WO2009028176A1 - カラートナー用バインダー樹脂およびこれを用いるカラートナー - Google Patents

カラートナー用バインダー樹脂およびこれを用いるカラートナー Download PDF

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Publication number
WO2009028176A1
WO2009028176A1 PCT/JP2008/002317 JP2008002317W WO2009028176A1 WO 2009028176 A1 WO2009028176 A1 WO 2009028176A1 JP 2008002317 W JP2008002317 W JP 2008002317W WO 2009028176 A1 WO2009028176 A1 WO 2009028176A1
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WO
WIPO (PCT)
Prior art keywords
color toners
thf
binder resin
same
less
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/002317
Other languages
English (en)
French (fr)
Inventor
Kazuya Sakata
Hiroshi Matsuoka
Hiroyuki Takei
Kenji Uchiyama
Ichirou Sasaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Mitsui Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Chemicals Inc filed Critical Mitsui Chemicals Inc
Priority to EP08828404.7A priority Critical patent/EP2192449B1/en
Priority to CN2008801018946A priority patent/CN101772737B/zh
Priority to KR1020107006859A priority patent/KR101154797B1/ko
Priority to US12/675,324 priority patent/US8445170B2/en
Priority to JP2009529989A priority patent/JP5118141B2/ja
Publication of WO2009028176A1 publication Critical patent/WO2009028176A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
    • G03G9/08797—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/0802—Preparation methods
    • G03G9/081—Preparation methods by mixing the toner components in a liquefied state; melt kneading; reactive mixing
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/0802—Preparation methods
    • G03G9/0815—Post-treatment
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08706—Polymers of alkenyl-aromatic compounds
    • G03G9/08708—Copolymers of styrene
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08706—Polymers of alkenyl-aromatic compounds
    • G03G9/08708—Copolymers of styrene
    • G03G9/08711—Copolymers of styrene with esters of acrylic or methacrylic acid
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08722—Polyvinylalcohols; Polyallylalcohols; Polyvinylethers; Polyvinylaldehydes; Polyvinylketones; Polyvinylketals
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08724—Polyvinylesters
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08726—Polymers of unsaturated acids or derivatives thereof
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08726—Polymers of unsaturated acids or derivatives thereof
    • G03G9/08728—Polymers of esters
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08726—Polymers of unsaturated acids or derivatives thereof
    • G03G9/08733—Polymers of unsaturated polycarboxylic acids
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08735—Polymers of unsaturated cyclic compounds having no unsaturated aliphatic groups in a side-chain, e.g. coumarone-indene resins
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/0874—Polymers comprising hetero rings in the side chains
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
    • G03G9/08793—Crosslinked polymers
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/087—Binders for toner particles
    • G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
    • G03G9/08795—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

　本発明によれば、少なくともカルボキシル基含有ビニル樹脂（Ｃ）、グリシジル基含有ビニル樹脂（Ｅ）、およびこれらの反応物を含み、テトラヒドロフラン（ＴＨＦ）の可溶分および不溶ゲル分の両方を含み、前記ＴＨＦ可溶分が、ゲルパーミエーションクロマトグラフィー（ＧＰＣ）のクロマトグラムにおいて、分子量１０，０００以上１５，０００未満の領域にメインピークを有し、前記ＴＨＦ不溶ゲル分の含有量が１質量％未満であり、軟化点が１３０°C以下である、カラートナー用バインダー樹脂が提供される。
PCT/JP2008/002317 2007-08-30 2008-08-27 カラートナー用バインダー樹脂およびこれを用いるカラートナー Ceased WO2009028176A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP08828404.7A EP2192449B1 (en) 2007-08-30 2008-08-27 Binder resin for color toners and color toners made by using the same
CN2008801018946A CN101772737B (zh) 2007-08-30 2008-08-27 彩色调色剂用粘合剂树脂以及使用该粘合剂树脂的彩色调色剂
KR1020107006859A KR101154797B1 (ko) 2007-08-30 2008-08-27 컬러 토너용 바인더 수지 및 이를 이용하는 컬러 토너
US12/675,324 US8445170B2 (en) 2007-08-30 2008-08-27 Binder resin for color toners and color toner using the same
JP2009529989A JP5118141B2 (ja) 2007-08-30 2008-08-27 カラートナー用バインダー樹脂およびこれを用いるカラートナー

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007224152 2007-08-30
JP2007-224152 2007-08-30

