WO2007020537A3 - Apparatus for high resolution nmr spectroscopy and/or imaging with an improved filling factor and rf field amplitude - Google Patents

Apparatus for high resolution nmr spectroscopy and/or imaging with an improved filling factor and rf field amplitude Download PDF

Info

Publication number
WO2007020537A3
WO2007020537A3 PCT/IB2006/003399 IB2006003399W WO2007020537A3 WO 2007020537 A3 WO2007020537 A3 WO 2007020537A3 IB 2006003399 W IB2006003399 W IB 2006003399W WO 2007020537 A3 WO2007020537 A3 WO 2007020537A3
Authority
WO
WIPO (PCT)
Prior art keywords
radio frequency
sample
frequency field
coil
nmr spectroscopy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2006/003399
Other languages
French (fr)
Other versions
WO2007020537A2 (en
Inventor
Dimitrios Sakellariou
Jacques-Francois Jacquinot
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to EP06809256A priority Critical patent/EP1910859A2/en
Priority to US11/993,793 priority patent/US8106657B2/en
Priority to JP2008520027A priority patent/JP2008545148A/en
Publication of WO2007020537A2 publication Critical patent/WO2007020537A2/en
Publication of WO2007020537A3 publication Critical patent/WO2007020537A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R33/00—Arrangements or instruments for measuring magnetic variables
    • G01R33/20—Arrangements or instruments for measuring magnetic variables involving magnetic resonance
    • G01R33/28—Details of apparatus provided for in groups G01R33/44 - G01R33/64
    • G01R33/32—Excitation or detection systems, e.g. using radio frequency signals
    • G01R33/34—Constructional details, e.g. resonators, specially adapted to MR
    • G01R33/34046—Volume type coils, e.g. bird-cage coils; Quadrature bird-cage coils; Circularly polarised coils
    • G01R33/34053—Solenoid coils; Toroidal coils
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R33/00—Arrangements or instruments for measuring magnetic variables
    • G01R33/20—Arrangements or instruments for measuring magnetic variables involving magnetic resonance
    • G01R33/28—Details of apparatus provided for in groups G01R33/44 - G01R33/64
    • G01R33/30—Sample handling arrangements, e.g. sample cells, spinning mechanisms
    • G01R33/307—Sample handling arrangements, e.g. sample cells, spinning mechanisms specially adapted for moving the sample relative to the MR system, e.g. spinning mechanisms, flow cells or means for positioning the sample inside a spectrometer
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R33/00—Arrangements or instruments for measuring magnetic variables
    • G01R33/20—Arrangements or instruments for measuring magnetic variables involving magnetic resonance
    • G01R33/28—Details of apparatus provided for in groups G01R33/44 - G01R33/64
    • G01R33/32—Excitation or detection systems, e.g. using radio frequency signals
    • G01R33/34—Constructional details, e.g. resonators, specially adapted to MR
    • G01R33/34092—RF coils specially adapted for NMR spectrometers

Landscapes

  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Investigating Or Analyzing Materials By The Use Of Magnetic Means (AREA)
  • Magnetic Resonance Imaging Apparatus (AREA)
  • Apparatus Associated With Microorganisms And Enzymes (AREA)
  • Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)

Abstract

The present invention concerns an apparatus (1' ) for NMR spectroscopy and/or NMR imaging of a sample. The apparatus comprises a static probe comprising an outer coil for excitation of nuclei of said sample by generating an incident radio frequency field at the Larmor frequency of said nuclei, and for reception of a return radio frequency field emitted by said sample, and a sensitive inner coil (6a' ) which is mounted closely around or in contact with the sample container and which is wirelessly coupled to said outer coil by an electromagnetic radio frequency field. The sensitive inner coil is embedded in an inner spinning rotor (2) which is rotatively mounted inside said static probe and which is integral with said sample container, so that the filling factor and the radio frequency field amplitude in said sensitive coil are maximized.
PCT/IB2006/003399 2005-07-05 2006-07-05 Apparatus for high resolution nmr spectroscopy and/or imaging with an improved filling factor and rf field amplitude Ceased WO2007020537A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP06809256A EP1910859A2 (en) 2005-07-05 2006-07-05 Apparatus for high resolution nmr spectroscopy and/or imaging with an improved filling factor and rf field amplitude
US11/993,793 US8106657B2 (en) 2005-07-05 2006-07-05 Apparatus for high-resolution NMR spectroscopy and/or imaging with an improved filling factor and RF field amplitude
JP2008520027A JP2008545148A (en) 2005-07-05 2006-07-05 High resolution NMR spectroscopy and / or imaging apparatus and method using improved fill factor and RF field amplitude.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PCT/EP2005/007978 WO2007003218A1 (en) 2005-07-05 2005-07-05 Apparatus for high-resolution nmr spectroscopy and/or imaging with an improved filling factor and rf field amplitude
EPPCT/EP2005/007978 2005-07-05

