WO2009049811A1 - Apparatus for detection of chemical or biological substances and method for cleaning the apparatus - Google Patents

Apparatus for detection of chemical or biological substances and method for cleaning the apparatus Download PDF

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Publication number
WO2009049811A1
WO2009049811A1 PCT/EP2008/008507 EP2008008507W WO2009049811A1 WO 2009049811 A1 WO2009049811 A1 WO 2009049811A1 EP 2008008507 W EP2008008507 W EP 2008008507W WO 2009049811 A1 WO2009049811 A1 WO 2009049811A1
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Prior art keywords
sensor
cleaning
substances
contamination
analytical instrument
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PCT/EP2008/008507
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French (fr)
Inventor
Gerhard Müller
Andreas Helwig
Johann Göbel
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Airbus Defence and Space GmbH
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EADS Deutschland GmbH
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Application filed by EADS Deutschland GmbH filed Critical EADS Deutschland GmbH
Priority to AT08802832T priority Critical patent/ATE522833T1/en
Priority to CN200880111845.0A priority patent/CN101842721B/en
Priority to EP08802832A priority patent/EP2201411B1/en
Priority to JP2010529274A priority patent/JP5255062B2/en
Publication of WO2009049811A1 publication Critical patent/WO2009049811A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/62—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating the ionisation of gases, e.g. aerosols; by investigating electric discharges, e.g. emission of cathode
    • G01N27/622—Ion mobility spectrometry
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01V—GEOPHYSICS; GRAVITATIONAL MEASUREMENTS; DETECTING MASSES OR OBJECTS; TAGS
    • G01V9/00—Prospecting or detecting by methods not provided for in groups G01V1/00 - G01V8/00
    • G01V9/007—Prospecting or detecting by methods not provided for in groups G01V1/00 - G01V8/00 by detecting gases or particles representative of underground layers at or near the surface