Publications (1)

Publication Number Publication Date
WO2009028176A1 true WO2009028176A1 (ja) 2009-03-05

Family

ID=40386916

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/002317 Ceased WO2009028176A1 (ja) 2007-08-30 2008-08-27 カラートナー用バインダー樹脂およびこれを用いるカラートナー

Country Status (7)

Country Link
US (1) US8445170B2 (ja)
EP (1) EP2192449B1 (ja)
JP (1) JP5118141B2 (ja)
KR (1) KR101154797B1 (ja)
CN (1) CN101772737B (ja)
TW (1) TWI424291B (ja)
WO (1) WO2009028176A1 (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011158544A (ja) * 2010-01-29 2011-08-18 Sanyo Chem Ind Ltd 電子写真用トナーバインダーおよびトナー
US20120231389A1 (en) * 2009-11-20 2012-09-13 Mitsui Chemicals, Inc. Binder resin for toner, toner and method for producing same
JPWO2013176016A1 (ja) * 2012-05-22 2016-01-12 三井化学株式会社 トナー用バインダー樹脂及びトナー
US9341969B2 (en) 2012-02-14 2016-05-17 Sharp Kabushiki Kaisha Toner for electrostatic development, image forming device using same, and image forming method

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5118704B2 (ja) * 2007-08-30 2013-01-16 三井化学株式会社 カラートナー用バインダー樹脂およびこれを用いるカラートナー
CA2807017C (en) * 2010-08-05 2014-09-30 Mitsui Chemicals, Inc. Binder resin for toner, toner and method for producing the same
JP6067981B2 (ja) * 2012-03-15 2017-01-25 シャープ株式会社 粉砕トナーの製造方法

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1090943A (ja) 1996-09-11 1998-04-10 Mitsui Petrochem Ind Ltd 電子写真用トナー
JPH10142838A (ja) * 1996-09-11 1998-05-29 Ricoh Co Ltd 電子写真用トナー及びその製造方法
JPH10171162A (ja) 1996-12-12 1998-06-26 Mitsubishi Chem Corp カラートナー
JP2002189316A (ja) 2000-10-12 2002-07-05 Mitsui Chemicals Inc 電子写真用トナーバインダーおよび電子写真用トナー
JP2004144860A (ja) 2002-10-23 2004-05-20 Canon Inc トナー
JP2004177969A (ja) 2003-12-17 2004-06-24 Mitsubishi Chemicals Corp 画像形成方法
WO2005028545A1 (ja) * 2003-09-24 2005-03-31 Mitsui Chemicals, Inc. トナー用バインダー樹脂、その製造方法及び該樹脂を用いた電子写真用トナー
JP2005134891A (ja) * 2003-10-06 2005-05-26 Canon Inc トナー
JP2006171364A (ja) * 2004-12-16 2006-06-29 Mitsui Chemicals Inc トナー用バインダー樹脂および電子写真用トナー