Publications (2)

Publication Number Publication Date
WO2007020537A2 WO2007020537A2 (en) 2007-02-22
WO2007020537A3 true WO2007020537A3 (en) 2007-10-04

Family

ID=35295410

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/EP2005/007978 Ceased WO2007003218A1 (en) 2005-07-05 2005-07-05 Apparatus for high-resolution nmr spectroscopy and/or imaging with an improved filling factor and rf field amplitude
PCT/IB2006/003399 Ceased WO2007020537A2 (en) 2005-07-05 2006-07-05 Apparatus for high resolution nmr spectroscopy and/or imaging with an improved filling factor and rf field amplitude

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/EP2005/007978 Ceased WO2007003218A1 (en) 2005-07-05 2005-07-05 Apparatus for high-resolution nmr spectroscopy and/or imaging with an improved filling factor and rf field amplitude

Country Status (4)

Country Link
US (1) US8106657B2 (en)
JP (1) JP2008545148A (en)
TW (1) TW200710426A (en)
WO (2) WO2007003218A1 (en)

Families Citing this family (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7844344B2 (en) 2004-03-30 2010-11-30 Medtronic, Inc. MRI-safe implantable lead
WO2007003218A1 (en) * 2005-07-05 2007-01-11 Commissariat A L'energie Atomique Apparatus for high-resolution nmr spectroscopy and/or imaging with an improved filling factor and rf field amplitude
EP1968426B1 (en) * 2005-12-19 2013-09-25 Techmin Pty Ltd Induction coil sensing
CA2672798A1 (en) * 2006-12-08 2008-06-12 Doty Scientific, Inc. Improved nmr cryomas probe for high-field wide-bore magnets
US9044593B2 (en) 2007-02-14 2015-06-02 Medtronic, Inc. Discontinuous conductive filler polymer-matrix composites for electromagnetic shielding
US8483842B2 (en) 2007-04-25 2013-07-09 Medtronic, Inc. Lead or lead extension having a conductive body and conductive body contact
JP5112001B2 (en) * 2007-10-16 2013-01-09 株式会社日立製作所 NMR probe
AU2008325088A1 (en) * 2007-11-06 2009-05-14 T2 Biosystems, Inc. Small magnet and RF coil for magnetic resonance relaxometry
WO2009088936A1 (en) * 2008-01-03 2009-07-16 The Government Of The United States Of America, As Represented By The Secretary, Department Of Health And Human Services Mri guidewire
US9037263B2 (en) 2008-03-12 2015-05-19 Medtronic, Inc. System and method for implantable medical device lead shielding
US8754644B2 (en) 2008-06-20 2014-06-17 The University Of Queensland MRI apparatus and method with moving field component
TWI395966B (en) * 2009-01-17 2013-05-11 Univ Nat Taiwan Method of time-domain magnetic resonance imaging and device thereof
US9205253B2 (en) 2009-04-30 2015-12-08 Medtronic, Inc. Shielding an implantable medical lead
US8788061B2 (en) 2009-04-30 2014-07-22 Medtronic, Inc. Termination of a shield within an implantable medical lead
US8063639B2 (en) 2009-07-31 2011-11-22 Agilent Technologies, Inc. Dual-use NMR probe
AU2010298385B2 (en) * 2009-09-22 2014-03-27 Adem, Llc Impedance sensing systems and methods for use in measuring constituents in solid and fluid objects
DE102009047565A1 (en) * 2009-12-07 2011-06-09 Bruker Biospin Ag Method for controlling RF signals in an NMR system and probe head for carrying out the method
JP5508081B2 (en) 2010-03-25 2014-05-28 株式会社神戸製鋼所 Flow-through NMR analyzer
TWI429935B (en) * 2010-08-09 2014-03-11 Shieh Yueh Yang Low magnetic field resonance system
US10292617B2 (en) * 2010-09-30 2019-05-21 Aspect Imaging Ltd. Automated tuning and frequency matching with motor movement of RF coil in a magnetic resonance laboratory animal handling system
US8773125B2 (en) * 2010-12-29 2014-07-08 Schlumberger Technology Corporation Microcoil NMR for downhole microfluidics platform
GB2489205B (en) * 2011-03-14 2014-08-20 Schlumberger Holdings Examining porous samples
US9528814B2 (en) 2011-05-19 2016-12-27 NeoVision, LLC Apparatus and method of using impedance resonance sensor for thickness measurement
GB2493746A (en) * 2011-08-17 2013-02-20 Schlumberger Holdings NMR Flow meter with superconducting polariser
US9465089B2 (en) 2011-12-01 2016-10-11 Neovision Llc NMR spectroscopy device based on resonance type impedance (IR) sensor and method of NMR spectra acquisition
US8952708B2 (en) 2011-12-02 2015-02-10 Neovision Llc Impedance resonance sensor for real time monitoring of different processes and methods of using same
EP2820439B1 (en) * 2012-02-27 2015-06-17 Koninklijke Philips N.V. Magnetic field probe sealed with a metallic plug
