WO2009098418A3 - Procede et systeme de production d'hydrogene integre a partir de matiere organique. - Google Patents

Procede et systeme de production d'hydrogene integre a partir de matiere organique. Download PDF

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Publication number
WO2009098418A3
WO2009098418A3 PCT/FR2009/050080 FR2009050080W WO2009098418A3 WO 2009098418 A3 WO2009098418 A3 WO 2009098418A3 FR 2009050080 W FR2009050080 W FR 2009050080W WO 2009098418 A3 WO2009098418 A3 WO 2009098418A3
Authority
WO
WIPO (PCT)
Prior art keywords
gas flow
pyrolysis
water vapor
organic matter
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2009/050080
Other languages
English (en)
Other versions
WO2009098418A2 (fr
Inventor
Raymond Guyomarc'h
Sébastien Roux
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bio3D Applications
Original Assignee
Bio3D Applications
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bio3D Applications filed Critical Bio3D Applications
Priority to US12/864,105 priority Critical patent/US9011813B2/en
Priority to EP09707866A priority patent/EP2247697A2/fr
Publication of WO2009098418A2 publication Critical patent/WO2009098418A2/fr
Publication of WO2009098418A3 publication Critical patent/WO2009098418A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/64—Processes with decomposition of the distillation products
    • C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/30—Fuel charging devices
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/34—Grates; Mechanical ash-removing devices
    • C10J3/40—Movable grates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/15—Details of feeding means
    • C10J2200/158—Screws
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0986—Catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Industrial Gases (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Le procédé selon l'invention comprend, dans un premier réacteur (20) une pyrolyse d'une charge matière organique (MO) humide. La pyrolyse produit, d'une part des éléments de carbone et, d'autre part un flux gazeux de pyrolyse comprenant de la vapeur d'eau et des composés organiques volatils (COV). Les COV présent dans le flux gazeux de pyrolyse sont ensuite soumis à une oxycombustion et/ou oxydation. Le flux gazeux de pyrolyse oxydé traverse ensuite ladite couche (302) et produit un flux gazeux de synthèse (FS) comprenant de l'hydrogène (H2) obten u par réduction de la vapeur d'eau (H2Og) par lesdits éléments de carbone (C) à haute température. La température du flux gazeux de synthèse ( FS) est ensuite diminuée pour réaliser une réaction de water-shift où une partie de la vapeur d'eau résiduelle (H2Og) est réduite par des éléments de monoxyde de carbone (CO) pour produire de l'hydrogène (H2). L'hydrogène (H2) obtenu est ensuite séparé.
PCT/FR2009/050080 2008-01-22 2009-01-21 Procede et systeme de production d'hydrogene integre a partir de matiere organique. Ceased WO2009098418A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US12/864,105 US9011813B2 (en) 2008-01-22 2009-01-21 Method and system for producing integrated hydrogen from organic matter
EP09707866A EP2247697A2 (fr) 2008-01-22 2009-01-21 Procede et systeme de production d'hydrogene integre a partir de matiere organique.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0850385 2008-01-22
FR0850385A FR2926543B1 (fr) 2008-01-22 2008-01-22 Procede et systeme de production d'hydrogene integre a partir de matiere organique

Publications (2)

Publication Number Publication Date
WO2009098418A2 WO2009098418A2 (fr) 2009-08-13
WO2009098418A3 true WO2009098418A3 (fr) 2010-04-15

Family

ID=39591026

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2009/050080 Ceased WO2009098418A2 (fr) 2008-01-22 2009-01-21 Procede et systeme de production d'hydrogene integre a partir de matiere organique.

Country Status (4)

Country Link
US (1) US9011813B2 (fr)
EP (1) EP2247697A2 (fr)
FR (1) FR2926543B1 (fr)
WO (1) WO2009098418A2 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2845883A1 (fr) * 2011-09-05 2013-03-14 Xylowatt S.A. Gazeifieur de combustible solide carbone
US9023243B2 (en) * 2012-08-27 2015-05-05 Proton Power, Inc. Methods, systems, and devices for synthesis gas recapture
WO2022133527A1 (fr) * 2020-12-23 2022-06-30 Clean Energy Resources Pty Ltd Processus de conversion de déchets en énergie propre et produits à valeur ajoutée
CN113403112B (zh) * 2021-07-21 2024-04-23 北京化工大学 一种超超临界蒸汽有机物热裂解气化装备

