WO2006115982A1 - Element de nettoyage et article de lavage - Google Patents

Element de nettoyage et article de lavage

Info

Publication number
WO2006115982A1
WO2006115982A1 PCT/US2006/014893 US2006014893W WO2006115982A1 WO 2006115982 A1 WO2006115982 A1 WO 2006115982A1 US 2006014893 W US2006014893 W US 2006014893W WO 2006115982 A1 WO2006115982 A1 WO 2006115982A1
Authority
WO
WIPO (PCT)
Prior art keywords
wiping member
yarn
flat
flat yarn
fiber yarn
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2006/014893
Other languages
English (en)
Other versions
WO2006115982A8 (fr
Inventor
Masako Kizuka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Priority to CA002606317A priority Critical patent/CA2606317A1/fr
Priority to AT06750837T priority patent/ATE439792T1/de
Priority to DE602006008602T priority patent/DE602006008602D1/de
Priority to US11/912,356 priority patent/US20090000050A1/en
Priority to EP06750837A priority patent/EP1876937B1/fr
Priority to MX2007013322A priority patent/MX2007013322A/es
Priority to CN2006800147584A priority patent/CN101170937B/zh
Priority to BRPI0610436A priority patent/BRPI0610436A2/pt
Publication of WO2006115982A1 publication Critical patent/WO2006115982A1/fr
Publication of WO2006115982A8 publication Critical patent/WO2006115982A8/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
    • A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
    • A47L13/16—Cloths; Pads; Sponges
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L17/00—Apparatus or implements used in manual washing or cleaning of crockery, table-ware, cooking-ware or the like
    • A47L17/04—Pan or pot cleaning utensils
    • A47L17/08—Pads; Balls of steel wool, wire, or plastic meshes
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/02—Pile fabrics or articles having similar surface features
    • D04B1/04—Pile fabrics or articles having similar surface features characterised by thread material
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B21/20—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting articles of particular configuration