Definitions

  • the invention relates to a device for detecting chemical or biological substances, having an analytical instrument for detecting the substances and for providing information concerning the qualitative or quantitative presence of the substances. Furthermore, the invention also relates to a method of cleaning the device and the analytical instrument contained therein.
  • Such detection devices are used for security screening portals
  • SSP which are frequently found at airports, at secured passage ways of buildings and the like.
  • the devices are used principally to detect chemical or biological substances, and in particular to avoid terror attacks by explosives.
  • a person or an object is exposed to one or more air blasts in order to detach any explosive particles that may be present on the clothing or the surface, and to deliver the latter to the detector usually constructed as an ion mobility spectrometer (IMS).
  • IMS ion mobility spectrometer
  • these are then converted to gaseous fragments — particularly nitrogen oxides (NOx) -, by which the explosive can be identified.
  • NOx nitrogen oxides
  • the above-mentioned systems have a high false alarm rate, which leads to problems because of the resulting delays, particularly in the processing of passengers.
  • the detectors are exposed to many different smelling substances, which have a tendency to accumulate on the interior surfaces of such portals, where they may be converted to secondary substances, and can prevent a reliable detection of traces of explosives in the most unfavorable case.
  • the detection device includes, in addition to the detection instrument, a contamination sensor that is constructed for measuring the degree of a contamination of the detector and/or of the device. More particularly, the invention is based on the idea of providing a sensor inside the device which measures the degree of contamination of the surfaces as well as particularly that of the analytical instrument. As a result, this contamination sensor provides a signal by which a need for cleaning the device (and particularly of the analytical instrument) can be determined. False alarms can thereby be reduced and an optimum cleaning interval can be determined, so that the cleaning will only take place when it is required. In addition, there is no further distortion of the measuring results, so that the sensor can also be reused after the cleaning. Contaminations in the analytical instrument by adsorption of water-soluble gases on the housing of the device or of the portal can be detected early. A required cleaning of the analytical instrument is therefore indicated early.
  • the contamination condition of adsorbed water layers within the device and the analytical instrument respectively is detected by means of a contamination sensor and resulting problems during the interpretation of the analytical results are indicated.
  • cleaning processes at the interior surfaces of the device and of the analytical instrument respectively are initiated as soon as the output signal of the contamination sensor exceeds a threshold value.
  • a sensor of this type consists, for example, of a diamond crystal having a hydrogenated surface.
  • undoped diamond crystals are nonconductors. It has been found, however, that undoped diamonds having hydrogenated surfaces have a P-type surface conductivity which depends on the presence of a thin adsorbed water layer. The thickness of this layer is estimated to be approximately 1 nm. It is found that the amount of surface conductivity is a function of the pH value in the adsorbed water layer. The latter, in turn, is influenced by the presence of electrolytically dissociating gases or vapors in the ambient gaseous atmosphere.
  • the sensor preferably has a semiconductor surface with a moisture film, the pH value of the moisture film being measurable and the substances being dissociable into the moisture film.
  • the pH value of the moisture film can be changed by the dissociation, in which case a charge transfer is generated into the semiconductor, so that the sensor is constructed as a pH sensor and is used as a threshold value sensor.
  • the device has a transducer which is constructed for measuring the charge transfer in the semiconductor. Such transducers are also called converters which, independently of the physical quantity of a received signal, provide an electric voltage, which are in a known or determinable connection with the measured quantity, so that the signal can be further processed.
  • the converter is constructed to permit the measurement of the charge transfer into the semiconductor, so that the change of the charge transfer is measured by the converter (transducer).
  • the contamination of the measuring device or of the portal can therefore be read off the sensor or off a connected read-out device.
  • the detector and/or the sensor according to the invention is advantageously constructed as an HD sensor, and has a diamond crystal with a hydrogenated surface having a surface conductivity.
  • the device may be constructed, for example, as a component of a security gate or of a portal for the detection of substances on persons and/or objects.
  • such devices are suitable for equipping security gates on airports or security-relevant buildings in order to check persons with respect to chemical or biological substances.
  • the present invention also provides a method of cleaning a chemical or biological substances detection device and the analytical instrument contained therein.
  • the point in time when it becomes necessary to clean the device (and the analytical instrument contained therein) is detected by measuring by means of the contamination sensor, and is provided as information.
  • the measuring detection of the point in time takes place by means of a pH value change.
  • the contamination of the analytical instrument or of the device reaches a value at which cleaning is required, the point in time of the cleaning as well as the span of the cleaning interval may be proportioned by means of information provided by the contamination sensor.
  • the occurrence of false alarms can thereby be excluded because, when the method according to the invention is used, the degree of contamination at which a false alarm can be triggered will no longer be reached.
  • One cleaning method utilizes a thermal evaporation of the surface water, which may also be a thermally accelerated, driving dissolved substances out of the absorbed water layer. It is known that the surface water quantitatively evaporates at temperatures of approximately 200°C. A temperature of 150°C, preferably a temperature of 175°C and particularly preferably a temperature of approximately 200°of the sensor or the detector is therefore provided in order to cause reliable evaporation of the water layer on the respective surface.
  • Another method for cleaning the corresponding surfaces is implemented by using oxidants, such as electrically generated ozone or metered added hydrogen peroxide (H2O2), upon the surfaces.
  • oxidants such as electrically generated ozone or metered added hydrogen peroxide (H2O2)
  • H2O2 metered added hydrogen peroxide
  • the resistance of the hydrogenated diamond can be reduced by means of a multiple action of ozone with a fraction of 300 ppb back to a neutral value.
  • Another method of cleaning the sensor surfaces includes irradiation of the semiconductor surface provided with the moisture film, using ultraviolet light. In this case, photocatalytical effects can be generated which lead to an accelerated reduction of the adsorbed chemical contaminations.
  • a photocatalytical cleaning of the interior surfaces of the device and of the analytical instrument respectively can be achieved by the application of nanocrystalline powder of titanium oxide.
  • the necessity of the above-described cleaning method can be demonstrated within the scope of the present invention by the following experiment: After a dissociation of HNO3 and NH3 exposures, which were carried out successively, a fast return to the sensor base line was observed. This compensation effect can be reached by the formation and precipitation of a saline compound according to
  • the single figure is a schematic view of an embodiment of the present invention.
  • the figure shows a device 1 for the detection of chemical or biological substances that is constructed essentially as rectangular portal.
  • the described preferred embodiment is also called a "security screening portal (SSP)" or security gate, and is used for the detection of chemical or biological substances on persons and/or objects.
  • SSP security screening portal
  • an analytical instrument 2 which, in the present case, is provided in the form of an ion mobility spectrometer (IMS), and is illustrated as a rectangular box at the right lower edge of the device 1.
  • IMS ion mobility spectrometer
  • a contamination sensor 3 is provided on the device 1 which, in the figure, is arranged slightly above the analytical instrument 2 laterally on the device 1.
  • the contamination sensor 3 is an HD sensor with a diamond crystal having a hydrogenated surface with a surface conductivity.
  • the sensor surface points to the interior surface of the device 1.
  • the semiconductor surface of the contamination sensor 3 has a moisture film 5 whose pH value can be measured by the contamination sensor 3.
  • the contamination sensor 3 detects that the water coatings or moisture films 5 occurring naturally on the interior surfaces of the device 1 and of the analytical instrument 2, contain substances which may impair the function of the analytical instrument, the contamination sensor 3 triggers a cleaning mechanism 4 in the device 1, which is outlined as fog or radiation, and/or a cleaning mechanism 6 in the analytical instrument 2. After the successful cleaning, the device 1 and the analytical instrument 2 are returned to their initial condition and can then again be fully utilized for detecting harmful substances.
  • the cleaning mechanism 4 in the device 1 and the cleaning mechanism 6 in the analytical instrument 2 contain, among other things, a photo catalysis by applying nanocrystalline powder of titanium oxide (TiO2) to the interior surfaces of the device 1 for the detection of chemical or biological substances and of the analytical instrument 2. Furthermore, a treatment with electrically generated ozone is provided which causes an oxidative conversion of interfering substances. Also, a metered addition of H2O2 is provided which causes an oxidative conversion of interfering substances. [0031]

