WO2007109240A3 - Silicone polyether elastomer gels - Google Patents
Silicone polyether elastomer gels Download PDFInfo
- Publication number
- WO2007109240A3 WO2007109240A3 PCT/US2007/006833 US2007006833W WO2007109240A3 WO 2007109240 A3 WO2007109240 A3 WO 2007109240A3 US 2007006833 W US2007006833 W US 2007006833W WO 2007109240 A3 WO2007109240 A3 WO 2007109240A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- silicone polyether
- polyether elastomer
- molecule
- elastomer gels
- gel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/671—Vitamin A; Derivatives thereof, e.g. ester of vitamin A acid, ester of retinol, retinol, retinal
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
- C08L83/12—Block- or graft-copolymers containing polysiloxane sequences containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/045—Polysiloxanes containing less than 25 silicon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/50—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms by carbon linkages
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dermatology (AREA)
- Dispersion Chemistry (AREA)
- Emergency Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
- Silicon Polymers (AREA)
Abstract
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07753459.2A EP2001933B9 (en) | 2006-03-21 | 2007-03-20 | Silicone polyether elastomer gels |
| KR1020087025573A KR101387294B1 (en) | 2006-03-21 | 2007-03-20 | Silicone polyether elastomer gels |
| JP2009501498A JP5424866B2 (en) | 2006-03-21 | 2007-03-20 | Silicone polyether elastomer gel |
| US12/293,580 US8273840B2 (en) | 2006-03-21 | 2007-03-20 | Silicone polyether elastomer gels |
| CN2007800155956A CN101432340B (en) | 2006-03-21 | 2007-03-20 | Silicone polyether elastomer gel |
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78434006P | 2006-03-21 | 2006-03-21 | |
| US60/784,340 | 2006-03-21 | ||
| US79986406P | 2006-05-12 | 2006-05-12 | |
| US60/799,864 | 2006-05-12 | ||
| US83880206P | 2006-08-18 | 2006-08-18 | |
| US60/838,802 | 2006-08-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2007109240A2 WO2007109240A2 (en) | 2007-09-27 |
| WO2007109240A3 true WO2007109240A3 (en) | 2008-05-29 |
Family
ID=38523036
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2007/006833 Ceased WO2007109240A2 (en) | 2006-03-21 | 2007-03-20 | Silicone polyether elastomer gels |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8273840B2 (en) |
| EP (1) | EP2001933B9 (en) |
| JP (1) | JP5424866B2 (en) |
| KR (1) | KR101387294B1 (en) |
| WO (1) | WO2007109240A2 (en) |
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2001934B9 (en) * | 2006-03-21 | 2016-02-24 | Dow Corning Corporation | Silicone-organic elastomer gels |
| JP5424866B2 (en) | 2006-03-21 | 2014-02-26 | ダウ・コーニング・コーポレイション | Silicone polyether elastomer gel |
| KR20090094044A (en) * | 2006-12-29 | 2009-09-02 | 다우 코닝 코포레이션 | Personal care compositions containing silicone elastomer gels |
| KR20100075855A (en) | 2007-09-25 | 2010-07-05 | 다우 코닝 코포레이션 | Emulsions of silicone elastomer and silicone organic elastomer gels |
| CN101808610B (en) * | 2007-09-26 | 2013-08-28 | 陶氏康宁公司 | Personal care compositions containing silicone-organic gels from polyalkyloxylene crosslinked silicone elastomers |
| KR20100065161A (en) * | 2007-09-26 | 2010-06-15 | 다우 코닝 코포레이션 | Personal care compositions containing hydrophobic silicone-organic gel blends |
| US8222363B2 (en) | 2007-09-26 | 2012-07-17 | Dow Corning Corporation | Silicone organic elastomer gels from organopolysiloxane resins |
| US20100092408A1 (en) * | 2008-10-14 | 2010-04-15 | Laurie Ellen Breyfogle | Resilient personal care composition comprising polyalkyl ether containing siloxane elastomers |
| DE102008053786A1 (en) * | 2008-10-22 | 2011-12-15 | Beiersdorf Ag | Hair care preparations with novel siloxane elastomers |
