WO2008143008A1 - スルホン酸基含有炭素質材料の製造方法、固体酸触媒、アルキル化反応生成物の製造方法、およびオレフィン重合体の製造方法 - Google Patents

スルホン酸基含有炭素質材料の製造方法、固体酸触媒、アルキル化反応生成物の製造方法、およびオレフィン重合体の製造方法 Download PDF

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Publication number
WO2008143008A1
WO2008143008A1 PCT/JP2008/058558 JP2008058558W WO2008143008A1 WO 2008143008 A1 WO2008143008 A1 WO 2008143008A1 JP 2008058558 W JP2008058558 W JP 2008058558W WO 2008143008 A1 WO2008143008 A1 WO 2008143008A1
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WIPO (PCT)
Prior art keywords
producing
carbonaceous material
sulfonic acid
acid group
containing carbonaceous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/058558
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English (en)
French (fr)
Inventor
Shinichirou Yanagawa
Hidesato Kondo
Michikazu Hara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokyo Institute of Technology NUC
Eneos Corp
Original Assignee
Tokyo Institute of Technology NUC
Nippon Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokyo Institute of Technology NUC, Nippon Oil Corp filed Critical Tokyo Institute of Technology NUC
Priority to US12/599,389 priority Critical patent/US8017724B2/en
Priority to EP08752449A priority patent/EP2159193A4/en
Priority to KR1020097025690A priority patent/KR101459171B1/ko
Priority to JP2009515145A priority patent/JP5339453B2/ja
Priority to CN2008800149339A priority patent/CN101675002B/zh
Publication of WO2008143008A1 publication Critical patent/WO2008143008A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/084—Decomposition of carbon-containing compounds into carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/12—Polycyclic non-condensed hydrocarbons
    • C07C15/16—Polycyclic non-condensed hydrocarbons containing at least two phenyl groups linked by one single acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C07C2/70—Catalytic processes with acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

　本発明のスルホン酸基含有炭素質材料の製造方法は、レゾルシノールに由来する構成単位を有する重合体について、不活性ガス雰囲気下の加熱による炭化処理およびスルホン化処理を行い、スルホン酸基含有炭素質材料を得る工程を備える。 得られるスルホン酸基含有炭素質材料を含有する触媒は、アルキル化反応やオレフィンの重合反応などの疎水性の媒体中での各種反応において、高い効率で目的物の製造を行う上で有用である。
PCT/JP2008/058558 2007-05-11 2008-05-08 スルホン酸基含有炭素質材料の製造方法、固体酸触媒、アルキル化反応生成物の製造方法、およびオレフィン重合体の製造方法 Ceased WO2008143008A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US12/599,389 US8017724B2 (en) 2007-05-11 2008-05-08 Method for producing sulfonic acid group-containing carbonaceous material, solid acid catalyst, method for producing alkylation reaction product, and method for producing olefin polymer
EP08752449A EP2159193A4 (en) 2007-05-11 2008-05-08 METHOD FOR PRODUCING SULFONIC ACID GROUP CARBONATING MATERIAL, SOLUBLE ACID CATALYST, METHOD FOR PRODUCING AN ALKYLATION REACTION PRODUCT AND METHOD FOR PRODUCING AN OLEFIN POLYMER
KR1020097025690A KR101459171B1 (ko) 2007-05-11 2008-05-08 술폰산기 함유 탄소질 재료의 제조 방법, 고체산 촉매, 알킬화 반응 생성물의 제조 방법, 및 올레핀 중합체의 제조 방법
JP2009515145A JP5339453B2 (ja) 2007-05-11 2008-05-08 スルホン酸基含有炭素質材料の製造方法、固体酸触媒、アルキル化反応生成物の製造方法、およびオレフィン重合体の製造方法
CN2008800149339A CN101675002B (zh) 2007-05-11 2008-05-08 含有磺酸基的碳质材料的制造方法、固体酸催化剂、烷基化反应产物的制造方法和烯烃聚合物的制造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007126882 2007-05-11
JP2007-126882 2007-05-11

Publications (1)

Publication Number Publication Date
WO2008143008A1 true WO2008143008A1 (ja) 2008-11-27

Family

ID=40031720

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/058558 Ceased WO2008143008A1 (ja) 2007-05-11 2008-05-08 スルホン酸基含有炭素質材料の製造方法、固体酸触媒、アルキル化反応生成物の製造方法、およびオレフィン重合体の製造方法

Country Status (6)