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  • Physics & Mathematics (AREA)
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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
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Abstract

A device (1) for detecting chemical or biological substances includes an analytical instrument (2) for detecting the substances and for providing information concerning the qualitative or quantitative presence of the substances, and also a contamination sensor for measuring the degree of contamination of the analytical instrument (2) and/or of the device (1).

Description

APPARATUS FOR DETECTION OF CHEMICAL OR BIOLOGICAL SUBSTANCES AND METHOD FOR CLEANING THE APPARATUS
BACKGROUND AND SUMMARY OF THE INVENTION
[0001] The invention relates to a device for detecting chemical or biological substances, having an analytical instrument for detecting the substances and for providing information concerning the qualitative or quantitative presence of the substances. Furthermore, the invention also relates to a method of cleaning the device and the analytical instrument contained therein.
[0002] Such detection devices are used for security screening portals
(SSP) which are frequently found at airports, at secured passage ways of buildings and the like. The devices are used principally to detect chemical or biological substances, and in particular to avoid terror attacks by explosives. In such portals, a person or an object is exposed to one or more air blasts in order to detach any explosive particles that may be present on the clothing or the surface, and to deliver the latter to the detector usually constructed as an ion mobility spectrometer (IMS). At the site of the detector, these are then converted to gaseous fragments — particularly nitrogen oxides (NOx) -, by which the explosive can be identified.
[0003] In practical operation, the above-mentioned systems have a high false alarm rate, which leads to problems because of the resulting delays, particularly in the processing of passengers. During the operation of such devices, the detectors are exposed to many different smelling substances, which have a tendency to accumulate on the interior surfaces of such portals, where they may be converted to secondary substances, and can prevent a reliable detection of traces of explosives in the most unfavorable case.
[0004] By means of measurements, it can be shown that thin water layers may be created by adsorption of ambient humidity on the interior surfaces of the portals, as well as by adsorption within the analytical instruments themselves. Such water layers, in turn, can relatively rapidly absorb and accumulate electrolytically dissociating vapors which subsequently are very slowly emitted again into the environment. In this desorption process, particularly a background of gaseous NO2 and/or of solid ammonium nitrate may form in the analytical instrument. Both trace substances can negatively influence the ability of detecting explosives.
[0005] It is therefore an object of the present invention to provide an improved device for the detection of chemical or biological substances, such that distortions of the detector for the detection of chemical of biological substances are reduced or avoided.
[0006] This and other objects and advantages are achieved by the method and apparatus according to the invention in which the detection device includes, in addition to the detection instrument, a contamination sensor that is constructed for measuring the degree of a contamination of the detector and/or of the device. More particularly, the invention is based on the idea of providing a sensor inside the device which measures the degree of contamination of the surfaces as well as particularly that of the analytical instrument. As a result, this contamination sensor provides a signal by which a need for cleaning the device (and particularly of the analytical instrument) can be determined. False alarms can thereby be reduced and an optimum cleaning interval can be determined, so that the cleaning will only take place when it is required. In addition, there is no further distortion of the measuring results, so that the sensor can also be reused after the cleaning. Contaminations in the analytical instrument by adsorption of water-soluble gases on the housing of the device or of the portal can be detected early. A required cleaning of the analytical instrument is therefore indicated early.
[0007] According to one aspect of the invention, the contamination condition of adsorbed water layers within the device and the analytical instrument respectively is detected by means of a contamination sensor and resulting problems during the interpretation of the analytical results are indicated.
[0008] According to another aspect of the invention, cleaning processes at the interior surfaces of the device and of the analytical instrument respectively, are initiated as soon as the output signal of the contamination sensor exceeds a threshold value.
[0009] Hereinafter, the function of a contamination sensor according to the invention, arranged inside a device for the detection of chemical or biological substances, will be described in detail. A sensor of this type consists, for example, of a diamond crystal having a hydrogenated surface.
[OOIO] In principle, undoped diamond crystals are nonconductors. It has been found, however, that undoped diamonds having hydrogenated surfaces have a P-type surface conductivity which depends on the presence of a thin adsorbed water layer. The thickness of this layer is estimated to be approximately 1 nm. It is found that the amount of surface conductivity is a function of the pH value in the adsorbed water layer. The latter, in turn, is influenced by the presence of electrolytically dissociating gases or vapors in the ambient gaseous atmosphere. Since air moisture can in principle adsorb on any surface, it is found that the processes of a dissociation into the moisture layer can take place on any surface, including in particular the surfaces of the security screening portal and likewise in the interior of the analytical instruments and measuring devices; without, however, causing simultaneously measurable effects.
