WO2009077168A3 - Process for spinning uhmwpe, uhmwpe multifilament yarns produced thereof and products comprising said yarns - Google Patents

Process for spinning uhmwpe, uhmwpe multifilament yarns produced thereof and products comprising said yarns Download PDF

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Publication number
WO2009077168A3
WO2009077168A3 PCT/EP2008/010748 EP2008010748W WO2009077168A3 WO 2009077168 A3 WO2009077168 A3 WO 2009077168A3 EP 2008010748 W EP2008010748 W EP 2008010748W WO 2009077168 A3 WO2009077168 A3 WO 2009077168A3
Authority
WO
WIPO (PCT)
Prior art keywords
uhmwpe
yarns
spinning
products
fluid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2008/010748
Other languages
French (fr)
Other versions
WO2009077168A2 (en
Inventor
Roelof Marissen
Joseph Arnold Paul Maria Simmelink
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DSM IP Assets BV
Original Assignee
DSM IP Assets BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CN2008801209731A priority Critical patent/CN101903573B/en
Priority to CA2708550A priority patent/CA2708550C/en
Priority to EA201001022A priority patent/EA018379B1/en
Priority to DK08863125T priority patent/DK2242878T3/en
Priority to AU2008337847A priority patent/AU2008337847B2/en
Priority to ES08863125T priority patent/ES2457823T3/en
Priority to BRPI0820787-9A priority patent/BRPI0820787A2/en
Priority to JP2010537334A priority patent/JP5333952B2/en
Priority to US12/747,968 priority patent/US20100268331A1/en
Priority to EP20080863125 priority patent/EP2242878B1/en
Priority to PL08863125T priority patent/PL2242878T3/en
Priority to HK11105376.0A priority patent/HK1151325B/en
Application filed by DSM IP Assets BV filed Critical DSM IP Assets BV
Publication of WO2009077168A2 publication Critical patent/WO2009077168A2/en
Publication of WO2009077168A3 publication Critical patent/WO2009077168A3/en
Priority to ZA2010/04199A priority patent/ZA201004199B/en
Anticipated expiration legal-status Critical
Priority to US13/889,204 priority patent/US9194059B2/en
Priority to US14/748,864 priority patent/US20150292116A1/en
Ceased legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/06—Wet spinning methods
    • D—TEXTILES; PAPER
    • D07—ROPES; CABLES OTHER THAN ELECTRIC
    • D07B—ROPES OR CABLES IN GENERAL
    • D07B1/00—Constructional features of ropes or cables
    • D07B1/02—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics
    • D07B1/025—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics comprising high modulus, or high tenacity, polymer filaments or fibres, e.g. liquid-crystal polymers
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/05—Filamentary, e.g. strands
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
    • D—TEXTILES; PAPER
    • D07—ROPES; CABLES OTHER THAN ELECTRIC
    • D07B—ROPES OR CABLES IN GENERAL
    • D07B2201/00—Ropes or cables
    • D07B2201/20—Rope or cable components
    • D07B2201/2001—Wires or filaments
    • D07B2201/2009—Wires or filaments characterised by the materials used
    • D—TEXTILES; PAPER
    • D07—ROPES; CABLES OTHER THAN ELECTRIC
    • D07B—ROPES OR CABLES IN GENERAL
    • D07B2205/00—Rope or cable materials
    • D07B2205/20—Organic high polymers
    • D07B2205/201—Polyolefins
    • D07B2205/2014—High performance polyolefins, e.g. Dyneema or Spectra
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/021—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
    • D10B2321/0211—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene high-strength or high-molecular-weight polyethylene, e.g. ultra-high molecular weight polyethylene [UHMWPE]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00—Industrial
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2509/00—Medical; Hygiene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2915—Rod, strand, filament or fiber including textile, cloth or fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/69—Autogenously bonded nonwoven fabric

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Artificial Filaments (AREA)
  • Materials For Medical Uses (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Woven Fabrics (AREA)

