WO2008154398A1 - Cut, abrasion and/or puncture resistant knitted gloves - Google Patents
Cut, abrasion and/or puncture resistant knitted gloves Download PDFInfo
- Publication number
- WO2008154398A1 WO2008154398A1 PCT/US2008/066146 US2008066146W WO2008154398A1 WO 2008154398 A1 WO2008154398 A1 WO 2008154398A1 US 2008066146 W US2008066146 W US 2008066146W WO 2008154398 A1 WO2008154398 A1 WO 2008154398A1
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- WO
- WIPO (PCT)
- Prior art keywords
- guard plates
- glove
- former
- array
- knitted glove
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01505—Protective gloves resistant to mechanical aggressions, e.g. cutting. piercing
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/04—Appliances for making gloves; Measuring devices for glove-making
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2500/00—Materials for garments
- A41D2500/10—Knitted
Definitions
- the invention relates generally to knitted gloves.
- High-performance fabrics have been developed for some abrasion applications.
- One approach is to tightly weave or knit high denier yarn (e.g. nylon, polyester, etc.) into a fabric.
- Thermoplastic coatings can be applied to such fabrics to enhance abrasion resistance.
- Various high strength fibers e.g. Kevlar*, PBO, steel, glass, Dyneema ® ) are sometimes used in high performance fabrics. However, these high strength fibers tend to be brittle, and therefore, are not associated with exceptional abrasion performance in many applications.
- HDM manufactures and sells sheets of SuperFabric ® brand material that provide slash and abrasion resistance through the use of hard plates screen printed onto and affixed to the surface of a fabric in a closely spaced geometric pattern.
- This material is made into gloves by die cutting parts from the sheets and sewing or bonding the parts onto a glove. This results in a glove with excellent cut and abrasion resistance.
- this glove manufacturing method can be inefficient.
- Gloves are often made from a knitting process. Rubber dots are sometimes printed onto knitted gloves to improve their grip properties. However, the material used in these dots is purposely chosen to be a relatively soft material since this gives the best grip enhancement for many applications. These soft rubber dots, however, provide little if any puncture or cut resistance. Moreover, when soft rubber dots are used, the abrasion resistance is not improved enough for practical applications where hard abrading objects can cut into and damage the material of the rubber dot.
- the invention is an improved protective knitted glove assembly.
- One embodiment of the invention includes a knitted glove and two or more non-coplanar arrays of printed guard plates.
- the guard plates are small, regularly-spaced, generally uniform thickness, non-overlapping, hard polymer material members arranged in a predetermined pattern having an area parallel to a surface of the glove with major and minor dimensions.
- the major dimension to minor dimension aspect ratio of the guard plates is between about 3 and 1.
- the overall abrasion resistance of the glove assembly is substantially greater than an abrasion resistance of the knitted glove without the guard plates.
- FIG. IA is an isometric view of a knitted glove with printed protective plates in accordance with one embodiment of the invention, generally showing the palm, the side of the forefinger facing the thumb, and the thumb crotch surface portions of the glove.
- FIG. IB is an isometric view of the knitted glove shown in FIG. IA, generally showing the palm side of the glove.
- FIG. 1C is an isometric view of the knitted glove shown in FIG. IA, generally showing the back and thumb crotch surface portions of the glove.
- FIGS. 2A-2C show various views of an example of a protective material comprising hexagonal plates attached to a flexible knitted substrate of the glove.
- FIG. 3 shows an example of a protective material comprising square and pentagonal plates with relatively tight gaps attached to a flexible knitted substrate of the glove.
- FIG. 4 shows an example of a protective material comprising square and pentagonal plates with relatively wide gaps attached to a flexible knitted substrate of the glove.
- FIG. 5 shows an example of a protective material comprising circular plates attached to a flexible knitted substrate of the glove.
- FIG. 6A shows a side view of protective plates attached to a knitted substrate of the glove.
- FIG. 6B shows an embodiment of the invention having a layer of an elastomer over the tops of the plates and substrate of the material shown in FIG. 6A.
- FIG. 7A shows a top view of a secondary former used in connection with one embodiment of the invention to make an array of guard plates on the side of the glove shown in FIG. IA between the forefinger and the thumb.