| DE102008053791A1 (en) | 2008-10-22 | 2010-04-29 | Beiersdorf Ag | Cosmetic formulation with siloxane elastomers and particulate matter |
| DE102008053782A1 (en) | 2008-10-22 | 2010-06-10 | Beiersdorf Ag | Use of ABC siloxane elastomers obtained from reacting organohydrogen siloxane with substance containing e.g. hydrocarbon, and hydrosilylation catalyst, in cosmetic shaving preparations to improve sliding and cutting capacity while shaving |
| DE102008053788A1 (en) | 2008-10-22 | 2010-04-29 | Beiersdorf Ag | Cosmetic formulation with siloxane elastomers to improve microbiological stability |
| DE102009049721A1 (en) | 2008-10-22 | 2010-04-29 | Beiersdorf Ag | Cosmetic formulation, useful e.g. for permanent browning of skin, comprises e.g. siloxane elastomers, obtained from reaction of organohydrogen siloxane with substances or mixtures containing e.g. aliphatic unsaturated groups |
| DE102008053789A1 (en) | 2008-10-22 | 2010-04-29 | Beiersdorf Ag | Cosmetic formulation with novel siloxane elastomers |
| WO2010080755A2 (en) * | 2009-01-07 | 2010-07-15 | Dow Corning Corporation | Silicone paste compositions |
| EP2408422A2 (en) * | 2009-03-20 | 2012-01-25 | The Procter & Gamble Company | Personal-care composition comprising a hydrocarbon wax and a polar oil |
| US8088364B2 (en) * | 2009-03-20 | 2012-01-03 | The Procter & Gamble Company | Personal-care composition comprising oil-soluble solid sunscreens |
| WO2010111267A2 (en) * | 2009-03-23 | 2010-09-30 | The Procter & Gamble Company | Personal-care composition comprising a cationic active |
| WO2010111266A2 (en) * | 2009-03-23 | 2010-09-30 | The Procter & Gamble Company | Personal-care composition comprising a cationic active |
| WO2011028765A1 (en) * | 2009-09-03 | 2011-03-10 | Dow Corning Corporation | Personal care compositions with pituitous silicone fluids |
| KR20120059599A (en) * | 2009-09-03 | 2012-06-08 | 다우 코닝 코포레이션 | Pituitous silicone fluids |
| EP2491065B1 (en) | 2009-10-23 | 2014-11-26 | Dow Corning Corporation | Hydrophilically-modified silicone compositions |
| EP2609140B1 (en) | 2010-08-23 | 2014-06-11 | Dow Corning Corporation | Emulsions containing saccharide siloxane copolymer emulsifiers and methods for their preparation and use |
| EP2609141A1 (en) | 2010-08-23 | 2013-07-03 | Dow Corning Corporation | Emulsions containing saccharide siloxane copolymer emulsifiers and methods for their preparation and use |
| US9192564B2 (en) | 2010-08-23 | 2015-11-24 | Dow Corning Corporation | Saccharide siloxane copolymers and methods for their preparation and use |
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| CA2825016C (en) * | 2011-01-24 | 2021-02-16 | Yissum Research Development Company Of The Hebrew University Of Jerusalem Ltd. | Nanoparticles for dermal and systemic delivery of drugs |
| KR101864579B1 (en) * | 2011-05-30 | 2018-06-07 | 다우 코닝 도레이 캄파니 리미티드 | Organopolysiloxane elastomer modified with mono-/diglycerin derivative, and use therefor |
| JP2015507671A (en) * | 2011-12-21 | 2015-03-12 | ダウ コーニング コーポレーションDow Corning Corporation | Hydrophilic silicone gel adhesive |
| WO2013096332A1 (en) * | 2011-12-21 | 2013-06-27 | Dow Corning Corporation | Polymerizable hybrid polysiloxanes and preparation |
| JP6313540B2 (en) | 2011-12-27 | 2018-04-18 | 東レ・ダウコーニング株式会社 | Diglycerin derivative-modified silicone, emulsifier for water-in-oil emulsion containing the same, external preparation and cosmetic |
| JP6369888B2 (en) | 2011-12-27 | 2018-08-08 | 東レ・ダウコーニング株式会社 | Novel liquid organopolysiloxane and use thereof |
| JP6369887B2 (en) | 2011-12-27 | 2018-08-08 | 東レ・ダウコーニング株式会社 | Novel co-modified organopolysiloxane, treatment agent containing the same, and external preparation |
| JP6105920B2 (en) | 2011-12-27 | 2017-03-29 | 東レ・ダウコーニング株式会社 | Co-modified organopolysiloxane, emulsifier for water-in-oil emulsion containing the same, external preparation and cosmetic |
