WO2006125036A3 - Cloth-like fiber reinforced polypropylene compositions and method of making thereof - Google Patents

Cloth-like fiber reinforced polypropylene compositions and method of making thereof Download PDF

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Publication number
WO2006125036A3
WO2006125036A3 PCT/US2006/019148 US2006019148W WO2006125036A3 WO 2006125036 A3 WO2006125036 A3 WO 2006125036A3 US 2006019148 W US2006019148 W US 2006019148W WO 2006125036 A3 WO2006125036 A3 WO 2006125036A3
Authority
WO
WIPO (PCT)
Prior art keywords
cloth
fiber reinforced
reinforced polypropylene
polypropylene compositions
making
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2006/019148
Other languages
French (fr)
Other versions
WO2006125036A2 (en
Inventor
Arnold Lustiger
Jeffrey Valentage
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Priority to BRPI0610189A priority Critical patent/BRPI0610189A2/en
Priority to CA002606611A priority patent/CA2606611A1/en
Priority to EP06760052A priority patent/EP1896531A2/en
Publication of WO2006125036A2 publication Critical patent/WO2006125036A2/en
Anticipated expiration legal-status Critical
Publication of WO2006125036A3 publication Critical patent/WO2006125036A3/en
Ceased legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/34Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
    • B29B7/38Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
    • B29B7/46Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
    • B29B7/48Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
    • B29B7/482Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws provided with screw parts in addition to other mixing parts, e.g. paddles, gears, discs
    • B29B7/483Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws provided with screw parts in addition to other mixing parts, e.g. paddles, gears, discs the other mixing parts being discs perpendicular to the screw axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58Component parts, details or accessories; Auxiliary operations
    • B29B7/60Component parts, details or accessories; Auxiliary operations for feeding, e.g. end guides for the incoming material
    • B29B7/603Component parts, details or accessories; Auxiliary operations for feeding, e.g. end guides for the incoming material in measured doses, e.g. proportioning of several materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58Component parts, details or accessories; Auxiliary operations
    • B29B7/72Measuring, controlling or regulating
    • B29B7/726Measuring properties of mixture, e.g. temperature or density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/80Component parts, details or accessories; Auxiliary operations
    • B29B7/82Heating or cooling
    • B29B7/823Temperature control
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/80Component parts, details or accessories; Auxiliary operations
    • B29B7/88Adding charges, i.e. additives
    • B29B7/90Fillers or reinforcements, e.g. fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/02Making granules by dividing preformed material
    • B29B9/06Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/12Making granules characterised by structure or composition
    • B29B9/14Making granules characterised by structure or composition fibre-reinforced
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/05Filamentary, e.g. strands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • B29C48/297Feeding the extrusion material to the extruder at several locations, e.g. using several hoppers or using a separate additive feeding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/046Reinforcing macromolecular compounds with loose or coherent fibrous material with synthetic macromolecular fibrous material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/047Reinforcing macromolecular compounds with loose or coherent fibrous material with mixed fibrous material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • B29C48/287Raw material pre-treatment while feeding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • B29C48/288Feeding the extrusion material to the extruder in solid form, e.g. powder or granules
    • B29C48/2886Feeding the extrusion material to the extruder in solid form, e.g. powder or granules of fillers or of fibrous materials, e.g. short-fibre reinforcements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/12Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of short lengths, e.g. chopped filaments, staple fibres or bristles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16Fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/10Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/12Applications used for fibers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Ethylene-propylene or ethylene-propylene-diene copolymers
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    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

The present invention is directed generally to cloth-like fiber reinforced polypropylene compositions, and the beneficial mechanical and aesthetic properties imparted by such compositions. The cloth-like fiber reinforced polypropylene compositions include at least 25 wt% polypropylene based polymer, from 5 to 60 wt% organic reinforcing fiber, from 0 to 60 wt% inorganic filler, and from 0.1 to 2.5 wt% colorant fiber. A method of making fiber reinforced polypropylene compositions and molding articles there from is also disclosed and includes the steps of twin screw extrusion compounding the composition to form a resin and injection molding the resin to form a cloth-like article. Articles molded from these fiber reinforced polypropylene compositions have a flexural modulus of at least 300,000 psi, exhibit ductility during instrumented impact testing, and exhibit a cloth-like appearance. The cloth-like fiber reinforced polypropylene compositions of the present invention are particularly suitable for making molded articles including, but not limited to household appliances, automotive parts, and boat hulls.
PCT/US2006/019148 2005-05-17 2006-05-17 Cloth-like fiber reinforced polypropylene compositions and method of making thereof Ceased WO2006125036A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BRPI0610189A BRPI0610189A2 (en) 2005-05-17 2006-05-17 polypropylene resin composition, method of producing an article, auto part, and method of producing a fiber reinforced polypropylene resin composition
CA002606611A CA2606611A1 (en) 2005-05-17 2006-05-17 Cloth-like fiber reinforced polypropylene compositions and method of making thereof
EP06760052A EP1896531A2 (en) 2005-05-17 2006-05-17 Cloth-like fiber reinforced polypropylene compositions and method of making thereof