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JP2578218B2 (ja) 1989-09-30 1997-02-05 積水化学工業株式会社 トナー用樹脂組成物及びトナー
US5262265A (en) 1989-07-31 1993-11-16 Sekisui Kagaku Kogyo Kabushiki Kaisha Resin composition for toners and a toner containing the same
JPH06175455A (ja) 1992-12-09 1994-06-24 Fujitsu Ltd カラー電子写真装置
JPH1069119A (ja) 1996-08-28 1998-03-10 Konica Corp 静電荷像現像用トナー及び熱定着方法
US5817443A (en) 1996-10-30 1998-10-06 Konica Corporation Toner for static charge developing and fixing method
JP3740759B2 (ja) 1996-11-01 2006-02-01 コニカミノルタホールディングス株式会社 静電荷像現像用トナー及び定着方法
SG70143A1 (en) 1997-12-25 2000-01-25 Canon Kk Toner and image forming method
JPH11316472A (ja) * 1998-03-03 1999-11-16 Mitsubishi Chemical Corp 静電荷像現像用トナー
JP3363856B2 (ja) * 1998-12-17 2003-01-08 キヤノン株式会社 正帯電性トナー、画像形成方法及び画像形成装置
JP4227268B2 (ja) 1999-12-28 2009-02-18 キヤノン株式会社 乾式トナー
EP1271256B1 (en) * 2000-09-07 2005-03-16 Mitsui Chemicals, Inc. Toner composition and method for production thereof
TWI227384B (en) * 2000-10-12 2005-02-01 Mitsui Chemicals Inc A toner binder for electrophotography and toner for electrophotography
JP3675738B2 (ja) 2001-06-06 2005-07-27 シャープ株式会社 静電荷像現像用トナーおよびその製造方法
JP2003255599A (ja) 2002-03-01 2003-09-10 Seiko Epson Corp トナーの製造方法およびトナー
US6916588B2 (en) 2002-06-03 2005-07-12 Mitsui Chemicals, Inc. Binder resin for toner and toner
JP4006283B2 (ja) 2002-07-16 2007-11-14 キヤノン株式会社 トナー、画像形成方法及び画像形成装置
JP4043475B2 (ja) 2002-08-08 2008-02-06 三井化学株式会社 トナー用バインダー樹脂およびトナー
US7288354B2 (en) 2003-08-01 2007-10-30 Canon Kabushiki Kaisha Toner
JP4208784B2 (ja) * 2003-08-01 2009-01-14 キヤノン株式会社 トナー
CN100428059C (zh) * 2003-10-06 2008-10-22 佳能株式会社 调色剂
JP4596887B2 (ja) * 2003-11-06 2010-12-15 キヤノン株式会社 カラートナー及び二成分系現像剤
US7351509B2 (en) 2004-02-20 2008-04-01 Canon Kabushiki Kaisha Toner
US7306889B2 (en) * 2004-02-20 2007-12-11 Canon Kabushiki Kaisha Process for producing toner, and toner
JP2005266788A (ja) 2004-02-20 2005-09-29 Canon Inc トナーの製造方法及びトナー
JP5118704B2 (ja) 2007-08-30 2013-01-16 三井化学株式会社 カラートナー用バインダー樹脂およびこれを用いるカラートナー

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1090943A (ja) 1996-09-11 1998-04-10 Mitsui Petrochem Ind Ltd 電子写真用トナー
JPH10142838A (ja) * 1996-09-11 1998-05-29 Ricoh Co Ltd 電子写真用トナー及びその製造方法
JPH10171162A (ja) 1996-12-12 1998-06-26 Mitsubishi Chem Corp カラートナー
JP2002189316A (ja) 2000-10-12 2002-07-05 Mitsui Chemicals Inc 電子写真用トナーバインダーおよび電子写真用トナー
JP2004144860A (ja) 2002-10-23 2004-05-20 Canon Inc トナー
WO2005028545A1 (ja) * 2003-09-24 2005-03-31 Mitsui Chemicals, Inc. トナー用バインダー樹脂、その製造方法及び該樹脂を用いた電子写真用トナー
JP2005134891A (ja) * 2003-10-06 2005-05-26 Canon Inc トナー
JP2004177969A (ja) 2003-12-17 2004-06-24 Mitsubishi Chemicals Corp 画像形成方法
JP2006171364A (ja) * 2004-12-16 2006-06-29 Mitsui Chemicals Inc トナー用バインダー樹脂および電子写真用トナー

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2192449A4 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120231389A1 (en) * 2009-11-20 2012-09-13 Mitsui Chemicals, Inc. Binder resin for toner, toner and method for producing same
US8586273B2 (en) * 2009-11-20 2013-11-19 Mitsui Chemicals, Inc. Binder resin for toner, toner and method for producing same
JP2011158544A (ja) * 2010-01-29 2011-08-18 Sanyo Chem Ind Ltd 電子写真用トナーバインダーおよびトナー
US9341969B2 (en) 2012-02-14 2016-05-17 Sharp Kabushiki Kaisha Toner for electrostatic development, image forming device using same, and image forming method
JPWO2013176016A1 (ja) * 2012-05-22 2016-01-12 三井化学株式会社 トナー用バインダー樹脂及びトナー

Also Published As

Publication number Publication date
US20100248121A1 (en) 2010-09-30
CN101772737A (zh) 2010-07-07
EP2192449B1 (en) 2015-06-17
TW200912568A (en) 2009-03-16
CN101772737B (zh) 2012-11-21
KR20100049675A (ko) 2010-05-12
EP2192449A4 (en) 2012-07-18
US8445170B2 (en) 2013-05-21
TWI424291B (zh) 2014-01-21
KR101154797B1 (ko) 2012-06-18
EP2192449A1 (en) 2010-06-02
JPWO2009028176A1 (ja) 2010-11-25
JP5118141B2 (ja) 2013-01-16

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