Definitions

  • This invention relates to wiping members.
  • the present invention relates to wiping members used for washing or polishing surfaces.
  • Products comprising a wiping member made by knitting or weaving flat yarn made of plastic film or flat metal yarn prepared by metalization of plastic film are well known products. Such products can be shaped into a bag and urethane sponge or the like enclosed in the bag. Such washing articles are superior in performance to remove bulky solid dirt because they have a knitted cloth having in its surface many bent parts of film and when the bent parts meet with dirt at certain angles, the articles can scratch or scrape away the dirt by virtue of the shape and stiffness of the film.
  • wiping articles do not have enough contact area with the surface of an object to be cleaned and, therefore, they are not very effective in removal of dirt spread thinly on the surface of an object to be cleaned, like oil film.
  • many wiping articles are also known in which acrylic fibers or ultrafine fibers having a heteromorphous cross section, are used for the purpose of removing oil film or the like without using detergent. When such fibers are used alone, a high effect is shown for dirt like oil film, but there is a problem that it is impossible to efficiently scrub off bulky solid dirt such as burnt sludge or soap sludge.
  • Registered Japanese Utility Model Publication No. 3037459 discloses, as a wiping member including a combination of plastic film and yarn such as acrylic yarn, a scrubbing brush cloth produced by knitting worsted acrylic yarn around which flat yarn made of metalized plastic film has been wound spirally. Such a structure, however, can not exert a sufficient effect of scrubbing off dirt by the film because the film are wound parallel to the worsted acrylic yarn and, therefore, the film is prevented to meet dirt at effective angles.
  • wiping members are also commercially available, which comprise a bag made of knitted cloth composed of worsted polypropylene yarn and worsted acryl yarn knitted together alternately with flat yarn made of polyester film to form stripes and a sponge core enclosed in the bag.
  • polyester films are linearly and unevenly distributed. It therefore is inconvenient because of its anisotropic ability to remove dirt and is poor in efficiency to scrub off dirt.
  • the present invention provides a wiping member comprising a flat yarn and a fiber yarn.
  • the flat yarn and fiber yarn are knitted together to form alternating separate loops of flat yarn and fiber yarn.
  • the present invention provides a washing article comprising a wiping member comprising a flat yarn and a fiber yarn, wherein the flat yarn and fiber yarn are knitted together to form alternating separate loops of flat yarn and fiber yarn. Further, an absorbent cleaning material is adjacent the wiping member.
  • Fig. 1 is an enlarged photograph showing the structure of the surface of the wiping member obtained in Example 1 ;
  • FIG. 2 is an enlarged photograph showing the structure of the surface of the wiping member obtained in Example 2;
  • Fig. 3 is a schematic view showing appearance configuration of a commercially available washing article;
  • Knitted cloths originally are cloths produced by interlocking loops lengthwise or crosswise to form a plane by using series of yarn.
  • the structure of a knitted cloth is constituted of a series of loops. Therefore, when a knitted cloth is composed of flexurally anisotropic yarn such as flat yarn made of plastic film, bent parts of the loops will project from a surface of the cloth at almost fixed angles (orientation) and will be arranged regularly.
  • plastic film loops and acrylic fiber loops are arranged regularly, for example, alternately stitch by stitch or every two or more stitches. This will make plastic film loops be arranged uniformly and regularly throughout a surface of the resulting knitted cloth and loops of acrylic fibers will be arranged with the same regularity between the loops of the plastic film.
  • a knitted cloth produced by uniformly knitting flat yarn made of plastic film with spun yarn made of acrylic fibers having been partially wet spun will have in its surface plural bent parts of plastic film arranged uniformly and regularly throughout a surface of the cloth. The front ends of the bent parts will project from the surface of the cloth with an almost fixed angle.
  • the wiping member of the present invention has the aforementioned arrangement of bent parts of flat yarn made of plastic film, the wiping member may further include yarn or fibers uniformly knitted together with the flat yarn of plastic film and the wet spun yarn made of acrylic fibers.
  • knitted cloth produced by interknitting knitted cloths each produced by knitting different types of yarn which is not uniform throughout the cloth, does not correspond to the uniformly knitted cloth as referred to herein.
  • the manner of knitting of the knitted cloth is not particularly restricted if it is a knitting manner usually used in wiping members for use in washing or polishing tableware, pans, etc, in the kitchen or the like.
  • Preferred is a knitting manner such that opening parts are formed between the bent parts of the flat yarn made of the plastic film and a surface of the knitted cloth.
  • the presence of the opening parts makes it easy for the flat yarn to enter between an object to be cleaned and a dirt attaching thereon and, therefore, it becomes easy to separate them.
  • such a knitted cloth can maintain its good scrubbing performance.
  • the manner of knitting of a knitted cloth is not particularly restricted as long as it is constituted of a series of loops.
  • a knitted cloth with a high gauge can not have an enough size of opening parts in loop portions thereof.
  • the projecting direction of the film gets close to parallel with a surface to be cleaned and the knitted cloth and it becomes more difficult to obtain a wiping effect.
  • a knitted cloth with a low gauge is used in the form of bag containing therein a foam member, it tends to allow foreign matter to enter it, resulting in troubles with its use and also in hygiene problems.
