WO2009060738A1 - 自動車材用ポリプロピレン系樹脂組成物 - Google Patents

自動車材用ポリプロピレン系樹脂組成物 Download PDF

Info

Publication number
WO2009060738A1
WO2009060738A1 PCT/JP2008/069414 JP2008069414W WO2009060738A1 WO 2009060738 A1 WO2009060738 A1 WO 2009060738A1 JP 2008069414 W JP2008069414 W JP 2008069414W WO 2009060738 A1 WO2009060738 A1 WO 2009060738A1
Authority
WO
WIPO (PCT)
Prior art keywords
dinsol
dsol
room
resin composition
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/069414
Other languages
English (en)
French (fr)
Inventor
Yoshiaki Tsukahara
Ikunori Sakai
Yoshio Sugimoto
Satoko Shimizu
Noriaki Fujiyama
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Prime Polymer Co Ltd
Original Assignee
Prime Polymer Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Prime Polymer Co Ltd filed Critical Prime Polymer Co Ltd
Priority to EP08847504.1A priority Critical patent/EP2208758B1/en
Priority to JP2009540014A priority patent/JP5495788B2/ja
Priority to BRPI0820496-9A priority patent/BRPI0820496B1/pt
Priority to CN2008801151849A priority patent/CN101855293B/zh
Priority to US12/741,480 priority patent/US20100311894A1/en
Publication of WO2009060738A1 publication Critical patent/WO2009060738A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

 (A-1)MFRが1~200g/10分であるプロピレン系ブロック共重合体であって、室温n-デカン不溶分(Dinsol(1))70~95重量%と、室温n-デカン可溶分(Dsol(1))5~30重量%とからなり、前記Dinsol(1)のmmmm分率が97%以上であり、前記Dsol(1)の[η]が4~10dl/gであるプロピレン系ブロック共重合体 14~39重量%、(A-2)MFRが1~200g/10分であるプロピレン系ブロック共重合体であって、室温n-デカン不溶分(Dinsol(2))70~95重量%と、室温n-デカン可溶分(Dsol(2))5~30重量%とからなり、前記Dinsol(2)のmmmm分率が97%以上であり、前記Dsol(2)の[η]が1.5~4dl/gであるプロピレン系ブロック共重合体 20~60重量%、(B)エチレン・α-オレフィン系共重合体ゴム 5~30重量%、(C)無機充填剤 10~30重量%からなる樹脂組成物。  本発明によれば、剛性、耐衝撃性に優れ、ウエルド、フローマークが少なく外観に優れた射出成形品が得られる自動車材用ポリプロピレン系樹脂組成物が提供される。
PCT/JP2008/069414 2007-11-09 2008-10-27 自動車材用ポリプロピレン系樹脂組成物 Ceased WO2009060738A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP08847504.1A EP2208758B1 (en) 2007-11-09 2008-10-27 Polypropylene resin composition for automotive material
JP2009540014A JP5495788B2 (ja) 2007-11-09 2008-10-27 自動車材用ポリプロピレン系樹脂組成物
BRPI0820496-9A BRPI0820496B1 (pt) 2007-11-09 2008-10-27 Composição de resina de polipropileno para partes de automóveis e artigo moldado por injeção
CN2008801151849A CN101855293B (zh) 2007-11-09 2008-10-27 汽车材料用聚丙烯类树脂组合物
US12/741,480 US20100311894A1 (en) 2007-11-09 2008-10-27 Polypropylene resin compositions for automobile parts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-291908 2007-11-09
JP2007291908 2007-11-09

Publications (1)

Publication Number Publication Date
WO2009060738A1 true WO2009060738A1 (ja) 2009-05-14

Family

ID=40625634

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/069414 Ceased WO2009060738A1 (ja) 2007-11-09 2008-10-27 自動車材用ポリプロピレン系樹脂組成物

Country Status (7)