US9063196B2 (en) * 2012-03-28 2015-06-23 Battelle Memorial Institute Slow magic angle spinning nuclear magnetic resonance device and process for metabolomics profiling of tissues and biofluids
US9411028B2 (en) 2012-04-14 2016-08-09 Bruker Biospin Corporation Multiple resonance sample coil for magic angle spinning NMR probe
EP2838609B1 (en) 2012-04-19 2019-03-06 Medtronic, Inc. Paired medical lead bodies with braided conductive shields having different physical parameter values
US8746762B2 (en) 2012-06-04 2014-06-10 Steven Darrett Car door shock absorber
GB2505232B (en) 2012-08-23 2018-08-01 Schlumberger Holdings Magnetic resonance examination of porous samples
US9366736B2 (en) * 2012-12-13 2016-06-14 Battelle Memorial Institute Sealed magic angle spinning nuclear magnetic resonance probe and process for spectroscopy of hazardous samples
CN104181480B (en) * 2013-05-21 2017-02-08 上海联影医疗科技有限公司 Method and system for measuring and correcting imaging magnetic field in magnetic resonance device
US9993638B2 (en) 2013-12-14 2018-06-12 Medtronic, Inc. Devices, systems and methods to reduce coupling of a shield and a conductor within an implantable medical lead
WO2016014427A1 (en) 2014-07-23 2016-01-28 Medtronic, Inc. Methods of shielding implantable medical leads and implantable medical lead extensions
WO2016014816A1 (en) 2014-07-24 2016-01-28 Medtronic, Inc. Methods of shielding implantable medical leads and implantable medical lead extensions
US10281416B2 (en) * 2014-08-04 2019-05-07 Waters Technologies Corporation Devices for use in solid-state NMR analysis
US10295487B2 (en) 2014-10-15 2019-05-21 The Curators Of The University Of Missouri In situ NMR parameter monitoring systems and methods for measuring pH and temperature
US10067079B2 (en) * 2014-10-15 2018-09-04 The Curators Of The University Of Missouri Solid state NMR spectroscopy/imaging in situ measuring devices and methods for calibration and determining one or more quantitative properties of a target sample
US9995801B2 (en) 2014-12-02 2018-06-12 University Of Kentucky Research Foundation Static multiple-sample NMR probe
DE102015201023B4 (en) * 2015-01-22 2016-09-15 Siemens Healthcare Gmbh MR field probes with additional turns to improve homogeneity and to limit the measurement volume
KR20160104403A (en) * 2015-02-26 2016-09-05 삼성전자주식회사 Method for charging with wireless and electronic device thereof
JP6677745B2 (en) * 2015-04-15 2020-04-08 日本電子株式会社 High-resolution nuclear magnetic resonance probe for magnetic coupling and use
US11921067B2 (en) * 2015-04-17 2024-03-05 New York University System and method for magnetic resonance mapping of physical and chemical changes in conducting structures
CN104898078A (en) * 2015-06-05 2015-09-09 东南大学 Miniature solenoid coil probe and manufacturing method thereof
WO2017083317A1 (en) * 2015-11-09 2017-05-18 Ohio State Innovation Foundation Non-invasive method for detecting a deadly form of malaria
WO2017203784A1 (en) * 2016-05-26 2017-11-30 国立大学法人九州大学 Overhauser effect mri resonator and overhauser effect mri measurement method
FR3063817B1 (en) * 2017-03-08 2021-02-26 Commissariat Energie Atomique NUCLEAR MAGNETIC RESONANCE MEASUREMENT CELL IN A LIQUID ENVIRONMENT, SYSTEM INCLUDING SUCH A CELL AND ITS USE
EP3709040B1 (en) * 2019-03-13 2025-04-30 Siemens Healthineers AG Method for operating a magnetic field camera
US10908239B1 (en) * 2020-04-14 2021-02-02 Jeol Ltd. Broad band inductive matching of a nuclear magnetic resonance circuit using inductive coupling
JP2023095773A (en) * 2021-12-24 2023-07-06 国立研究開発法人産業技術総合研究所 Resonant circuit and method of manufacturing inductor and capacitor
US12422508B1 (en) 2022-08-26 2025-09-23 Jeol Ltd. Sliding band capacitor inductive coupling in a low temperature nuclear magnetic resonance probe and methods of use
US11726152B1 (en) * 2022-08-26 2023-08-15 Jeol Ltd. Solid sample magnetic coupling high resolution nuclear magnetic resolution probe and method of use
CN117783974B (en) * 2024-02-26 2024-05-28 哈尔滨医科大学 A hydrogen and fluorine double resonance radio frequency coil for rectum
US12584981B2 (en) 2024-03-08 2026-03-24 Jeol Ltd. Inductive tuning with a sliding band capacitor in a low temperature nuclear magnetic resonance probe and methods of use
CN120507416B (en) * 2025-07-22 2025-10-10 中国科学院大连化学物理研究所 Method and device for improving in-situ electrochemical nuclear magnetic resonance sensitivity and signal-to-noise ratio