| US20130230474A1 (en) | 2012-03-01 | 2013-09-05 | The Procter & Gamble Company | Sunscreen Composition Comprising UV Composite |
| US9549891B2 (en) | 2012-03-19 | 2017-01-24 | The Procter & Gamble Company | Superabsorbent polymers and sunscreen actives for use in skin care compositions |
| JP6063197B2 (en) | 2012-10-02 | 2017-01-18 | 東レ・ダウコーニング株式会社 | Novel co-modified organopolysiloxane, powder treating agent and powder composition containing the same |
| JP6022289B2 (en) | 2012-10-02 | 2016-11-09 | 東レ・ダウコーニング株式会社 | Treatment agent and cosmetic comprising co-modified organopolysiloxane |
| US20140178314A1 (en) | 2012-12-19 | 2014-06-26 | The Procter & Gamble Company | Compositions and/or articles with improved solubility of a solid active |
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| EP3009466B1 (en) | 2013-06-13 | 2021-02-24 | Dow Toray Co., Ltd. | Silicone modified by long-chain hydrocarbon group-containing diglycerin derivative, and use thereof |
| CN105531301B (en) | 2013-10-31 | 2018-04-20 | 道康宁公司 | Crosslinked compositions and methods of forming the same |
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| JP6585066B2 (en) | 2013-10-31 | 2019-10-02 | ダウ シリコーンズ コーポレーション | Cross-linked composition and method for producing the same |
| CN104800102A (en) * | 2014-01-29 | 2015-07-29 | 道康宁公司 | Elastomer-containing cosmetic composition |
| EP3126450B1 (en) | 2014-04-03 | 2025-02-19 | Dow Toray Co., Ltd. | Novel silicone surfactant, w/o emulsion composition, powder composition, and cosmetic/medical application thereof |
| CN106232100B (en) | 2014-04-28 | 2020-08-28 | 美国陶氏有机硅公司 | Cross-linked composition and cosmetic composition comprising the same |
| US10940099B2 (en) | 2015-04-08 | 2021-03-09 | Dow Silicones Corporation | Pituitous silicone emulsions |
| US10285926B2 (en) | 2015-06-29 | 2019-05-14 | The Procter & Gamble Company | Superabsorbent polymers and starch powders for use in skin care compositions |
| US10933011B2 (en) | 2016-03-14 | 2021-03-02 | Dow Silicones Corporation | Composition and method of preparation |
| JP6949831B2 (en) | 2016-05-02 | 2021-10-13 | ダウ・東レ株式会社 | Silicone particles, cosmetics and paints containing them, and resins |
| WO2018081005A1 (en) | 2016-10-25 | 2018-05-03 | Access Business Group International Llc | Compositions of lithospermum erythrorhizon (gromwell root) and methods of making and using the compositions |
| US10918587B2 (en) | 2017-03-08 | 2021-02-16 | Dow Silicones Corporation | Long lasting cosmetic composition comprising silicone elastomer |
| WO2019045831A1 (en) * | 2017-08-31 | 2019-03-07 | Dow Silicones Corporation | Film forming compositions having a tack-free surface |
| EP3732229A4 (en) * | 2017-12-30 | 2021-12-29 | Saint-Gobain Performance Plastics Corporation | Heterochain polymer composition |
| US11771630B2 (en) * | 2018-08-10 | 2023-10-03 | Shiseido Company, Ltd. | Oil-based cosmetic |
| EP3834810A4 (en) | 2018-08-10 | 2022-05-04 | Shiseido Company, Ltd. | COSMETIC PRODUCT IN EMULSION |
| CN118667167B (en) * | 2024-08-20 | 2024-11-29 | 浙江润禾有机硅新材料有限公司 | Organosilicon elastomer, gel, preparation method and application |
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- 2007-03-20 KR KR1020087025573A patent/KR101387294B1/en not_active Expired - Fee Related
- 2007-03-20 WO PCT/US2007/006833 patent/WO2007109240A2/en not_active Ceased
- 2007-03-20 US US12/293,580 patent/US8273840B2/en not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2009530476A (en) | 2009-08-27 |
| EP2001933A2 (en) | 2008-12-17 |
| WO2007109240A2 (en) | 2007-09-27 |
| EP2001933B9 (en) | 2016-02-17 |
| KR20080108558A (en) | 2008-12-15 |
| KR101387294B1 (en) | 2014-04-18 |
| US20100158824A1 (en) | 2010-06-24 |
| EP2001933B1 (en) | 2015-11-04 |
| JP5424866B2 (en) | 2014-02-26 |
| US8273840B2 (en) | 2012-09-25 |
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