  • the number of stitches per square having 10-cm sides is typically from about 20 stitches by 20 rows to 100 stitches by 70 rows, more preferably from about 30 stitches by 30 rows to 65 stitches by 50 rows.
  • plastic film with a thickness of from 30 to 45 ⁇ m and a width of from 0.7 to 0.85 mm is typically used because an operation of scratching or scraping bulky solid dirt can be achieved by virtue of the stiffness of the film.
  • material of the plastic film polypropylene, polyester, polystyrene, and the like are used.
  • flat metal yarn prepared by metalizing plastic film, or other multilayer film for example, film comprising plastic layers sandwiching a metal layer therebetween
  • wet spun acrylic fibers are used because acrylic fibers can easily remove oily dirt, and spun yarn can secure enough contact area with a surface to be cleaned. It is also permitted to use ultrafine fibers having a heterornorphous cross section by forming them into spun yarn.
  • the wiping member of the present invention can be used alone as a wiper or a washing article for tableware such as dishes and the like. It also can be used as a washing article for tableware such as dishes and the like when being shaped into a bag, followed by enclosing a foam member such as polyurethane sponge or the like or when being applied to a foam member.
  • the wiping member has a sufficient washing power for both bulky dirt and dirt like oil film because it is composed of a knitted or woven combination of flat yarn made of plastic film which can scrub bulky dirt effectively and yarn made of fibers, such as acryl, which exerts a washing power for dirt, like oil film, which can be scrubbed only when the washing article intimately comes into firm contact with the surface to be cleaned.
  • flat yarn of rigid plastic film comes into contact with the surface to be cleaned at a certain angle, the power applied during the wiping will be concentrated to a restricted part of dirt and can easily produce a start point for peeling the dirt from the surface to be cleaned.
  • Example 1 Flat yarn made of 38- ⁇ m thick, slit PET film having a width of 0.7575 mm was combined, for reinforcement, with 100-denier PET yarn. This yarn group and 48-denier two-folded acrylic yarn were uniformly knitted by means of a circular knitting machine.
  • FIG. 1 is an enlarged photograph showing the structure of the front surface of the resulting wiping member (namely, the rear surface of the knitted cloth). Loops of the flat yarn of PET film and loops of the acrylic spun yarn are located alternately at several millimeter intervals.
  • the film surface comes into contact -with the surface to be cleaned at an angle of about 45 degrees at its loop sections.
  • the so prepared wiping member was evaluated for its performance to remove a bulky dirt (soap sludge) and its performance to remove oil film together with the wiping members of Comparative Examples 1-3.
  • the Comparative Examples are shown in Table 2 with their evaluation results.
  • the dirts used in the evaluation were prepared by the following methods:
  • a dispersion of a fatty acid calcium powder in alcohol was applied uniformly to a stainless steel plate JIS G4305 (SUS 304)2B). After evaporation of the alcohol, the stainless steel plate was heated for about two minutes on a heated hotplate.
  • Fig. 2 is an enlarged photograph showing the structure of the front surface of the resulting wiping member (namely, the rear surface of the knitted cloth).
  • Groups of loops of PET film flat yarn and groups of loops of acrylic yarn are located alternately at several millimeter intervals.
  • the so prepared wiping member was evaluated for its performance to remove a bulky dirt (soap sludge) and its performance to remove oil film in the same manner as Example 1.
  • the evaluation results are shown in Table 2.
  • Example 3 The tubular knitted cloth produced in Example 1 was shaped into a bag and a block of polyurethane sponge having a length of 140 mm, a width of 70 mm and a thickness of 20 mm was enclosed therein. Thus, a washing article was produced.
  • This article was damped with water and applied to a stainless steel plate on which dirts had been attached in the same manner as Example 1. It was manually moved back and forth once in the direction along the longer sides of the washing article, thereby wiping the dirts. Then, the condition of the stainless steel plate was observed visually and evaluated according to the criteria shown in Table 1.
  • FIG. 3 is a schematic view showing the appearance configuration of this washing article.
  • the washing article had external dimensions the same as those of the washing article of Example 3.
  • worsted polypropylene knitted cloth 1 and worsted acryl knitted cloth 2 are knitted together alternately with aluminum-metalized polyester flat yarn 3 to form stripes.
  • the performance of this washing article was evaluated in the same manner as Example 3. The evaluation results are shown in Table 3. Table 3
  • the washing article of Example 3 exerted excellent removing performance for two types of dirt regardless of the wiping direction.
  • the washing article of Comparative Example 4 when dirt was wiped in the direction along the shorter sides of the article, the dirt remained streakedly and therefore was not wiped away sufficiently.
  • the amount of film effective for scrubbing was insufficient and therefore the dirt was not wiped away sufficiently.
  • the washing article of the present invention exerts excellent removing performance for two types of dirt regardless of the wiping direction because film portions which will exhibit an effect in scrubbing and acrylic yarns effective in wiping oil film are distributed uniformly throughout the entire wiping surface.
  • a high scrubbing power is probably derived from a structure in which loop portions of film appear successively and scrub dirt one after another.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
  • Knitting Of Fabric (AREA)
  • Washing And Drying Of Tableware (AREA)
  • Detergent Compositions (AREA)

