WO2007012756A3 - Traitement du gaz résiduaire d'un procédé fischer-tropsch - Google Patents

Traitement du gaz résiduaire d'un procédé fischer-tropsch Download PDF

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Publication number
WO2007012756A3
WO2007012756A3 PCT/FR2006/001824 FR2006001824W WO2007012756A3 WO 2007012756 A3 WO2007012756 A3 WO 2007012756A3 FR 2006001824 W FR2006001824 W FR 2006001824W WO 2007012756 A3 WO2007012756 A3 WO 2007012756A3
Authority
WO
WIPO (PCT)
Prior art keywords
fischer
tropsch process
residue gas
major part
hydrocarbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2006/001824
Other languages
English (en)
Other versions
WO2007012756A2 (fr
Inventor
Martine Schneider
Souza Guillaume De
Paul Wentink
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Priority to US11/996,847 priority Critical patent/US20080300326A1/en
Priority to AU2006273920A priority patent/AU2006273920A1/en
Priority to EP06794222A priority patent/EP1913119A2/fr
Publication of WO2007012756A2 publication Critical patent/WO2007012756A2/fr
Publication of WO2007012756A3 publication Critical patent/WO2007012756A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047Pressure swing adsorption
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/007Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/32Purifying combustible gases containing carbon monoxide with selectively adsorptive solids, e.g. active carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/104Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/16Hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/18Noble gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/22Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/24Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40001Methods relating to additional, e.g. intermediate, treatment of process gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/41Further details for adsorption processes and devices using plural beds of the same adsorbent in series
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Analytical Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Separation Of Gases By Adsorption (AREA)

Abstract

L'invention concerne un procédé de conversion de gaz hydrocarbonés en liquides hydrocarbonés dans lequel le procédé Fischer-Tropsch est mis en oeuvre, ledit procédé Fischer-Tropsch produisant des liquides hydrocarbonés et un gaz résiduaire comprenant au moins de l'hydrogène, du monoxyde de carbone, du dioxyde de carbone et des hydrocarbures présentant un nombre de carbone d'au plus 6, dans lequel le gaz résiduaire est soumis à un procédé de séparation produisant : - au moins un flux gazeux comprenant majoritairement de l'hydrogène, - au moins un flux comprenant majoritairement du méthane, - au moins un flux gazeux comprenant majoritairement des inertes (dioxyde de carbone, azote, argon) et des hydrocarbures présentant un nombre de carbone d'au moins 2.
PCT/FR2006/001824 2005-07-28 2006-07-26 Traitement du gaz résiduaire d'un procédé fischer-tropsch Ceased WO2007012756A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US11/996,847 US20080300326A1 (en) 2005-07-28 2006-07-26 Processing Residue Gas of a Fischer-Tropsch Process
AU2006273920A AU2006273920A1 (en) 2005-07-28 2006-07-26 Processing residue gas of a fischer-tropsch process
EP06794222A EP1913119A2 (fr) 2005-07-28 2006-07-26 Traitement du gaz résiduaire d'un procédé fischer-tropsch

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0552354 2005-07-28
FR0552354A FR2889199A1 (fr) 2005-07-28 2005-07-28 Traitement de gaz residuaire d'un procede fischer-tropsch

Publications (2)

Publication Number Publication Date
WO2007012756A2 WO2007012756A2 (fr) 2007-02-01
WO2007012756A3 true WO2007012756A3 (fr) 2007-03-22

Family

ID=36273391

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2006/001824 Ceased WO2007012756A2 (fr) 2005-07-28 2006-07-26 Traitement du gaz résiduaire d'un procédé fischer-tropsch

Country Status (6)

Country Link
US (1) US20080300326A1 (fr)
EP (1) EP1913119A2 (fr)
AU (1) AU2006273920A1 (fr)
FR (1) FR2889199A1 (fr)
RU (1) RU2008107589A (fr)
WO (1) WO2007012756A2 (fr)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8303676B1 (en) 2008-02-19 2012-11-06 Proton Power, Inc. Conversion of C-O-H compounds into hydrogen for power or heat generation
US9698439B2 (en) 2008-02-19 2017-07-04 Proton Power, Inc. Cellulosic biomass processing for hydrogen extraction
RU2507240C2 (ru) 2008-02-20 2014-02-20 ДжиТиЭлПЕТРОЛ ЭлЭлСи Системы и способы для переработки водорода и моноксида углерода
AU2012330384B2 (en) 2011-10-25 2016-04-14 Shell Internationale Research Maatschappij B.V. Method for processing Fischer-Tropsch off-gas
WO2013060800A1 (fr) 2011-10-25 2013-05-02 Shell Internationale Research Maatschappij B.V. Procédé pour le traitement d'effluent gazeux de procédé fischer-tropsch
US10005961B2 (en) 2012-08-28 2018-06-26 Proton Power, Inc. Methods, systems, and devices for continuous liquid fuel production from biomass
WO2014102393A1 (fr) 2012-12-31 2014-07-03 Shell Internationale Research Maatschappij B.V. Procédé pour traiter un gaz de dégagement de procédé fischer-tropsch
MY177560A (en) 2012-12-31 2020-09-19 Shell Int Research Method for processing fischer-tropsch off-gas
US20150307784A1 (en) * 2014-03-05 2015-10-29 Proton Power, Inc. Continuous liquid fuel production methods, systems, and devices
GB2527372A (en) * 2014-06-21 2015-12-23 Inventure Fuels Ltd Synthesising hydrocarbons
AP2016009598A0 (en) 2014-06-30 2016-11-30 Shell Int Research Method for processing a gas mixture
CN107257775A (zh) 2015-02-10 2017-10-17 国际壳牌研究有限公司 用于获得富氢气的方法和系统
CN107428527A (zh) 2015-03-03 2017-12-01 国际壳牌研究有限公司 用于处理废气和制造氢气的方法
US9890332B2 (en) 2015-03-08 2018-02-13 Proton Power, Inc. Biochar products and production
DE102015004213A1 (de) * 2015-03-31 2016-10-06 Linde Aktiengesellschaft Verfahren und eine Anlage zur Erzeugung von Synthesegas
EP3328965B1 (fr) * 2015-07-28 2019-04-24 Shell International Research Maatschappij B.V. Procede de preparation d'un produit de paraffine

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4259091A (en) * 1978-09-16 1981-03-31 Linde Aktiengesellschaft Adiabatic adsorption method for gas purification or separation
WO2002038699A1 (fr) * 2000-11-10 2002-05-16 Sasol Technology (Proprietary) Limited Production de produits à base d'hydrocarbures liquides
WO2004092306A1 (fr) * 2003-04-15 2004-10-28 L'air Liquide Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Procede de production de liquides hydrocarbones mettant en oeuvre un procede fischer-tropsch

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4259091A (en) * 1978-09-16 1981-03-31 Linde Aktiengesellschaft Adiabatic adsorption method for gas purification or separation
WO2002038699A1 (fr) * 2000-11-10 2002-05-16 Sasol Technology (Proprietary) Limited Production de produits à base d'hydrocarbures liquides
WO2004092306A1 (fr) * 2003-04-15 2004-10-28 L'air Liquide Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude Procede de production de liquides hydrocarbones mettant en oeuvre un procede fischer-tropsch

Also Published As

Publication number Publication date
US20080300326A1 (en) 2008-12-04
WO2007012756A2 (fr) 2007-02-01
AU2006273920A1 (en) 2007-02-01
EP1913119A2 (fr) 2008-04-23
FR2889199A1 (fr) 2007-02-02
RU2008107589A (ru) 2009-09-10

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