[OOll] The storage capacity of absorbed water coatings could be detected by exposing an HD (hydrogenated diamond) sensor to different acid and base vapors. In this case, a reaction of the sensor takes place upon two successive exposures to HNO3 vapors and NH4OH vapors. In the former case, NO2 vapors (that is, reactive gases) develop over the acid, which are present everywhere in variable concentrations in the form of combustion gases. NH3 vapors develop in the latter case. NH3 may occur in the ambient air as a result of agricultural emissions. Furthermore, NH3 is chemically related to the large group of amines present in many smelling substances.
[0012] In this case, it is found that acid- containing and base-containing vapors have a strong and opposite reaction to the electric conductivity of an HD sensor. It is also been found that the absorption of these vaporous contaminations in the adsorbed moisture layer takes place very rapidly. In this case, the recovery of the sensor signal takes place very slowly, which can be recognized by a signal drop by approaching the neutral point (pH=7).
[0013] The slow decay after a concluded exposure can be explained by the hydration of the NO3- ions that follows in the dissolution process (hydration = formation of a coordination sphere of aligned water dipoles around the central NO3- ion). This hydration makes the re -evaporation of the absorbed NO2 more difficult. In connection with the portal surfaces, this means that NO2 present in the environment in low concentrations accumulates in the moisture layers absorbed on the walls and, in the future, may be released again over long periods of time. Similar considerations therefore also apply to the case of an NH3 exposure. In particular, the absorption of the NH3 again takes place quite rapidly and, in contrast, the release occurs very slowly. The fact that the sensor resistance again approaches the sensor base resistance after the NH3 exposure suggests a neutralization effect.
[0014] Further investigations with other substances show that reactions may occur that have different intensities as a function of the substances. On the whole, examinations showed that particularly strong reactions are to be expected in the case of the NO2 overlying the detection of explosives and in the case of the amine-type smelling substances. Reactions of different intensities can be explained by the variability of three quantities which concern the vapor pressure of the various liquids, the solubility of the vapors in the liquid electrolyte on the sensor surface and the ease by which an electrolytic dissociation can take place in the absorbed water layer. In the following, Table 1 shows the vapor pressure, the solubility and the dissociation capacity of different vapors in water.
Acid/ Base Pvapor (200C) Solubility pKa/pKb
HCL 4260 mbar Good Solubility in -6 in water (850 g/L)
HNO3 9.4 mbar (68%) Completely mixable -1.32 56 mbar (100%) with water
H2SO4 0.0001 mbar Completely mixable -3 with water
H3PO4 0.038 mbar Completely mixable 1.96 With water
CH2O2 28 mbar Mixable with water 3.75 ethanol and glycol
NH3 8.572 bar Mixable with water pKa=23, (702 liters of NH3 in pKb=-9 1 liter of H2O)
NaOH 1.19 mbar Well mixable with Water
H2O2 1.9 mbar Completely mixable 11.6 with water
(CH3) 2CO 233 mbar Well mixable with 20 (acetone) water
Table 1: Vapor Pressure, Solubility and Dissociation Capacity of Various Vapors in Water
[0015] The sensor preferably has a semiconductor surface with a moisture film, the pH value of the moisture film being measurable and the substances being dissociable into the moisture film. The pH value of the moisture film can be changed by the dissociation, in which case a charge transfer is generated into the semiconductor, so that the sensor is constructed as a pH sensor and is used as a threshold value sensor. The device has a transducer which is constructed for measuring the charge transfer in the semiconductor. Such transducers are also called converters which, independently of the physical quantity of a received signal, provide an electric voltage, which are in a known or determinable connection with the measured quantity, so that the signal can be further processed. In the present case, the converter is constructed to permit the measurement of the charge transfer into the semiconductor, so that the change of the charge transfer is measured by the converter (transducer). The contamination of the measuring device or of the portal can therefore be read off the sensor or off a connected read-out device.
[0016] The detector and/or the sensor according to the invention is advantageously constructed as an HD sensor, and has a diamond crystal with a hydrogenated surface having a surface conductivity. The device may be constructed, for example, as a component of a security gate or of a portal for the detection of substances on persons and/or objects. In particular, such devices are suitable for equipping security gates on airports or security-relevant buildings in order to check persons with respect to chemical or biological substances.
[0017] The present invention also provides a method of cleaning a chemical or biological substances detection device and the analytical instrument contained therein. According to the invention, the point in time when it becomes necessary to clean the device (and the analytical instrument contained therein) is detected by measuring by means of the contamination sensor, and is provided as information. The measuring detection of the point in time takes place by means of a pH value change. When the contamination of the analytical instrument or of the device reaches a value at which cleaning is required, the point in time of the cleaning as well as the span of the cleaning interval may be proportioned by means of information provided by the contamination sensor. The occurrence of false alarms can thereby be excluded because, when the method according to the invention is used, the degree of contamination at which a false alarm can be triggered will no longer be reached. In the following, several methods are therefore described for the cleaning of surfaces for the reduction and prevention of interfering substances on the analytical instruments as well as on the portal or the device. [0018] One cleaning method utilizes a thermal evaporation of the surface water, which may also be a thermally accelerated, driving dissolved substances out of the absorbed water layer. It is known that the surface water quantitatively evaporates at temperatures of approximately 200°C. A temperature of 150°C, preferably a temperature of 175°C and particularly preferably a temperature of approximately 200°of the sensor or the detector is therefore provided in order to cause reliable evaporation of the water layer on the respective surface.
