WO2009059457A1 - Fibre fonctionnelle, procédé de préparation de celle-ci et étoffe faite de cette fibre - Google Patents

Fibre fonctionnelle, procédé de préparation de celle-ci et étoffe faite de cette fibre Download PDF

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Publication number
WO2009059457A1
WO2009059457A1 PCT/CN2007/003152 CN2007003152W WO2009059457A1 WO 2009059457 A1 WO2009059457 A1 WO 2009059457A1 CN 2007003152 W CN2007003152 W CN 2007003152W WO 2009059457 A1 WO2009059457 A1 WO 2009059457A1
Authority
WO
WIPO (PCT)
Prior art keywords
functional
fiber
oxide
polyolefin
fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2007/003152
Other languages
English (en)
French (fr)
Other versions
WO2009059457A8 (zh
Inventor
Hung-Jen Chen
Tina Huang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
U BOND Inc
Original Assignee
U BOND Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CA2705217A priority Critical patent/CA2705217A1/en
Priority to EP07816764A priority patent/EP2221399A4/en
Priority to AU2007361262A priority patent/AU2007361262A1/en
Priority to KR1020107012017A priority patent/KR20100112549A/ko
Priority to BRPI0722265-3A priority patent/BRPI0722265B1/pt
Priority to MX2010005102A priority patent/MX2010005102A/es
Priority to NZ585145A priority patent/NZ585145A/en
Priority to CN200780101449A priority patent/CN101855393A/zh
Priority to EA201000586A priority patent/EA201000586A1/ru
Priority to JP2010528259A priority patent/JP5520826B2/ja
Priority to PCT/CN2007/003152 priority patent/WO2009059457A1/zh
Application filed by U BOND Inc filed Critical U BOND Inc
Publication of WO2009059457A1 publication Critical patent/WO2009059457A1/zh
Publication of WO2009059457A8 publication Critical patent/WO2009059457A8/zh
Priority to TN2010000164A priority patent/TN2010000164A1/fr
Priority to IL205229A priority patent/IL205229A/en
Priority to NO20100618A priority patent/NO20100618L/no
Priority to US12/775,241 priority patent/US20100221969A1/en
Anticipated expiration legal-status Critical
Priority to MA32887A priority patent/MA31897B1/fr
Ceased legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00—Wearing apparel
    • D10B2501/04—Outerwear; Protective garments
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00—Wearing apparel
    • D10B2501/04—Outerwear; Protective garments
    • D10B2501/042—Headwear
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00—Domestic or personal
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00—Domestic or personal
    • D10B2503/02—Curtains
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00—Industrial
    • D10B2505/04—Filters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2927—Rod, strand, filament or fiber including structurally defined particulate matter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/298—Physical dimension
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3065—Including strand which is of specific structural definition

Definitions

  • the invention relates to a functional fiber, a preparation method thereof and a fabric made of the fiber, in particular to a functional microparticle, a thermoplastic elastomer (TPB) and a polyene, which are subjected to secondary kneading, and
  • TPB thermoplastic elastomer
  • the fiber is melt-spun to form a fiber, and the fiber can be woven into a fabric, which has deodorizing, antibacterial, anti-mildew, or can generate negative ions or far-infrared rays, and enhance the filtering effect of the fabric and improve the air quality.
  • the negative ion generator generates ozone (0 3 ), which is harmful to the human body, must be less than 0.12 ppm, and the negative ion range generated is only within one meter, and the aging of the negative ions is also limited.
  • the invention develops a long-acting multi-functionality for improving the indoor air quality IAQ (Inder Air Quality), improving health, and maintaining a comfortable and comfortable environment for improving the existing environmental pollution, thereby developing a long-lasting multi-functionality.
  • Self-cleaning filter, its functional fiber can effectively utilize the natural physical basis effects such as ambient wind, light, water, heat, etc., and stimulate the multi-functional function in the fiber by the principles of air flow, cold and heat difference, fiber vibration friction, photocatalytic catalysis.
  • Piezoelectric effect itself, piezoelectric effect, thermoelectric effect, photoelectric effect, catalytic effect, catalytic effect, slow release effect to achieve full effective sterilization, antibacterial, anti-mildew, anti-mite, negative ion, far infrared, fire, anti-static, anti-electromagnetic wave and exclude Contaminants such as odor, hair, TV0Cs, PMx, CO, C0 2 , furfural (HCH0), ozone 0 3 , ammonia (NH 3 ), acetaldehyde (CH 3 CH0 ), acetic acid (CH 3 C00H ), etc. Automatic air purification.
  • a first object of the present invention is to provide a method of making fibers having better functional properties.
  • the method features a multi-functional functional particle, a thermoplastic elastomer (TPE) and a polyolef ine, which are kneaded and drawn in a preferred ratio to form a fiber, which is elasticized by a thermoplastic elastomer. , and make the functional particles to achieve the best results.
  • TPE thermoplastic elastomer
  • polyolef ine which are kneaded and drawn in a preferred ratio to form a fiber, which is elasticized by a thermoplastic elastomer.
  • the fiber produced by the method of the invention comprises 5-30% multifunctional functional particles (such as tourmaline, nano metal particles, photocatalyst, enzyme, microcapsule, etc.), and the fiber is woven into a mesh body and composed of Functional fiber, which can make indoor air quality "IAQ", stimulate the piezoelectric effect, thermoelectric effect, catalytic effect, photoelectric effect and catalytic effect of multi-functional functional particles by the principles of air flow, cold and hot electricity, fiber vibration friction and so on.
  • multifunctional functional particles such as tourmaline, nano metal particles, photocatalyst, enzyme, microcapsule, etc.
  • a second object of the present invention is to provide a process which can be made into a fiber which is economically efficient and which can generate negative ions.
  • the method features that the functional particles used are sub-micron tourmaline.
  • the fabric woven by the fiber generates better vibration when the air flows, and then the tourmaline tourmaline It is possible to efficiently generate negative ions.
  • a third object of the present invention is to provide a method for producing fibers having antibacterial efficacy.
  • the method features that the functional particles used may be either nano or an enzyme.
