WO2007136873A3 - Process for decarboxylation of fatty acids and oils to produce paraffins or olefins - Google Patents

Process for decarboxylation of fatty acids and oils to produce paraffins or olefins Download PDF

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Publication number
WO2007136873A3
WO2007136873A3 PCT/US2007/012226 US2007012226W WO2007136873A3 WO 2007136873 A3 WO2007136873 A3 WO 2007136873A3 US 2007012226 W US2007012226 W US 2007012226W WO 2007136873 A3 WO2007136873 A3 WO 2007136873A3
Authority
WO
WIPO (PCT)
Prior art keywords
oils
decarboxylation
olefins
fatty acids
feedstock
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2007/012226
Other languages
French (fr)
Other versions
WO2007136873A2 (en
Inventor
Jeffrey John Scheibel
Randall Thomas Reilman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP07809147A priority Critical patent/EP2024467A2/en
Publication of WO2007136873A2 publication Critical patent/WO2007136873A2/en
Publication of WO2007136873A3 publication Critical patent/WO2007136873A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42Catalytic treatment
    • C10G3/44Catalytic treatment characterised by the catalyst used
    • C10G3/48Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00Reforming naphtha
    • C10G35/04Catalytic reforming
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1011Biomass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20C2-C4 olefins
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22Higher olefins
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Detergent Compositions (AREA)
  • Catalysts (AREA)

Abstract

The invention is directed to a process of decarboxylation of natural fats and oils comprising the use of an activated acidic catalyst essentially free of Group VIII metals. Embodiments of the present process comprise the steps of supplying a feedstock comprising of natural fats, oils and mixtures thereof to a reaction vessel, subjecting the feedstock to an activated acidic catalyst essentially free of Group VIII metals, purging the reaction vessel with an inert gas; and subjecting the feedstock and catalyst to a temperature of from about 250°C to about 500°C.
PCT/US2007/012226 2006-05-19 2007-05-19 Process for decarboxylation of fatty acids and oils to produce paraffins or olefins Ceased WO2007136873A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP07809147A EP2024467A2 (en) 2006-05-19 2007-05-19 Process for decarboxylation of fatty acids and oils to produce paraffins or olefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US80205406P 2006-05-19 2006-05-19
US60/802,054 2006-05-19

Publications (2)

Publication Number Publication Date
WO2007136873A2 WO2007136873A2 (en) 2007-11-29
WO2007136873A3 true WO2007136873A3 (en) 2008-04-10

Family

ID=38646589

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/012226 Ceased WO2007136873A2 (en) 2006-05-19 2007-05-19 Process for decarboxylation of fatty acids and oils to produce paraffins or olefins

Country Status (3)

Country Link
US (1) US20070281875A1 (en)
EP (1) EP2024467A2 (en)
WO (1) WO2007136873A2 (en)

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EP2238217A1 (en) * 2008-02-01 2010-10-13 Johnson Matthey PLC Process for the conversion of fatty acids and derivatives thereof
US8193399B2 (en) * 2008-03-17 2012-06-05 Uop Llc Production of diesel fuel and aviation fuel from renewable feedstocks
US8198492B2 (en) 2008-03-17 2012-06-12 Uop Llc Production of transportation fuel from renewable feedstocks
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US8766025B2 (en) 2008-06-24 2014-07-01 Uop Llc Production of paraffinic fuel from renewable feedstocks
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US8471079B2 (en) * 2008-12-16 2013-06-25 Uop Llc Production of fuel from co-processing multiple renewable feedstocks
US8283506B2 (en) * 2008-12-17 2012-10-09 Uop Llc Production of fuel from renewable feedstocks using a finishing reactor
US8314274B2 (en) * 2008-12-17 2012-11-20 Uop Llc Controlling cold flow properties of transportation fuels from renewable feedstocks
CN101898151B (en) * 2009-05-25 2012-05-30 中国石油化工股份有限公司 Three-crystal-phase composite molecular sieve and preparation method thereof
EP2290045A1 (en) * 2009-07-27 2011-03-02 Total Petrochemicals Research Feluy A process for the production of bio-naphtha from complex mixtures of natural occurring fats and oils
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US8471081B2 (en) 2009-12-28 2013-06-25 Uop Llc Production of diesel fuel from crude tall oil
US8366907B2 (en) 2010-08-02 2013-02-05 Battelle Memorial Institute Deoxygenation of fatty acids for preparation of hydrocarbons
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WO2012138423A1 (en) 2011-02-17 2012-10-11 The Procter & Gamble Company Compositions comprising mixtures of c10-c13 alkylphenyl sulfonates
US8900443B2 (en) 2011-04-07 2014-12-02 Uop Llc Method for multi-staged hydroprocessing using quench liquid
US8507741B2 (en) 2011-09-23 2013-08-13 Uop Llc Methods for co-production of alkylbenzene and biofuel from natural oils using hydrocracking
US8853479B2 (en) 2011-09-23 2014-10-07 Uop Llc Methods for co-production of alkylbenzene and biofuel from natural oils
US8865956B2 (en) 2011-09-23 2014-10-21 Uop Llc Methods for co-production of alkylbenzene and biofuel from natural oils using hydrocracking
US8546629B2 (en) 2011-09-23 2013-10-01 Uop Llc Methods for co-production of alkylbenzene and biofuel from natural oils
FR2992326B1 (en) * 2012-06-21 2014-06-20 IFP Energies Nouvelles PROCESS FOR THE PRODUCTION OF SURFACTANTS FROM RENEWABLE MATERIALS COMPRISING A HYDROTREATING STEP AND A PROCESSING PROCESS OF SURFACTANT PARAFFINS
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US9079811B2 (en) 2013-06-10 2015-07-14 Uop Llc Linear alkylbenzenes from natural oils and methods of producing
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Also Published As

Publication number Publication date
EP2024467A2 (en) 2009-02-18
WO2007136873A2 (en) 2007-11-29
US20070281875A1 (en) 2007-12-06

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