[0019] Another method for cleaning the corresponding surfaces is implemented by using oxidants, such as electrically generated ozone or metered added hydrogen peroxide (H2O2), upon the surfaces. For example, the resistance of the hydrogenated diamond can be reduced by means of a multiple action of ozone with a fraction of 300 ppb back to a neutral value.
[0020] Another method of cleaning the sensor surfaces includes irradiation of the semiconductor surface provided with the moisture film, using ultraviolet light. In this case, photocatalytical effects can be generated which lead to an accelerated reduction of the adsorbed chemical contaminations.
[0021] A photocatalytical cleaning of the interior surfaces of the device and of the analytical instrument respectively can be achieved by the application of nanocrystalline powder of titanium oxide. [0022] The necessity of the above-described cleaning method can be demonstrated within the scope of the present invention by the following experiment: After a dissociation of HNO3 and NH3 exposures, which were carried out successively, a fast return to the sensor base line was observed. This compensation effect can be reached by the formation and precipitation of a saline compound according to
NO3-+NH4+ → ammonium nitrate.
[0023] However, ammonium nitrate itself is an explosive. The collection and detection of precipitated particles can therefore easily lead to false alarms. In order to prevent the generation of direct interfering substances, the absorption layers in a security screening portal should be photo-catalytically cleaned after each measurable deviation from the neutral point of the sensor base line (pH = 7). In the latter case, a true cleaning according to the reaction equation
NO3- + NH4' → N2 + 2 H2O + 1A 02
can be used as the basis. As a result of the above-mentioned methods for cleaning the detector surfaces and for the reduction and prevention of interfering substances on the surfaces, an automatic cleaning system can be developed, so that at least one of the above-mentioned cleaning methods can be used for cleaning the sensor surfaces when the sensor for the detection of the contamination provides the information for the cleaning. [0024] Other objects, advantages and novel features of the present invention will become apparent from the following detailed description of the invention when considered in conjunction with the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
[0025] The single figure is a schematic view of an embodiment of the present invention.
DETAILED DESCRIPTION OF THE INVENTION
[0026] The figure shows a device 1 for the detection of chemical or biological substances that is constructed essentially as rectangular portal. The described preferred embodiment is also called a "security screening portal (SSP)" or security gate, and is used for the detection of chemical or biological substances on persons and/or objects.
[0027] The detection of such substances takes place by an analytical instrument 2 which, in the present case, is provided in the form of an ion mobility spectrometer (IMS), and is illustrated as a rectangular box at the right lower edge of the device 1.
[0028] In addition, a contamination sensor 3 is provided on the device 1 which, in the figure, is arranged slightly above the analytical instrument 2 laterally on the device 1. In the present embodiment, the contamination sensor 3 is an HD sensor with a diamond crystal having a hydrogenated surface with a surface conductivity. In this case, the sensor surface points to the interior surface of the device 1. The semiconductor surface of the contamination sensor 3 has a moisture film 5 whose pH value can be measured by the contamination sensor 3.
[0029] As soon as the contamination sensor 3 detects that the water coatings or moisture films 5 occurring naturally on the interior surfaces of the device 1 and of the analytical instrument 2, contain substances which may impair the function of the analytical instrument, the contamination sensor 3 triggers a cleaning mechanism 4 in the device 1, which is outlined as fog or radiation, and/or a cleaning mechanism 6 in the analytical instrument 2. After the successful cleaning, the device 1 and the analytical instrument 2 are returned to their initial condition and can then again be fully utilized for detecting harmful substances.
[0030] In the present embodiment, the cleaning mechanism 4 in the device 1 and the cleaning mechanism 6 in the analytical instrument 2 contain, among other things, a photo catalysis by applying nanocrystalline powder of titanium oxide (TiO2) to the interior surfaces of the device 1 for the detection of chemical or biological substances and of the analytical instrument 2. Furthermore, a treatment with electrically generated ozone is provided which causes an oxidative conversion of interfering substances. Also, a metered addition of H2O2 is provided which causes an oxidative conversion of interfering substances. [0031] The foregoing disclosure has been set forth merely to illustrate the invention and is not intended to be limiting. Since modifications of the disclosed embodiments incorporating the spirit and substance of the invention may occur to persons skilled in the art, the invention should be construed to include everything within the scope of the appended claims and equivalents thereof.

