WO2008020167A3 - Biomass pyrolysis - Google Patents

Biomass pyrolysis Download PDF

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Publication number
WO2008020167A3
WO2008020167A3 PCT/GB2007/002975 GB2007002975W WO2008020167A3 WO 2008020167 A3 WO2008020167 A3 WO 2008020167A3 GB 2007002975 W GB2007002975 W GB 2007002975W WO 2008020167 A3 WO2008020167 A3 WO 2008020167A3
Authority
WO
WIPO (PCT)
Prior art keywords
product
produce
biomass pyrolysis
biomass
vapour
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2007/002975
Other languages
French (fr)
Other versions
WO2008020167A2 (en
Inventor
Anthony Bridgwater
Heiko Gerhauser
Astrid Effendi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aston University
Original Assignee
Aston University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aston University filed Critical Aston University
Priority to EP07789118.2A priority Critical patent/EP2074192B1/en
Priority to ES07789118.2T priority patent/ES2480943T3/en
Priority to CA2660497A priority patent/CA2660497C/en
Publication of WO2008020167A2 publication Critical patent/WO2008020167A2/en
Publication of WO2008020167A3 publication Critical patent/WO2008020167A3/en
Priority to US12/369,407 priority patent/US7998315B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10CWORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C5/00Production of pyroligneous acid distillation of wood, dry distillation of organic waste
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/04Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/16Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with non-aqueous liquids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/145Feedstock the feedstock being materials of biological origin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process for pyrolysing biomass is provided. The process comprises providing biomass to a pyrolysis reactor to produce a vapour product and condensing said vapour product to produce a condensed product, wherein a phase separation suppression agent is added during said process so as to promote the formation of a single phase condensed product.
PCT/GB2007/002975 2006-08-16 2007-08-06 Biomass pyrolysis Ceased WO2008020167A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP07789118.2A EP2074192B1 (en) 2006-08-16 2007-08-06 Biomass pyrolysis process
ES07789118.2T ES2480943T3 (en) 2006-08-16 2007-08-06 Biomass Pyrolysis Process
CA2660497A CA2660497C (en) 2006-08-16 2007-08-06 Biomass pyrolysis
US12/369,407 US7998315B2 (en) 2006-08-16 2009-02-11 Biomass pyrolysis

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0616298.6 2006-08-16
GBGB0616298.6A GB0616298D0 (en) 2006-08-16 2006-08-16 Biomass pyrolysis

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/369,407 Continuation US7998315B2 (en) 2006-08-16 2009-02-11 Biomass pyrolysis

Publications (2)

Publication Number Publication Date
WO2008020167A2 WO2008020167A2 (en) 2008-02-21
WO2008020167A3 true WO2008020167A3 (en) 2008-04-03

Family

ID=37081090

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2007/002975 Ceased WO2008020167A2 (en) 2006-08-16 2007-08-06 Biomass pyrolysis

Country Status (7)

Country Link
US (1) US7998315B2 (en)
EP (1) EP2074192B1 (en)
CA (1) CA2660497C (en)
ES (1) ES2480943T3 (en)
GB (1) GB0616298D0 (en)
PT (1) PT2074192E (en)
WO (1) WO2008020167A2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9347005B2 (en) 2011-09-13 2016-05-24 Ensyn Renewables, Inc. Methods and apparatuses for rapid thermal processing of carbonaceous material
US9410091B2 (en) 2011-12-12 2016-08-09 Ensyn Renewables, Inc. Preparing a fuel from liquid biomass
US9441887B2 (en) 2011-02-22 2016-09-13 Ensyn Renewables, Inc. Heat removal and recovery in biomass pyrolysis