  • a fourth object of the present invention is to provide a method for permanently producing a plant aroma fiber.
  • the method features that the functional microparticles used are microcapsules, and the microcapsules are coated with plant extract essential oil, and the thermoplastic elastomer can properly block the release of the essential oil, thereby achieving the purpose of making the fiber aromatic. .
  • the invention mainly aims at research and development and testing of functional fibers.
  • the basic feature of the technology is that the fiber of the present invention is made of a polyolefinic fiber (polyolefin), a thermoplastic elastomer (TPE), and a multifunctional functional particle as a substrate, and is made into a functional fiber by air flow.
  • Using fiber woven into filter 3D structure, honeycomb type, etc. it can reduce wind resistance, improve load carrying capacity, improve filtration efficiency, remove pollen and dust, and achieve long-acting water-washable acid, alkali and other environmental requirements and environmental protection and energy saving effects. .
  • the invention mainly aims at research and development and testing of functional fibers.
  • the basic feature of the technology is that the fiber of the present invention is produced by blending organic energy particles, a thermoplastic elastomer and a polyolefin, thereby imparting special functionality to the fiber, and is woven into a fabric or the like.
  • the fabric may be an air filter, or an insole, or a hat, or a screen window, or a curtain, or a TV goggle.
  • the fiber of the invention mainly comprises functional particles (the functional particles can be sub-micron tourmaline particles, micro-adhesive coated plant extract essential oil, nano silver particles, or enzyme), thermoplastic elastomer (TPE) and A fiber obtained by blending polyolef ine (for example, polypropylene or polyethylene), by adding a thermoplastic elastomer, the fiber of the present invention has better elasticity and friction characteristics, thereby allowing addition
  • the functional particles produce better performance.
  • the functional particles of the particle size of 1 micron to 100 nanometers of tourmaline, the fiber diameter of the fiber is 0. 01mm ⁇ 3imn.
  • the content of tourmaline particles is in the range of 1 to 10% by weight of the entire fiber, and the far infrared radiance of tourmaline: 0. 948 ⁇ (3. 48*102w/m 2 ) , particle size distribution: D50 (average particle size)
  • the diameter of 493 nm) has been found to be the best economic benefit of tourmaline particles accounting for 3% by weight of the entire fiber.
  • the mesh body woven by the fiber has the effects of generating negative ions, far infrared rays, self-cleaning, deodorizing, antistatic, anti-electromagnetic waves and the like.
  • One or more microparticle self-cleaning factors such as nano-charcoal, zinc oxide, copper oxide, iron oxide, silicon oxide, tungsten oxide, manganese oxide, cobalt oxide, and nickel oxide may be added.
  • the functional particles are made of nano-silver particles, thereby producing an antibacterial and anti-mildew function, and the added nano-silver accounts for 1 to 10% by weight of the entire fiber.
  • the mesh body woven by the fiber has the health functions of sterilization, antibacterial, anti-mildew, and anti-mite. It can also be added with one or more kinds of microbial bactericidal, antibacterial and antifungal factors such as chitin, enzyme or nano precious metal copper, zinc, gold, platinum, palladium and ruthenium.
  • the method for producing functional rayon according to the present invention mainly comprises preparing a plurality of first polyenef ine fragments as a substrate, and the first polyene group accounts for 70% to 95% by weight of the total weight, which may be molecular weight of 3.
  • the spinning temperature is in the range of 200 ° C ⁇ 300 ° C (the spinning temperature of the specific embodiment of the invention is 200 ° C ⁇ 250 ° C heating, polyethylene 250 ° C ⁇ 30 (TC)
  • the draw ratio is 3 to 8 times (the draw ratio in the specific operation example of the present invention is 6 times)
  • the heat extension temperature is 130 - 160 ° C (in the specific operation example of the present invention, the hot water is extended at 100 ° C)
  • the heating setting temperature is 70 ° C ⁇ 100 ° C.
  • the above-mentioned melt drawing is to heat and melt the synthetic material, and the molten material is extruded from the spinning hole into the air, and is cooled in the air, and is curled at a certain speed. At this stage, the melt of the synthetic material is refined while solidifying, that is, the fiber is formed. Then, hot stretching is performed to improve the mechanical properties of the fiber.
  • the melted wire drawing plate is extruded through a fine hole, cooled and refined into a filamentous solid, and simultaneously wound.
  • the functional particles used in the present invention are submicron tourmaline particles.
  • the functional microparticles used in the present invention are nano silver particles, and the test results shown later show that the present invention also has a better antibacterial and antifungal effect.
  • the functional microparticles added in the fibers are microcapsules (in the experimental example of the present invention, containing microcapsules, 1% by weight), and are packaged in microcapsules.
  • the functional material wherein the material of the microcapsule may be chitin, and the functional material may be a plant extracting essential oil, so that the present invention has an aromatic effect, and the test results shown later show the present invention. It has the effect of making the fragrance last.
  • the functional particles used in the present invention may also be used. For the enzyme, it has a certain help to the human body.
  • the experimental example of the present invention uses polypropylene having a molecular weight of 3.15 x l0 5 g/mole as a substrate, and first takes 20% by weight of polypropylene, and the following materials: (1) Functionality alone: Fireproof material and accounted for 15% by weight, (2) functional microparticles are 10% by weight of submicron tourmaline, and (3) functional microparticles are antibacterial and mildew resistant materials and account for 5% of the total weight.
  • Functional particles are deodorizing materials (gas removal) and account for 10% by weight; (5) Functional particles are antistatic electromagnetic resistant materials and account for 5% by weight; and (6) Thermoplastic elastomer (TPE)
  • TPE Thermoplastic elastomer
  • the above materials were granulated by twin-screw kneading to prepare a plurality of masterbatch. And taking the plurality of masterbatch 40% and the additional polypropylene 60%, and then mixing the masterbatch with the additional polypropylene into a synthetic material, so that the final content of the functional masterbatch is 32% of the total weight. percentage.
  • the synthetic material is then subjected to spinning, cooling, heat extension, and heat setting to form fibers.