- FIG. 7B shows an alternative secondary former that allows for additional coverage beyond that of the former shown in FIG. 7A.
- FIG. 7C shows another alternative former that allows for still more coverage beyond that of the former shown in FIG. 7B.
- FIG. 8 A shows a knitted glove that can be used in connection with the invention.
- FIG. 8B shows the knitted glove of FIG. 8A mounted to the former shown in FIG 7A.
- FIG. 9 shows a top view of a glove former that can be used in connection with the invention.
- FIG. IA shows a front view of one embodiment of the glove assembly of the present invention where guard plates 2 between the thumb and forefinger region are visible.
- guard plates 2 cover the generally planar palm side of the glove assembly 1, including the palm side of the fingers.
- the portion of the glove assembly 1 with guard plates 2 between the thumb and forefinger is effectively on the side of the forefinger and in the crotch between the forefinger and thumb, surfaces that are effectively non-coplanar and non-parallel with the guard plates on the palm of the glove assembly.
- the edges of the guard plates 2 on the side of the forefinger and in the thumb crotch are positioned adjacent to the edges of the guard plates on the palm.
- FIG. 1C shows glove assembly 1 from the side of the back of the hand.
- An array of guard plates 2 is shown on the sides of the thumb and forefinger and in the crotch of the forefinger and thumb.
- Another array of guard plates 2 is shown on the back of the glove assembly 1.
- the guard plates 2 on the sides of the thumb and forefinger and in the crotch of the thumb are non-coplanar and non-parallel with the guard plates 2 on the back of the glove assembly 1.
- FIG. 2A is a detailed view of a portion of an array of guard plates 2 in accordance with one embodiment of the invention.
- a plurality of plates 2 is affixed to the knitted glove fabric 3.
- the plates 2 are printed onto the outer surface 4 of the knitted glove fabric 3 using standard screen printing processes after placing the knitted glove over a generally planar former plate 50 such as that shown in FIG. 9.
- the former plate 50 shown in FIG. 9 is generally hand-shaped and can be used as a base for printing guard plates 2 on the palm and back sides of the knitted glove 3 such as that shown in FIG 8A.
- the former plate 50 is chosen so that the glove 3 fits snuggly on the former.
- the resin used to form guard plates 2 is chosen to have a rheology suitable to screen printing and to have cured properties suitable to providing protective properties.
- the plurality of plates 2 enhances the abrasion, wear, and cut resistance of glove 3.
- the resistance of glove 3 to puncture by nails or items of similar dimension is also enhanced by the plurality of plates 2.
- Puncture resistance to smaller diameter objects, such as hypodermic needles can be enhanced by using multiple layers of guard plates 2 or multiple layers of fabric substrates with the guard plates. For example a two layer glove assembly can be made by taking two gloves and stretching one over the other. A slightly larger outer layer glove can be used to prevent excessive stretching from causing too tight a fit. Three, or even more, layers could be used similarly.
- abrasion resistance can range from low intensity rubbing typical of gloves repeatedly worn and laundered, to high intensity abrasion (high loading and/or high speed) such as for gloves worn to provide protection in, for example, motorcycle riding.
- fabrics of the present invention can be heat resistant, which is meant to include fabrics that are relatively heat tolerant and heat insulating.
- cut resistant plates 2 to the gloves 3, as is done in this invention, will substantially improve the cut resistance and other mechanical properties.
- the cut resistance can be further increased by adding hard fillers, such as ceramic beads or glass beads, to the resin used to construct the plates 2.
- the thickness of the plates can be adjusted to provide a balance between overall glove weight and the desired level of slash resistance.
- the present invention is an alternative way of making gloves that incorporate the essential features of SuperFabric ® technology without the processing costs associated with making SuperFabric ® sheets into gloves. These gloves are made by printing guard plates 2 directly onto the surface of a finished knitted or woven glove 3. The resulting glove assembly 1 has comparable abrasion resistance to gloves made from SuperFabric ® sheets without the extra costs associated with sewing in the SuperFabric ® patches. Although in some embodiments there may be some modest reduction in cut resistance due to the stretchability of the knitted glove, the gloves of the present invention offer improved comfort compared to typical gloves made from SuperFabric ® sheets because of this stretchability afforded by the knitted substrate.