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102702139B (en) 2006-04-03 2016-01-20 药物热化学品公司 Thermal extraction method and product
US7905990B2 (en) 2007-11-20 2011-03-15 Ensyn Renewables, Inc. Rapid thermal conversion of biomass
GB0808740D0 (en) * 2008-05-14 2008-06-18 Univ Aston Biomass processing
CL2009001034A1 (en) * 2009-04-30 2009-12-04 Univ Concepcion Equipment and process for producing bio-fuel by means of rapid pyrolysis of organic material comprising a system of three reactors of fluidized bed in series, lower combustion reactor, intermediate of rapid pyrolysis and superior preheating, in addition to a pneumatic material recirculation system particulate
WO2011009056A1 (en) * 2009-07-16 2011-01-20 Tolero Energy, Llc Miscible bio-oil fuels and production thereof
US8864999B2 (en) 2009-12-23 2014-10-21 Uop Llc Methods for regenerating acidic ion-exchange resins and reusing regenerants in such methods
US20110146140A1 (en) * 2009-12-23 2011-06-23 Brandvold Timothy A Low water biomass-derived pyrolysis oil and processes for preparing the same
US8524087B2 (en) 2009-12-23 2013-09-03 Uop Llc Low metal, low water biomass-derived pyrolysis oils and methods for producing the same
CN101818080B (en) * 2010-03-23 2013-03-13 武汉凯迪工程技术研究总院有限公司 Process and system for manufacturing synthesis gas from biomass by pyrolysis
US20110284359A1 (en) 2010-05-20 2011-11-24 Uop Llc Processes for controlling afterburn in a reheater and for controlling loss of entrained solid particles in combustion product flue gas
GB201010111D0 (en) 2010-06-16 2010-07-21 Univ Aston Bio-fuel composition and method for manufacture of bio-fuel composition
US8499702B2 (en) 2010-07-15 2013-08-06 Ensyn Renewables, Inc. Char-handling processes in a pyrolysis system
US8323456B2 (en) * 2010-08-26 2012-12-04 Kior, Inc. Removal of bound water from bio-oil
US8183422B2 (en) * 2010-10-25 2012-05-22 Conocophillips Company Hydrocarbons from pyrolysis oil
US9447350B2 (en) 2010-10-29 2016-09-20 Inaeris Technologies, Llc Production of renewable bio-distillate
US9382489B2 (en) 2010-10-29 2016-07-05 Inaeris Technologies, Llc Renewable heating fuel oil
CN102476128B (en) * 2010-11-29 2014-12-10 华中农业大学 Method for green conversion of urban and rural household reuse into renewable energy sources
CN102031132B (en) * 2010-12-30 2013-08-21 东北林业大学 Device and method for producing biological fuel oil cleaning fuel via self-heated rapid cracking of biomass
US9315739B2 (en) 2011-08-18 2016-04-19 Kior, Llc Process for upgrading biomass derived products
US9023181B2 (en) * 2011-03-25 2015-05-05 The United States Of America, As Represented By The Secretary Of Agriculture Fast pyrolysis catalytic cracking pipe for producing bio-oils
CN102199440A (en) * 2011-04-20 2011-09-28 安徽理工大学 Method for preparing low-acidity and low-oxygen content biological oil by two-section conversion
US8100990B2 (en) * 2011-05-15 2012-01-24 Avello Bioenery, Inc. Methods for integrated fast pyrolysis processing of biomass
CN102226531B (en) * 2011-05-17 2012-10-31 苏州辰昌新能源技术有限公司 Purification and burn integral device for thermal gas from biomass carbonization furnace
US9546315B2 (en) * 2011-05-28 2017-01-17 Avello Bioenergy, Inc. Compositions, methods, apparatus, and systems for incorporating bio-derived materials in drilling and hydraulic fracturing
US10427069B2 (en) 2011-08-18 2019-10-01 Inaeris Technologies, Llc Process for upgrading biomass derived products using liquid-liquid extraction
GB201114679D0 (en) 2011-08-24 2011-10-12 Univ Aston Bio-fuel composition and method for manufacture of bio-fuel composition
US10400175B2 (en) 2011-09-22 2019-09-03 Ensyn Renewables, Inc. Apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material
US9044727B2 (en) 2011-09-22 2015-06-02 Ensyn Renewables, Inc. Apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material
US10041667B2 (en) 2011-09-22 2018-08-07 Ensyn Renewables, Inc. Apparatuses for controlling heat for rapid thermal processing of carbonaceous material and methods for the same
EP2583753B1 (en) * 2011-10-21 2015-05-13 Enefit Outotec Technology Oü Process and apparatus for dedusting a vapour gas mixture
RS54064B1 (en) * 2011-10-21 2015-10-30 Enefit Outotec Technology Oü PROCEDURE AND APPARATUS FOR OBTAINING OIL FROM VARIETY OF STEAM AND GAS
US9206365B2 (en) 2012-01-10 2015-12-08 Kior, Llc Fungible bio-oil
WO2013151571A1 (en) * 2012-04-02 2013-10-10 De Lima Jose Railton Souza System and apparatus for generating electricity from vegetable and animal mass
US9527022B2 (en) * 2012-06-08 2016-12-27 Uop Llc Method and apparatus for producing pyrolysis oil having improved stability
US9670413B2 (en) 2012-06-28 2017-06-06 Ensyn Renewables, Inc. Methods and apparatuses for thermally converting biomass
CN102816581B (en) * 2012-07-12 2015-05-20 华中科技大学 Vertical tube moving bed continuous pyrolysis apparatus for biomass
CN104718010B (en) * 2012-08-24 2017-08-15 安辛可再生能源有限公司 System and method for the devolatilization of heat liquid processed
US9199889B2 (en) 2013-03-15 2015-12-01 Altex Technologies Corporation Method and apparatus for conversion of carbonaceous materials to liquid fuel
CA2913180A1 (en) * 2013-05-31 2014-12-04 Tolero Energy, Llc Pyrolysis system and method for bio-oil component extraction
US10767114B2 (en) * 2013-05-31 2020-09-08 Tolero Energy, Llc Pyrolysis system and method for bio-oil component extraction
US10589187B2 (en) * 2013-05-31 2020-03-17 Tolero Energy, Llc Pyrolysis system for bio-oil component extraction
EP3013922A4 (en) 2013-06-26 2017-02-08 Ensyn Renewables, Inc. Systems and methods for renewable fuel
US10266774B2 (en) 2014-10-03 2019-04-23 Southwest Research Institute Feedstock conversion to fuel on high pressure circulating fluidized bed
EP3337966B1 (en) 2015-08-21 2021-12-15 Ensyn Renewables, Inc. Liquid biomass heating system
BR112019013387B1 (en) 2016-12-29 2023-03-28 Ensyn Renewables, Inc DEMETALIZATION OF BIOMASS
US11300284B2 (en) 2019-05-07 2022-04-12 Kore Infrastructure Production of renewable fuel for steam generation for heavy oil extraction
CN112143513A (en) * 2019-06-29 2020-12-29 西北农林科技大学 An industrial device for continuous production of bio-oil by rapid thermal cracking of biomass
US11553715B2 (en) 2019-07-08 2023-01-17 University Of Kentucky Research Foundation Synthesis and formulation of lignin derived compounds as treatment of plant diseases
WO2021130679A1 (en) * 2019-12-23 2021-07-01 Kerry Luxembourg S.a.r.l. Methods for formaldehyde control
EP4019612A1 (en) * 2020-12-23 2022-06-29 Ingelia, S.L. Apparatus to obtain valuable products from biomass and process thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9426066D0 (en) 1994-12-22 1995-02-22 Radlein Desmond S G Method of upgrading biomass pyrolysis liquids for use as fuels and as a source of chemicals by reaction with alcohols
US5820640A (en) 1997-07-09 1998-10-13 Natural Resources Canada Pyrolysis liquid-in-diesel oil microemulsions
US6326461B1 (en) 1998-01-30 2001-12-04 Ensyn Group, Inc. Natural resin formulations
CN1357031A (en) 1999-07-02 2002-07-03 大型界面系统校际研究中心 Engine fuels consisting of emulsion comprising mineral and/or natural oils, their prepn. and use in I.C. engine
GB0200476D0 (en) 2002-01-10 2002-02-27 Univ Aston Reactor
US20090054711A1 (en) 2005-05-04 2009-02-26 Tom Lawrence Pyrolysis Systems, Methods of Use Thereof, and Methods of Bio-Oil Transformation

