WO2007093532A3 - Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen - Google Patents

Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen Download PDF

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Publication number
WO2007093532A3
WO2007093532A3 PCT/EP2007/051148 EP2007051148W WO2007093532A3 WO 2007093532 A3 WO2007093532 A3 WO 2007093532A3 EP 2007051148 W EP2007051148 W EP 2007051148W WO 2007093532 A3 WO2007093532 A3 WO 2007093532A3
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WO
WIPO (PCT)
Prior art keywords
copper
material streams
adsorption composition
adsorption
oxides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2007/051148
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English (en)
French (fr)
Other versions
WO2007093532A2 (de
Inventor
Stephan Hatscher
Michael Hesse
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP07704406A priority Critical patent/EP1986773A2/de
Priority to JP2008553755A priority patent/JP2009526628A/ja
Priority to US12/279,358 priority patent/US20090098036A1/en
Publication of WO2007093532A2 publication Critical patent/WO2007093532A2/de
Publication of WO2007093532A3 publication Critical patent/WO2007093532A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3483—Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20715—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/502—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/56—Use in the form of a bed
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

Kohlenmonoxid wird aus Stoffströmen entfernt durch Adsorption an einer Kupfer-, Zink- und Zirkonoxide enthaltenden Adsorptionsmasse, deren Kupfer enthaltender Anteil einen Reduktionsgrad, ausgedrückt als Gewichtsverhältnis von metallischem Kupfer zur Summe aus metallischem Kupfer und Kupferoxiden, gerechnet als CuO, von mindestens 90 % und höchstens 97 % aufweist.
PCT/EP2007/051148 2006-02-14 2007-02-07 Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen Ceased WO2007093532A2 (de)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP07704406A EP1986773A2 (de) 2006-02-14 2007-02-07 Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen
JP2008553755A JP2009526628A (ja) 2006-02-14 2007-02-07 吸着組成物及び流れからのｃｏの除去方法
US12/279,358 US20090098036A1 (en) 2006-02-14 2007-02-07 Adsorption composition and method of removing co from streams

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP06101648 2006-02-14
EP06101648.1 2006-02-14

Publications (2)

Publication Number Publication Date
WO2007093532A2 WO2007093532A2 (de) 2007-08-23
WO2007093532A3 true WO2007093532A3 (de) 2007-11-22

Family

ID=38283990

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2007/051148 Ceased WO2007093532A2 (de) 2006-02-14 2007-02-07 Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen

Country Status (7)

Country Link
US (1) US20090098036A1 (de)
EP (1) EP1986773A2 (de)
JP (1) JP2009526628A (de)
CN (1) CN101384355A (de)
RU (1) RU2008136690A (de)
WO (1) WO2007093532A2 (de)
ZA (1) ZA200807783B (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20090086106A (ko) * 2006-12-01 2009-08-10 바스프 에스이 흡착 조성물 및 스트림으로부터 ｃｏ의 제거 방법
US8597407B2 (en) * 2008-12-17 2013-12-03 Basf Se Method for removing contaminants from gas flows containing water
CN111122793B (zh) * 2020-01-09 2022-08-05 宁波博之越环境科技有限公司 空气质量多组分气体颗粒物在线分析仪
CN117920128B (zh) * 2022-10-25 2026-06-30 中国石油化工股份有限公司 用于烯烃歧化原料除co和h2的净化剂及其制备方法和应用
CN117548111B (zh) * 2023-10-25 2024-06-11 广东绿峰能源科技有限公司 一种天然气制氢用催化剂及其制备方法与应用

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3676516A (en) * 1970-05-18 1972-07-11 Phillips Petroleum Co Purification of ethylene or propylene streams containing carbon monoxide
US4552861A (en) * 1984-03-02 1985-11-12 Institut Francais Du Petrole Process for manufacturing catalysts containing copper, zinc, aluminum and at least one metal from the group formed of rare earths and zirconium and the resultant catalysts for reactions involving a synthesis gas
EP0296734A1 (de) * 1987-06-22 1988-12-28 Imperial Chemical Industries Plc Kupferkatalysator für die Umwandlung von Kohlenoxid
US4835132A (en) * 1986-01-29 1989-05-30 Dyson Refractories Limited Catalyst and method of making a precursor for the catalyst
US5328672A (en) * 1991-09-03 1994-07-12 Ford Motor Company Method for purification of lean-burn engine exhaust gas
WO1995021146A1 (en) * 1994-02-07 1995-08-10 Exxon Chemical Patents Inc. Removal of carbon monoxide from hydrocarbon streams
WO1996014280A1 (en) * 1994-11-07 1996-05-17 Shell Internationale Research Maatschappij B.V. Process and catalyst for the direct hydrogenation of carboxylic esters
DE19848595A1 (de) * 1998-10-21 2000-04-27 Basf Ag Hochtemperaturstabile Katalysatoren zur Zersetzung von N¶2¶0
DE19950325A1 (de) * 1999-10-19 2001-04-26 Basf Ag Spinellmonolith-Katalysator und Verfahren zu seiner Herstellung
DE10241529A1 (de) * 2002-09-05 2004-03-11 Basf Ag Adsorptionsmasse und Verfahren zur Entfernung von Kohlenmonoxid aus Stoffströmen

