WO2006134488A3 - Thermosetting paint compositions - Google Patents

Thermosetting paint compositions Download PDF

Info

Publication number
WO2006134488A3
WO2006134488A3 PCT/IB2006/001665 IB2006001665W WO2006134488A3 WO 2006134488 A3 WO2006134488 A3 WO 2006134488A3 IB 2006001665 W IB2006001665 W IB 2006001665W WO 2006134488 A3 WO2006134488 A3 WO 2006134488A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydroxyl group
resin
mass
mgkoh
structural units
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2006/001665
Other languages
French (fr)
Other versions
WO2006134488A2 (en
Inventor
Tetsu Konishi
Shinji Mitsumune
Masayuki Takemoto
Takehito Ito
Hiroyuki Tagkagi
Rui Niimi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Japan Ltd
Original Assignee
BASF Coatings Japan Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Coatings Japan Ltd filed Critical BASF Coatings Japan Ltd
Priority to US11/917,360 priority Critical patent/US7981964B2/en
Priority to CA002611560A priority patent/CA2611560A1/en
Priority to EP06765561.3A priority patent/EP1891175B1/en
Priority to MX2007013250A priority patent/MX2007013250A/en
Publication of WO2006134488A2 publication Critical patent/WO2006134488A2/en
Publication of WO2006134488A3 publication Critical patent/WO2006134488A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
    • C08G81/027—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G containing polyester or polycarbonate sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/7806—Nitrogen containing -N-C=0 groups
    • C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/062—Copolymers with monomers not covered by C08L33/06
    • C08L33/066—Copolymers with monomers not covered by C08L33/06 containing -OH groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

To provide a heat-hardenable paint composition with which paint films which have excellent scratch resistance, acid resistance and durability and which also have excellent staining resistance can be formed and which can be used ideally as automobile top-coat paints . [Means of Resolution] A heat-hardenable paint composition of which the base resin comprises (A) a hydroxyl group containing lactone modified resin of which the hydroxyl group value is from 50 to 400 mgKOH/g and which contains from 20 to 70 mass% of structural units based on a lactone compound and (B) a hydroxyl group and cyclic structure containing acrylic resin of which the hydroxyl group value is from 50 to 150 mgKOH/g and which contains from 10 to 80 mass% of structural units based on a radically polymerizable monomer which has a cyclic structure, and in which the crosslinking resin is an isocyanate compound, in which the mass ratio of the resin solid fractions (A) / (B) is from 95/5 to 20/80.
PCT/IB2006/001665 2005-06-16 2006-06-13 Thermosetting paint compositions Ceased WO2006134488A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US11/917,360 US7981964B2 (en) 2005-06-16 2006-06-13 Thermosetting paint compositions
CA002611560A CA2611560A1 (en) 2005-06-16 2006-06-13 Thermosetting paint compositions
EP06765561.3A EP1891175B1 (en) 2005-06-16 2006-06-13 Thermosetting paint compositions
MX2007013250A MX2007013250A (en) 2005-06-16 2006-06-13 Thermosetting paint compositions.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2005176181A JP4872247B2 (en) 2005-06-16 2005-06-16 Thermosetting coating composition
JP2005-176181 2005-06-16

Publications (2)

Publication Number Publication Date
WO2006134488A2 WO2006134488A2 (en) 2006-12-21
WO2006134488A3 true WO2006134488A3 (en) 2007-06-14

Family

ID=37532678

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2006/001665 Ceased WO2006134488A2 (en) 2005-06-16 2006-06-13 Thermosetting paint compositions

Country Status (6)

Country Link
US (1) US7981964B2 (en)
EP (1) EP1891175B1 (en)
JP (1) JP4872247B2 (en)
CA (1) CA2611560A1 (en)
MX (1) MX2007013250A (en)
WO (1) WO2006134488A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102076797B (en) * 2008-07-01 2014-03-12 昭和电工株式会社 Coating composition and coating film formation method using same

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5183222B2 (en) * 2007-01-22 2013-04-17 三菱レイヨン株式会社 Thermosetting coating resin composition
JP4974971B2 (en) * 2007-06-14 2012-07-11 株式会社日本触媒 Thermoplastic resin composition, resin molded article and polarizer protective film using the same, and method for producing resin molded article
JP4539688B2 (en) * 2007-07-24 2010-09-08 Ｂａｓｆコーティングスジャパン株式会社 Reactive diluent for modifying thermosetting coating composition and coating composition using the same
JP4368395B2 (en) * 2007-08-22 2009-11-18 Ｂａｓｆコーティングスジャパン株式会社 Coating composition, coating finishing method, and coated article
JP5604870B2 (en) * 2008-03-06 2014-10-15 三菱レイヨン株式会社 Thermosetting coating resin composition
JP5362324B2 (en) * 2008-10-31 2013-12-11 日産自動車株式会社 Coating composition, coating finishing method, and coated article
CA2859861A1 (en) * 2011-12-22 2013-06-27 Bayer Intellectual Property Gmbh Aqueous polyacrylate copolymer dispersions with high oh group content
EP2841970B1 (en) 2012-04-23 2017-11-08 Covestro Deutschland AG Light-resistant polyurethane compound
WO2015033624A1 (en) * 2013-09-09 2015-03-12 関西ペイント株式会社 Coating composition and coated article
JP5692482B1 (en) * 2013-09-10 2015-04-01 関西ペイント株式会社 Coating composition and coated article
JP6402973B2 (en) * 2014-06-06 2018-10-10 凸版印刷株式会社 Non-adsorbing layer forming coating agent and non-adsorbing laminate
WO2016153711A1 (en) * 2015-03-23 2016-09-29 Dow Global Technologies Llc Photocurable compositions for three-dimensional printing
JP6718197B2 (en) * 2015-10-30 2020-07-08 関西ペイント株式会社 Organic solvent-based undercoat coating composition
US10500788B2 (en) * 2017-11-07 2019-12-10 Thermwood Corporation Apparatus and methods for additive manufacturing at ambient temperature
WO2019227319A1 (en) * 2018-05-29 2019-12-05 南通纺织丝绸产业技术研究院 Fluorine-containing polycaprolactone film and preparation method therefor