  • the spinning temperature is in the range of 240 ° C
  • the drafting ratio is 5-6 times
  • the heat extension temperature is ⁇ ⁇ ⁇
  • the heating setting temperature is 85 °C.
  • the sample size is 101. 6mm * 203.
  • the woven fabric is woven into a fabric, the fiber is woven into a fabric, and the plurality of fibers are woven in a weft direction.
  • the sample size is 101. 6mm * 203. 2mm (4 in * 8 in), the distribution of the unit length of the warp fibers is 42 per inch, and the distribution of the unit length of the weft fibers is 34 per inch.
  • a. Mechanical test of the present invention The results of the mechanical tests of the above samples of the present invention are as follows.
  • Table 1 shows that as the tourmaline content increases, the tensile strength will gradually decrease, but the required strength is still maintained. Therefore, the tourmaline particles added by the present invention account for 1 to 5% of the total weight. good.
  • the tensile strength of the fabric of the present invention also decreases as the tourmaline content increases.
  • the tensile strength of the warp decreases by about 5%
  • the tensile strength of the warp decreases by about 8.6% when the tourmaline content is 5%, but still maintains a relatively high tensile strength. Therefore, the installation of tourmaline in the range of 1-5% does not affect the tensile strength.
  • the sub-micron tourmaline polypropylene filter material has 265-489 Ion/cc of negative ions at different levels under one layer.
  • Ion/cc the content of 1% sub-micron tourmaline polypropylene filter material ion dry 265-712 Ion / cc.
  • the deodorizing and antibacterial efficacy test of the fabric woven by the fiber of the present invention was as follows.
  • Table 4 shows the results of the elimination of the concentration of acetic acid (CH 3 C00H ) by measuring the concentration of ammonia (leg 3 ) and acetaldehyde (CH 3 CH0 ) according to the TEM 1467 test method. . From Table 4, it was found that the fabric of the present invention has a better deodorizing performance.
  • the antibacterial efficacy test results of the fabric woven by the fiber of the present invention are as follows ⁇
  • Test items Antibacterial mildew ring N Antibacterial rate Staphylococcus aureus 1 Omm 100 (%) Escherichia coli 4.5mm 100( )
  • Aroma durability test of fabrics woven from the fibers of the present invention From the results shown in Table 8, the present invention has an effective aroma effect for three months, which proves that the process of the present invention and the produced fiber can ensure the persistence of the aromatic oil in the added microcapsule.
  • Test item Test result (initial test) Test result (tested after three months)
  • the insole has a long-lasting fire resistance VTM-0.
  • Table 15 :
  • the fiber of the present invention adds functional particles (e.g., sub-micron tourmaline particles), and the mechanical strength of the filter made by the fiber is only slightly reduced, but does not have much influence.
  • functional particles e.g., sub-micron tourmaline particles
  • the fiber of the present invention adds functional particles (such as sub-micron tourmaline particles), and has a certain function after being tested for washing fastness.