Claims

1. A device for detecting chemical or biological substances, said device comprising^ an analytical instrument for detecting the substances and for providing information concerning qualitative or quantitative presence of the substances; and a contamination sensor which measures a degree of contamination of the analytical instrument or the device.
2. The device according to Claim 1, wherein: the contamination sensor has a semiconductor surface having a moisture film; a pH value of the moisture film is measurable; and the substances are dissociable into the moisture film.
3. The device according to Claim 2, wherein^ the pH value of the moisture film is changed by the dissociation; and a charge transfer into the semiconductor is generated, such that the contamination sensor forms a pH sensor that operates as a threshold value sensor.
4. The device according to Claim 3, further comprising a transducer which measures the charge transfer into the semiconductor.
5. The device according to Claim 1, wherein the contamination sensor is an HD sensor.
6. The device according to Claim 5, wherein the contamination sensor has a diamond crystal, with a hydrogenated surface having a surface conductivity.
7. The device according to Claim 1, wherein the device comprises a security gate for detection of substances on persons and/or objects.
8. A method of cleaning an analytical instrument for detecting chemical or biological agents having a contamination sensor which measures a degree of contamination of the analytical instrument, wherein : a point in time when it becomes necessary to clean the analytical instrument and/or of the device is detected by measuring by means of the contamination sensor and is provided as information! and measuring detection of the point in time is performed by means of a pH value change.
9. The method according to Claim 8, wherein cleaning is performed by thermal desorption of the moisture film.
10. The method according to Claim 8, wherein: cleaning is performed by surface regeneration; and , oxidants, including at least one of electrically generated ozone and metered added H2O2, are used for the surface regeneration.
11. The method according to Claim 8, wherein the cleaning is performed by illuminating the semiconductor surface provided with the moisture film, using ultraviolet light.
12. The method according to Claim 8, wherein^ the interior surfaces of the device are coated with nanocrystalline Tiθ2J cleaning of the interior surfaces of the device and/or the analytical instrument is performed by photo-catalytic oxidation.
PCT/EP2008/008507 2007-10-18 2008-10-08 Apparatus for detection of chemical or biological substances and method for cleaning the apparatus Ceased WO2009049811A1 (en)

