WO2008082499A2 - Process for electroblowing a multiple layered sheet - Google Patents

Process for electroblowing a multiple layered sheet Download PDF

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Publication number
WO2008082499A2
WO2008082499A2 PCT/US2007/025796 US2007025796W WO2008082499A2 WO 2008082499 A2 WO2008082499 A2 WO 2008082499A2 US 2007025796 W US2007025796 W US 2007025796W WO 2008082499 A2 WO2008082499 A2 WO 2008082499A2
Authority
WO
WIPO (PCT)
Prior art keywords
web
spinning
solvent
fibers
webs
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2007/025796
Other languages
French (fr)
Other versions
WO2008082499A3 (en
Inventor
Joseph Brian Hovanec
Michael John Moore, Sr.
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to DE602007010031T priority Critical patent/DE602007010031D1/en
Priority to AT07863035T priority patent/ATE485406T1/en
Priority to CN2007800467661A priority patent/CN101563485B/en
Priority to JP2009542861A priority patent/JP5377325B2/en
Priority to EP07863035A priority patent/EP2094886B1/en
Priority to BRPI0719501A priority patent/BRPI0719501B8/en
Publication of WO2008082499A2 publication Critical patent/WO2008082499A2/en
Publication of WO2008082499A3 publication Critical patent/WO2008082499A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/0007—Electro-spinning
    • D01D5/0015—Electro-spinning characterised by the initial state of the material
    • D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
    • D01D5/0038—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion the fibre formed by solvent evaporation, i.e. dry electro-spinning
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/0007—Electro-spinning
    • D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
    • D01D5/0069—Electro-spinning characterised by the electro-spinning apparatus characterised by the spinning section, e.g. capillary tube, protrusion or pin
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4374—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/56—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in association with fibre formation, e.g. immediately following extrusion of staple fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
    • D04H1/728—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by electro-spinning
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • D04H3/166—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion the filaments being flash-spun