- cut resistant plates 2 are used with a sufficiently tight gap that it is improbable or impossible for a blade to slash through the glove without cutting the plates.
- wear resistant plates 2 are used and these can dramatically improve the lifetime of the glove.
- a relatively soft dot (not shown) can be printed on top of the cut-resistant 2 plates for enhanced grip properties if desired.
- a dip coating can be applied over the plates 2.
- the surface properties of the hard plates 2 may be preferred.
- the base fabric of the knitted gloves 3 is nylon. In other embodiments, polyester, aramid, ultra high molecular weight polyethylene or blends of these materials are used. In still another embodiment, the base fabric comprises a blend of aramid and thin steel wires.
- FIGS. 3, 4 and 5 illustrate alternative geometries for the plates 2. FIG.
- FIG. 3 shows a pattern having pentagons and squares.
- FIG. 4 is a similar pattern but with larger gaps. The gaps 5 between the plates 2 in FIG. 4 are still small enough that a blade can not penetrate the glove 3 for a significant distance without cutting through guard plates 2. This allows the printed glove assembly 1 to have significantly enhanced cut resistance as well as abrasion resistance.
- FIG. 5 shows an alternative embodiment with circular plates.
- Having rigid plates with tight gaps 5 as shown in FIG. 2 A may reduce the overall stretchability of the glove assembly 1.
- the glove assembly 1 can however be re-designed so that it fits the appropriate sized hand after the printing operation. So, for example, a glove 3 that was originally designed for a large sized hand might fit a medium sized hand well after it is made into a glove assembly 1 by printing with rigid plates 2. In one embodiment, only certain areas of the glove 3 are covered with guard plates 2 and the non-covered areas allows for stretchability.
- Plurality of plates 2 are non-overlapping and are arrayed and affixed on the outer surface 4 of the knitted glove 3. Plates 2 define a plurality of gaps 5 between adjacent plates 2.
- Gaps 5 are continuous and inter-linking and each has a selected width so that the glove assembly 1 retains flexibility while simultaneously inhibiting objects from abrading directly against and degrading the glove's substrate 3.
- the glove 3 can be printed in several stages. For example, after a glove such as 3 is placed on a former plate such as 50, plates 2 can be printed on the opposite sides during separate printing steps. The gaps 5 between the plates 2 can be significantly smaller than the largest plate dimension when the gloves are in the unstretched state.
- FIGS. 2A, 3, 4 and 5 illustrate various plate 2 dimensions and patterns that can be selected for a desired abrasion, cut and/or puncture resistance. Plates 2 have an approximately uniform thickness (shown on FIGS.
- plates 2B and 2C that is in the range of 4 to 40 mils in some embodiments.
- plates 2 have an approximately uniform thickness in the range of 4 to 20 mils. It is important to note that although plates 2 can be shaped as identical regular hexagons, plates 2 can be embodied in any regular or non-regular shape, and be identical or non-identical to one another. In some embodiments, the maximum dimension is in the range of 20 to 200 mils for any plate shape, including hexagonal.
- plates 2 can have any polygonal shape such as a square, rectangle, octagon, or a non-regular polygon shape. Plates 2 can also have any curved shape such as a circle, ellipse, or a non-regular curved shape. Plates 2 can also be embodied as a composite shape or combination of any regular or non-regular polygon and/or any regular or non-regular curved shape. [0036] In one embodiment of the present invention the ratio of the major dimension of the guard plate 2 to the minor dimension of the guard plate is between 1 and about 3.
- the guard plates 2 can have horizontal aspect ratios outside this range.
- the ratio of the major dimension of the guard plate to the thickness the guard plate is between 3 and about 10. This is a preferred range, because vertical aspect ratios greater than about 10 would result in plates that are more prone to cracking and vertical aspect ratios less than about 3 would be difficult to produce in a screen printing operation. In other embodiments of the invention the guard plates 2 can have vertical aspect ratios outside this range.
