WO2007093532A3 - Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen - Google Patents

Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen Download PDF

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Publication number
WO2007093532A3
WO2007093532A3 PCT/EP2007/051148 EP2007051148W WO2007093532A3 WO 2007093532 A3 WO2007093532 A3 WO 2007093532A3 EP 2007051148 W EP2007051148 W EP 2007051148W WO 2007093532 A3 WO2007093532 A3 WO 2007093532A3
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WO
WIPO (PCT)
Prior art keywords
copper
material streams
adsorption composition
adsorption
oxides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2007/051148
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English (en)
French (fr)
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WO2007093532A2 (de
Inventor
Stephan Hatscher
Michael Hesse
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BASF SE
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BASF SE
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Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP07704406A priority Critical patent/EP1986773A2/de
Priority to US12/279,358 priority patent/US20090098036A1/en
Priority to JP2008553755A priority patent/JP2009526628A/ja
Publication of WO2007093532A2 publication Critical patent/WO2007093532A2/de
Publication of WO2007093532A3 publication Critical patent/WO2007093532A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/945Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3007Moulding, shaping or extruding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3078Thermal treatment, e.g. calcining or pyrolizing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/32Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234Inorganic material layers
    • B01J20/3236Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3433Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/345Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3483Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20715Zirconium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20761Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/502Carbon monoxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/50Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/56Use in the form of a bed
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

Kohlenmonoxid wird aus Stoffströmen entfernt durch Adsorption an einer Kupfer-, Zink- und Zirkonoxide enthaltenden Adsorptionsmasse, deren Kupfer enthaltender Anteil einen Reduktionsgrad, ausgedrückt als Gewichtsverhältnis von metallischem Kupfer zur Summe aus metallischem Kupfer und Kupferoxiden, gerechnet als CuO, von mindestens 90 % und höchstens 97 % aufweist.
PCT/EP2007/051148 2006-02-14 2007-02-07 Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen Ceased WO2007093532A2 (de)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP07704406A EP1986773A2 (de) 2006-02-14 2007-02-07 Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen
US12/279,358 US20090098036A1 (en) 2006-02-14 2007-02-07 Adsorption composition and method of removing co from streams
JP2008553755A JP2009526628A (ja) 2006-02-14 2007-02-07 吸着組成物及び流れからのcoの除去方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP06101648.1 2006-02-14
EP06101648 2006-02-14

Publications (2)

Publication Number Publication Date
WO2007093532A2 WO2007093532A2 (de) 2007-08-23
WO2007093532A3 true WO2007093532A3 (de) 2007-11-22

Family

ID=38283990

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2007/051148 Ceased WO2007093532A2 (de) 2006-02-14 2007-02-07 Adsorptionsmasse und verfahren zur entfernung von co aus stoffströmen

Country Status (7)

Country Link
US (1) US20090098036A1 (de)
EP (1) EP1986773A2 (de)
JP (1) JP2009526628A (de)
CN (1) CN101384355A (de)
RU (1) RU2008136690A (de)
WO (1) WO2007093532A2 (de)
ZA (1) ZA200807783B (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101547733B (zh) * 2006-12-01 2014-01-22 巴斯夫欧洲公司 吸附组合物和从料流中除去co的方法
JP2012512018A (ja) * 2008-12-17 2012-05-31 ビーエーエスエフ ソシエタス・ヨーロピア 水を含有するガス流から夾雑物を除去する方法
CN111122793B (zh) * 2020-01-09 2022-08-05 宁波博之越环境科技有限公司 空气质量多组分气体颗粒物在线分析仪
CN117920128A (zh) * 2022-10-25 2024-04-26 中国石油化工股份有限公司 用于烯烃歧化原料除co和h2的净化剂及其制备方法和应用
CN117548111B (zh) * 2023-10-25 2024-06-11 广东绿峰能源科技有限公司 一种天然气制氢用催化剂及其制备方法与应用

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3676516A (en) * 1970-05-18 1972-07-11 Phillips Petroleum Co Purification of ethylene or propylene streams containing carbon monoxide
US4552861A (en) * 1984-03-02 1985-11-12 Institut Francais Du Petrole Process for manufacturing catalysts containing copper, zinc, aluminum and at least one metal from the group formed of rare earths and zirconium and the resultant catalysts for reactions involving a synthesis gas
EP0296734A1 (de) * 1987-06-22 1988-12-28 Imperial Chemical Industries Plc Kupferkatalysator für die Umwandlung von Kohlenoxid
US4835132A (en) * 1986-01-29 1989-05-30 Dyson Refractories Limited Catalyst and method of making a precursor for the catalyst
US5328672A (en) * 1991-09-03 1994-07-12 Ford Motor Company Method for purification of lean-burn engine exhaust gas
WO1995021146A1 (en) * 1994-02-07 1995-08-10 Exxon Chemical Patents Inc. Removal of carbon monoxide from hydrocarbon streams
WO1996014280A1 (en) * 1994-11-07 1996-05-17 Shell Internationale Research Maatschappij B.V. Process and catalyst for the direct hydrogenation of carboxylic esters
DE19848595A1 (de) * 1998-10-21 2000-04-27 Basf Ag Hochtemperaturstabile Katalysatoren zur Zersetzung von N¶2¶0
DE19950325A1 (de) * 1999-10-19 2001-04-26 Basf Ag Spinellmonolith-Katalysator und Verfahren zu seiner Herstellung
DE10241529A1 (de) * 2002-09-05 2004-03-11 Basf Ag Adsorptionsmasse und Verfahren zur Entfernung von Kohlenmonoxid aus Stoffströmen

