WO2009060050A3 - Single-step catalytic preparation of para-aminophenol - Google Patents

Single-step catalytic preparation of para-aminophenol Download PDF

Info

Publication number
WO2009060050A3
WO2009060050A3 PCT/EP2008/065100 EP2008065100W WO2009060050A3 WO 2009060050 A3 WO2009060050 A3 WO 2009060050A3 EP 2008065100 W EP2008065100 W EP 2008065100W WO 2009060050 A3 WO2009060050 A3 WO 2009060050A3
Authority
WO
WIPO (PCT)
Prior art keywords
para
aminophenol
step catalytic
catalytic preparation
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2008/065100
Other languages
French (fr)
Other versions
WO2009060050A2 (en
Inventor
Francois Figueras
Abhay Deshpande
Lakshmi Kantam Mannepalli
Jeeva Ratnam Katuri
Sudarshan Reddy Ragireddy
Subrahmanya Sekhar Nujilla
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Council of Scientific and Industrial Research CSIR
Vinati Organics Ltd (V O L)
Original Assignee
Centre National de la Recherche Scientifique CNRS
Council of Scientific and Industrial Research CSIR
Vinati Organics Ltd (V O L)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre National de la Recherche Scientifique CNRS, Council of Scientific and Industrial Research CSIR, Vinati Organics Ltd (V O L) filed Critical Centre National de la Recherche Scientifique CNRS
Priority to BRPI0820250-8A priority Critical patent/BRPI0820250A2/en
Priority to US12/741,655 priority patent/US8604246B2/en
Priority to JP2010532596A priority patent/JP5395086B2/en
Priority to CN2008801241898A priority patent/CN101990461A/en
Priority to EP08846552A priority patent/EP2214816A2/en
Publication of WO2009060050A2 publication Critical patent/WO2009060050A2/en
Publication of WO2009060050A3 publication Critical patent/WO2009060050A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/02—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/06—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The present invention relates to the use of a bi-functional catalyst for the one-step preparation of para-am inophenol, said catalyst comprising a mixture of a hydrogenation noble metal and a zirconium sulfate. The present invention also relates to an improved single-step process for the preparation of para- aminophenol from nitrobenzene, in an aqueous medium, using said bi-functional catalyst.
PCT/EP2008/065100 2007-11-07 2008-11-07 Single-step catalytic preparation of para-aminophenol Ceased WO2009060050A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BRPI0820250-8A BRPI0820250A2 (en) 2007-11-07 2008-11-07 Use of a bifunctional catalyst and para-aminophenol and zirconium sulfate preparation processes
US12/741,655 US8604246B2 (en) 2007-11-07 2008-11-07 Single step catalytic preparation of para-aminophenol
JP2010532596A JP5395086B2 (en) 2007-11-07 2008-11-07 Catalytic preparation of paraaminophenol in a single step
CN2008801241898A CN101990461A (en) 2007-11-07 2008-11-07 Single-step catalytic preparation of para-aminophenol
EP08846552A EP2214816A2 (en) 2007-11-07 2008-11-07 Single-step catalytic preparation of para-aminophenol

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07291339.5 2007-11-07
EP07291339A EP2058050A1 (en) 2007-11-07 2007-11-07 Single-step catalytic preparation of para-aminophenol

Publications (2)

Publication Number Publication Date
WO2009060050A2 WO2009060050A2 (en) 2009-05-14
WO2009060050A3 true WO2009060050A3 (en) 2009-07-16

Family

ID=39246840

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/065100 Ceased WO2009060050A2 (en) 2007-11-07 2008-11-07 Single-step catalytic preparation of para-aminophenol

Country Status (6)

Country Link
US (1) US8604246B2 (en)
EP (2) EP2058050A1 (en)
JP (1) JP5395086B2 (en)
CN (1) CN101990461A (en)
BR (1) BRPI0820250A2 (en)
WO (1) WO2009060050A2 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011089253A1 (en) * 2010-01-25 2011-07-28 Albemarle Europe Sprl Zirconium-based catalyst compositions and their use for biodiesel production
CN104628592B (en) * 2015-03-02 2017-08-01 河北工业大学 Method for directly synthesizing p-acetamidophenol from nitrobenzene in acetic acid solution in one step
CN108778497A (en) * 2016-03-11 2018-11-09 东洋合成工业株式会社 Load type metal catalyst
CN109847762B (en) * 2019-01-18 2022-04-19 中国科学院宁波材料技术与工程研究所 Catalyst for reaction of synthesizing p-aminophenol by hydrogenation, preparation method and application
CN112536030B (en) * 2020-12-07 2021-08-17 浙江胜烯环境科技有限公司 Metal particle loaded graphene catalyst and preparation method thereof
CN113304785B (en) * 2021-06-04 2022-08-09 南京工业大学 Preparation method of p-nitrophenol hydrogenation catalyst
CN114181098A (en) * 2021-12-23 2022-03-15 辽宁世星药化有限公司 Production method of o-aminophenol
CN119016075A (en) * 2024-08-29 2024-11-26 宁波世贤科技有限公司 Production process and application of nitro hydrogenation catalyst