  • the invention adds a thermoplastic elastomer and a sub-micron tourmaline particle.
  • the tourmaline has a negatively charged effect, and the "electrostatic adsorption principle" can effectively increase the filtration efficiency, and the other is due to the thermal plasticity.
  • the filter material made not only has better elasticity and friction, but also has high elastic vibration frequency and high frictional force due to the special effect of negative ions - thermoelectricity and piezoelectricity, which accelerates water decomposition of negative ions (H 3 0 2 - ). Large, dynamic mode can release a large amount of negative ions, and can indeed meet the needs of human health (1 000-2000i on / cc). It has been found through experiments that the release amount of negative ions in the volume of 4m*4m* 4 m is about 1856 ⁇ 1983 (Ion/cc), and has a good release amount.
  • thermoplastic elastomer since the thermoplastic elastomer is added at the same time, the elastomer can be prevented from rapidly evaporating by the action of the elastomer, and the essential oil can be released in a near quantitative manner to avoid waste. Improve durability.
  • the screen of the present invention has a certain antibacterial effect.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)
  • Woven Fabrics (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Multicomponent Fibers (AREA)
  • Filtering Materials (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Nonwoven Fabrics (AREA)

Description

机能性纤维、 其制法及以该纤維制成之织品
发明所属之技术领域
本发明系有关一种机能性纤维、 其制法及以该纤维制成之织品， 尤指 一种采用机能性微粒、 热可塑弹性体（TPB)与聚烯类， 经二次混练， 及熔融 抽丝而制成纤维， 并可以该纤维织制成织品， 而具有除臭， 或抗菌、 防霉， 或可产生负离子或远红外线之功能， 及增进织品过滤效果及提升空气质量。
先前技术
由于环境污染越来越严重， 空气中负离子数越来越少，再者，一般人每 天生活在室内环境中时间几乎占了百分之八十， 在有限空间内， 确保良好空 气质量实为生活之必要， 而室内环境中及与人体接近的网材例如空气滤网、 纱窗网等则变戒， 维护人体健康的很重要原因。 应用空气过滤网来改善空气 质量， 为目前已知最经济有效方式之一。 含机能性 粒如可产生负离子的纺 织产品， 由于对于人体健康有很大帮助， 已受到纺织产业与国际间的重视和 关注。惟因目前传统纺织技术尚未开发出较佳而可制出可有效产生负离子的 纺物， 因而大部份仍然采用负离子产生器来产生负离子。 然而， 负离子产生 器会产生臭氧（03 ), 对人体有害， 必需低于 0. 12ppm以下， 而且所产生负离 子范围仅在一米以内， 且负离子之时效性也有限。
因鉴于习用无一种具有较佳机能性的纤维及织物的制造技术，本发明人 等乃积极投入研发， 且已研发多年， 并不断改良与进步。 多年前研发而有一 定成果， 才于 2004年提出第一代的专利申请， 其技术如台湾申请第 93129156 号专利案， 该案目前已获准专利。 此外， 在经过多次的试验与改良又有新研 发技术产出， 乃又申请美国专利 11/416， 155号案。 近来又有新的技术研发完 成， 因而提出本案之申请。
目前习用也有抗菌除臭的织品或纤维技术， 例如美国第 4, 784, 909号专 利案， 系为抗菌除臭纤维的技术， 其主要是在纤维内添加铜。 美国第 6, 540, 807号专利案， 系为抗菌织品的技术， 其主要是以织品制成滤材， 而 织品则包括有热塑性塑料树脂及抗菌剂。 美国第 5, 690, 922号专利案， 系为 除臭纤维的技术， 其纤维包括四价的金属磷酸盐和二价的金属氢氧化物。 然 而， 该等前案技术均与本发明技术特征不同。 本发明乃本发明人多年研究及 制造经验的研发成果， 且经实臉证明确具实用功效， 已符合专利要件， 爰提 出专利之申请， 以保障研发心血。
本发明系为改善现有环境污染而针对改善室内空气质量 IAQ (Inder Air Qual i ty) , 维护健康， 养生舒适环境目的进而研发改善现有纤维结构， 而发 展出一种长效型多机能性自净滤网，其机能性纤维能有效利用环境中风、光、 水、 热等自然物理基础影响， 而藉由空气流动及冷热差、 纤维震动摩擦、 光 触媒催化等原理而激发纤维中多功能机能性微粒本身压电效应、 热电效应、 光电效应、 催化效应、 触媒效应、 緩释效应以达到充分有效杀菌、 抗菌、 防 霉、 防螨、 负离子、 远红外线、 防火、 抗静电、 抗电磁波及排除异味、 毛发、 TV0Cs、 PMx、 CO, C02、 曱醛 （HCH0)、 臭氧 03、 氨气（ NH3 )、 乙醛（CH3CH0 )、 醋酸（CH3C00H )等污染物等符合健康自动净化空气功效。
发明内容
本发明之第一目的， 在于提供一种可制成具较佳机能性纤维的方法。 其方法特征， 系采用多功能机能性微粒、 热可塑弹性体（TPE)与聚烯类 (polyolef ine)以较佳的比例混炼及抽丝制成纤维， 藉由热可塑弹性体的弹 性作用， 而使其机能性微粒得以发挥最佳的效果。本发明方法所制成的纤维 含有 5 ~ 30 %多功能机能性微粒（如电气石、 奈米金属粒子、 光触媒、 酵素、 微胶嚢等微粒）， 以该纤维织制成网体， 并组成机能性纤维， 可使室内空气 质量『IAQ』， 藉由空气流动及冷热电、 纤维震动摩擦等原理而激发多功能机 能性微粒本身压电效应、 热电效应、 催化效应、 光电效应、 催化效应、 触媒 效应、 緩释效应、 气味中和以达到充分有效杀菌、 抗菌、 防霉、 防螨、 负离 子、 远红外线、 防火、 抗静电、 抗电磁波及排除异味、 毛发、 TV0Cs、 PMx 等污染物等健康自动净化空气功效。