- Gaps 5 are continuous due to the non-overlapping characteristics of plates 2. Gaps 5 also have a width that can be approximately uniform or nonuniform. However, generally, the gap 5 width is in the range of approximately 4 to 20 mils, which is the same range provided for plate thickness. In other embodiments, both gap 5 width and plate thickness is in the approximate range of 4 to 40 mils.
- the co-extending ranges for gap 5 width and plate thickness have been found to be an appropriate compromise between adequate flexibility and adequate mechanical strength against outside forces (i.e. abrasion, wear, cut and tear resistance) as well as providing optional heat resistance. Other embodiments of the invention have dimension outside these ranges.
- the knitted gloves can be printed by mounting the gloves on a flat hand former 50 such as that shown in FIG. 9 and then screen printing resin onto the gloves in a flat-bed screen printing operation. Tack can be applied to the former 50 in order to prevent the glove 3 from pulling up from the former during the printing operation.
- the former is chosen to have an extended shape so that when the printed glove 1 is removed from the former, guard plates 2 will be present on the sides of the glove.
- the former 50 shown in FIG. 9 has widened pinky and thumb areas for this purpose.
- FIG. IA shows a knitted glove 3 with guard plates 2 on the side of the small finger (i.e. pinky) extending down the side of the hand.
- a second, third or even more screen printing stages or steps are applied.
- the second printing can take place on the same former 50 by simply rotating the former 180 degrees and then applying the second printing step. If the glove 3 needs to be removed from the first former 50 and placed onto a second former for the second printing (e.g., as would be the case for printing between the thumb and forefinger area as described below), it is generally preferable to pre-cure the first array of guard plates 2 before removing the glove from the first former. The glove 3 would then be placed over the second former and the second screen printing would be applied.
- the area on the side of the glove 3 between the thumb and the forefinger is printed in a secondary printing step where an appropriately shaped former is used to stretch the area of the glove 3 extending from the thumb through the forefinger area into a flat surface.
- a second array of guard plates is created that is non-coplanar with the first printed array of guard plates.
- An example of a former 52 that can be used for this purpose is shown in FIG. 7A. One end of this former 52 can be inserted into the forefinger of the glove 3 and the thumb of the glove can then be stretched over the other end of the former.
- FIGS. 8A and 8B show an un-mounted glove 60 and the glove 60 mounted on the former of FIG. 7A, respectively.
- the former 52 provides a generally planar surface perpendicular to the palm of the glove 60 between the tips of the thumb and forefinger.
- the appropriate shape for this former 52 will vary with the size of the glove.
- the shape of the former 52 is a rectangular shape with rounded ends having a length of about 6" - 12" and a width of about 0.5" to 1.5". In other embodiments (shown in FIGS.
- the shape of this former (52' and 52") is bulged out in the thumb crotch area (the area between the thumb and the forefinger) in order to give extended coverage in that area.
- the former can be made in two or more pieces (not shown) that can attach together after the parts are placed into the glove.
- the guard plates formed during each individual printing step can be pre-cured after those steps.
- the guard plates 2 can then be exposed to heat, or UV radiation, or otherwise cured, during a final curing step.
- FIGS. IA and 1C Embodiments having guard plates 2 in the thumb though forefinger area are shown in FIGS. IA and 1C.
- the guard plates in these embodiments are located in the thumb crotch region, but in other embodiments the guard plates can extend the full length between the thumb and the forefinger.
- the glove assembly 1 can be given a 3-D shape to improve comfort by printing the glove on a flat former (such as 50 and 52), only partially curing the resin while it is on the flat former, then removing the glove from the flat former and placing it on a former (not shown) having a 3-D shape corresponding to the desired shape of the portion of the glove with the plates 2 (e.g., hand-shaped).
- FIG. 6A shows a side view of plates 2 attached to a substrate 3.
- FIG. 6B shows a layer of an elastomer 6 applied over the tops of the plates 2 as an example of this embodiment of the invention.
- Abrasion is a complex phenomenon or process and is influenced, for examples, by the types of materials that are being abraded, the surface characteristics, the relative speed between surfaces, lubrication, and the like.