Country Link
US (1) US20100311894A1 (ja)
EP (1) EP2208758B1 (ja)
JP (1) JP5495788B2 (ja)
CN (1) CN101855293B (ja)
AR (1) AR069183A1 (ja)
BR (1) BRPI0820496B1 (ja)
WO (1) WO2009060738A1 (ja)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011057789A (ja) * 2009-09-08 2011-03-24 Mitsui Chemicals Inc ポリプロピレン系樹脂組成物およびその製造方法
JPWO2010074001A1 (ja) * 2008-12-22 2012-06-14 株式会社プライムポリマー プロピレン系樹脂組成物、成形体および容器
JP2012117005A (ja) * 2010-12-03 2012-06-21 Prime Polymer Co Ltd ポリプロピレン系樹脂組成物
WO2012102050A1 (ja) * 2011-01-27 2012-08-02 株式会社プライムポリマー ポリプロピレン系樹脂組成物
WO2012132421A1 (ja) * 2011-03-29 2012-10-04 マツダ株式会社 自動車部材用ポリプロピレン系樹脂組成物及び自動車用外装部材
JP2013203839A (ja) * 2012-03-28 2013-10-07 Japan Polypropylene Corp ポリプロピレン系樹脂組成物およびその成形体
JP2013209472A (ja) * 2012-03-30 2013-10-10 Japan Polypropylene Corp ポリプロピレン系樹脂組成物及びその成形体
JP2014074102A (ja) * 2012-10-03 2014-04-24 Prime Polymer Co Ltd ポリプロピレン系樹脂組成物
JP2014074155A (ja) * 2012-09-13 2014-04-24 Sumitomo Chemical Co Ltd ポリプロピレン系樹脂組成物およびそれからなる成形体
WO2017082358A1 (ja) * 2015-11-11 2017-05-18 株式会社プライムポリマー ポリプロピレン系樹脂組成物
JP2019085478A (ja) * 2017-11-06 2019-06-06 サンアロマー株式会社 ポリプロピレン系樹脂組成物及び成形品
JP2022083191A (ja) * 2020-11-24 2022-06-03 三井化学株式会社 ペレット
JP2022083190A (ja) * 2020-11-24 2022-06-03 三井化学株式会社 エチレン・1-オクテン共重合体

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2669329A1 (en) 2012-06-01 2013-12-04 Basell Poliolefine Italia S.r.l. Mineral-filled polypropylene composition for foaming
ES2542435T3 (es) 2012-11-29 2015-08-05 Borealis Ag Modificador del defecto de rayas de tigre
CN112119122B (zh) * 2018-04-24 2022-12-23 普瑞曼聚合物株式会社 丙烯系树脂组合物
WO2021049585A1 (ja) * 2019-09-13 2021-03-18 株式会社プライムポリマー ポリプロピレン系樹脂組成物及びそれを含む成形体

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11147975A (ja) 1997-02-05 1999-06-02 Mitsui Chem Inc 樹脂バインダー組成物
JP2003041088A (ja) 2001-05-24 2003-02-13 Mitsui Chemicals Inc 自動車外装用樹脂組成物
JP2003105163A (ja) * 2001-09-28 2003-04-09 Japan Polychem Corp ポリプロピレン系樹脂組成物
JP2004262993A (ja) 2003-02-28 2004-09-24 Mitsui Chemicals Inc ポリプロピレン共重合体の製造方法
JP2004359877A (ja) * 2003-06-06 2004-12-24 Mitsui Chemicals Inc プロピレン系樹脂組成物
JP2005232413A (ja) * 2004-02-23 2005-09-02 Japan Polypropylene Corp ポリプロピレン系樹脂組成物及びその成形体
JP2005264017A (ja) * 2004-03-19 2005-09-29 Mitsui Chemicals Inc ポリプロピレン系樹脂組成物

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2128920C (en) * 1993-07-28 1999-06-01 Akihiko Yamamoto Propylene polymer compositions
JP2802023B2 (ja) * 1993-08-10 1998-09-21 宇部興産株式会社 強化ポリプロピレン樹脂組成物
JP3213481B2 (ja) * 1994-07-07 2001-10-02 トヨタ自動車株式会社 自動車内装用ポリプロピレン樹脂組成物
TW420692B (en) * 1995-06-26 2001-02-01 Japan Polyolefins Co Ltd Propylene block copolymer, process for preparation thereof and propylene resin composition comprising same
US5880198A (en) * 1996-03-04 1999-03-09 Tonen Chemical Corporation Thermoplastic resin composition comprising propylene elastomer, and talc components
US6214934B1 (en) * 1997-05-28 2001-04-10 Mitsui Chemicals Inc Polypropylene resin composition for use in automotive inner and outer trims
JP3683409B2 (ja) * 1997-05-28 2005-08-17 三井化学株式会社 自動車内外装用ポリプロピレン樹脂組成物
EP1400565B1 (en) * 2001-05-24 2008-09-10 Prime Polymer Co., Ltd. Resin composition for automobile exterior parts
JP4041705B2 (ja) * 2002-07-19 2008-01-30 日産自動車株式会社 自動車内装成形品
JP2005126697A (ja) * 2003-09-29 2005-05-19 Sumitomo Chemical Co Ltd 熱可塑性樹脂組成物および射出成形体
WO2005030867A2 (en) * 2003-09-29 2005-04-07 Sumitomo Chemical Company, Limited Thermoplastic resin composition and injection molded articles comprising the same
JP2005105037A (ja) * 2003-09-29 2005-04-21 Sumitomo Chemical Co Ltd 熱可塑性樹脂組成物および射出成形体
JP4543648B2 (ja) * 2003-09-29 2010-09-15 住友化学株式会社 熱可塑性樹脂組成物および射出成形体
EP1548054B1 (en) * 2003-12-26 2016-03-23 Japan Polypropylene Corporation Polypropylene-based resin composition and molded article thereof
US7166677B2 (en) * 2004-03-19 2007-01-23 Mitsui Chemicals, Inc. Polypropylene resin compositions

