WO2009024675A3 - Nouveaux complexes et procede de synthese d'organometalliques du groupe 4 greffes sur anions. procede d'oligomerisation et de polymerisation des olefines - Google Patents

Nouveaux complexes et procede de synthese d'organometalliques du groupe 4 greffes sur anions. procede d'oligomerisation et de polymerisation des olefines Download PDF

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Publication number
WO2009024675A3
WO2009024675A3 PCT/FR2008/000954 FR2008000954W WO2009024675A3 WO 2009024675 A3 WO2009024675 A3 WO 2009024675A3 FR 2008000954 W FR2008000954 W FR 2008000954W WO 2009024675 A3 WO2009024675 A3 WO 2009024675A3
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WO
WIPO (PCT)
Prior art keywords
group
oligomerisation
polymerisation
anions
olefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2008/000954
Other languages
English (en)
Other versions
WO2009024675A2 (fr
Inventor
Christine Bibal
Catherine Santini
Yves Chauvin
Helene Olivier-Bourbigou
Christophe Vallee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies nouvelles
Original Assignee
IFP Energies nouvelles
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies nouvelles filed Critical IFP Energies nouvelles
Priority to EP08827999.7A priority Critical patent/EP2164855B1/fr
Priority to US12/667,557 priority patent/US8470940B2/en
Publication of WO2009024675A2 publication Critical patent/WO2009024675A2/fr
Publication of WO2009024675A3 publication Critical patent/WO2009024675A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

De nouveaux composés organométalliques du groupe 4, supportés sur anions par l'intermédiaire d'au moins une liaison covalente métal-oxygène, sont obtenus par réaction d'au moins un borate ou aluminate comportant au moins un groupement hydroxy, avec au moins un composé d'un métal de transition du groupe 4. Ces composés sont utilisés dans une composition catalytique mise en oeuvre dans un procédé d'oligomérisation ou de polymérisation des oléfines.
PCT/FR2008/000954 2007-07-05 2008-07-03 Nouveaux complexes et procede de synthese d'organometalliques du groupe 4 greffes sur anions. procede d'oligomerisation et de polymerisation des olefines Ceased WO2009024675A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP08827999.7A EP2164855B1 (fr) 2007-07-05 2008-07-03 Nouveaux complexes et procede de synthese d'organometalliques du groupe 4 greffes sur anions. procede d'oligomerisation et de polymerisation des olefines
US12/667,557 US8470940B2 (en) 2007-07-05 2008-07-03 Complexes and method for synthesis of group 4 organometallics grafted on anions olefin oligomerization and polymerization method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0704935A FR2918374B1 (fr) 2007-07-05 2007-07-05 Nouveaux complexes et procede de synthese d'organometalliques du groupe 4 greffes sur anions. procede d'oligomerisation et de polymerisation des olefines
FR0704935 2007-07-05

Publications (2)

Publication Number Publication Date
WO2009024675A2 WO2009024675A2 (fr) 2009-02-26
WO2009024675A3 true WO2009024675A3 (fr) 2009-04-23

Family

ID=38863107

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2008/000954 Ceased WO2009024675A2 (fr) 2007-07-05 2008-07-03 Nouveaux complexes et procede de synthese d'organometalliques du groupe 4 greffes sur anions. procede d'oligomerisation et de polymerisation des olefines

Country Status (4)

Country Link
US (1) US8470940B2 (fr)
EP (1) EP2164855B1 (fr)
FR (1) FR2918374B1 (fr)
WO (1) WO2009024675A2 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2423178C2 (ru) * 2009-07-02 2011-07-10 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран Катализатор для получения 1-этил-2,3-диалкил(фенил)алюминациклопент-2-енов
FR2968655B1 (fr) * 2010-12-13 2012-12-07 IFP Energies Nouvelles Procede d'oligomerisation d'ethylene en alpha-olefines lineaires mettant en oeuvre une composition catalytique a base de complexes organometalliques du groupe 4 greffes sur anions
WO2014139861A1 (fr) 2013-03-11 2014-09-18 Universität Bayreuth Complexes pour l'oligomérisation catalytique d'oléfines

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2829133A1 (fr) * 2001-08-31 2003-03-07 Inst Francais Du Petrole Procede d'alkylation des olefines par les isoparaffines
US20050215738A1 (en) * 2004-03-26 2005-09-29 Goodall Brian L Olefin polymerization catalyst and polymerization process
WO2005090373A1 (fr) * 2004-03-17 2005-09-29 Georg-August-Universität Göttingen Complexe bimetallique ponte par oxygene, sa production et son utilisation pour la catalyse de polymerisation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2829133A1 (fr) * 2001-08-31 2003-03-07 Inst Francais Du Petrole Procede d'alkylation des olefines par les isoparaffines
WO2005090373A1 (fr) * 2004-03-17 2005-09-29 Georg-August-Universität Göttingen Complexe bimetallique ponte par oxygene, sa production et son utilisation pour la catalyse de polymerisation
US20050215738A1 (en) * 2004-03-26 2005-09-29 Goodall Brian L Olefin polymerization catalyst and polymerization process

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
CHOUKROUN R ET AL: "Disproportionation of Cationic Zirconium Complexes: A Possible Pathway to the Deactivation of Catalytic Cationic Systems", ORGANOMETALLICS, ACS, WASHINGTON, DC, US, vol. 16, 1 January 1997 (1997-01-01), pages 5517 - 5521, XP002463680, ISSN: 0276-7333 *
GURUBASAVARAJ PRABHUODEYARA M ET AL: "Synthesis, Structural Characterization, Catalytic Properties, and Theoretical Study of Compounds Containing an Al-O-M (M = Ti, Hf) Core", INORGANIC CHEMISTRY, AMERICAN CHEMICAL SOCIETY. EASTON.; US, vol. 46, no. 4, 1 January 2007 (2007-01-01), pages 1056 - 1061, XP002463679, ISSN: 0020-1669 *
MANDAL SWADHIN K ET AL: "Synthesis, Structural Characterization, and Theoretical Investigation of Compounds Containing an Al-O-M-O-Al (M = Ti, Zr) Core", INORGANIC CHEMISTRY, AMERICAN CHEMICAL SOCIETY. EASTON.; US, vol. 46, no. 18, 1 January 2007 (2007-01-01), pages 7594 - 7600, XP002463678, ISSN: 0020-1669 *
RODRIGUEZ-DELGADO A ET AL: "Ligand exchange and abstraction reactions involving titanium isopropoxide with tris(pentafluorophenyl)borane and -alane: ramifications for ring-opening polymerization of propylene oxide", INORGANICA CHIMICA ACTA, ELSEVIER BV, NL, vol. 357, no. 13, 1 November 2004 (2004-11-01), pages 3911 - 3919, XP004608573, ISSN: 0020-1693 *
WANG X ET AL: "Polyoxometalates supporting cyclopendienylzirconium CpZrXW11O39n-: a new kind of olefin polymerization catalyst", INORGANIC CHEMISTRY COMMUNICATIONS, ELSEVIER, AMSTERDAM, NL, vol. 8, no. 1, 1 January 2005 (2005-01-01), pages 70 - 71, XP004700263, ISSN: 1387-7003 *

Also Published As

Publication number Publication date
US8470940B2 (en) 2013-06-25
FR2918374A1 (fr) 2009-01-09
EP2164855A2 (fr) 2010-03-24
EP2164855B1 (fr) 2013-06-19
US20100286349A1 (en) 2010-11-11
WO2009024675A2 (fr) 2009-02-26
FR2918374B1 (fr) 2009-10-02

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