Definitions

  • the present invention is related to an improvement for electroblowing a multiple layered sheet.
  • Fabrics and webs made from fibers can be used in a variety of customer end-use applications, such as filtration media, energy storage separators, protective apparel and the like.
  • a process to make these webs is electroblowing wherein a polymer solution is spun through a nozzle in the presence of an electrostatic field and a blowing or forwarding fluid to evaporate the solvent and form fibers that are collected on a screen.
  • a polymer solution is spun through a nozzle in the presence of an electrostatic field and a blowing or forwarding fluid to evaporate the solvent and form fibers that are collected on a screen.
  • not all of the solvent is removed from the fibers at laydown requiring additional solvent removal processes.
  • the web can stick to the screen resulting in web damage when removing the web from the screen.
  • too little solvent remains in the fiber at fiber laydown on the screen then the web does not exhibit sufficient tackiness for good surface stability to allow for web handling.
  • the present invention is directed to a process for electroblowing a multiple layered sheet comprising spinning an electrically conductive liquid stream comprising a polymer dissolved in a solvent through at least two spinning beams comprising a linear array of spinning nozzles in the presence of a forwarding gas and an electric field to form fibers and deposit the fibers onto a collecting screen, wherein: (a) a first spinning beam provides fibers that are deposited onto the collecting screen with a solvent concentration of about 0 to about 30 weight percent that make a first web; and (b) a second spinning beam provides fibers that are deposited onto the first web with a solvent concentration of about 30 to about 70 weight percent that make a second web, wherein the difference in solvent concentration between the webs is at least about 10 weight percent.
  • the present invention is related to an improvement for a multiple layered sheet made from webs produced by an electroblowing process described in World Patent Publication No. WO 03/080905, corresponding to U.S. Patent Application No. 10/477,882, incorporated herein by reference in its entirety.
  • the electroblowing method comprises feeding a stream of polymeric solution comprising a polymer and a solvent from a storage tank to a series of spinning nozzles within a spinneret, to which a high voltage is applied and through which the polymeric solution is discharged. Meanwhile, compressed air that is optionally heated is issued from air nozzles disposed in the sides of, or at the periphery of the spinning nozzle. The air is directed generally downward as a blowing gas stream which envelopes and forwards the newly issued polymeric solution and aids in the formation of the fibrous web, which is collected on a grounded porous collection screen above a vacuum chamber.
  • the polymer solution can be mixed with additives including any resin compatible with an associated polymer, plasticizer, ultraviolet ray stabilizer, crosslink agent, curing agent, reaction initiator and etc. Although dissolving most of the polymers may not require any specific temperature ranges, heating may be needed for assisting the dissolution reaction.
  • a multiple layered sheet according to the invention can be made by combining a low solvent containing web with a high solvent containing web that does not stick to the collection screen while providing sufficient surface stability for web handling.
  • the multiple layered sheet can be made by spinning a polymer solution through a first spinning beam that provides fibers that are deposited onto the collecting screen with a solvent concentration of about 0 to about 30 weight percent to make a first web and a second spinning beam provides fibers that are deposited onto the first web with a solvent concentration of about 30 to about 70 weight percent to make a second web, wherein the difference in solvent concentration between the webs is at least about 10 weight percent.
  • the first web can be prepared by spinning the fiber from a spinning beam that has a liquid stream throughput per nozzle of about 0.5 to about 2.0 cc/hole/min.
  • the second web can be prepared by spinning the fiber from a spinning beam that has a liquid stream throughput per nozzle of about 2.0 to about 4.0 cc/hole/min.
  • the difference in throughput between the two liquid streams is at least about 1 cc/hole/min.
  • Another way to make webs with different solvent concentrations at laydown is to control the forwarding gas temperatures.
  • the first web can be prepared by spinning the fiber with a first forwarding gas with a temperature of about 50 0 C to about 150 0 C.
  • the second web can be prepared by spinning the fibers with a second forwarding gas with a temperature of about 25°C to about 50 0 C. The difference in temperature between the forwarding gases is at least about 25°C.
  • Alternative process variables that can be manipulated to independently control the fiber spun from each spinning beam to achieve the desired level of solvent concentration at laydown include spinning cell temperature and die to collector or beam to collection screen distance. Additional spinning beams can be added to the process to deposit additional webs between the first and second webs, onto the second web or a combination of both.
  • the process further comprises removing the solvent from the collected webs to a desired solvent content depending on the end use.
  • a preferred polymer/solvent combination is polyamide dissolved in formic acid to prepare a polyamide multiple layered sheet.
  • Solvent Content in a web is measured by weighing the as produced web, then drying the web and reweighing the web and is calculated by the formula:
  • % solvent (weight of solvent containing web - weight of solvent free web) x 100%
  • Webs used to make a multiple layered sheet of the present invention can be produced by the electroblowing process described in World Patent Publication No. WO 2003/080905, corresponding to U.S. Patent Application No. 10/477,882, incorporated herein by reference in its entirety.
  • a web is prepared from a polymer solution having a concentration of
  • nylon 6,6 polymer Zytel® FE3218 (available from E. I. du Pont de Nemours and Company, Wilmington, Delaware) dissolved in formic acid solvent at 99% purity (available from Kemira Oyj, Helsinki, Finland).
  • the polymer solution is electrospun at room temperature using blowing air at a temperature of about 50 0 C and potential difference between the spinning beam and the collector of 50 kV.
  • a spinning beam has a polymer solution throughput of about 4.0 cc/hole/min which produces fibers that are collected on a screen to form a web with about 60% formic acid content. The web sticks to the collection screen causing damage to the web when it is removed.
  • Another web is prepared in a similar manner to Comparative Example A except the spinning beam has a polymer solution throughput of about 1.0 cc/hole/min which produces fibers that are collected on a screen to form a web with about 25% formic acid content.
  • the web does not stick to the collection screen when it is removed.
  • the surface stability of the web is insufficient to stop damage to the web when handling.
  • a multiple layered sheet according to the invention is made by combining Comparative Examples A and B in a specific order.
  • a first spinning beam has a polymer solution throughput of about 1.0 cc/hole/min which produces fibers that are collected on a screen to form a first web with about 25% formic acid content.
  • a second spinning beam has a polymer solution throughput of about 4.0 cc/hole/min which produces fibers that are collected on top of the first web to form a second web with about 60% formic acid content.
  • the two webs produce a multiple layered sheet.
  • the sheet is removed from the screen without sticking to the screen. Furthermore, the additional tackiness of the second web helps to hold the sheet together with good surface stability allowing the web to be handled.
  • the multiple layered sheet is solvent stripped to remove residual formic acid.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Nonwoven Fabrics (AREA)
  • Laminated Bodies (AREA)
  • Coloring (AREA)