Abstract

Elément de nettoyage et article de lavage qui peuvent enlever la saleté finement déposée sur la surface à nettoyer tout en gardant la capacité d’enlever la saleté solide épaisse. L’élément de nettoyage comprend un fil plat et un fil de fibre. Le fil plat et le fil de fibre sont maillés ensemble pour former des boucles distinctes alternantes de fil plat et de fil de fibre.
PCT/US2006/014893 2005-04-28 2006-04-21 Element de nettoyage et article de lavage Ceased WO2006115982A1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
CA002606317A CA2606317A1 (fr) 2005-04-28 2006-04-21 Element de nettoyage et article de lavage
AT06750837T ATE439792T1 (de) 2005-04-28 2006-04-21 Wischelement und waschartikel
DE602006008602T DE602006008602D1 (de) 2005-04-28 2006-04-21 Wischelement und waschartikel
US11/912,356 US20090000050A1 (en) 2005-04-28 2006-04-21 Wiping Member and Washing Article
EP06750837A EP1876937B1 (fr) 2005-04-28 2006-04-21 Element de nettoyage et article de lavage
MX2007013322A MX2007013322A (es) 2005-04-28 2006-04-21 Miembro de limpieza y articulo de lavado.
CN2006800147584A CN101170937B (zh) 2005-04-28 2006-04-21 擦拭构件和洗涤制品
BRPI0610436A BRPI0610436A2 (pt) 2005-04-28 2006-04-24 elemento de limpeza e artigo de lavagem

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2005132453A JP4629489B2 (ja) 2005-04-28 2005-04-28 払拭部材及び洗浄具
JP132453/2005 2005-04-28

Publications (2)

Publication Number Publication Date
WO2006115982A1 true WO2006115982A1 (fr) 2006-11-02
WO2006115982A8 WO2006115982A8 (fr) 2007-02-22

Family

ID=36754629

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/014893 Ceased WO2006115982A1 (fr) 2005-04-28 2006-04-21 Element de nettoyage et article de lavage

Country Status (12)

Country Link
US (1) US20090000050A1 (fr)
EP (1) EP1876937B1 (fr)
JP (1) JP4629489B2 (fr)
KR (1) KR20080004612A (fr)
CN (1) CN101170937B (fr)
AT (1) ATE439792T1 (fr)
BR (1) BRPI0610436A2 (fr)
CA (1) CA2606317A1 (fr)
DE (1) DE602006008602D1 (fr)
MX (1) MX2007013322A (fr)
TW (1) TW200706148A (fr)
WO (1) WO2006115982A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010118320A2 (fr) 2009-04-10 2010-10-14 3M Innovative Properties Company Éponge de nettoyage

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007151803A (ja) * 2005-12-05 2007-06-21 Three M Innovative Properties Co 払拭部材
FR3001117B1 (fr) * 2013-01-18 2015-03-06 Essilor Int Lingette seche a action antibuee et/ou nettoyante
JP6152945B2 (ja) * 2014-03-03 2017-06-28 原田織物株式会社 洗浄用布及びそれを用いた洗浄具
JP6722431B2 (ja) * 2015-08-17 2020-07-15 スリーエム イノベイティブ プロパティズ カンパニー 洗浄具
USD807605S1 (en) * 2016-11-18 2018-01-09 Suk Su Kim Dish and pot scrubber
DE102018005487A1 (de) * 2018-07-12 2020-01-16 lris Fleege Putzwerkzeug
EP4231889B1 (fr) * 2020-10-23 2025-01-22 3M Innovative Properties Company Article à récurer tridimensionnel comprenant des fils métalliques
CN113862882A (zh) * 2021-10-16 2021-12-31 盐城市天马日用品有限公司 一种多股纤维制成的擦洗织物、洗涤制品

Citations (6)