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB610549A (en) * 1946-01-11 1948-10-18 F W Berk And Company Ltd A process for the manufacture of basic zirconium sulphate
GB1181969A (en) * 1967-10-16 1970-02-18 Int Nickel Ltd Manufacture of rho-Aminophenol by the Catalytic Hydrogenation of Nitrobenzene
JPS6156158A (en) * 1984-08-27 1986-03-20 Mitsui Toatsu Chem Inc Production of p-aminophenol
US6028227A (en) * 1999-02-12 2000-02-22 Council Of Scientific & Industrial Research Single step process for the preparation of p-aminophenol
CN1426964A (en) * 2001-12-21 2003-07-02 淄博广通化工有限责任公司 Production method of ultrafine zirconium oxide
CN1559915A (en) * 2004-02-16 2005-01-05 华南理工大学 Method for preparing zirconia nanopowder by ultrasonic sol-gel method
US20050175525A1 (en) * 2004-02-06 2005-08-11 Millennium Inorganic Chemicals, Inc. Nano-structured particles with high thermal stability

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3383416A (en) 1965-07-08 1968-05-14 Roland G. Benner Process for preparing aminophenol
US3683025A (en) * 1969-05-06 1972-08-08 Henry W Pons Hydrogenation of nitrobenzenes
CA905083A (en) 1970-02-11 1972-07-18 O. Archambault Jacques Process for recovery of sulphur from sulphur dioxide
US3715397A (en) 1970-04-16 1973-02-06 Engelhard Min & Chem Process for preparing para-aminophenol
US3964509A (en) 1975-02-14 1976-06-22 Da/Pro Rubber, Inc. Check valve
US4051187A (en) 1975-03-05 1977-09-27 Oxamine, Inc. Method of producing aminophenol using a rhodium/carbon catalyst with synergistic quantities of rhodium, trichloride or rhodium tribromide
US4264529A (en) 1980-03-24 1981-04-28 Mallinckrodt, Inc. Method for preparing p-aminophenol
US4307249A (en) 1981-01-07 1981-12-22 Mallinckrodt, Inc. Process for the selective preparation of p-aminophenol from nitrobenzene
EP0085511B1 (en) 1982-01-29 1986-03-12 MALLINCKRODT, INC.(a Missouri corporation) Process for preparing p-aminophenol and alkyl substituted p-aminophenol
US4415753A (en) 1982-01-29 1983-11-15 Mallinckrodt, Inc. Process for preparing p-aminophenol and alkyl substituted p-aminophenol
US5166435A (en) 1983-12-06 1992-11-24 Akzo N.V. Process for the preparation of a hydroxylamine
US4885389A (en) 1987-06-08 1989-12-05 Industrial Technology Research Institute Process for manufacturing p-aminophenol
DE4039862A1 (en) 1990-12-13 1992-06-17 Bayer Ag METHOD FOR PRODUCING P-AMINO-PHENOLS
DE4443701C1 (en) * 1994-12-08 1996-08-29 Degussa Shell catalyst, process for its production and its use
DE19709124A1 (en) * 1997-03-06 1998-09-10 Bayer Ag Process for the preparation of 4-aminodiphenylamine
US6005143A (en) * 1998-08-07 1999-12-21 Air Products And Chemicals, Inc. Use of a monolith catalyst for the hydrogenation of dinitrotoluene to toluenediamine
IN191266B (en) 1999-09-16 2003-10-18 Council Scient Ind Res
EP1199096A1 (en) 2000-10-21 2002-04-24 Degussa AG Catalyst for destruction of CO, VOC, and halogenated organic emissions

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB610549A (en) * 1946-01-11 1948-10-18 F W Berk And Company Ltd A process for the manufacture of basic zirconium sulphate
GB1181969A (en) * 1967-10-16 1970-02-18 Int Nickel Ltd Manufacture of rho-Aminophenol by the Catalytic Hydrogenation of Nitrobenzene
JPS6156158A (en) * 1984-08-27 1986-03-20 Mitsui Toatsu Chem Inc Production of p-aminophenol
US6028227A (en) * 1999-02-12 2000-02-22 Council Of Scientific & Industrial Research Single step process for the preparation of p-aminophenol
CN1426964A (en) * 2001-12-21 2003-07-02 淄博广通化工有限责任公司 Production method of ultrafine zirconium oxide
US20050175525A1 (en) * 2004-02-06 2005-08-11 Millennium Inorganic Chemicals, Inc. Nano-structured particles with high thermal stability
CN1559915A (en) * 2004-02-16 2005-01-05 华南理工大学 Method for preparing zirconia nanopowder by ultrasonic sol-gel method

