitting device, and lighting system, backlight for display and display using the same |
| EP05765436A EP1780805A4 (en) | 2004-06-30 | 2005-06-29 | LIGHT-EMITTING COMPONENT AND ILLUMINATOR THEREFOR, LIGHTING FOR A DISPLAY AND DISPLAY |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004194153A JP2006019409A (ja) | 2004-06-30 | 2004-06-30 | 発光装置並びにそれを用いた照明、ディスプレイ用バックライト及びディスプレイ |
| JP2004-194153 | 2004-06-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2006003930A1 true WO2006003930A1 (ja) | 2006-01-12 |
Family
ID=35782738
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2005/011939 Ceased WO2006003930A1 (ja) | 2004-06-30 | 2005-06-29 | 発光装置並びにそれを用いた照明、ディスプレイ用バックライト及びディスプレイ |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7474050B2 (ja) |
| EP (1) | EP1780805A4 (ja) |
| JP (1) | JP2006019409A (ja) |
| KR (1) | KR20070039569A (ja) |
| CN (1) | CN1981391A (ja) |
| TW (1) | TW200607125A (ja) |
| WO (1) | WO2006003930A1 (ja) |
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| WO2008068689A1 (en) * | 2006-12-05 | 2008-06-12 | Philips Intellectual Property & Standards Gmbh | Illumination device, particularly with luminescent ceramics |
| JP2009135306A (ja) * | 2007-11-30 | 2009-06-18 | Panasonic Electric Works Co Ltd | 発光装置 |
| US7737623B2 (en) | 2004-06-30 | 2010-06-15 | Mitsubishi Chemical Corporation | Light emitting device, lighting system, backlight unit for display device, and display device |
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| EP2061095A4 (en) * | 2006-08-30 | 2012-03-07 | Kyocera Corp | LIGHT-EMITTING DEVICE |
| US8153023B2 (en) * | 2006-07-18 | 2012-04-10 | Showa Denko K.K. | Phosphor, method for production thereof, and light-emitting apparatus |
| US8427044B2 (en) | 2004-06-30 | 2013-04-23 | Mitsubishi Chemical Corporation | Light emitting device, and lighting system, image display using the same |
| JP2014225677A (ja) * | 2014-06-30 | 2014-12-04 | レノボ・イノベーションズ・リミテッド(香港) | 蓄光材料を用いた発光システムおよびこれを備えた携帯機器 |
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| US20090026920A1 (en) | 2004-06-30 | 2009-01-29 | Mitsubishi Chemical Corporation | Phosphor, light-emitting device using same, image display and illuminating device |
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| US20080151143A1 (en) * | 2006-10-19 | 2008-06-26 | Intematix Corporation | Light emitting diode based backlighting for color liquid crystal displays |
| JP4753904B2 (ja) | 2007-03-15 | 2011-08-24 | シャープ株式会社 | 発光装置 |
| US9046634B2 (en) * | 2007-06-14 | 2015-06-02 | Philips Lumileds Lighting Company, Llc | Thin flash or video recording light using low profile side emitting LED |
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| JP6242437B2 (ja) * | 2016-06-10 | 2017-12-06 | シャープ株式会社 | 発光装置 |
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- 2005-06-29 WO PCT/JP2005/011939 patent/WO2006003930A1/ja not_active Ceased
- 2005-06-29 US US11/631,396 patent/US7474050B2/en not_active Expired - Fee Related
- 2005-06-29 CN CNA2005800223653A patent/CN1981391A/zh active Pending
- 2005-06-30 TW TW094122050A patent/TW200607125A/zh unknown
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| US8030840B2 (en) | 2004-06-30 | 2011-10-04 | Mitsubishi Chemical Corporation | Light emitting device, lighting system, backlight unit for display device and display device |
| US8884514B2 (en) | 2004-06-30 | 2014-11-11 | Mitsubishi Chemical Corporation | Phosphor composition, light-emitting device having the same, cured product having the same, lighting system having the same, and display having the same |
| US8427044B2 (en) | 2004-06-30 | 2013-04-23 | Mitsubishi Chemical Corporation | Light emitting device, and lighting system, image display using the same |
| US7737623B2 (en) | 2004-06-30 | 2010-06-15 | Mitsubishi Chemical Corporation | Light emitting device, lighting system, backlight unit for display device, and display device |
| US8080828B2 (en) | 2006-06-09 | 2011-12-20 | Philips Lumileds Lighting Company, Llc | Low profile side emitting LED with window layer and phosphor layer |
| CN101467269B (zh) * | 2006-06-09 | 2011-11-16 | 飞利浦拉米尔德斯照明设备有限责任公司 | 薄外形侧面发光的发光二极管 |
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| US8153023B2 (en) * | 2006-07-18 | 2012-04-10 | Showa Denko K.K. | Phosphor, method for production thereof, and light-emitting apparatus |
| EP2061095A4 (en) * | 2006-08-30 | 2012-03-07 | Kyocera Corp | LIGHT-EMITTING DEVICE |
| US8247828B2 (en) | 2006-12-05 | 2012-08-21 | Koninklijke Philips Electronics N.V. | Illumination device, particularly with luminescent ceramics |
| WO2008068689A1 (en) * | 2006-12-05 | 2008-06-12 | Philips Intellectual Property & Standards Gmbh | Illumination device, particularly with luminescent ceramics |
| CN105206733A (zh) * | 2006-12-05 | 2015-12-30 | 皇家飞利浦电子股份有限公司 | 特别具有发光陶瓷的照明装置 |
| JP2009135306A (ja) * | 2007-11-30 | 2009-06-18 | Panasonic Electric Works Co Ltd | 発光装置 |
| JP2012004485A (ja) * | 2010-06-21 | 2012-01-05 | Nec Corp | 蓄光材料を用いた発光システムおよびこれを備えた携帯機器 |
| JP2014225677A (ja) * | 2014-06-30 | 2014-12-04 | レノボ・イノベーションズ・リミテッド(香港) | 蓄光材料を用いた発光システムおよびこれを備えた携帯機器 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW200607125A (en) | 2006-02-16 |
| KR20070039569A (ko) | 2007-04-12 |
| EP1780805A4 (en) | 2013-02-20 |
| US7474050B2 (en) | 2009-01-06 |
| JP2006019409A (ja) | 2006-01-19 |
| CN1981391A (zh) | 2007-06-13 |
| EP1780805A1 (en) | 2007-05-02 |
| US20070222360A1 (en) | 2007-09-27 |
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