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AT08802832T ATE522833T1 (en) 2007-10-18 2008-10-08 DEVICE FOR DETECTING CHEMICAL OR BIOLOGICAL SUBSTANCES AND METHOD FOR CLEANING THE DEVICE
CN200880111845.0A CN101842721B (en) 2007-10-18 2008-10-08 Apparatus for detection of chemical or biological substances and method for cleaning the apparatus
EP08802832A EP2201411B1 (en) 2007-10-18 2008-10-08 Apparatus for detection of chemical or biological substances and method for cleaning the apparatus
JP2010529274A JP5255062B2 (en) 2007-10-18 2008-10-08 Apparatus for the detection of chemical or biological substances and method for cleaning the equipment

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US11/874,672 US7895881B2 (en) 2007-10-18 2007-10-18 Apparatus for detection of chemical or biological substances and method for cleaning the apparatus
US11/874,672 2007-10-18

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US9347917B2 (en) * 2012-03-28 2016-05-24 Dh Technologies Development Pte. Ltd. Mass spectrometry systems and methods for analyses on lipid and other ions using a unique workflow
WO2014045061A1 (en) * 2012-09-24 2014-03-27 Smiths Detection-Watford Limited Contamination reduction apparatus
CN121276014A (en) * 2025-12-08 2026-01-06 南京农业大学 Intelligent high-density aquaculture water quality monitoring and sensor cleaning system and method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5606264A (en) 1995-04-21 1997-02-25 Licari; James J. Moisture sensor for electronic modules
US20050254996A1 (en) * 2004-05-11 2005-11-17 Haupt Steven G Chemical agent detection
WO2007095203A2 (en) * 2006-02-14 2007-08-23 Excellims Corporation Ion mobility spectrometer apparatus and methods

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3101776B2 (en) * 1991-11-11 2000-10-23 東亜電波工業株式会社 Turbidity measuring device
JP3289522B2 (en) * 1994-11-25 2002-06-10 富士電機株式会社 BOD measuring device
US5656827A (en) * 1995-05-30 1997-08-12 Vanderbilt University Chemical sensor utilizing a chemically sensitive electrode in combination with thin diamond layers
JPH09257736A (en) * 1996-03-25 1997-10-03 Tokai Univ Gas sensor and gas detector
CA2306761A1 (en) * 1997-10-22 1999-04-29 Ids Intelligent Detection Systems, Inc. A sample trapping ion mobility spectrometer for portable molecular detection
US5915268A (en) * 1997-12-22 1999-06-22 Sandia Corporation Vertical flow chemical detection portal
JP2002055132A (en) * 2000-08-10 2002-02-20 Dkk Toa Corp Method for detecting contamination of electric conductivity cell and electric conductivity measuring device
CN1712820A (en) * 2004-06-21 2005-12-28 乐金电子(天津)电器有限公司 Operation controller and control for air purifier
US20060057026A1 (en) * 2004-09-14 2006-03-16 Boiadjiev Vassil I Gold thiolate and photochemically functionalized microcantilevers using molecular recognition agents
US20060231420A1 (en) * 2005-04-19 2006-10-19 The Regents Of The University Of California Explosives detection sensor
CN2879189Y (en) * 2005-10-13 2007-03-14 秦和平 Safety gate detecting off-limits person and contraband object
JP2008064612A (en) * 2006-09-07 2008-03-21 Kurita Water Ind Ltd Water quality measuring method and water quality measuring device

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5606264A (en) 1995-04-21 1997-02-25 Licari; James J. Moisture sensor for electronic modules
US20050254996A1 (en) * 2004-05-11 2005-11-17 Haupt Steven G Chemical agent detection
WO2007095203A2 (en) * 2006-02-14 2007-08-23 Excellims Corporation Ion mobility spectrometer apparatus and methods

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