Country Link
US (1) US8017724B2 (ja)
EP (1) EP2159193A4 (ja)
JP (1) JP5339453B2 (ja)
KR (1) KR101459171B1 (ja)
CN (1) CN101675002B (ja)
WO (1) WO2008143008A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011132112A (ja) * 2009-11-30 2011-07-07 Equos Research Co Ltd スルホン化多孔性カーボン
JP2011201733A (ja) * 2010-03-26 2011-10-13 Equos Research Co Ltd スルホン化カーボンのハメット酸度関数制御方法
JP2012121796A (ja) * 2010-11-23 2012-06-28 Hutchinson Sa 新規な硫黄改質モノリシック多孔質炭素系材料、その調製のための方法、ならびにエネルギーの貯蔵および放出におけるその使用

Families Citing this family (10)

* Cited by examiner, † Cited by third party
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JP5263738B2 (ja) * 2006-06-26 2013-08-14 国立大学法人東京工業大学 多糖類の加水分解による他の多糖類および／または単糖類の製造方法
US20100312008A1 (en) * 2009-06-09 2010-12-09 Kastner James R Solid acid catalysts, methods of making, and methods of use
KR101701787B1 (ko) 2009-08-31 2017-02-02 도오쿄 인스티튜드 오브 테크놀로지 살균 방법
CN102069011B (zh) * 2011-01-06 2013-07-17 太原理工大学 炼焦酚渣制备碳基固体酸催化剂的方法
US9079171B2 (en) 2011-02-28 2015-07-14 Midori Usa, Inc. Polymeric acid catalysts and uses thereof
KR102057134B1 (ko) * 2012-06-05 2019-12-18 닛폰세이시가부시키가이샤 촉매를 사용한 탄소 재료의 제조 방법 및 탄소 재료
EP2850231B1 (en) * 2012-07-12 2017-03-08 Dow Global Technologies LLC Processes for preparing carbonized polymers
US9238845B2 (en) 2012-08-24 2016-01-19 Midori Usa, Inc. Methods of producing sugars from biomass feedstocks
WO2017221205A1 (en) 2016-06-24 2017-12-28 Sabic Global Technologies B.V. Cross-linked polystyrene catalyst, method of making, and uses thereof
CN110270371B (zh) * 2019-05-31 2021-09-28 青岛科技大学 一种木质素基固体酸催化苄基化反应方法

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WO2005029508A1 (ja) * 2003-09-16 2005-03-31 The Circle For The Promotion Of Science And Engineering スルホン酸基導入無定形炭素、その製造法、及びその用途
JP2007039313A (ja) * 2005-05-27 2007-02-15 Sumitomo Chemical Co Ltd 活性炭及びその製造方法
JP2007172887A (ja) * 2005-12-19 2007-07-05 Equos Research Co Ltd 燃料電池用担持触媒、燃料電池用反応層、燃料電池、及び燃料電池用担持触媒の製造方法。

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JP2610490B2 (ja) * 1988-09-08 1997-05-14 コスモ石油株式会社 アルキル化反応用固体酸触媒
JP2002104816A (ja) * 1999-11-16 2002-04-10 Kuraray Co Ltd 活性炭及びその製造方法
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WO2005029508A1 (ja) * 2003-09-16 2005-03-31 The Circle For The Promotion Of Science And Engineering スルホン酸基導入無定形炭素、その製造法、及びその用途
JP2007039313A (ja) * 2005-05-27 2007-02-15 Sumitomo Chemical Co Ltd 活性炭及びその製造方法
JP2007172887A (ja) * 2005-12-19 2007-07-05 Equos Research Co Ltd 燃料電池用担持触媒、燃料電池用反応層、燃料電池、及び燃料電池用担持触媒の製造方法。

Non-Patent Citations (2)

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Title
BAKER W.S. ET AL.: "Sulfur-functionalized carbon aerogels: a new approach for loading high-surface-area electrode nanoarchitectures with precious metal catalysts", JOURNAL OF NON-CRYSTALLINE SOLIDS, vol. 350, 2004, pages 80 - 87, XP004665335 *
See also references of EP2159193A4 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011132112A (ja) * 2009-11-30 2011-07-07 Equos Research Co Ltd スルホン化多孔性カーボン
JP2011201733A (ja) * 2010-03-26 2011-10-13 Equos Research Co Ltd スルホン化カーボンのハメット酸度関数制御方法
JP2012121796A (ja) * 2010-11-23 2012-06-28 Hutchinson Sa 新規な硫黄改質モノリシック多孔質炭素系材料、その調製のための方法、ならびにエネルギーの貯蔵および放出におけるその使用

Also Published As

Publication number Publication date
US20100216953A1 (en) 2010-08-26
CN101675002B (zh) 2013-11-06
EP2159193A1 (en) 2010-03-03
JPWO2008143008A1 (ja) 2010-08-05
US8017724B2 (en) 2011-09-13
KR20100017729A (ko) 2010-02-16
EP2159193A4 (en) 2011-06-22
CN101675002A (zh) 2010-03-17
JP5339453B2 (ja) 2013-11-13
KR101459171B1 (ko) 2014-11-07

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