WO2006116471A3 - Altering the crystal size distribution of n-(phosphonomethyl) iminodiacetic acid for improved filtration and product quality - Google Patents

Altering the crystal size distribution of n-(phosphonomethyl) iminodiacetic acid for improved filtration and product quality Download PDF

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Publication number
WO2006116471A3
WO2006116471A3 PCT/US2006/015765 US2006015765W WO2006116471A3 WO 2006116471 A3 WO2006116471 A3 WO 2006116471A3 US 2006015765 W US2006015765 W US 2006015765W WO 2006116471 A3 WO2006116471 A3 WO 2006116471A3
Authority
WO
WIPO (PCT)
Prior art keywords
phosphonomethyl
iminodiacetic acid
altering
size distribution
product quality
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2006/015765
Other languages
French (fr)
Other versions
WO2006116471A2 (en
Inventor
Sunder S Rangachari
Todd C Friedman
Sherrol Lee Baysdon
David Z Becher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Technology LLC
Original Assignee
Monsanto Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Technology LLC filed Critical Monsanto Technology LLC
Priority to BRPI0610412-6A priority Critical patent/BRPI0610412A2/en
Priority to CA002605406A priority patent/CA2605406A1/en
Priority to EP06751464A priority patent/EP1877414A2/en
Priority to AU2006241162A priority patent/AU2006241162A1/en
Priority to MX2007013236A priority patent/MX2007013236A/en
Publication of WO2006116471A2 publication Critical patent/WO2006116471A2/en
Publication of WO2006116471A3 publication Critical patent/WO2006116471A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D9/00—Crystallisation
    • B01D9/0036—Crystallisation on to a bed of product crystals; Seeding
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Improved processes for preparing and crystallizing N-(phosphonomethyl)iminodiacetic acid are provided. The processes include adding N-(phosphonomethyl)iminodiacetic acid seed crystals to N-(phosphonomethyl)iminodiacetic acid reaction solutions. Provided are beds of crystallized N-(phosphonomethyl)iminodiacetic acid having improved permeability and filtration rate and reduced impurities.
PCT/US2006/015765 2005-04-25 2006-04-25 Altering the crystal size distribution of n-(phosphonomethyl) iminodiacetic acid for improved filtration and product quality Ceased WO2006116471A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BRPI0610412-6A BRPI0610412A2 (en) 2005-04-25 2006-04-25 Alteration of crystal size distribution of n- (phosphonomethyl) iminodiacetic acid for improved filtration and product quality
CA002605406A CA2605406A1 (en) 2005-04-25 2006-04-25 Altering the crystal size distribution of n-(phosphonomethyl) iminodiacetic acid for improved filtration and product quality
EP06751464A EP1877414A2 (en) 2005-04-25 2006-04-25 Altering the crystal size distribution of n-(phosphonomethyl) iminodiacetic acid for improved filtration and product quality
AU2006241162A AU2006241162A1 (en) 2005-04-25 2006-04-25 Altering the crystal size distribution of N-(phosphonomethyl) iminodiacetic acid for improved filtration and product quality
MX2007013236A MX2007013236A (en) 2005-04-25 2006-04-25 Altering the crystal size distribution of n-(phosphonomethyl) iminodiacetic acid for improved filtration and product quality.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US67464405P 2005-04-25 2005-04-25
US60/674,644 2005-04-25

Publications (2)

Publication Number Publication Date
WO2006116471A2 WO2006116471A2 (en) 2006-11-02
WO2006116471A3 true WO2006116471A3 (en) 2007-05-31

Family

ID=37012122

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/015765 Ceased WO2006116471A2 (en) 2005-04-25 2006-04-25 Altering the crystal size distribution of n-(phosphonomethyl) iminodiacetic acid for improved filtration and product quality

Country Status (10)

Country Link
US (1) US7705178B2 (en)
EP (1) EP1877414A2 (en)
CN (1) CN101208348A (en)
AR (1) AR056660A1 (en)
AU (1) AU2006241162A1 (en)
BR (1) BRPI0610412A2 (en)
CA (1) CA2605406A1 (en)
MX (1) MX2007013236A (en)
TW (1) TW200718706A (en)
WO (1) WO2006116471A2 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101607969B (en) * 2008-06-20 2011-07-20 南通江山农药化工股份有限公司 Cycling application of condensation evaporated water of N-phosphonomethyliminodiacetic acid
CN101525350B (en) * 2009-04-22 2012-07-18 北京颖新泰康国际贸易有限公司 Method for preparing N-(phosphonomethyl)iminodiacetic acid
US20110024354A1 (en) * 2009-07-30 2011-02-03 General Electric Company Desalination system and method
US10584944B2 (en) 2017-03-06 2020-03-10 Rocky Research Burst mode cooling system
US11692779B2 (en) 2020-01-23 2023-07-04 Rocky Research Flexible cooling system with thermal energy storage
CN111659330B (en) * 2020-04-23 2021-05-07 河北威远生物化工有限公司 Process and equipment for continuously producing glufosinate-ammonium
US11435145B2 (en) * 2020-07-28 2022-09-06 Rocky Research Thermal energy storage system with nucleation cooling
US20240158423A1 (en) * 2021-03-04 2024-05-16 Monsanto Technology Llc Two-compartment bipolar membrane electrodialysis of salts of amino acids