Abstract

A process for electroblowing a multiple layered sheet using multiple spinning beams to produce different component webs wherein the sheet doesn't stick to the forming screen and has improved web stability.

Description

TITLE OF THE INVENTION
PROCESS FOR ELECTROBLOWING A MULTIPLE LAYERED SHEET
FIELD OF THE INVENTION
The present invention is related to an improvement for electroblowing a multiple layered sheet.
BACKGROUND OF THE INVENTION
Fabrics and webs made from fibers can be used in a variety of customer end-use applications, such as filtration media, energy storage separators, protective apparel and the like. A process to make these webs is electroblowing wherein a polymer solution is spun through a nozzle in the presence of an electrostatic field and a blowing or forwarding fluid to evaporate the solvent and form fibers that are collected on a screen. Typically, not all of the solvent is removed from the fibers at laydown requiring additional solvent removal processes. However, if too much solvent remains in the fiber at fiber laydown on the screen, then the web can stick to the screen resulting in web damage when removing the web from the screen. Also, if too little solvent remains in the fiber at fiber laydown on the screen, then the web does not exhibit sufficient tackiness for good surface stability to allow for web handling.
What is needed is a process for electroblowing a sheet structure that can be removed from the collection screen while having sufficient surface stability for handling.
SUMMARY OF THE INVENTION
The present invention is directed to a process for electroblowing a multiple layered sheet comprising spinning an electrically conductive liquid stream comprising a polymer dissolved in a solvent through at least two spinning beams comprising a linear array of spinning nozzles in the presence of a forwarding gas and an electric field to form fibers and deposit the fibers onto a collecting screen, wherein: (a) a first spinning beam provides fibers that are deposited onto the collecting screen with a solvent concentration of about 0 to about 30 weight percent that make a first web; and (b) a second spinning beam provides fibers that are deposited onto the first web with a solvent concentration of about 30 to about 70 weight percent that make a second web, wherein the difference in solvent concentration between the webs is at least about 10 weight percent.
DETAILED DESCRIPTION OF THE INVENTION
The present invention is related to an improvement for a multiple layered sheet made from webs produced by an electroblowing process described in World Patent Publication No. WO 03/080905, corresponding to U.S. Patent Application No. 10/477,882, incorporated herein by reference in its entirety.
The electroblowing method comprises feeding a stream of polymeric solution comprising a polymer and a solvent from a storage tank to a series of spinning nozzles within a spinneret, to which a high voltage is applied and through which the polymeric solution is discharged. Meanwhile, compressed air that is optionally heated is issued from air nozzles disposed in the sides of, or at the periphery of the spinning nozzle. The air is directed generally downward as a blowing gas stream which envelopes and forwards the newly issued polymeric solution and aids in the formation of the fibrous web, which is collected on a grounded porous collection screen above a vacuum chamber.
The polymer solution can be mixed with additives including any resin compatible with an associated polymer, plasticizer, ultraviolet ray stabilizer, crosslink agent, curing agent, reaction initiator and etc. Although dissolving most of the polymers may not require any specific temperature ranges, heating may be needed for assisting the dissolution reaction.
It has been observed that in preparing a web according to this electroblowing process, if the web contains fibers with too much solvent at laydown on the collection screen, then the web sticks to the screen causing damage to the web upon removal from the screen. The sticking problem can be averted if the web at laydown has a solvent concentration of about 0 to about 30 weight percent. It has been further observed that in preparing a web according to this electroblowing process, if the web contains fibers with too little solvent at laydown on the collection screen, then the fibers do not have sufficient tackiness to stick to each other in order to develop enough surface stability to prevent web damage when handling the web. The surface stability can be improved if the web at laydown has a solvent concentration of about 30 to about 70 weight percent.