本发明之第二目的， 在于提供一种可制成经济效益较高而可产生负离 子之纤维的方法。 其方法特征， 系所采用的机能性微粒为次微米电气石， 藉 由热可塑弹性体的弹性作用，使纤维所织成的织品在空气流动时产生较佳的 振动， 进而让次 米电气石得以有效率地产生负离子。
本发明之第三目的， 在于提供一种可制成具抗菌效能之纤维的方法。 其方法特征， 系所采用的机能性微粒可为奈米 亦可为酵素。
本发明之第四目的，在于提供一种可持久产生植物芳香之纤维的方法。 其方法特征， 系所采用的机能性微粒为微胶嚢，且于微胶嚢内包覆有植物萃 取精油，藉由热可塑弹性体适当的阻挡精油的释放，故可达到使纤维芳香持 久的目的。
如上述健康养生需求， 藉由空气流动及冷热电、 纤维震动摩擦等原理 或光源等影响，而使多功能机能性微粒纤维能产生各类功效而形成长效型可 水洗机能性健康养生自净滤网。
实施方式
本发明主要是针对具有机能性之纤维做研发与试验。 其基本特征的技 术， 系本发明的纤维由包括有聚烯类（polyolef ine)、 热可塑弹性体 (TPE)、 多功能机能性微粒为基材混练制成机能性纤维，藉由空气流动及冷热电、纤 维震动摩擦、阳光照射等原理，而强化激发多功能机能性微粒本身压电效应、 热电效应、光催化效应、触媒效应、緩释效应等以达到充分有效杀菌、抗菌、 防霉、 防螨、 负离子、 远红外线、 防火、 抗静电、 抗电磁波及排除异味、 毛 发、 TV0Cs、 PMx等污染物等健康自动净化空气功效。 利用其纤维织成滤材 3D 结构、 蜂巢式等并能降低风阻、 提高承载能力、 提高过滤效能、 去除花粉、 尘埃， 而达成长效型可水洗耐酸、 碱等环境需求及环保节能等功效者。
为便于审查员了解本发明的可行性， 兹举具体实施例详细说明如后。
A.本发明的基本技术特征 本发明主要是针对具有机能性之纤维做研发与试验。 其基本特征的技 术， 系本发明的纤维由包括有机能性微粒、 热可塑弹性体与聚烯类所共混制 造而成， 进而使纤维具有特殊的机能性， 并可供织造成织品等。 其中， 该织 品可以是空气过滤网， 或鞋垫， 或帽子， 或紗窗， 或窗帘， 或电视护目罩。
B.关于本发明的纤维
本发明之纤维， 主要为包括机能性微粒（该机能性微粒可为次微米电气 石粒子， 微胶嚢包覆植物萃取精油， 奈米银粒子， 或酵素）、 热可塑弹性体 (TPE)与聚烯类（polyolef ine) (例如聚丙烯或聚乙烯）共混而成之纤维，藉由 热可塑弹性体的添加， 而使本发明之纤维具有较佳的弹性与摩擦特性， 进而 让所添加的机能性微粒产生较佳的效能。
本发明第一种具体实施例 ,机能性微粒采用粒径为 1微米至 100奈米之范 围内的电气石， 所制成之纤维线径为 0. 01mm ~ 3imn。 其中， 电气石粒子含量 占整个纤维的 1 ~ 10 %重量百分比的范围内， 电气石之远红外辐射率： 0. 948μαι (3. 48*102w/m2) , 粒径分布： D50 (平均粒径 493nm) , 经实验发现电气 石粒子占整个纤维的 3 %重量百分比的经济效益最佳。 藉以使过其纤维所织 成的网体具有产生负离子、 远红外线、 自净、 除臭、 抗静电、 防电磁波等功 效。 并可加入奈米竹炭、 氧化锌、 氧化铜、 氧化铁、 氧化硅、 氧化钨、 氧化 锰、 氧化钴、 氧化镍等一种或多种微粒自净因子。
本发明第二种具体实施例，机能性微粒采用奈米银粒子，藉以产生抗菌、 防霉功能， 其所添加的奈米银占整个纤维的 1 ~ 10 %重量百分比。 藉以使其 纤维所织成的网体具有杀菌、 抗菌、 防霉、 防螨等健康功能。 且可加入曱壳 素、 酵素或奈米贵金属铜、 锌、 金、 铂、 钯、 铌等一种或多种微粒杀菌、 抗 菌、 防霉因子。
本发明制造机能性人造纤维的方法， 主要是准备复数个第一聚烯类 (polyolef ine)碎片作为基材， 其第一聚烯类占整体重量之 70 % ~ 95 %重量 百分比， 其可以是分子量为 3. 15 x l 05g/mole的聚丙烯， 或是分子量为 1. 5 ~ 2, 5xl05g/mole的聚乙烯碎片 （其中， 本发明以下各项试验系以聚丙烯占 80 %重量百分比为具体实施例做说明）和占整体重量之 5% ~ 30%重量百分比 的机能性微粒（本段以次微米电气石粒子为例做说明），及占整体重量之 1 ~ 40%的热可塑弹性体（TPE或 EPDM) , 以双螺杆混练造粒而制成复数个母粒， 再取该复数个母粒及额外且相同于第一聚烯类的第二聚烯类，将该复数个母 粒与该第二聚烯类混练而成一合成材料，使电气石的最终含量为占该合成材 料之 1 ~ 10%的重量百分比， 再使该合成材料经抽丝、 冷却、 热延伸、 加热 定型制成纤维。 其中， 抽丝温度为 200°C ~ 300°C的范围内 （本发明具体操作 之实施例中抽丝温度聚丙烯 200°C ~ 250°C增温， 聚乙烯 250°C ~ 30(TC ), 牵 伸倍率 3~ 8倍（本发明具体操作之实施例中牵伸倍率为 6倍）， 热延伸温度 130 - 160°C (本发明具体操作之实施例中系以 100°C热水延伸）， 加热定型温 度为 70°C ~ 100°C。
上述熔融抽丝是将该合成材料加热熔融， 熔融从喷丝孔挤出进入空气， 在空气中冷却的同时， 以一定速度卷曲， 在该阶段合成材料熔体细化的同时 凝固， 即形成纤维， 再进行热拉伸， 以提高纤维的力学等性能。 熔融抽丝工 板细孔挤出， 冷却细化成丝状固体， 同时进行卷绕。
C.本发明机能性微粒的实施例
本发明为了能让纤维产生负离子,其所采用的机能性微粒为次微米电气 石粒子。 本发明为了能产生抗菌及防霉效果， 其所采用的机能性微粒为奈米 银粒子， 而如后面所示的试验结果显示本发明亦具有较佳的抗菌及防霉效 果。 再者， 本发明为了能产生其它机能效果， 在纤维中混练添加的机能性微 粒为微胶嚢（在本发明实验例中是含有微胶嚢 1 %重量百分比）， 且在微胶嚢 内包覆机能性材料， 其中该微胶嚢的材料可为曱壳素， 而该机能性材料可为 植物萃取精油， 藉以使本发明具有产生芳香的效果， 而如后所示的试验结果 显示本发明具有使芳香持久的效果。 此外， 本发明所采用的机能性微粒亦可 为酵素， 其对人体都有一定的帮助。
D.本发明之实验例
本发明之实验例， 系以分子量为 3. 15 x l05g/mole的聚丙烯做为基材，先 取聚丙烯占 20 %重量百分比， 与以下的材料： （1)机能性獨:粒为防火材料且 占 15%重量百分比， （2)机能性微粒为次微米电气石占 10%重量百分比， （3)机 能性微粒为抗菌防霉材料且占整体重量之 5%。 （4)机能性微粒为除臭材料（气 体去除）且占 10%重量百分比； （5)机能性微粒为抗静电抗电磁波材料且占 5% 重量百分比； 及（6)热可塑弹性体（TPE)占 35%重量百分比， 将上述材料以双 螺杆混练造粒而制成复数个母粒。 再取该复数个母粒 40%及额外的聚丙烯 60%, 再将母粒与该额外聚丙烯混练成一合成材料， 使该机能性母粒的最终 含量为占整体重量之 32 %的重量百分比。 再将该合成材料经抽丝、 冷却、 热 延伸、加热定型制成纤维。 其中，抽丝温度为 240°C范围内， 牵伸倍率 5- 6倍， 热延伸温度 Ι ΟΟ Ό , 加热定型温度为 85 °C。