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3977844A (en) * 1973-05-09 1976-08-31 Slyke William J Van Process for producing a sulfur free combustible gas
EP0271477A1 (fr) * 1986-11-26 1988-06-15 VOEST-ALPINE Aktiengesellschaft Dispositif pour le dégazage et la gazéification de combustible solide
DE4030644A1 (de) * 1990-09-25 1992-03-26 Sanhog Technik Dr Ing Horst Ga Verfahren zur erzeugung brennbarer gase mit anschliessender gasumwandlung in einem bewegten koksbett
EP1371713A1 (fr) * 2001-01-18 2003-12-17 Japan Science and Technology Corporation Appareil de gazeification d'un combustible solide
WO2007102032A2 (fr) * 2006-03-07 2007-09-13 Lampros Elefsiniotis Unité de gazéification combinée à deux étages à cocourant/contre-courant

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4497637A (en) * 1982-11-22 1985-02-05 Georgia Tech Research Institute Thermochemical conversion of biomass to syngas via an entrained pyrolysis/gasification process
DE3323981C2 (de) * 1983-07-02 1986-10-02 Kernforschungsanlage Jülich GmbH, 5170 Jülich Verfahren zur Vergasung von Abfallflüssigkeiten, die organische Bestandteile enthalten und Schachtofen zur Durchführung des Verfahrens
US4865625A (en) * 1988-05-02 1989-09-12 Battelle Memorial Institute Method of producing pyrolysis gases from carbon-containing materials
JP3840632B2 (ja) * 2000-05-08 2006-11-01 三井造船株式会社 ナトリウム系脱塩剤および廃棄物処理装置
US6333015B1 (en) * 2000-08-08 2001-12-25 Arlin C. Lewis Synthesis gas production and power generation with zero emissions
ES2343167T3 (es) * 2000-12-04 2010-07-26 Emery Energy Company L.L.C. Gasificador de multiples facetas y procedimientos relacionados.
US6685754B2 (en) * 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
US6863878B2 (en) * 2001-07-05 2005-03-08 Robert E. Klepper Method and apparatus for producing synthesis gas from carbonaceous materials
WO2007121268A2 (fr) * 2006-04-11 2007-10-25 Thermo Technologies, Llc Procédés et appareil destiné à la production de gaz de synthèse de matières carbonées solides
WO2008117119A2 (fr) * 2006-11-02 2008-10-02 Plasco Energy Group Inc. Système de conditionnement de résidus
SE531101C2 (sv) * 2006-12-14 2008-12-16 Rolf Ljunggren Förfarande och anläggning för framställning av syntesgas från biomassa
US7833512B2 (en) * 2007-01-16 2010-11-16 Peter Pulkrabek Production of synthesis gas from biomass and any organic matter by reactive contact with superheated steam
US8202332B2 (en) * 2007-08-01 2012-06-19 Virginia Tech Intellectual Properties Fractional catalytic pyrolysis of biomass
US20090077891A1 (en) * 2007-09-25 2009-03-26 New York Energy Group Method for producing fuel gas

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3977844A (en) * 1973-05-09 1976-08-31 Slyke William J Van Process for producing a sulfur free combustible gas
EP0271477A1 (fr) * 1986-11-26 1988-06-15 VOEST-ALPINE Aktiengesellschaft Dispositif pour le dégazage et la gazéification de combustible solide
DE4030644A1 (de) * 1990-09-25 1992-03-26 Sanhog Technik Dr Ing Horst Ga Verfahren zur erzeugung brennbarer gase mit anschliessender gasumwandlung in einem bewegten koksbett
EP1371713A1 (fr) * 2001-01-18 2003-12-17 Japan Science and Technology Corporation Appareil de gazeification d'un combustible solide
WO2007102032A2 (fr) * 2006-03-07 2007-09-13 Lampros Elefsiniotis Unité de gazéification combinée à deux étages à cocourant/contre-courant

Also Published As

Publication number Publication date
FR2926543A1 (fr) 2009-07-24
US9011813B2 (en) 2015-04-21
FR2926543B1 (fr) 2013-01-04
US20100297001A1 (en) 2010-11-25
EP2247697A2 (fr) 2010-11-10
WO2009098418A2 (fr) 2009-08-13

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