A multiple layered sheet according to the invention can be made by combining a low solvent containing web with a high solvent containing web that does not stick to the collection screen while providing sufficient surface stability for web handling. The multiple layered sheet can be made by spinning a polymer solution through a first spinning beam that provides fibers that are deposited onto the collecting screen with a solvent concentration of about 0 to about 30 weight percent to make a first web and a second spinning beam provides fibers that are deposited onto the first web with a solvent concentration of about 30 to about 70 weight percent to make a second web, wherein the difference in solvent concentration between the webs is at least about 10 weight percent.
One way to make webs with different solvent concentrations at laydown is to control the liquid stream throughput of the polymer solution exiting the spinning beam. The first web can be prepared by spinning the fiber from a spinning beam that has a liquid stream throughput per nozzle of about 0.5 to about 2.0 cc/hole/min. The second web can be prepared by spinning the fiber from a spinning beam that has a liquid stream throughput per nozzle of about 2.0 to about 4.0 cc/hole/min. The difference in throughput between the two liquid streams is at least about 1 cc/hole/min. Another way to make webs with different solvent concentrations at laydown is to control the forwarding gas temperatures. The first web can be prepared by spinning the fiber with a first forwarding gas with a temperature of about 500C to about 1500C. The second web can be prepared by spinning the fibers with a second forwarding gas with a temperature of about 25°C to about 500C. The difference in temperature between the forwarding gases is at least about 25°C. Alternative process variables that can be manipulated to independently control the fiber spun from each spinning beam to achieve the desired level of solvent concentration at laydown include spinning cell temperature and die to collector or beam to collection screen distance. Additional spinning beams can be added to the process to deposit additional webs between the first and second webs, onto the second web or a combination of both.
The process further comprises removing the solvent from the collected webs to a desired solvent content depending on the end use. A preferred polymer/solvent combination is polyamide dissolved in formic acid to prepare a polyamide multiple layered sheet.
TEST METHOD
Solvent Content in a web is measured by weighing the as produced web, then drying the web and reweighing the web and is calculated by the formula:
% solvent = (weight of solvent containing web - weight of solvent free web) x 100%
(weight of solvent containing web)
EXAMPLES
Hereinafter the present invention will be described in more detail in the following examples.
Webs used to make a multiple layered sheet of the present invention can be produced by the electroblowing process described in World Patent Publication No. WO 2003/080905, corresponding to U.S. Patent Application No. 10/477,882, incorporated herein by reference in its entirety.
COMPARATIVE EXAMPLE A A web is prepared from a polymer solution having a concentration of
24 wt% of nylon 6,6 polymer, Zytel® FE3218 (available from E. I. du Pont de Nemours and Company, Wilmington, Delaware) dissolved in formic acid solvent at 99% purity (available from Kemira Oyj, Helsinki, Finland). The polymer solution is electrospun at room temperature using blowing air at a temperature of about 500C and potential difference between the spinning beam and the collector of 50 kV. A spinning beam has a polymer solution throughput of about 4.0 cc/hole/min which produces fibers that are collected on a screen to form a web with about 60% formic acid content. The web sticks to the collection screen causing damage to the web when it is removed.
COMPARATIVE EXAMPLE B
Another web is prepared in a similar manner to Comparative Example A except the spinning beam has a polymer solution throughput of about 1.0 cc/hole/min which produces fibers that are collected on a screen to form a web with about 25% formic acid content. The web does not stick to the collection screen when it is removed. However, the surface stability of the web is insufficient to stop damage to the web when handling.
EXAMPLE 1
A multiple layered sheet according to the invention is made by combining Comparative Examples A and B in a specific order. As in Comparative Example B, a first spinning beam has a polymer solution throughput of about 1.0 cc/hole/min which produces fibers that are collected on a screen to form a first web with about 25% formic acid content. As in Comparative Example A1 a second spinning beam has a polymer solution throughput of about 4.0 cc/hole/min which produces fibers that are collected on top of the first web to form a second web with about 60% formic acid content. The two webs produce a multiple layered sheet. The sheet is removed from the screen without sticking to the screen. Furthermore, the additional tackiness of the second web helps to hold the sheet together with good surface stability allowing the web to be handled. The multiple layered sheet is solvent stripped to remove residual formic acid.