为了做具体的实验， 本发明再取上述的纤维纺织成织品， 即以复数条呈 经向延伸的纤维及复数条呈纬向延伸的纤维编织成织品， 其样本尺寸为 101. 6mm * 203. 2mm (4 in * 8 in) , 经向纤维的单位长度分布数量为每英吋 42 条， 而纬向纤维的单位长度分布数量为每英吋 34条。 a .本发明之机械性试验 本发明上述样本之各项机械性试验结果如下。
(1)抗拉强度 表 1 (kgf/cm2)
Figure imgf000009_0001
由实验结果表 1得知， 随着电气石含量越多， 其抗拉强度将逐渐下降， 但仍保有要求的强度， 因而本发明所添加的电气石粒子占整体重量的 1 ~ 5% 为较佳。
(2)抗张强度：
表 2 (kgf/cm2)
Figure imgf000009_0002
由表 2得知， 本发明织品的抗张强度也随着电气石含量增加而减少， 在 电气石含量 1 %时经向抗张强度下降约 5 % , 在电气石含量 5 %时经向抗张强 度下降约 8.6%, 但仍然保持相当高的抗张强度。 因此电气石添加 1-5%之范 围内， 并不影响抗张强度。
(3)水洗牢度试验（测试时条件：湿度 58 % ,温度 29°C)：
表 3 ( Ion/ cc )
Figure imgf000010_0001
如表 3 ,测试前后仍维持良好的坚牢度， 负离子的产生量并未因水洗而 减少。
b.本发明负离子释放分析
(1)负离子静态释放情能分析：
静态模式负离子释放性能分析， 环境条件： 湿度 58%, 温度 28°C。
表 4-1 (Ion/cc)
Figure imgf000010_0002
由表 4-1分析可以得知电气石添加量跟层数都为显著影响因子， 但层数 是其主要影响因子。次微米电气石聚丙烯过滤材在一层下其不同含量下负离 子#放265- 489个 Ion/cc。 在含量 1 %次微米电气石聚丙烯过滤材离子幹放 265- 712个 Ion/cc。两者间相差了 223个 Ion/cc,在相同体积含有电气石数下； 层数的增加较有效于添加率的增加在负离子释放量上。
(2) 负离子动态释放情能分析：
动态模式负离子幹放性能分析， 环境条件： 湿度 64 % , 温度 29°C。
表 4-2 ( % )
Figure imgf000011_0001
由上表 4- 2中可看出在动态负离子幹放量上来说电气石添加量及过滤层 数都是重要因素， 但过滤层数为主要重要因素。 b.本发明除臭及抗菌效能试验
本发明纤维所编织成的织品的除臭及抗菌效能试验， 结果如下。 表 4是 分别以本发明织品， 依 TEM 1467测试法对于测量氨气（腿3 )及乙醛（CH3CH0 ) 之浓度， 再测试醋酸（CH3C00H )之浓度的消除效能而得之结果。 由表 4发现 本发明织品具有较佳的除臭效能。 表 4
项目 Item 氨气 NH3 乙醛 醋酸
CH3CH0 CH3C00H :½HThe beginning 24.00PPM 8. OOPPM 0.20PPM concentrat ion
30分钟后浓度 The 4. OOPPM 1.00PPM 0.04PPM concentration after 30minutes
the removing rate of multi pollution 84.33%
Figure imgf000012_0001
各污染成分去除率
总去除率 Total Removing Rate 84.58% c.实检例三
本发明纤维所编织成的织品的抗菌效能试验结果如下 <
表 5
Figure imgf000012_0002
JIS Z 2911黑曲菌 ATCC9642 0无生长
JIS Z 2911青霉菌属 ATCC9849 0无生长
JIS Z 2911球毛壳 ATCC6205 0无生长
JIS Z 2911袍漆菌 ATCC9095 0无生长
ASTM G21-96 癣霉菌 ATCC9533 0无生长
Figure imgf000013_0001
测试项目 抗菌防霉环 N抗菌率 金黄色葡萄球菌 1 Omm 100 (%) 大肠杆菌 4.5mm 100( )
肺炎杆菌 3.5mm
金黄色葡萄球菌 12mm 100(°/o) 大肠杆菌 2 mm 100 (%)
由表 5得知以 ASTM E 2149- 01试验法， 及表 6得知以 JISZ2911及 ASTM G21- 96试猃法， 证明本发明添加有奈米银粒子时， 纤维具有较佳的抗菌及防 霉效能。 由表 7得知以 AATCC 147试验法， 本发明添加有人工酵素时， 也具 有较佳的抗菌效能。
d.本发明芳香持久效能试验
本发明纤维所编织成的织品的芳香持久效能试验。 由表 8的结果显示， 本发明历经三个月仍具有有效的芳香效果,足证本发明的制法及所制成的纤 维， 可以确保所添加微胶嚢中精油之芳香的持久性。
表 8:添加含有精油之微胶嚢的芳香持久测试
试验项目 试验结果（初始测试） 试验结果（三个月后 再测试）
气味官能评估 3.4 4.0 再者，藉由 GC- MS测试本发明网体纤维内含有天然精油成分而得下表之 结果。
由表 9发现本发明网体能有效含有天然精油成分清净能力。 表 9
Figure imgf000014_0001
e.本发明抗静电效能试验
依据 AATCC 756-1995 温度 20 °C湿度 40 % RH由下表发现本发明纤维所 织成的网体有良好有抗静电效能能力。 试验项目 试验结果 电磁波遮蔽效果 DB/ 300MHZ 0. 2
电磁波遮蔽效果 DB/ 1800MHZ 0. 1
f .本发明防火效能试验
依 UL 94- 97方法由下表发现本鞋垫有长久有防火能力 VTM - 0。 表 15:
Figure imgf000015_0001
g.主要实猃例测试结果总表
本发明主要实验例测试结果总表及检测单位一览如表 9。 表 9:
Figure imgf000016_0001
E.本发明的特点
1.本发明纤维添加机能性微粒（如次微米电气石粒子）， 其所制成之滤网的 机械强度， 仅些微的减低， 但无太大影响。
2.本发明纤维添加机能性微粒（如次微米电气石粒子） ， 经水洗牢度试验， 仍保有一定的功能。
3.本发明添加热可塑弹性体及次微米电气石粒子， 一方面在过滤效能方面， 因电气石带负电效果，在「静电吸附原理」下而能有效增加提升过滤效能， 另方面因热可塑弹性体， 所制成之滤材不仅具有较佳弹性、 摩擦性， 由于 负离子特殊功效 -热电性、压电性加速水分解负离子（H302— )下， 弹性振动 频率高， 摩擦力较大， 动态模式下便可大量释放出负离子量， 而能确实符 合人体健康的需求量（1 000-2000i on/ cc )。经实验发现，本发明在 4m*4m*4m 的容积中负离子的释放量含量约 1856 ~ 1983 (Ion/cc) , 具有良好的释放 量。
4.本发明添加包含有精油的微胶嚢时， 因同时添加有热可塑弹性体， 藉由弹 性体的作用可避免精油快速挥发， 而可使精油以接近定量的方式释出， 避 免浪费及增进耐久性。
5.本发明于纤维中添加奈米银粒子时，使得本发明的滤网具有一定的抗菌效 果。
6.本发明于纤维中添加酵素时， 经实验证明本发明具有良好的抑菌及防霉效 果。
7.而使用本发明纤维所制成之滤材， 经实险证明， 室内空气质量得以有效提 升如表 9所示。
以上所述，仅为本发明之可行实施例，并非用以限定本发明之专利范围， 凡举依据下列申请专利范围所述之内容、特征以及其精神而为之其它变化的 等效实施， 皆应包含于本发明之专利范围内。

Claims

权 利 要 求 书