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US68160905P 2005-05-17 2005-05-17
US60/681,609 2005-05-17
US11/395,493 US20060264544A1 (en) 2005-05-17 2006-03-31 Cloth-like fiber reinforced polypropylene compositions and method of making thereof
US11/395,493 2006-03-31

Publications (2)

Publication Number Publication Date
WO2006125036A2 WO2006125036A2 (en) 2006-11-23
WO2006125036A3 true WO2006125036A3 (en) 2008-07-03

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PCT/US2006/019148 Ceased WO2006125036A2 (en) 2005-05-17 2006-05-17 Cloth-like fiber reinforced polypropylene compositions and method of making thereof

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Country Link
US (1) US20060264544A1 (en)
EP (1) EP1896531A2 (en)
BR (1) BRPI0610189A2 (en)
CA (1) CA2606611A1 (en)
WO (1) WO2006125036A2 (en)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8119725B2 (en) * 2005-05-17 2012-02-21 Exxonmobil Chemical Patents Inc. Fiber reinforced polypropylene composite interior trim cover panels
US7482402B2 (en) * 2005-05-17 2009-01-27 Exxonmobil Research And Engineering Company Fiber reinforced polypropylene compositions
US20080237914A1 (en) * 2005-12-13 2008-10-02 Arnold Lustiger Methods for making fiber reinforced polypropylene composites using pre-cut fiber
US20080214703A1 (en) * 2005-12-13 2008-09-04 Amold Lustiger Pellet and fiber length for polyester fiber reinforced polypropylene composites
WO2008109093A1 (en) * 2007-03-06 2008-09-12 Exxonmobil Research And Engineering Company Fiber reinforced polypropylene composite front end modules
KR100921332B1 (en) * 2007-08-31 2009-10-13 지에스칼텍스 주식회사 Colored long-fiber reinforced pellets and colored resin molded articles prepared using the same
GB0901433D0 (en) * 2009-01-29 2009-03-11 Salvtech Ltd A composite material made from waste material and methods of manufacturing such
PL2363299T3 (en) 2010-03-05 2013-02-28 Unilin Bvba A method of manufacturing a floor board
US10899166B2 (en) 2010-04-13 2021-01-26 Valinge Innovation Ab Digitally injected designs in powder surfaces
CN103476840B (en) * 2011-04-14 2019-02-05 帝人株式会社 Fiber Reinforced Composites
US10035358B2 (en) 2012-07-17 2018-07-31 Ceraloc Innovation Ab Panels with digital embossed in register surface
US9446602B2 (en) 2012-07-26 2016-09-20 Ceraloc Innovation Ab Digital binder printing
GB2538492A (en) 2015-05-11 2016-11-23 Cook Medical Technologies Llc Aneurysm treatment assembly
US9528011B2 (en) 2013-01-11 2016-12-27 Ceraloc Innovation Ab Digital binder and powder print
EA029513B1 (en) * 2013-01-11 2018-04-30 Сералок Инновейшн Аб Dry ink for digital printing
US10041212B2 (en) 2013-02-04 2018-08-07 Ceraloc Innovation Ab Digital overlay
US9708471B2 (en) 2013-08-09 2017-07-18 Equistar Chemicals, Lp Filled polypropylene compositions and related automotive components
US10696830B2 (en) * 2015-06-29 2020-06-30 Lotte Chemical Corporation Polyolefin resin, preparation method therefor, and vehicle rear bumper beam using same
PT3445481T (en) * 2016-04-22 2022-02-01 Steerlife India Private Ltd A processor and a process for granulation of powders
CN105906944A (en) * 2016-06-23 2016-08-31 吴国庆 Impact-resistant toughened PP/PBT (polypropylene/polybutylene terephthalate) plastic alloy and preparation method thereof
ES2865425T3 (en) * 2016-06-29 2021-10-15 Borealis Ag Fiber-reinforced polypropylene composite material
PL3309211T3 (en) 2016-10-17 2019-05-31 Borealis Ag Fiber reinforced polypropylene composite
EP3326835A1 (en) * 2016-11-25 2018-05-30 Akzenta Paneele + Profile GmbH Substrate for a decorated wall or floor panel
US20190184619A1 (en) * 2017-12-15 2019-06-20 GM Global Technology Operations LLC Long fiber reinforced thermoplastic filament
CN108641198A (en) * 2018-05-25 2018-10-12 宁波星陆汽车部件有限公司 The preparation process of modified high melt-flow wheel cover
CN108997638A (en) * 2018-09-14 2018-12-14 蚌埠星烁新材料科技有限公司 A kind of production method for the PE plastics that safety is good
CN108976611A (en) * 2018-09-19 2018-12-11 蚌埠星烁新材料科技有限公司 A kind of modified polypropylene plastic with rock-steady structure
WO2020102970A1 (en) * 2018-11-20 2020-05-28 Borouge Compounding Shanghai Co., Ltd. Fiber-reinforced polypropylene composition with high oil resistance
US20230211537A1 (en) * 2019-01-30 2023-07-06 Nan Ya Plastics Corporation Method for manufacturing an lft extrusion member
CN120059240A (en) * 2021-02-03 2025-05-30 旭化成株式会社 Method for producing resin composition
CN114605740B (en) * 2022-03-29 2023-10-03 江苏金发科技新材料有限公司 Long glass fiber reinforced polypropylene material and preparation method and application thereof
EP4349556A1 (en) * 2022-10-07 2024-04-10 Coperion GmbH Processing plant and method for processing a polymer filler composition, in particular a polyvinyl chloride filler composition