- One typical test is the ASTM D 3884. In this test, two round-shaped wheels with specified surface characteristics apply pressure and rotate on the surface of the test sample with a given speed under a predetermined load (e.g. up to 100Og). Test results are given either as the number of cycles for the fabric to wear through or as the fabric's weight loss after a fixed number of cycles.
- one test can comprise washing gloves continuously in a washing machine containing rocks.
- gloves can be wrapped around a concrete weight and thrown from a speeding vehicle in order to test gloves suitable for wear by motorcycle riders and the like.
- the affixed plates enhance the abrasion and wear resistance of the base glove fabric by a enhancement factor F.
- An enhancement factor F is the ratio of abrasion and/or wear resistance of the fabric assembly of the glove to that of the knitted fabric.
- the enhancement factor F can be the ratio of any measurement that is associated or correlated with abrasion and/or wear resistance.
- the enhancement factor can be influenced by selecting various substrate fabrics, guard plate shape and dimensions such as thickness, gap width, plate diameter or maximum dimensions.
- the enhancement factor can generally range from 2 to 200 depending on various selections made. In other embodiments, the enhancement factor can range from 3 to 100, 3 to 10, 10 to 50, and 12 to 30, respectively.
- the present invention offers a number of advantages over known gloves such as those having printed rubber material dots on the knitted gloves.
- One major improvement of the present invention is the increase in both abrasion resistance, cut and puncture resistance from using a geometry where the gaps between plates are smaller than the largest plate dimension. Using smaller gaps will generally enhance abrasion resistance since a larger area of the fabric will be covered. Using gaps sufficiently small that extended straight lines between plates are avoided improves both the abrasion and slash resistance since it will reduce the chances of any sharp edges penetrating the fabric. Using a gap smaller than likely puncturing object, will provide puncture resistance against those objects. Using multiple layers of the gloves can further enhance the puncture resistance.
- the width of the gaps, when the glove is unstretched is between 4 and 75 percent of the size of the largest plate dimension. In other embodiments, the width of the gaps, when the glove is unstretched, is between 4 and 20 percent of the size of the largest plate dimension. In other embodiments of the invention the dimensions can be outside these ranges.
- a second major advantage of the present invention is the use of a cut resistant plate.
- the plates used in the present invention provide slash protection due either to the inherent hardness of the resin used to construct the plate or to hard fillers added to the resin (or from a combination of both effects). Using cut resistant plates increases the real-world abrasion resistance as well as the slash resistance, since the cut resistant plates will prevent sharp edges of rocks, for example, from cutting into the gloves.
- the plate material is applied in a wet form and slightly permeates and affixes to outer surface 4.
- Plate material includes resins such as epoxy resins, phenol-based resins, and other like substances. Such materials can require heat or ultraviolet curing.
- Plate materials can be resins such as epoxy or phenol based resins that are capable of being solid or hard. It is generally preferred that plate material has tensile strength higher than about 100 kgf/cm 2 (typical epoxy tensile strength when cured of approximately 700 kgf/cm 2 ). It is also generally preferred that the plate hardness be higher than about Shore D 10.
- additives can be added to the resins in order to increase abrasion, wear and/or slash resistance when appropriate. Examples of additives include alumina or titanium particles or ceramic or glass beads. Resin materials can also be specifically selected for their heat resistant properties.
- an additional layer of plate material can be applied to the outer surface of the printed glove either by a printing operation or by dip coating.
- This material can be chosen to be polyurethane, nitrile, silicone, plastisol, or other elastomeric material for improved grip properties.
- the material will go between the gaps in the guard plates to form a bond with the underlying knitted fabric of the base glove layer.
- the diameter of the elastomeric material is applied as dots with a diameter between 10 and 500 mils and with gaps between 10 and 500 mils.
- plate dimensions are selected so that plate maximum dimension is in the range of approximately 20 to 200 mils.
- the plates are shaped as polygons such as equilateral hexagons; curved shapes; or composite shapes arrayed in a pattern with gap widths between adjacent plates in the range of 4 to 100 mils.
- the plate thickness is in the range of 4 to 100 mils.
- plate thickness and gap width is in the range of 4 to 20 mils.
- Other embodiments of the invention have other dimensions and features.
- These various print patterns can be achieved by the appropriate selection of a screen in the screen printing operation.
