WO2009019225A3 - Assoziativverdicker-dispersion - Google Patents

Assoziativverdicker-dispersion Download PDF

Info

Publication number
WO2009019225A3
WO2009019225A3 PCT/EP2008/060167 EP2008060167W WO2009019225A3 WO 2009019225 A3 WO2009019225 A3 WO 2009019225A3 EP 2008060167 W EP2008060167 W EP 2008060167W WO 2009019225 A3 WO2009019225 A3 WO 2009019225A3
Authority
WO
WIPO (PCT)
Prior art keywords
associative thickener
alkylacrylate
ethylene unsaturated
dispersion
thickener dispersion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2008/060167
Other languages
English (en)
French (fr)
Other versions
WO2009019225A2 (de
Inventor
Reinhold Leyrer
Kati Schmidt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ES08802954.1T priority Critical patent/ES2449747T3/es
Priority to AU2008285686A priority patent/AU2008285686A1/en
Priority to EP08802954.1A priority patent/EP2178933B1/de
Priority to PL08802954T priority patent/PL2178933T3/pl
Priority to CA2694212A priority patent/CA2694212C/en
Priority to JP2010519442A priority patent/JP5409629B2/ja
Priority to NZ582947A priority patent/NZ582947A/en
Priority to KR1020107003999A priority patent/KR101533858B1/ko
Priority to BRPI0814375-7A2A priority patent/BRPI0814375A2/pt
Priority to CN2008801017483A priority patent/CN101772522B/zh
Application filed by BASF SE filed Critical BASF SE
Priority to US12/671,596 priority patent/US8524649B2/en
Publication of WO2009019225A2 publication Critical patent/WO2009019225A2/de
Publication of WO2009019225A3 publication Critical patent/WO2009019225A3/de
Priority to EG2010010158A priority patent/EG26003A/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/43—Thickening agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Detergent Compositions (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Beschrieben wird eine wässrige Dispersion eines Copolymers mit einpolymerisierten Einheiten a) wenigstens einer ethylenisch ungesättigten Carbonsäure, b) wenigstens eines nichtionischen ethylenisch ungesättigten Tensidmonomers, c) wenigstens eines C1-C2-Alkylmethacrylats, d) wenigstens eines C2-C4-Alkylacrylats, wobei die über die Zahl der Alkylgruppen des Alkylacrylats gemittelte Alkylkettenlänge 2,1 bis 4,0 beträgt. Nach Neutralisation mit Alkali dient die Dispersion als Assoziativverdicker insbesondere für flüssige Wasch- und Reinigungsmittelformulierungen. Die Verdicker zeichnen sich durch hohe Transparenz und hohe Verdickungswirkung bei gleichzeitiger hoher Scherverdünnung aus.
PCT/EP2008/060167 2007-08-03 2008-08-01 Assoziativverdicker-dispersion Ceased WO2009019225A2 (de)

Priority Applications (12)

Application Number Priority Date Filing Date Title
BRPI0814375-7A2A BRPI0814375A2 (pt) 2007-08-03 2008-08-01 Espessante associativo, composição líquida de agente de lavagem e limpeza, e, métodos para preparação de uma composição líquida de agente de lavagem e limpeza, e para preparação de um espessante associativo.
EP08802954.1A EP2178933B1 (de) 2007-08-03 2008-08-01 Assoziativverdicker-dispersion
PL08802954T PL2178933T3 (pl) 2007-08-03 2008-08-01 Dyspersja zagęszczacza asocjacyjnego
CA2694212A CA2694212C (en) 2007-08-03 2008-08-01 Associative thickener dispersion
JP2010519442A JP5409629B2 (ja) 2007-08-03 2008-08-01 会合性増粘剤分散液
NZ582947A NZ582947A (en) 2007-08-03 2008-08-01 Associative thickener dispersion
KR1020107003999A KR101533858B1 (ko) 2007-08-03 2008-08-01 회합 증점제 분산액
ES08802954.1T ES2449747T3 (es) 2007-08-03 2008-08-01 Dispersión de espesante asociativo
AU2008285686A AU2008285686A1 (en) 2007-08-03 2008-08-01 Associative thickener dispersion
CN2008801017483A CN101772522B (zh) 2007-08-03 2008-08-01 缔合性增稠剂分散体
US12/671,596 US8524649B2 (en) 2007-08-03 2008-08-01 Associative thickener dispersion
EG2010010158A EG26003A (en) 2007-08-03 2010-01-31 A thickened companion agent comprising a water-soluble alkyl dissolved co-polymer of conjugated polymerized units

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
EP07113807 2007-08-03
EP07113807.7 2007-08-03
EP08150202 2008-01-11
EP08150202.3 2008-01-11
EP08159645.4 2008-07-03
EP08159645 2008-07-03

Publications (2)

Publication Number Publication Date
WO2009019225A2 WO2009019225A2 (de) 2009-02-12
WO2009019225A3 true WO2009019225A3 (de) 2009-05-28

Family

ID=39769068

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/060167 Ceased WO2009019225A2 (de) 2007-08-03 2008-08-01 Assoziativverdicker-dispersion

Country Status (13)

Country Link
US (1) US8524649B2 (de)
EP (1) EP2178933B1 (de)
JP (1) JP5409629B2 (de)
KR (1) KR101533858B1 (de)
CN (1) CN101772522B (de)
AU (1) AU2008285686A1 (de)
BR (1) BRPI0814375A2 (de)
CA (1) CA2694212C (de)
EG (1) EG26003A (de)
ES (1) ES2449747T3 (de)
NZ (1) NZ582947A (de)
PL (1) PL2178933T3 (de)
WO (1) WO2009019225A2 (de)

Cited By (2)

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US9200242B2 (en) 2011-11-11 2015-12-01 Basf Se Thickener comprising at least one cationic polymer
US11136534B2 (en) 2011-11-11 2021-10-05 Basf Se Thickener comprising at least one cationic polymer preparable by inverse emulsion polymerization

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JP5460625B2 (ja) * 2010-03-23 2014-04-02 ローム アンド ハース カンパニー 疎水性に改質されたアクリル系レオロジー調整剤を製造する方法
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JP2012136694A (ja) * 2010-12-27 2012-07-19 Rohm & Haas Co 高−界面活性剤配合物のためのポリマー
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US20110230387A1 (en) 2011-09-22
CA2694212A1 (en) 2009-02-12
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US8524649B2 (en) 2013-09-03
NZ582947A (en) 2011-06-30
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