Family Cites Families (11)

* Cited by examiner, † Cited by third party
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NL156117B (nl) * 1968-06-17 1978-03-15 Stamicarbon Werkwijze voor het zuiveren van etheen en/of propeen.
US4173090A (en) * 1978-05-11 1979-11-06 High Standard, Inc. Cylinder-locking device for revolvers
US4593148A (en) * 1985-03-25 1986-06-03 Phillips Petroleum Company Process for removal of arsine impurities from gases containing arsine and hydrogen sulfide
FR2595689B1 (fr) * 1986-03-17 1988-11-04 Inst Francais Du Petrole Procede de fabrication d'un melange d'alcools primaires a partir de gaz de synthese en presence d'un catalyseur contenant du cuivre, du cobalt, du zinc et au moins un metal alcalin et/ou alcalino-terreux
GB8610196D0 (en) * 1986-04-25 1986-05-29 Ici Plc Sulphur compounds removal
US4917711A (en) * 1987-12-01 1990-04-17 Peking University Adsorbents for use in the separation of carbon monoxide and/or unsaturated hydrocarbons from mixed gases
US5589151A (en) * 1993-12-31 1996-12-31 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process for the preparation of high-purity liquid nitrogen
FR2735990B1 (fr) * 1995-06-30 1997-08-14 Air Liquide Procede et dispositif pour la preparation d'un flux substantiellement epure en l'une au moins des impuretes oxygene et monoxyde de carbone
FR2751243B1 (fr) * 1996-07-22 1998-08-21 Air Liquide Elimination o2/co d'un gaz inerte par adsoption sur oxyde metallique poreux
JP2000143209A (ja) * 1998-11-05 2000-05-23 Idemitsu Kosan Co Ltd 一酸化炭素の転化方法および触媒
DE10124962A1 (de) * 2001-05-21 2002-12-05 Basf Ag Katalysatoren für die Reinigung von Ethylen

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3676516A (en) * 1970-05-18 1972-07-11 Phillips Petroleum Co Purification of ethylene or propylene streams containing carbon monoxide
US4552861A (en) * 1984-03-02 1985-11-12 Institut Francais Du Petrole Process for manufacturing catalysts containing copper, zinc, aluminum and at least one metal from the group formed of rare earths and zirconium and the resultant catalysts for reactions involving a synthesis gas
US4835132A (en) * 1986-01-29 1989-05-30 Dyson Refractories Limited Catalyst and method of making a precursor for the catalyst
EP0296734A1 (de) * 1987-06-22 1988-12-28 Imperial Chemical Industries Plc Kupferkatalysator für die Umwandlung von Kohlenoxid
US5328672A (en) * 1991-09-03 1994-07-12 Ford Motor Company Method for purification of lean-burn engine exhaust gas
WO1995021146A1 (en) * 1994-02-07 1995-08-10 Exxon Chemical Patents Inc. Removal of carbon monoxide from hydrocarbon streams
WO1996014280A1 (en) * 1994-11-07 1996-05-17 Shell Internationale Research Maatschappij B.V. Process and catalyst for the direct hydrogenation of carboxylic esters
DE19848595A1 (de) * 1998-10-21 2000-04-27 Basf Ag Hochtemperaturstabile Katalysatoren zur Zersetzung von N¶2¶0
DE19950325A1 (de) * 1999-10-19 2001-04-26 Basf Ag Spinellmonolith-Katalysator und Verfahren zu seiner Herstellung
DE10241529A1 (de) * 2002-09-05 2004-03-11 Basf Ag Adsorptionsmasse und Verfahren zur Entfernung von Kohlenmonoxid aus Stoffströmen

Also Published As

Publication number Publication date
ZA200807783B (en) 2010-01-27
RU2008136690A (ru) 2010-03-20
WO2007093532A2 (de) 2007-08-23
JP2009526628A (ja) 2009-07-23
CN101384355A (zh) 2009-03-11
EP1986773A2 (de) 2008-11-05
US20090098036A1 (en) 2009-04-16

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