Claims

CLAIMSWhat is claimed is:
1. A process for electroblowing a multiple layered sheet comprising spinning an electrically conductive liquid stream comprising a polymer dissolved in a solvent through at least two spinning beams comprising a linear array of spinning nozzles in the presence of a forwarding gas and an electric field to form fibers and deposit the fibers onto a collecting screen, wherein: (a) a first spinning beam provides fibers that are deposited onto the collecting screen with a solvent concentration of about 0 to about 30 weight percent that make a first web; and
(b) a second spinning beam provides fibers that are deposited onto the first web with a solvent concentration of about 30 to about 70 weight percent that make a second web, wherein the difference in solvent concentration between the webs is at least 10 weight percent.
2. The process of claim 1 , further comprising:
(c) one or more additional spinning beams provides fibers that are deposited between the first and second webs, onto the second web, or a combination of both and make up one or more additional webs.
3. The process of claim 1 , further comprising removing the solvent from the collected fibers.
4. The process of claim 1 , wherein the first spinning beam has a liquid stream throughput per nozzle of about 0.5 to about 2.0 cc/hole/min and the second spinning beam has a liquid stream throughput per nozzle of about 2.0 to about 4.0 cc/hole/min wherein the difference in throughput between the liquid streams is at least about 1 cc/hole/min.
5. The process of claim 1 , wherein the first spinning beam has a first forwarding gas with a temperature of about 5O0C to about 1500C and the second spinning beam has a second forwarding gas with a temperature of about 250C to about 500C wherein the difference in temperature between the forwarding gases is at least about 25°C.
6. The process of claim 1 , wherein the polymer is polyamide and the solvent is formic acid.
PCT/US2007/025796 2006-12-20 2007-12-18 Process for electroblowing a multiple layered sheet Ceased WO2008082499A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
DE602007010031T DE602007010031D1 (en) 2006-12-20 2007-12-18 ELECTROBLASTING METHOD FOR A MULTILAYER FABRIC
AT07863035T ATE485406T1 (en) 2006-12-20 2007-12-18 ELECTROBLOWING PROCESS FOR A MULTI-LAYER FABRIC
CN2007800467661A CN101563485B (en) 2006-12-20 2007-12-18 Process for electroblowing a multiple layered sheet
JP2009542861A JP5377325B2 (en) 2006-12-20 2007-12-18 Method for electroblowing multilayer sheets
EP07863035A EP2094886B1 (en) 2006-12-20 2007-12-18 Process for electroblowing a multiple layered sheet
BRPI0719501A BRPI0719501B8 (en) 2006-12-20 2007-12-18 "multi-layer sheet electrosurfing process"

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US87592506P 2006-12-20 2006-12-20
US60/875,925 2006-12-20

Publications (2)

Publication Number Publication Date
WO2008082499A2 true WO2008082499A2 (en) 2008-07-10
WO2008082499A3 WO2008082499A3 (en) 2009-01-22

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PCT/US2007/025796 Ceased WO2008082499A2 (en) 2006-12-20 2007-12-18 Process for electroblowing a multiple layered sheet

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US (1) US8361365B2 (en)
EP (1) EP2094886B1 (en)
JP (1) JP5377325B2 (en)
KR (1) KR101468242B1 (en)
CN (1) CN101563485B (en)
AT (1) ATE485406T1 (en)
BR (1) BRPI0719501B8 (en)
DE (1) DE602007010031D1 (en)
WO (1) WO2008082499A2 (en)

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US8361365B2 (en) 2013-01-29
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