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Publication number Priority date Publication date Assignee Title
GB433115A (en) * 1935-01-18 1935-08-08 Daniel John Mayer Improvements relating to fabrics employed for cleansing purposes
US3418200A (en) * 1964-11-27 1968-12-24 Du Pont Splittable composite filament
US4187669A (en) * 1977-02-01 1980-02-12 Hamanaka Kabushiki Kaisha Knitting material
GB2192327A (en) * 1985-12-12 1988-01-13 S R Holbrook Limited Cleaning pad
GB2199053A (en) * 1986-12-03 1988-06-29 Watterson Textiles Limited Scouring pads
EP0429802A2 (fr) * 1989-11-30 1991-06-05 Guilford Mills, Inc. Article textile avec couches opposées, une absorbante et une non-absorbante, et procédé pour fabriquer celui-ci

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CA807873A (en) * 1969-03-11 Gropper Harry Cleaning pad
US2152697A (en) * 1936-10-22 1939-04-04 Metal Textile Corp Scouring and cleaning implement
US2156549A (en) * 1936-11-07 1939-05-02 Metal Textile Corp Absorbent and abrasive fabric
US2347005A (en) * 1939-02-03 1944-04-18 Hemphill Co Knitted fabric and method
US3526569A (en) * 1969-04-10 1970-09-01 Sohinder Nath Chopra Crinkled plastic ribbon
JPS566058Y2 (fr) * 1978-10-13 1981-02-09
JPH039198U (fr) * 1989-06-12 1991-01-29
US5591507A (en) * 1995-04-04 1997-01-07 Jones; Samuel S. Absorbant cloth with agitating feature
US5636533A (en) * 1996-03-12 1997-06-10 Domestic Fabrics Corporation Composite fabric with integral thermal layer
JPH10117982A (ja) * 1996-10-16 1998-05-12 Nitsuten Kk 広幅縁シート付きタワシ
JP2007151803A (ja) * 2005-12-05 2007-06-21 Three M Innovative Properties Co 払拭部材
SE530476C2 (sv) * 2006-11-02 2008-06-17 Smart Products Scandinavia Ab Rengöringsduk med både tork- och skrubbfunktion
JP5314041B2 (ja) * 2007-11-19 2013-10-16 スリーエム イノベイティブ プロパティズ カンパニー 払拭部材及び払拭部材を備える清掃用具
KR101502121B1 (ko) * 2008-07-04 2015-03-11 코웨이 주식회사 물탱크의 삽입부재 어셈블리
KR101089085B1 (ko) * 2009-07-10 2011-12-06 한국타미나 주식회사 수세미

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB433115A (en) * 1935-01-18 1935-08-08 Daniel John Mayer Improvements relating to fabrics employed for cleansing purposes
US3418200A (en) * 1964-11-27 1968-12-24 Du Pont Splittable composite filament
US4187669A (en) * 1977-02-01 1980-02-12 Hamanaka Kabushiki Kaisha Knitting material
GB2192327A (en) * 1985-12-12 1988-01-13 S R Holbrook Limited Cleaning pad
GB2199053A (en) * 1986-12-03 1988-06-29 Watterson Textiles Limited Scouring pads
EP0429802A2 (fr) * 1989-11-30 1991-06-05 Guilford Mills, Inc. Article textile avec couches opposées, une absorbante et une non-absorbante, et procédé pour fabriquer celui-ci

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010118320A2 (fr) 2009-04-10 2010-10-14 3M Innovative Properties Company Éponge de nettoyage

Also Published As

Publication number Publication date
DE602006008602D1 (de) 2009-10-01
CA2606317A1 (fr) 2006-11-02
US20090000050A1 (en) 2009-01-01
BRPI0610436A2 (pt) 2016-11-08
MX2007013322A (es) 2008-01-16
ATE439792T1 (de) 2009-09-15
EP1876937A1 (fr) 2008-01-16
CN101170937B (zh) 2011-04-06
JP4629489B2 (ja) 2011-02-09
TW200706148A (en) 2007-02-16
CN101170937A (zh) 2008-04-30
EP1876937B1 (fr) 2009-08-19
WO2006115982A8 (fr) 2007-02-22
KR20080004612A (ko) 2008-01-09
JP2006305129A (ja) 2006-11-09

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