Family Cites Families (11)

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NL156117B (nl) * 1968-06-17 1978-03-15 Stamicarbon Werkwijze voor het zuiveren van etheen en/of propeen.
US4173090A (en) * 1978-05-11 1979-11-06 High Standard, Inc. Cylinder-locking device for revolvers
US4593148A (en) * 1985-03-25 1986-06-03 Phillips Petroleum Company Process for removal of arsine impurities from gases containing arsine and hydrogen sulfide
FR2595689B1 (fr) * 1986-03-17 1988-11-04 Inst Francais Du Petrole Procede de fabrication d'un melange d'alcools primaires a partir de gaz de synthese en presence d'un catalyseur contenant du cuivre, du cobalt, du zinc et au moins un metal alcalin et/ou alcalino-terreux
GB8610196D0 (en) * 1986-04-25 1986-05-29 Ici Plc Sulphur compounds removal
US4917711A (en) * 1987-12-01 1990-04-17 Peking University Adsorbents for use in the separation of carbon monoxide and/or unsaturated hydrocarbons from mixed gases
US5589151A (en) * 1993-12-31 1996-12-31 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process for the preparation of high-purity liquid nitrogen
FR2735990B1 (fr) * 1995-06-30 1997-08-14 Air Liquide Procede et dispositif pour la preparation d'un flux substantiellement epure en l'une au moins des impuretes oxygene et monoxyde de carbone
FR2751243B1 (fr) * 1996-07-22 1998-08-21 Air Liquide Elimination o2/co d'un gaz inerte par adsoption sur oxyde metallique poreux
JP2000143209A (ja) * 1998-11-05 2000-05-23 Idemitsu Kosan Co Ltd 一酸化炭素の転化方法および触媒
DE10124962A1 (de) * 2001-05-21 2002-12-05 Basf Ag Katalysatoren für die Reinigung von Ethylen

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3676516A (en) * 1970-05-18 1972-07-11 Phillips Petroleum Co Purification of ethylene or propylene streams containing carbon monoxide
US4552861A (en) * 1984-03-02 1985-11-12 Institut Francais Du Petrole Process for manufacturing catalysts containing copper, zinc, aluminum and at least one metal from the group formed of rare earths and zirconium and the resultant catalysts for reactions involving a synthesis gas
US4835132A (en) * 1986-01-29 1989-05-30 Dyson Refractories Limited Catalyst and method of making a precursor for the catalyst
EP0296734A1 (de) * 1987-06-22 1988-12-28 Imperial Chemical Industries Plc Kupferkatalysator für die Umwandlung von Kohlenoxid
US5328672A (en) * 1991-09-03 1994-07-12 Ford Motor Company Method for purification of lean-burn engine exhaust gas
WO1995021146A1 (en) * 1994-02-07 1995-08-10 Exxon Chemical Patents Inc. Removal of carbon monoxide from hydrocarbon streams
WO1996014280A1 (en) * 1994-11-07 1996-05-17 Shell Internationale Research Maatschappij B.V. Process and catalyst for the direct hydrogenation of carboxylic esters
DE19848595A1 (de) * 1998-10-21 2000-04-27 Basf Ag Hochtemperaturstabile Katalysatoren zur Zersetzung von N¶2¶0
DE19950325A1 (de) * 1999-10-19 2001-04-26 Basf Ag Spinellmonolith-Katalysator und Verfahren zu seiner Herstellung
DE10241529A1 (de) * 2002-09-05 2004-03-11 Basf Ag Adsorptionsmasse und Verfahren zur Entfernung von Kohlenmonoxid aus Stoffströmen

Also Published As

Publication number Publication date
US20090098036A1 (en) 2009-04-16
EP1986773A2 (de) 2008-11-05
CN101384355A (zh) 2009-03-11
RU2008136690A (ru) 2010-03-20
WO2007093532A2 (de) 2007-08-23
JP2009526628A (ja) 2009-07-23
ZA200807783B (en) 2010-01-27

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