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
BOUCHER M E ET AL: "Bio-oils obtained by vacuum pyrolysis of softwood bark as a liquid fuel for gas turbines. Part II: stability and ageing of bio-oil and its blends with methanol and a pyrolytic aqueous phase", BIOMASS BIOENERGY; BIOMASS AND BIOENERGY 2000 ELSEVIER SCIENCE LTD, EXETER, ENGL, vol. 19, no. 5, 2000, pages 351 - 361, XP002456818 *
BRIDGWATER A.V. (ED.) (ET AL.): "FAST PYROLYSIS OF BIOMASS: A HANDBOOK. Volume 2", 2002, CPL PRESS, NEWBURY; GB, ISBN: 1-872691-47-1, XP002456819 *
OASMAA ANJA ET AL: "Fast pyrolysis of forestry residue and pine. 4. Improvement of the product quality by solvent addition", ENERGY AND FUELS, vol. 18, no. 5, September 2004 (2004-09-01), pages 1578 - 1583, XP002456817 *
OASMAA, ANJA; PEACOCKE, CORDNER: "A guide to physical property characterisation of biomass-derived fast pyrolysis liquids", VTT PUBLICATIONS, no. 450, December 2001 (2001-12-01), XP007903206, ISBN: 951-38-6365-4, Retrieved from the Internet <URL:http://www.vtt.fi/inf/pdf/publications/2001/P450.pdf> [retrieved on 20071008] *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9441887B2 (en) 2011-02-22 2016-09-13 Ensyn Renewables, Inc. Heat removal and recovery in biomass pyrolysis
US9347005B2 (en) 2011-09-13 2016-05-24 Ensyn Renewables, Inc. Methods and apparatuses for rapid thermal processing of carbonaceous material
US9410091B2 (en) 2011-12-12 2016-08-09 Ensyn Renewables, Inc. Preparing a fuel from liquid biomass

Also Published As

Publication number Publication date
GB0616298D0 (en) 2006-09-27
WO2008020167A2 (en) 2008-02-21
ES2480943T3 (en) 2014-07-29
US20090227766A1 (en) 2009-09-10
EP2074192A2 (en) 2009-07-01
CA2660497C (en) 2013-05-28
EP2074192B1 (en) 2014-05-07
CA2660497A1 (en) 2008-02-21
PT2074192E (en) 2014-07-24
US7998315B2 (en) 2011-08-16

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