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0425131A1 (en) * 1989-10-11 1991-05-02 Hampshire Chemical Corporation Recovery of IDA and glauber's salt from waste crystal liquors
DE19707994A1 (en) * 1997-02-27 1998-09-03 Sued Chemie Ag Process for the production of zeolites with a high Si / Al atomic ratio
WO2000014093A1 (en) * 1998-09-08 2000-03-16 Hampshire Chemical Corp. Synthesis of phosphonomethyliminodiacetic acid with reduced effluent
DE19914375A1 (en) * 1999-03-30 2000-10-05 Sueddeutsche Kalkstickstoff Production of N-phosphonomethyliminodiacetic acid by liberating iminodiacetic acid from sodium salt with strong mineral acid and reaction with formaldehyde and phosphorous acid uses mother liquor from second stage in first stage

Family Cites Families (24)

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Publication number Priority date Publication date Assignee Title
GB1191635A (en) 1966-07-27 1970-05-13 Marchon Products Ltd Improvements in the manufacture of Orthophosphates
US3950402A (en) * 1972-05-31 1976-04-13 Monsanto Company Process for producing N-phosphonomethyl glycine
SE7703448L (en) 1976-03-29 1977-09-30 Grace W R & Co PROCEDURE FOR THE EXTRACTION OF GLYCIN AND IMINODIATIC ACID FROM SOLUTIONS CONTAINING SODIUM GLYCINATE AND DINATRIUMIMINODIACETATE
US4299978A (en) 1979-04-04 1981-11-10 Showa Denko Kabushiki Kaisha Process for separating iminodiacetic acid from aqueous glycine solution
US4357172A (en) * 1980-12-17 1982-11-02 Cpc International Inc. Process for continuous crystallization of alpha monohydrate dextrose utilizing high agitation
US4724103A (en) * 1984-02-27 1988-02-09 Monsanto Company Process for preparing N,N-diacetic acid aminomethylenephosphonic acid
DE3564115D1 (en) 1984-06-04 1988-09-08 Stauffer Chemical Co Method for preparation of n-phosphonomethylglycine
US4775498A (en) * 1984-12-05 1988-10-04 Monsanto Company Process for preparing N,N-diacetic acid aminomethylenephosphonic acid
US4618429A (en) * 1984-12-06 1986-10-21 Resources Conservation Co. Method of maintaining adequate seed crystal in preferential precipitation systems
US4657705A (en) * 1985-09-23 1987-04-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
US4831185A (en) * 1987-12-18 1989-05-16 Hoffmann-La Roche Inc. Asymmetric synthesis of natural vitamin E
US5041627A (en) 1988-11-25 1991-08-20 Monsanto Company Preparation of N-acyl-aminomethylphosphonates
US4986976A (en) * 1989-04-11 1991-01-22 W. R. Grace & Co.-Conn. Recovery of glycine and glauber's salt from waste crystal liquors
US5047088A (en) * 1989-06-30 1991-09-10 A. E. Staley Manufacturing Company Method for crystallization of fructose
US5312972A (en) 1992-10-29 1994-05-17 Hampshire Chemical Corp. Conversion of hydroxymethyl-iminodiacetic acid to phosphonomethyl-iminodiacetic acid
GB9300641D0 (en) 1993-01-14 1993-03-03 Zeneca Ltd Process
ATE172465T1 (en) 1994-07-01 1998-11-15 Monsanto Co METHOD FOR PRODUCING N-PHOSPHONOMETHYLAMINO CARBOXYLIC ACIDS
AU694781B2 (en) 1994-07-01 1998-07-30 Monsanto Company Process for preparing n-phosphonomethylamino carboxylic acids
US6013835A (en) * 1995-06-07 2000-01-11 Hfm International, Inc. Method and apparatus for preparing purified terephthalic acid
RO116964B1 (en) * 1995-06-07 2001-08-30 Monsanto Co Process for preparing n-phosphonomethyliminodiacetic acid
US5986128A (en) 1996-11-01 1999-11-16 Monsanto Company Use of monosodium iminodiacetic acid solutions in the preparation of N-phosphonomethyliminodiacetic acid
IES980552A2 (en) 1998-07-09 1999-08-11 Agritech Chemical Ltd Improved process for preparing N-phosphonomethyl iminodiacetic acid
CA2339839A1 (en) * 1998-08-12 2000-02-24 Monsanto Company Continuous process for the preparation of n-(phosphonomethyl) iminodiacetic acid
EP1353930B1 (en) * 2001-01-12 2004-08-11 Basf Aktiengesellschaft Method for producing n-phosphonomethyl iminodiacetic acid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0425131A1 (en) * 1989-10-11 1991-05-02 Hampshire Chemical Corporation Recovery of IDA and glauber's salt from waste crystal liquors
DE19707994A1 (en) * 1997-02-27 1998-09-03 Sued Chemie Ag Process for the production of zeolites with a high Si / Al atomic ratio
WO2000014093A1 (en) * 1998-09-08 2000-03-16 Hampshire Chemical Corp. Synthesis of phosphonomethyliminodiacetic acid with reduced effluent
DE19914375A1 (en) * 1999-03-30 2000-10-05 Sueddeutsche Kalkstickstoff Production of N-phosphonomethyliminodiacetic acid by liberating iminodiacetic acid from sodium salt with strong mineral acid and reaction with formaldehyde and phosphorous acid uses mother liquor from second stage in first stage

Also Published As

Publication number Publication date
TW200718706A (en) 2007-05-16
CN101208348A (en) 2008-06-25
AU2006241162A1 (en) 2006-11-02
US7705178B2 (en) 2010-04-27
CA2605406A1 (en) 2006-11-02
EP1877414A2 (en) 2008-01-16
US20060247463A1 (en) 2006-11-02
WO2006116471A2 (en) 2006-11-02
MX2007013236A (en) 2008-01-24
AR056660A1 (en) 2007-10-17
BRPI0610412A2 (en) 2010-06-22

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