1.一种机能性纤维的制造方法， 其包括有：
(a)准备包括有以下材料：
(al) 70 % ~ 95 %重量百分比的第一聚烯类（polyolef ine)碎片作为基 材；
(a2) 5 % ~ 30 %重量百分比的至少一种复数个机能性微粒； 及
(a 3) 1 - 40重量百分比的热可塑弹性体（TPE)；
(b)将该第一聚烯类、 该复数个机能性微粒及该热可塑弹性体混练制成 复数个母粒；
(c)取该复数个母粒与一第二聚烯类碎， 该第二聚烯类与该第一聚烯类 为相同材料，并将该复数个母粒与该第二聚烯类碎片熔融混合而成一合成材 料， 使该复数个机能性微粒的含量占该合成材料之 1 ~ 10 %的重量百分比； 及
(d)将该合成材料经抽丝、 冷却、 热延伸及加热定型而制成纤维。
2.如申请专利范围第 1项所述之方法， 其中该第一聚烯类及该第二聚烯 类均为聚丙烯。
3.如申请专利范围第 2项所述之方法， 其中该聚丙烯之分子量为 3. 15 X X 105g/mo le。
4.如申请专利范围第 1项所述之方法， 其中该第一聚烯类及该第二聚烯 类均为为聚乙烯。
5.如申请专利范围第 4项所述之方法， 其中该聚乙烯之分子量为 1. 5 ~ 2. 5 X l 05g/raole。
6.如申请专利范围第 1项之方法， 其中， 该机能性 粒可为微胶嚢， 且 该微胶嚢内包覆有机能性材料。
7.如申请专利范围第 6项之方法， 其中， 该机能性材料为植物萃取精油。
8.如申请专利范围第 6项之方法， 其中， 该微胶嚢之材料系选自甲壳素、 聚氨脂弹性、 热可塑弹性体中的一种或多种。
9.如申请专利范围第 1项之方法， 其中， 该机能性^:粒的材料系选自甲 壳素、 酵素、 奈米贵金属铜、 锌、 金、 铂、 钯、 铌、 银其中至少一种。
1 0.如申请专利范围第 1项之方法， 其中， 该机能性微粒材料系选自次微 米电气石、 奈米竹炭、 氧化锌、 氧化铜、 氧化铁、 氧化硅、 氧化钨、 氧化锰、 氧化钴及氧化镍其中至少一种。
11.如申请专利范围第 1项之方法， 其中， 该次微米电气石之粒径为 1微 米至 100奈米之范围内。
12.如申请专利范围第 1项之方法，其中，抽丝温度为 250°C ~ 300°C增温， 该热延伸温度 1 Q(TC , 该加热定型温度 90 °C
1 3.一种以如申请专利范围第 1项所述之方法制成的机能性纤维， 该纤维 线径为 0. 01mm ~ 3醒， 该纤维内部包括有该复数个机能性微粒。
14.如申请专利范围第 13项之纤维， 其中， 该机能性微粒包括有微胶嚢， 该微胶嚢内包覆有机能性材料。
15.如申请专利范围第 14项之纤维， 其中， 该机能性材料为植物萃取精 油。
16.如申请专利范围第 14项之纤维， 其中， 该微胶嚢之材料系选自曱壳 素、 聚氨脂弹性、 热可塑弹性体中的一种或多种。
17.如申请专利范围第 1 3项之纤维， 其中， 该机能性微粒的材料系选自 曱壳素、 酵素、 奈米贵金属铜、 锌、 金、 铂、 钯、 铌、 银其中至少一种。
18.如申请专利范围第 13项之纤维， 其中， 该机能性獨:粒的材料选自次 微米电气石、 奈米竹炭、 氧化锌、 氧化铜、 氧化铁、 氧化硅、 氧化钨、 氧化
、 锰、 氧化钴及氧化镍其中至少一种。
19如申请专利范围第 18项之方法， 其中， 该次 米电气石之粒径为 1微 米至 100奈米之范围内。
20.一种以如申请专利范围第 13项所述之纤维制成之织品， 该织品包括 有相互编织的复数条呈经向延伸的该纤维及复数条呈繂向延伸的该纤维。
21.如申请专利范围第 20项所述之织品， 该织品系选自空气过滤网、 鞋 垫、 帽子、 纱窗、 窗帘及电视护目罩其中一种。
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Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63135512A (ja) * 1986-11-18 1988-06-07 Daicel Chem Ind Ltd 脱臭性ポリオレフイン繊維
US4784909A (en) 1986-09-16 1988-11-15 Teijin Limited Anti-fungus, deodorant fiber material
JPH02104712A (ja) * 1988-10-11 1990-04-17 Nippon Foil Mfg Co Ltd 抗菌性繊維
US5690922A (en) 1995-02-15 1997-11-25 Takeda Chemical Industries, Ltd. Deodorizable fibers and method of producing the same
US5869180A (en) * 1996-01-04 1999-02-09 Buedenbender; Juergen Melt-spun abrasion-resistant monofilaments
JP2000212826A (ja) * 1999-01-14 2000-08-02 Hagihara Industries Inc セメント補強用繊維
CN1350072A (zh) * 2001-12-11 2002-05-22 上海依福瑞实业有限公司 一种聚烯烃纤维及其制造方法
CN1355335A (zh) * 2000-11-28 2002-06-26 上海兰格科技发展有限公司 抗菌防霉聚丙烯丝的制法及空调过滤网
US6540807B1 (en) 1998-06-22 2003-04-01 Ei Kawaguchi Anti-mold and anti-bacteria air filter
CN1448551A (zh) * 2002-12-25 2003-10-15 沈阳工业大学 一种聚丙烯弹性纤维
CN1683614A (zh) * 2005-03-09 2005-10-19 丁宏广 能够发射负离子的单丝及其制备方法和用途
CN1766184A (zh) * 2004-10-27 2006-05-03 上海依福瑞实业有限公司 一种功能性聚丙烯纤维及其制备方法
CN1776034A (zh) * 2005-12-06 2006-05-24 颜志勇 一种医用x光显影纤维及其制造方法
CN101063235A (zh) * 2006-04-26 2007-10-31 上海展扬纳米科技有限公司 一种抗菌多功能纤维材料及其制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5206080A (en) * 1991-02-13 1993-04-27 Tree Extracts Research Association Fragrant non-hollow core-in-sheath type composite staple fiber and textile material containing same
JP3071594B2 (ja) * 1993-01-29 2000-07-31 帝人株式会社 芯鞘型消臭抗菌性複合繊維
JPH11117165A (ja) * 1997-10-14 1999-04-27 Tonen Tapirusu Kk 伸縮性メルトブロー不織布
DE60135691D1 (de) * 2000-09-21 2008-10-16 Outlast Technologies Inc Mehrkomponentenfasern mit reversiblen thermischen Eigenschaften