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999014101A1 (en) * 1997-09-17 1999-03-25 Ab Volvo Exterior autobody part of reinforced plastic, and arrangement and method for its forming
CA2243288A1 (en) * 1997-10-27 1999-04-27 James M. Hurley Method for making metallic-effect polyamides with improved color development and brightness
EP1095976A1 (en) * 1999-10-29 2001-05-02 Ticona GmbH Colored structure of polyolefin resins and its articles reinforced by long fibres
EP1234853A1 (en) * 2001-02-21 2002-08-28 Dainichiseika Color & Chemicals Mfg. Co. Ltd. Resin compositions and molded products making use of the same

Family Cites Families (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH423197A (en) * 1964-08-27 1966-10-31 Basf Ag Process for the production of glass fiber reinforced thermoplastics
US3639424A (en) * 1970-02-19 1972-02-01 Eastman Kodak Co Extrudable and moldable plastic compositions reinforced with heat set polyester fibers
US4559262A (en) * 1981-01-21 1985-12-17 Imperial Chemical Industries, Plc Fibre reinforced compositions and methods for producing such compositions
US5213889B1 (en) * 1981-01-21 1996-10-29 Kawasaki Chem Holding Fibre-reinforced compositions and methods for producing such compositions
US4549920A (en) * 1981-07-28 1985-10-29 Imperial Chemical Industries, Plc Method for impregnating filaments with thermoplastic
JPS59167240A (en) * 1983-03-14 1984-09-20 Chisso Corp Method and apparatus for manufacturing molding of organic filler-mixed thermoplastic resin composition
CA1275523C (en) * 1985-12-19 1990-10-23 Hiroyoshi Asakuno Polypropylene resin composition
US5145892A (en) * 1985-12-19 1992-09-08 Chisso Corporation Polypropylene resin composition
JPS63305169A (en) * 1987-06-05 1988-12-13 Marubishi Yuka Kogyo Kk Flame-retarding synthetic resin composition
FR2629636B1 (en) * 1988-04-05 1990-11-16 Thomson Csf METHOD FOR PRODUCING AN ALTERNATION OF LAYERS OF SINGLE-CRYSTAL SEMICONDUCTOR MATERIAL AND LAYERS OF INSULATING MATERIAL
JPH0742664B2 (en) * 1988-11-10 1995-05-10 日本石油株式会社 Fiber reinforced composite cable
US5447793A (en) * 1989-10-20 1995-09-05 Montsinger; Lawrence V. Apparatus and method for forming fiber filled thermoplastic composite materials
EP0510927A3 (en) * 1991-04-23 1993-03-17 Teijin Limited Fiber-reinforced thermoplastic sheet and process for the production thereof
JP2635253B2 (en) * 1991-10-29 1997-07-30 日東紡績株式会社 Short fiber-containing polymer composition and method for controlling electric resistance of polymer composition
JP3280433B2 (en) * 1992-10-09 2002-05-13 株式会社日清製粉グループ本社 Fiber or woven fabric in which ultrafine particles are uniformly dispersed and adhered to the surface, method for producing the same, and fiber-reinforced composite material using the same
US5401154A (en) * 1993-05-26 1995-03-28 Continental Structural Plastics, Inc. Apparatus for compounding a fiber reinforced thermoplastic material and forming parts therefrom
KR950003362A (en) * 1993-07-21 1995-02-16 마에다 가츠노스케 Fiber Reinforced Thermoplastic Structures, Manufacturing Method and Extruder
JPH07216104A (en) * 1994-01-26 1995-08-15 Polyplastics Co Method for manufacturing long fiber reinforced resin structure
DE4419579A1 (en) * 1994-06-03 1995-12-07 Basf Ag Plastic material and process for its manufacture
JP3456301B2 (en) * 1995-03-30 2003-10-14 チッソ株式会社 Fiber-reinforced thermoplastic composite containing fibers and specific carbon black uniformly
US6037056A (en) * 1997-01-08 2000-03-14 Owens Corning Fiberglas Technology, Inc. Transversely and axially reinforced pultrusion product
DE19848124A1 (en) * 1998-10-19 2000-04-20 Krupp Werner & Pfleiderer Gmbh Process for the production of filled, modified and fiber-reinforced thermoplastics and twin-screw extruder for carrying out the process