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990001705A1 (en) * 1988-08-03 1990-02-22 The Regents Of The University Of California Probe for high resolution nmr with sample reorientation
US5424644A (en) * 1992-06-30 1995-06-13 Bruker Analytische Messtechnik Gmbh Probehead for the measuring of magnetic resonance
US5539315A (en) * 1995-03-24 1996-07-23 Bruker Instruments, Inc. NMR probe for cross-polarization measurements
EP0823640A2 (en) * 1996-08-09 1998-02-11 Varian Associates, Inc. Suppression of radiation damping in NMR
US6317091B1 (en) * 1998-09-29 2001-11-13 Siemens Aktiengesellschaft Apparatus for inductively coupling a nuclear magnetic resonance signal into a reception antenna, and medical instrument incorporating such an apparatus
US20030173967A1 (en) * 2002-03-12 2003-09-18 The University Of Chicago Passively shimmed principal detector elements for toroid cavity detector NMR probes

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3038115A (en) * 1957-02-11 1962-06-05 Socony Mobil Oil Co Inc Orientation of nuclear magnetic resonance samples
US4456882A (en) * 1982-01-04 1984-06-26 University Of South Carolina High speed cylindrical nuclear magnetic resonance (NMR) sample spinner
US4940942A (en) * 1989-04-14 1990-07-10 Bartuska Victor J Method and apparatus for conducting variable-temperature solid state magnetic resonance spectroscopy
AU3390697A (en) * 1996-06-11 1998-01-07 California Institute Of Technology Force-detected nuclear magnetic resonance
US6653832B2 (en) * 2001-03-09 2003-11-25 Battelle Memorial Institute Method for high resolution magnetic resonance analysis using magic angle technique
DE10130283C1 (en) * 2001-06-26 2003-03-13 Bruker Biospin Gmbh NMR sample holder and associated operating procedures
GB0212581D0 (en) * 2002-05-30 2002-07-10 Imp College Innovations Ltd Medical analysis device
US7271592B1 (en) * 2004-06-14 2007-09-18 U.S. Department Of Energy Toroid cavity/coil NMR multi-detector
US7081753B2 (en) * 2004-07-26 2006-07-25 Varian, Inc. Multiple tuned scroll coil
WO2007003218A1 (en) * 2005-07-05 2007-01-11 Commissariat A L'energie Atomique Apparatus for high-resolution nmr spectroscopy and/or imaging with an improved filling factor and rf field amplitude

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990001705A1 (en) * 1988-08-03 1990-02-22 The Regents Of The University Of California Probe for high resolution nmr with sample reorientation
US5424644A (en) * 1992-06-30 1995-06-13 Bruker Analytische Messtechnik Gmbh Probehead for the measuring of magnetic resonance
US5539315A (en) * 1995-03-24 1996-07-23 Bruker Instruments, Inc. NMR probe for cross-polarization measurements
EP0823640A2 (en) * 1996-08-09 1998-02-11 Varian Associates, Inc. Suppression of radiation damping in NMR
US6317091B1 (en) * 1998-09-29 2001-11-13 Siemens Aktiengesellschaft Apparatus for inductively coupling a nuclear magnetic resonance signal into a reception antenna, and medical instrument incorporating such an apparatus
US20030173967A1 (en) * 2002-03-12 2003-09-18 The University Of Chicago Passively shimmed principal detector elements for toroid cavity detector NMR probes