Abstract

The invention relates to a gel-spinning process for producing a high tensile strength ultra high molecular weight polyethylene (UHMWPE) multifilament yarn comprising ultra-low dtex filaments, the process being characterized in that the draw ratio DRfluid applied to fluid filaments obtained by spinning a solution of UHMWPE through a spinneret and into an air gap, is at least 450, wherein DRfluid = DRsp * DRag, the DRsp and DRag being the draw ratios in the spinholes and in the air gap, respectively; and provided that DRag is at least 30. The UHMWPE multifilament yarns produced thereof were characterized by a tensile strength of at least 3.5 GPa and contained filaments having a dtex of at most 0.5. The invention further relates to products comprising said yarns, e.g. fabrics, medical devices and composite and ballistic articles.
PCT/EP2008/010748 2007-12-17 2008-12-17 Process for spinning uhmwpe, uhmwpe multifilament yarns produced thereof and products comprising said yarns Ceased WO2009077168A2 (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
CA2708550A CA2708550C (en) 2007-12-17 2008-12-17 Process for spinning uhmwpe, uhmwpe multifilament yarns produced thereof and their use
EA201001022A EA018379B1 (en) 2007-12-17 2008-12-17 Process for spinning ultra high molecular weight polyethylene (uhmwpe) multifilament yarns and multifilament yarn produced thereby
DK08863125T DK2242878T3 (en) 2007-12-17 2008-12-17 PROCEDURE FOR SPINDING UHMWPE, UHMWPE MULTIFILAMENT WIRE PRODUCED THEREOF AND PRODUCTS INCLUDING THE WIRES
AU2008337847A AU2008337847B2 (en) 2007-12-17 2008-12-17 Process for spinning UHMWPE, UHMWPE multifilament yarns produced thereof and products comprising said yarns
ES08863125T ES2457823T3 (en) 2007-12-17 2008-12-17 UHMWPE spinning process, UHMWPE multifilament threads produced by it and their use
BRPI0820787-9A BRPI0820787A2 (en) 2007-12-17 2008-12-17 Peuapm spinning process, multi-filament peuapm yarns produced and their use
JP2010537334A JP5333952B2 (en) 2007-12-17 2008-12-17 UHMWPE spinning method
EP20080863125 EP2242878B1 (en) 2007-12-17 2008-12-17 Process for spinning uhmwpe, uhmwpe multifilament yarns produced thereof and products comprising said yarns
US12/747,968 US20100268331A1 (en) 2007-12-17 2008-12-17 Process for spinning uhmwpe, uhmwpe multifilament yarns produced thereof and their use
CN2008801209731A CN101903573B (en) 2007-12-17 2008-12-17 Process for spinning UHMWPE, UHMWPE multifilament yarns produced thereof and products comprising said yarns
HK11105376.0A HK1151325B (en) 2007-12-17 2008-12-17 Process for spinning uhmwpe, uhmwpe multifilament yarns produced thereof and products comprising said yarns
PL08863125T PL2242878T3 (en) 2007-12-17 2008-12-17 Process for spinning uhmwpe, uhmwpe multifilament yarns produced thereof and products comprising said yarns
ZA2010/04199A ZA201004199B (en) 2007-12-17 2010-06-11 Process for spinninh,uhmwpe multifilament yarns produced thereof and products comprising said yarns
US13/889,204 US9194059B2 (en) 2007-12-17 2013-05-07 Process for spinning UHMWPE, UHMWPE multifilament yarns produced thereof and their use
US14/748,864 US20150292116A1 (en) 2007-12-17 2015-06-24 Process for spinning uhmwpe, uhmwpe multifilament yarns produced thereof and their use

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07024437.1 2007-12-17
EP07024437 2007-12-17

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/747,968 A-371-Of-International US20100268331A1 (en) 2007-12-17 2008-12-17 Process for spinning uhmwpe, uhmwpe multifilament yarns produced thereof and their use
US13/889,204 Division US9194059B2 (en) 2007-12-17 2013-05-07 Process for spinning UHMWPE, UHMWPE multifilament yarns produced thereof and their use

Publications (2)

Publication Number Publication Date
WO2009077168A2 WO2009077168A2 (en) 2009-06-25
WO2009077168A3 true WO2009077168A3 (en) 2009-09-11

Family

ID=39522450

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/010748 Ceased WO2009077168A2 (en) 2007-12-17 2008-12-17 Process for spinning uhmwpe, uhmwpe multifilament yarns produced thereof and products comprising said yarns

Country Status (15)

Country Link
US (3) US20100268331A1 (en)
EP (1) EP2242878B1 (en)
JP (1) JP5333952B2 (en)
KR (1) KR101612968B1 (en)
CN (1) CN101903573B (en)
AU (1) AU2008337847B2 (en)
BR (1) BRPI0820787A2 (en)
CA (1) CA2708550C (en)
DK (1) DK2242878T3 (en)
EA (1) EA018379B1 (en)
ES (1) ES2457823T3 (en)
PL (1) PL2242878T3 (en)
TW (1) TWI470125B (en)
WO (1) WO2009077168A2 (en)
ZA (1) ZA201004199B (en)

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RU2612714C2 (en) * 2012-02-24 2017-03-13 Ханивелл Интернешнл Инк. High modulus high strength uhmwpe fiber and method for its production