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6031579A (en) * 1983-07-29 1985-02-18 Dainippon Ink & Chem Inc Coating resin composition
JPH04366191A (en) * 1991-06-14 1992-12-18 Nippon Oil & Fats Co Ltd Coating composition
WO2001038415A1 (en) * 1999-11-23 2001-05-31 E.I. Du Pont De Nemours And Company Clear coating composition having improved early hardness and water resistance
EP1479704A2 (en) * 2003-05-20 2004-11-24 Bayer MaterialScience AG High-solids binder combinations for scratch resistant finishing lacquers

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2101121B (en) * 1981-05-11 1985-07-10 Daicel Chem Process for producing e-caprolactone-modified hydroxyalkyl acrylate or methacrylate and coating copolymer from the same
JP2861146B2 (en) * 1989-11-17 1999-02-24 大日本インキ化学工業株式会社 Resin composition for paint
JPH0418475A (en) * 1990-05-11 1992-01-22 Kansai Paint Co Ltd Top-coating composition
JPH05171103A (en) 1991-12-25 1993-07-09 Nippon Oil & Fats Co Ltd Resin composition for coating
JPH0641496A (en) * 1992-07-21 1994-02-15 Kansai Paint Co Ltd Coating composition, coating film forming method and coated article
JPH07118605A (en) * 1993-10-27 1995-05-09 Kansai Paint Co Ltd Coating composition for top-coating
JPH09157589A (en) 1995-12-08 1997-06-17 Mazda Motor Corp Resin composition for coating having excellent chipping resistance, coating composition using the same, and coating and film forming method thereof
JP2000273393A (en) * 1999-03-26 2000-10-03 Kansai Paint Co Ltd Coating composition
PT1173491E (en) * 1999-04-21 2004-04-30 Ppg Ind Lacke Gmbh POLYMERS
JP2002080781A (en) * 2000-09-11 2002-03-19 Nippon Yushi Basf Coatings Kk Thermosetting coating composition
JP2002105397A (en) 2000-10-04 2002-04-10 Kansai Paint Co Ltd High-solid coating composition
US6652971B1 (en) * 2000-10-30 2003-11-25 E. I. Du Pont De Nemours And Company Hydroxy-functional (meth)acrylic copolymers and coating composition
JP2002256205A (en) * 2000-12-28 2002-09-11 Hitachi Chem Co Ltd Curable coating composition
JP2003313493A (en) 2002-04-23 2003-11-06 Nippon Yushi Basf Coatings Kk Top coating composition, paint finishing method and painted article
JP4443276B2 (en) 2003-03-28 2010-03-31 関西ペイント株式会社 Coating method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6031579A (en) * 1983-07-29 1985-02-18 Dainippon Ink & Chem Inc Coating resin composition
JPH04366191A (en) * 1991-06-14 1992-12-18 Nippon Oil & Fats Co Ltd Coating composition
WO2001038415A1 (en) * 1999-11-23 2001-05-31 E.I. Du Pont De Nemours And Company Clear coating composition having improved early hardness and water resistance
EP1479704A2 (en) * 2003-05-20 2004-11-24 Bayer MaterialScience AG High-solids binder combinations for scratch resistant finishing lacquers

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 198513, Derwent World Patents Index; AN 1985-078371, XP002426676 *
DATABASE WPI Week 199305, Derwent World Patents Index; AN 1993-040738, XP002426677 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102076797B (en) * 2008-07-01 2014-03-12 昭和电工株式会社 Coating composition and coating film formation method using same

Also Published As

Publication number Publication date
WO2006134488A2 (en) 2006-12-21
MX2007013250A (en) 2008-03-13
US7981964B2 (en) 2011-07-19
EP1891175A2 (en) 2008-02-27
EP1891175B1 (en) 2013-08-14
US20100130668A1 (en) 2010-05-27
CA2611560A1 (en) 2006-12-21
JP4872247B2 (en) 2012-02-08
JP2006348172A (en) 2006-12-28

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