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
CESÁRIO FRANCISCO DAS VIRGENS ET AL: "Influence of the preparation method on the textural properties of zirconia", REACTION KINETICS AND CATALYSIS LETTERS, KLUWER ACADEMIC PUBLISHERS, DO, vol. 84, no. 1, 1 January 2005 (2005-01-01), pages 183 - 188, XP019265328, ISSN: 1588-2837 *
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; CHEN, LING ET AL: "Method for preparing zirconium oxide nanopowders by ultrasonic sol-gel process", XP002489262, retrieved from STN Database accession no. 2005:1066961 *
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; LIU, QIYONG ET AL: "Process for production of superfine zirconia", XP002489261, retrieved from STN Database accession no. 2005:466443 *
KOMATSU T ET AL: "Gas phase synthesis of para-aminophenol from nitrobenzene on Pt/zeolite catalysts", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 276, no. 1-2, 25 November 2004 (2004-11-25), pages 95 - 102, XP004613245, ISSN: 0926-860X *
SONG X ET AL: "SULFATED ZIRCONIA-BASED STRONG SOLID-ACID CATALYSTS: RECENT PROGRESS", CATALYSIS REVIEWS: SCIENCE AND ENGINEERING, MARCEL DEKKER INC. NEW YORK, US, vol. 38, no. 2, 1996, pages 329 - 412, XP001536474, ISSN: 0161-4940 *
ZYUZIN ET AL: "X-ray, Raman and FTIRS studies of the microstructural evolution of zirconia particles caused by the thermal treatment", JOURNAL OF SOLID STATE CHEMISTRY, ORLANDO, FL, US, vol. 179, no. 10, 1 October 2006 (2006-10-01), pages 2965 - 2971, XP005624309, ISSN: 0022-4596 *

Also Published As

Publication number Publication date
BRPI0820250A2 (en) 2015-06-23
JP2011502759A (en) 2011-01-27
CN101990461A (en) 2011-03-23
EP2058050A1 (en) 2009-05-13
EP2214816A2 (en) 2010-08-11
US8604246B2 (en) 2013-12-10
WO2009060050A2 (en) 2009-05-14
US20110092740A1 (en) 2011-04-21
JP5395086B2 (en) 2014-01-22

Similar Documents

Publication Publication Date Title
WO2009060050A3 (en) Single-step catalytic preparation of para-aminophenol
GB2453424B (en) New Catalyst design and preparation process for steam-reforming catalysts
WO2011113881A3 (en) Hydrogenation catalyst
IL176098A0 (en) Ni catalyst, process for making catalysts and selective hydrogenation process
BRPI0608827A2 (en) process for hydrogenating aldehydes, hydrogenation catalyst, and process for preparing a catalyst
WO2011056597A3 (en) Process for making ethanol from acetic acid using acidic catalysts
WO2010089346A3 (en) Hydrogenation catalysts, the production and use thereof
TW200833417A (en) Bimetallic alkylation catalysts
EG25217A (en) Catalytically coated support process for the production thereof and reactor equipped therewith use thereof.
WO2009050292A3 (en) Catalyst for the hydrogenation of unsaturated hydrocarbons and process for its preparation
ZA201008776B (en) High activity ziegler-natta catalysts,process for producing catalyst and use thereof
WO2010130604A3 (en) Method for producing aromatic amines
EP3144064A3 (en) Selective hydrogenation catalyst and methods of making and using same
EP2209759A4 (en) Manufacture of 1,1,1,2,3,3-hexafluoropropane and 1,1,1,2-tetrafluoropropane via catalytic hydrogenation
WO2009062848A3 (en) Methods of preparing, optionally supported, ordered intermetallic palladium gallium compounds, the compounds as such, and their use in catalysis
WO2008107109A8 (en) Process for the preparation of hydroxytyrosol
WO2009097082A8 (en) Spray-dried transition metal zeolite and its use
WO2010039222A3 (en) Processes for the selective amination of ketomorphinans
GB2466346B (en) Shell catalyst, process for its preparation and use
CA2558194A1 (en) Hydrogenation of acetone
ZA200906692B (en) Catalytically highly effective precious metal-carboxylate compounds of IR, RU, RH, PD, PT and AU
WO2007108011A3 (en) Process for the preparation of highly pure donepezil
SG131094A1 (en) Process for producing catalyst for use in producing unsaturated aldehyde and unsaturated carboxylic acid, and process for producing unsaturated aldehyde and unsaturated carboxylic acid
MY153887A (en) Silver catalyst for formaldehyde preparation
AR070210A1 (en) METAL CATALIZADORM AND METHOD FOR THE PRODUCTION OF METAL CATALYST

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880124189.8

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08846552

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: 2010532596

Country of ref document: JP

Ref document number: 2008846552

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 3419/CHENP/2010

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 12741655

Country of ref document: US

ENP Entry into the national phase

Ref document number: PI0820250

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20100506