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11147975A (ja) 1997-02-05 1999-06-02 Mitsui Chem Inc 樹脂バインダー組成物
JP2003041088A (ja) 2001-05-24 2003-02-13 Mitsui Chemicals Inc 自動車外装用樹脂組成物
JP2003105163A (ja) * 2001-09-28 2003-04-09 Japan Polychem Corp ポリプロピレン系樹脂組成物
JP2004262993A (ja) 2003-02-28 2004-09-24 Mitsui Chemicals Inc ポリプロピレン共重合体の製造方法
JP2004359877A (ja) * 2003-06-06 2004-12-24 Mitsui Chemicals Inc プロピレン系樹脂組成物
JP2005232413A (ja) * 2004-02-23 2005-09-02 Japan Polypropylene Corp ポリプロピレン系樹脂組成物及びその成形体
JP2005264017A (ja) * 2004-03-19 2005-09-29 Mitsui Chemicals Inc ポリプロピレン系樹脂組成物

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
POLYMER, vol. 34, no. 14, 1993, pages 3129 - 3131
See also references of EP2208758A4 *

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2010074001A1 (ja) * 2008-12-22 2012-06-14 株式会社プライムポリマー プロピレン系樹脂組成物、成形体および容器
JP2011057789A (ja) * 2009-09-08 2011-03-24 Mitsui Chemicals Inc ポリプロピレン系樹脂組成物およびその製造方法
JP2012117005A (ja) * 2010-12-03 2012-06-21 Prime Polymer Co Ltd ポリプロピレン系樹脂組成物
WO2012102050A1 (ja) * 2011-01-27 2012-08-02 株式会社プライムポリマー ポリプロピレン系樹脂組成物
US8975354B2 (en) 2011-01-27 2015-03-10 Prime Polymer Co., Ltd. Polypropylene resin composition
JP2012207062A (ja) * 2011-03-29 2012-10-25 Japan Polypropylene Corp 自動車部材用ポリプロピレン系樹脂組成物及び自動車用外装部材
WO2012132421A1 (ja) * 2011-03-29 2012-10-04 マツダ株式会社 自動車部材用ポリプロピレン系樹脂組成物及び自動車用外装部材
JP2013203839A (ja) * 2012-03-28 2013-10-07 Japan Polypropylene Corp ポリプロピレン系樹脂組成物およびその成形体
JP2013209472A (ja) * 2012-03-30 2013-10-10 Japan Polypropylene Corp ポリプロピレン系樹脂組成物及びその成形体
JP2014074155A (ja) * 2012-09-13 2014-04-24 Sumitomo Chemical Co Ltd ポリプロピレン系樹脂組成物およびそれからなる成形体
JP2014074102A (ja) * 2012-10-03 2014-04-24 Prime Polymer Co Ltd ポリプロピレン系樹脂組成物
JP2017088742A (ja) * 2015-11-11 2017-05-25 株式会社プライムポリマー ポリプロピレン系樹脂組成物
WO2017082358A1 (ja) * 2015-11-11 2017-05-18 株式会社プライムポリマー ポリプロピレン系樹脂組成物
CN108699303A (zh) * 2015-11-11 2018-10-23 普瑞曼聚合物株式会社 聚丙烯系树脂组合物
US11873392B2 (en) 2015-11-11 2024-01-16 Prime Polymer Co., Ltd. Polypropylene-based resin composition
JP2019085478A (ja) * 2017-11-06 2019-06-06 サンアロマー株式会社 ポリプロピレン系樹脂組成物及び成形品
JP2022083191A (ja) * 2020-11-24 2022-06-03 三井化学株式会社 ペレット
JP2022083190A (ja) * 2020-11-24 2022-06-03 三井化学株式会社 エチレン・1-オクテン共重合体
JP7638677B2 (ja) 2020-11-24 2025-03-04 三井化学株式会社 エチレン・1-オクテン共重合体
JP7638678B2 (ja) 2020-11-24 2025-03-04 三井化学株式会社 ペレット