- the plates formed during the several printing steps can also be positioned sufficiently close to one another as to provide an essentially seamless characteristic.
- the glove assembly is considered attractive.
- the plates can be colored to match or contrast with the glove's fabric substrate.
- the plates can be arrayed in attractive patterns. It is also possible that plate patterns and/or colors can be selected to form images or lettering due to the small yet discrete characteristics of the affixed plates.
- the affixed plates can also be made to be heat insulating.
- Various embodiments of protective material and methods of manufacturing the protective material that can be used in connection with the gloves described herein are described in commonly owned U.S. Patent No. 6,962,739, titled SUPPLE PENETRATION RESISTANT FABRIC AND METHOD OF MAKING, filed July 6, 2000, U.S. Patent No.
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Abstract
Description
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Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010511371A JP2010529320A (en) | 2007-06-06 | 2008-06-06 | Cut-resistant, wear-resistant and / or punch-resistant knitted gloves |
| EP08770361.7A EP2157875B1 (en) | 2007-06-06 | 2008-06-06 | Cut, abrasion and/or puncture resistant knitted gloves |
| KR1020107000174A KR101161490B1 (en) | 2007-06-06 | 2008-06-06 | Cut, abrasion and/or puncture resistant knitted gloves |
| CN2008800192019A CN101715307B (en) | 2007-06-06 | 2008-06-06 | Cut, abrasion and/or puncture resistant knitted gloves |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US94237707P | 2007-06-06 | 2007-06-06 | |
| US60/942,377 | 2007-06-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2008154398A1 true WO2008154398A1 (en) | 2008-12-18 |
Family
ID=40130155
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2008/066146 Ceased WO2008154398A1 (en) | 2007-06-06 | 2008-06-06 | Cut, abrasion and/or puncture resistant knitted gloves |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US20090007313A1 (en) |
| EP (1) | EP2157875B1 (en) |
| JP (2) | JP2010529320A (en) |
| KR (1) | KR101161490B1 (en) |
| CN (1) | CN101715307B (en) |
| WO (1) | WO2008154398A1 (en) |
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| DK201370565A1 (en) * | 2013-10-08 | 2015-04-20 | Würth Danmark As | Protective working glove, a method for making a protective working glove and use of protective working glove |
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2008
- 2008-06-06 KR KR1020107000174A patent/KR101161490B1/en not_active Expired - Fee Related
- 2008-06-06 JP JP2010511371A patent/JP2010529320A/en not_active Withdrawn
- 2008-06-06 WO PCT/US2008/066146 patent/WO2008154398A1/en not_active Ceased
- 2008-06-06 EP EP08770361.7A patent/EP2157875B1/en not_active Not-in-force
- 2008-06-06 CN CN2008800192019A patent/CN101715307B/en not_active Expired - Fee Related
- 2008-06-06 US US12/134,862 patent/US20090007313A1/en not_active Abandoned
-
2014
- 2014-02-17 JP JP2014027583A patent/JP5886887B2/en not_active Expired - Fee Related
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2016
- 2016-08-05 US US15/230,028 patent/US10455875B2/en not_active Expired - Fee Related
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| US5625900A (en) | 1995-03-08 | 1997-05-06 | Specialty Sports Limited | High grip glove |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK201370565A1 (en) * | 2013-10-08 | 2015-04-20 | Würth Danmark As | Protective working glove, a method for making a protective working glove and use of protective working glove |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5886887B2 (en) | 2016-03-16 |
| US20170055608A1 (en) | 2017-03-02 |
| US10455875B2 (en) | 2019-10-29 |
| EP2157875B1 (en) | 2016-10-26 |
| JP2010529320A (en) | 2010-08-26 |
| US20090007313A1 (en) | 2009-01-08 |
| EP2157875A1 (en) | 2010-03-03 |
| KR20100028094A (en) | 2010-03-11 |
| JP2014101621A (en) | 2014-06-05 |
| KR101161490B1 (en) | 2012-07-12 |
| CN101715307A (en) | 2010-05-26 |
| EP2157875A4 (en) | 2012-03-28 |
| CN101715307B (en) | 2013-09-25 |
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