JP4319785B2 (en) * 1999-02-03 2009-08-26 ビーエーエスエフ コーティングス アクチェンゲゼルシャフト Polyurethane and its use in aqueous synthetic resin coatings
JP3073988B1 (en) * 1999-08-12 2000-08-07 株式会社神戸製鋼所 Manufacturing method of organic fiber reinforced resin pellets
DE10015984A1 (en) * 2000-03-31 2001-10-18 Ticona Gmbh Long fiber-reinforced polyolefin structure used for colored parts comprises polyolefin(s), polyamide(s), modified polyolefin(s), reinforcing fiber(s) and sulfur-containing additive(s)
US20020007900A1 (en) * 2000-07-18 2002-01-24 Keller Michael D. Composite feather filament material
US20030114575A1 (en) * 2000-08-25 2003-06-19 General Electric Company Fiber reinforced thermoplastic composition
GB0022183D0 (en) * 2000-09-11 2000-10-25 Univ Manchester Self-forming polymer composites
US6627701B2 (en) * 2000-12-28 2003-09-30 General Electric Company Method for the preparation of a poly(arylene ether)-polyolefin composition, and composition prepared thereby
DE10155709C1 (en) * 2001-11-13 2003-02-13 Basf Coatings Ag Production of colored and effect multicoat coatings, used in e.g. vehicle (repair) lacquer, comprises applying effect pigment coating, transparent colored pigment coating and unpigmented coating with intermediate drying and final hardening
CA2366430A1 (en) * 2002-01-02 2003-07-02 Chengjie Zhang Composite plastic materials produced from waste materials and method of producing same
US6756003B2 (en) * 2002-03-04 2004-06-29 Visteon Global Technologies, Inc. Method of attaching thermoplastic attachments to a substrate
WO2003092984A1 (en) * 2002-04-30 2003-11-13 G P Daikyo Corporation Resinous interior member of opening/closing body, mold therefor and method of molding the same
US6908573B2 (en) * 2003-04-17 2005-06-21 General Electric Polymeric resin blends and methods of manufacture thereof
US20050058822A1 (en) * 2003-08-04 2005-03-17 Ittel Steven Dale Fiber-reinforced thermoplastic matrices
US20060264554A1 (en) * 2005-05-17 2006-11-23 Arnold Lustiger Fiber reinforced polypropylene composite door core modules
WO2006125037A2 (en) * 2005-05-17 2006-11-23 Exxonmobil Research And Engineering Company In-line compounding and molding process for making fiber reinforced polypropylene composites
US20060261508A1 (en) * 2005-05-17 2006-11-23 Arnold Lustiger Fiber reinforced polypropylene composite headliner substrate panel
US20060264556A1 (en) * 2005-05-17 2006-11-23 Arnold Lustiger Fiber reinforced polypropylene composite body panels
US7482402B2 (en) * 2005-05-17 2009-01-27 Exxonmobil Research And Engineering Company Fiber reinforced polypropylene compositions
WO2006125038A1 (en) * 2005-05-17 2006-11-23 Exxnonmobil Research And Engineering Company Paint system and method of painting fiber reinforced polypropylene composite components
US20060261509A1 (en) * 2005-05-17 2006-11-23 Arnold Lustiger Method for making fiber reinforced polypropylene composites
US8119725B2 (en) * 2005-05-17 2012-02-21 Exxonmobil Chemical Patents Inc. Fiber reinforced polypropylene composite interior trim cover panels

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999014101A1 (en) * 1997-09-17 1999-03-25 Ab Volvo Exterior autobody part of reinforced plastic, and arrangement and method for its forming
CA2243288A1 (en) * 1997-10-27 1999-04-27 James M. Hurley Method for making metallic-effect polyamides with improved color development and brightness
EP1095976A1 (en) * 1999-10-29 2001-05-02 Ticona GmbH Colored structure of polyolefin resins and its articles reinforced by long fibres
EP1234853A1 (en) * 2001-02-21 2002-08-28 Dainichiseika Color & Chemicals Mfg. Co. Ltd. Resin compositions and molded products making use of the same

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