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JP4937930B2 (en) * 2006-01-23 2012-05-23 有限会社よつあみ Fishing line and its manufacturing method
US8747715B2 (en) 2007-06-08 2014-06-10 Honeywell International Inc Ultra-high strength UHMW PE fibers and products
US9365953B2 (en) * 2007-06-08 2016-06-14 Honeywell International Inc. Ultra-high strength UHMWPE fibers and products
EP2459784B1 (en) * 2009-07-27 2013-05-01 DSM IP Assets B.V. Polyolefin member and method of manufacturing by using an antifoaming agent
US8697220B2 (en) 2009-08-11 2014-04-15 Honeywell International, Inc. High strength tape articles from ultra-high molecular weight polyethylene
US8852714B2 (en) 2009-08-11 2014-10-07 Honeywell International Inc. Multidirectional fiber-reinforced tape/film articles and the method of making the same
DE102010029633A1 (en) 2010-06-02 2011-12-08 Hd Kunststoffe & Kunststofferzeugnisse Gmbh Comminution of ultra-high molecular weight polyethylene fibers
NO2697414T3 (en) 2011-04-13 2018-02-03
JP2014531800A (en) * 2011-09-12 2014-11-27 ディーエスエム アイピー アセッツ ビー．ブイ． Composite radome wall
USRE50459E1 (en) * 2011-12-14 2025-06-17 Avient Protective Materials B.V. Ultra high molecular weight polyethylene multifilament yarn
US10132010B2 (en) 2012-07-27 2018-11-20 Honeywell International Inc. UHMW PE fiber and method to produce
CN103122489A (en) * 2013-02-19 2013-05-29 金云良 Ultrahigh molecular weight polyethylene monofilament combination and stretching forming method
CN104073898A (en) * 2013-03-27 2014-10-01 金云良 Migrated bipolar functional group additive
CN103213652A (en) * 2013-04-26 2013-07-24 东华大学 Landing boat and manufacturing method thereof
CN103213651B (en) * 2013-04-26 2016-04-20 东华大学 A kind of collapsible canoe and manufacture method thereof
CN103213653B (en) * 2013-04-26 2016-04-06 东华大学 A kind of assault boat and manufacture method thereof
CN104233547A (en) * 2013-06-20 2014-12-24 郑州中远防务材料有限公司 Single yarn, manufacturing method of single yarn, single yarn products and manufacturing method of single yarn product
CN206204500U (en) * 2013-06-20 2017-05-31 郑州中远防务材料有限公司 high strength fabric
EP3020368B1 (en) * 2013-07-10 2019-04-24 Terumo Kabushiki Kaisha Biological lumen graft substrate, production method for biological lumen graft substrate, and biological lumen graft made using biological lumen graft substrate
RU2670970C1 (en) * 2013-11-29 2018-10-26 Торэй Индастриз, Инк. Vascular prosthesis
US9909240B2 (en) 2014-11-04 2018-03-06 Honeywell International Inc. UHMWPE fiber and method to produce
CN104805555A (en) * 2015-05-19 2015-07-29 江苏工程职业技术学院 Production technology of pure spinning yarns of polyethylene fibers with ultra-high molecular weight
EP3390704B1 (en) * 2015-12-15 2020-07-01 DSM IP Assets B.V. Low creep fiber
CN107379514A (en) * 2016-05-14 2017-11-24 浙江微科机电有限公司 A kind of new medical operation suture thread processing method
JP7014354B2 (en) * 2017-08-07 2022-02-01 国立大学法人群馬大学 High-strength fiber and method for manufacturing high-strength fiber
US12343449B2 (en) 2018-03-06 2025-07-01 Dsm Ip Assets B.V. Osteoconductive fibers, medical implant comprising such osteoconductive fibers, and methods of making
US10512826B1 (en) * 2019-05-21 2019-12-24 Callaway Golf Company Golf club head with structural tension cable
CN112144131B (en) * 2019-06-26 2021-08-13 中石化南京化工研究院有限公司 Method for removing residual solvent from high performance polyethylene fibers
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Publication number Priority date Publication date Assignee Title
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Also Published As

Publication number Publication date
TW200936830A (en) 2009-09-01
US20130241104A1 (en) 2013-09-19
US9194059B2 (en) 2015-11-24
BRPI0820787A2 (en) 2015-06-16
EA201001022A1 (en) 2010-12-30
KR101612968B1 (en) 2016-04-15
AU2008337847B2 (en) 2013-06-06
DK2242878T3 (en) 2014-04-22
EA018379B1 (en) 2013-07-30
JP5333952B2 (en) 2013-11-06
CN101903573B (en) 2013-06-19
ZA201004199B (en) 2011-11-30
HK1151325A1 (en) 2012-01-27
EP2242878A2 (en) 2010-10-27
AU2008337847A1 (en) 2009-06-25
CN101903573A (en) 2010-12-01
ES2457823T3 (en) 2014-04-29
KR20100100973A (en) 2010-09-15
EP2242878B1 (en) 2014-01-22
WO2009077168A2 (en) 2009-06-25
CA2708550C (en) 2016-06-21
CA2708550A1 (en) 2009-06-25
US20150292116A1 (en) 2015-10-15
TWI470125B (en) 2015-01-21
US20100268331A1 (en) 2010-10-21
JP2011506787A (en) 2011-03-03
PL2242878T3 (en) 2014-06-30

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