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
D.SAKELLARIOU ET AL.: "Rotating micro-coils in Nuclear Magnetic Resonance", 2006, XP002436373, Retrieved from the Internet <URL:http://66.102.9.104/search?q=cache:IzOr7BpUNnIJ:www.enc-conference.org/LongAbs/E070558.2500VER.3.PDF+sakellariou+euromar+2005&hl=de&ct=clnk&cd=1&gl=de> [retrieved on 20070605] *
I.FARNAN ET AL.: "High-resolution solid-state nuclear magnetic resonance experiments on highly radioactive ceramics", REVIEW OF SCIENTIFIC INSTRUMENTS, vol. 75, no. 12, 2004, pages 5232 - 5236, XP002354839 *
SCHNALL M D ET AL: "WIRELESS IMPLANTED MAGNETIC RESONANCE PROBES FOR IN VIVO NMR", JOURNAL OF MAGNETIC RESONANCE, ACADEMIC PRESS, LONDON, GB, vol. 68, no. 1, June 1986 (1986-06-01), pages 161 - 167, XP008048565, ISSN: 0022-2364 *
YAMAUCHI K ET AL: "Implementing solenoid microcoils for wide-line solid-state NMR", JOURNAL OF MAGNETIC RESONANCE, ACADEMIC PRESS, ORLANDO, FL, US, vol. 167, no. 1, March 2004 (2004-03-01), pages 87 - 96, XP004491644, ISSN: 1090-7807 *

Also Published As

Publication number Publication date
US20100156414A1 (en) 2010-06-24
JP2008545148A (en) 2008-12-11
WO2007003218A1 (en) 2007-01-11
TW200710426A (en) 2007-03-16
WO2007020537A2 (en) 2007-02-22
US8106657B2 (en) 2012-01-31

Similar Documents

Publication Publication Date Title
TW200710426A (en) Apparatus and method for NMR spectroscopy and/or imaging with an improved filling factor and RF field amplitude
US6600319B2 (en) Magnetic resonance imaging device
Wiggins et al. High‐performance radiofrequency coils for 23Na MRI: brain and musculoskeletal applications
Hong et al. New design concept of monopole antenna array for UHF 7T MRI
WO2006119085A3 (en) Integrated pet-mri scanner
JP6373192B2 (en) Active position marker for use in MRI equipment
WO2008078284A3 (en) Rf coil for use in an mr imaging system, in combination with a metamaterial
JP2001526920A (en) NMR apparatus and method for non-invasive in vivo testing of patient fluid glucose levels
JP2010518935A (en) Sinusoidally resonating radio frequency volume coil for high field magnetic resonance applications
ATE474231T1 (en) HF VOLUME COIL WITH SELECTABLE FIELD OF VIEW
US20090085567A1 (en) Magnetic resonance apparatus with shim arrangement
WO2006047580A2 (en) System and method for providing a rotating magnetic field
CN103364745A (en) Magnetic resonance tomography apparatus
Barmet et al. Concurrent higher-order field monitoring for routine head MRI: an integrated heteronuclear setup
CA2413115A1 (en) Nuclear magnetic resonance tool with active rf spoiler antenna
US20140347054A1 (en) Magnetic Resonance System with Whole-Body Transmitting Array
Seo et al. A preliminary study for reference RF coil at 11.7 T MRI: Based on electromagnetic field simulation of hybrid-BC RF coil according to diameter and length at 3.0, 7.0 and 11.7 T
WO2007075625A3 (en) Dual- frequency endo-rectal mr receive-only probe
WO2006033047A3 (en) Adjustment of rf-field homogeneity in high-field mr imaging
WO2012172471A3 (en) Optical angular momentum induced hyperpolarisation in interventional applications
JPS62101007A (en) Surface coil for nuclear magnetic resonance inspection
US9576712B2 (en) Magnetic circuit for magnetic field generator
US20050174115A1 (en) Magnetic resonance system
JP5069471B2 (en) Planar RF resonator for open MRI systems
US6943552B2 (en) Magnetic resonance system with a transport element, an examination tunnel and an outer antenna arrangement

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 2008520027

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

WWW Wipo information: withdrawn in national office

Country of ref document: DE

WWE Wipo information: entry into national phase

Ref document number: 2006809256

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 11993793

Country of ref document: US

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 06809256

Country of ref document: EP

Kind code of ref document: A2

WWP Wipo information: published in national office

Ref document number: 2006809256

Country of ref document: EP