Also Published As

Publication number Publication date
BRPI0820496B1 (pt) 2019-02-12
EP2208758B1 (en) 2015-11-25
JP5495788B2 (ja) 2014-05-21
EP2208758A1 (en) 2010-07-21
EP2208758A4 (en) 2011-06-22
BRPI0820496A2 (pt) 2015-06-16
AR069183A1 (es) 2010-01-06
US20100311894A1 (en) 2010-12-09
CN101855293B (zh) 2012-12-05
JPWO2009060738A1 (ja) 2011-03-24
CN101855293A (zh) 2010-10-06

Similar Documents

Publication Publication Date Title
SG160416A1 (en) IMPACT MODIFICATION OF THERMOPLASTICS WITH ETHYLENE/a- OLEFIN INTERPOLYMERS
JP6690040B1 (ja) 立体造形装置用樹脂成形材料および立体造形装置用フィラメント
AR069183A1 (es) Composiciones de resina de polipropileno para autopartes
EA200702275A1 (ru) Полимер с высокой текучестью расплава, имеющий улучшенную износостойкость, для применения в трубах
AU2001227968A1 (en) Hot melt adhesive based on semicrystalline flexible polyolefins
PL1655338T3 (pl) Wielomodalna kompozycja polietylenowa do wytwarzania wtryskiwanych opakowań do transportowania
BRPI0809637A2 (pt) Tubo ou artigo de tubo suplementar e uso de uma composição de polietileno
WO2008106206A3 (en) Composition comprising polyvinyl chloride and halogenated polyethylene or core-shell resin
PL2014715T3 (pl) ß-nukleowana kompozycja polipropylenu
MX2010003446A (es) Composicion de resina de polipropileno.
WO2007027862A3 (en) Soft polymer compositions having improved high temperature properties
US20180272671A1 (en) Bi-Oriented, Cavitated, Linear, Low-Density Films with Good Sealing Properties
EP2006326A4 (en) OLEFINBLOCKPOLYMER RESIN COMPOSITION AND USE THEREOF
DE602004020914D1 (de) Schmelzkleber mit verbessertem arbeitsfenster
WO2006101924A3 (en) Polymer blends from interpolymer of ethylene/alpha-olefin with improved compatibility
WO2008002841A3 (en) Thermoplastic articles and processes for making the same using an improved masterbatch
WO2005056644A3 (en) Nanoclay-containing composites and methods of making them
WO2006065307A3 (en) Thermoplastic olefin compositions and injection molded articles made thereof
TW200635998A (en) Excellent anti-scratch characteristic polypropylene resin composition
KR102180651B1 (ko) 비축합형 열가소성 수지 접착용 화성처리 금속판, 비축합형 열가소성 수지 접착용 표면처리 금속판, 복합 부재, 및 비축합형 열가소성 수지 접착용 화성처리 금속판의 제조 방법
EP1486517A4 (en) ADHESIVE RESIN AND ADHESIVE COMPOSITION FOR LIQUID CRYSTALLINE POLYMER
TW200505985A (en) Polyolefin composition having a high balance of stiffness and impact strength
CA2683693A1 (en) Soft heterogeneous isotactic polypropylene compositions
PL1788022T3 (pl) Żywica polipropylenowa posiadająca niską kurczliwość, wysoką udarność, twardość oraz odporność na zarysowanie
EP1837351A4 (en) POLYPROPYLENE BLOCK COPOLYMER, THEIR USE AND POLYPROPYLENE RESIN COMPOSITION WITH SPECIFIC POLYPROPYLENE BLOCK COPOLYMER

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880115184.9

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08847504

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 2009540014

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 12741480

Country of ref document: US

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2008847504

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 3417/DELNP/2010

Country of ref document: IN

ENP Entry into the national phase

Ref document number: PI0820496

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20100504