JP2002138322A (ja) * 2000-10-31 2002-05-14 Pilot Ink Co Ltd 感温変色性繊維
ITMI20021155A1 (it) * 2002-05-28 2003-11-28 Atex S R L Procedimento per la realizzazione di un tessuto non tessuto in fibra sintetica con mezzi profumanti
JP2007283173A (ja) * 2006-04-13 2007-11-01 Miki Riken Kogyo Kk マイクロカプセルの製造方法
US8231968B2 (en) * 2006-05-03 2012-07-31 Noveko Trading 2008 Llc Natural tourmaline anion fiber and filter and producing method
US7735402B2 (en) * 2006-06-22 2010-06-15 Sharp Kabushiki Kaisha Punching apparatus
CN201039770Y (zh) * 2007-03-12 2008-03-26 陈宏任 多功能机能性健康养生自净鞋材
CA2706980A1 (en) * 2007-11-27 2009-06-04 Noveko Trading 2008 Llc Imitating natural plant fiber, preparation method thereof and the fabric made of it

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4784909A (en) 1986-09-16 1988-11-15 Teijin Limited Anti-fungus, deodorant fiber material
JPS63135512A (ja) * 1986-11-18 1988-06-07 Daicel Chem Ind Ltd 脱臭性ポリオレフイン繊維
JPH02104712A (ja) * 1988-10-11 1990-04-17 Nippon Foil Mfg Co Ltd 抗菌性繊維
US5690922A (en) 1995-02-15 1997-11-25 Takeda Chemical Industries, Ltd. Deodorizable fibers and method of producing the same
US5869180A (en) * 1996-01-04 1999-02-09 Buedenbender; Juergen Melt-spun abrasion-resistant monofilaments
US6540807B1 (en) 1998-06-22 2003-04-01 Ei Kawaguchi Anti-mold and anti-bacteria air filter
JP2000212826A (ja) * 1999-01-14 2000-08-02 Hagihara Industries Inc セメント補強用繊維
CN1355335A (zh) * 2000-11-28 2002-06-26 上海兰格科技发展有限公司 抗菌防霉聚丙烯丝的制法及空调过滤网
CN1350072A (zh) * 2001-12-11 2002-05-22 上海依福瑞实业有限公司 一种聚烯烃纤维及其制造方法
CN1448551A (zh) * 2002-12-25 2003-10-15 沈阳工业大学 一种聚丙烯弹性纤维
CN1766184A (zh) * 2004-10-27 2006-05-03 上海依福瑞实业有限公司 一种功能性聚丙烯纤维及其制备方法
CN1683614A (zh) * 2005-03-09 2005-10-19 丁宏广 能够发射负离子的单丝及其制备方法和用途
CN1776034A (zh) * 2005-12-06 2006-05-24 颜志勇 一种医用x光显影纤维及其制造方法
CN101063235A (zh) * 2006-04-26 2007-10-31 上海展扬纳米科技有限公司 一种抗菌多功能纤维材料及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2221399A4

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013511627A (ja) * 2009-11-19 2013-04-04 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 高湿度環境用濾過媒体
CN102230251A (zh) * 2011-06-13 2011-11-02 台州东海塑料品制造有限公司 一种tpe网布的制备方法
CN102230251B (zh) * 2011-06-13 2012-11-21 台州东海塑料品制造有限公司 一种tpe网布的制备方法
US12144903B2 (en) 2020-04-27 2024-11-19 Mechoshade Systems, Llc Sanitizing window shade system
CN113684551A (zh) * 2020-05-18 2021-11-23 张文礼 纳米前处理长效功能性复合材料及其织物
CN112172276A (zh) * 2020-09-30 2021-01-05 胡智勇 一种抗菌纺织面料及其制备方法
CN112172276B (zh) * 2020-09-30 2022-05-24 泉州海天染整有限公司 一种抗菌纺织面料及其制备方法
CN112575448A (zh) * 2020-12-11 2021-03-30 浙江理工大学 一种具有抗菌功能多孔无纺布的制备方法
CN113073416A (zh) * 2021-05-11 2021-07-06 李昌荣 一种基于可降解纤维生产的面料及其生产工艺

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MA31897B1 (fr) 2010-12-01
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MX2010005102A (es) 2010-08-02
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BRPI0722265A2 (pt) 2014-04-22
IL205229A0 (en) 2011-07-31
TN2010000164A1 (en) 2011-11-11
US20100221969A1 (en) 2010-09-02
IL205229A (en) 2013-02-28
EP2221399A4 (en) 2012-06-27
KR20100112549A (ko) 2010-10-19
BRPI0722265B1 (pt) 2018-06-26
CN101855393A (zh) 2010-10-06
WO2009059457A8 (zh) 2009-11-26
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